CN103666156B - A kind of UV resistant copper sculpture paints with acrylic resin - Google Patents
A kind of UV resistant copper sculpture paints with acrylic resin Download PDFInfo
- Publication number
- CN103666156B CN103666156B CN201310676008.5A CN201310676008A CN103666156B CN 103666156 B CN103666156 B CN 103666156B CN 201310676008 A CN201310676008 A CN 201310676008A CN 103666156 B CN103666156 B CN 103666156B
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- acrylic resin
- paint
- acrylic
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- auxiliary agent
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- 239000003973 paint Substances 0.000 title claims abstract description 21
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000010949 copper Substances 0.000 title claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 15
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 14
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 claims abstract description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 16
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 229940044927 ceric oxide Drugs 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims abstract description 7
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims abstract description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims abstract description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 alkenyl imidazoline Chemical compound 0.000 claims abstract description 5
- CTKINSOISVBQLD-UHFFFAOYSA-N glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims abstract description 5
- PAZHGORSDKKUPI-UHFFFAOYSA-N Lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 4
- NNHHDJVEYQHLHG-UHFFFAOYSA-N Potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N TMPTA Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052912 lithium silicate Inorganic materials 0.000 claims abstract description 4
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 4
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 4
- STDMRMREKPZQFJ-UHFFFAOYSA-H tricopper;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[Cu+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O STDMRMREKPZQFJ-UHFFFAOYSA-H 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004113 Sepiolite Substances 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 229910052570 clay Inorganic materials 0.000 claims description 6
- TUKQLEWOUPCTOS-UHFFFAOYSA-N dimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane;hydrate Chemical compound O.[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O TUKQLEWOUPCTOS-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 229910052624 sepiolite Inorganic materials 0.000 claims description 6
- 235000019355 sepiolite Nutrition 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 claims description 3
- 240000009301 Coix lacryma-jobi Species 0.000 claims description 3
- 241001272567 Hominoidea Species 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- XBVVKNHQSFUHLZ-UHFFFAOYSA-N decanedioic acid;sodium Chemical compound [Na].OC(=O)CCCCCCCCC(O)=O XBVVKNHQSFUHLZ-UHFFFAOYSA-N 0.000 claims description 3
- 229930003335 epicatechin Natural products 0.000 claims description 3
- 235000012734 epicatechin Nutrition 0.000 claims description 3
- 235000021190 leftovers Nutrition 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N propyl 3,4,5-trihydroxybenzoate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 235000010388 propyl gallate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- ILJSQTXMGCGYMG-UHFFFAOYSA-M triacetate(1-) Chemical compound CC(=O)CC(=O)CC([O-])=O ILJSQTXMGCGYMG-UHFFFAOYSA-M 0.000 claims description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000003287 optical Effects 0.000 abstract description 2
- MAVFMKWHKMBKDF-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(N)(CO)CO.CCC(CO)(CO)CO MAVFMKWHKMBKDF-UHFFFAOYSA-N 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,2-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 102100006017 TAC3 Human genes 0.000 description 1
- 101700070528 TAC3 Proteins 0.000 description 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N Triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 1
- 229960002622 Triacetin Drugs 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Abstract
The present invention relates to a kind of paint, being specifically related to a kind of UV resistant copper sculpture acrylic resin paints, the present invention's paint is made up of the raw material of following weight portion: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2, 2-aminoethyl 17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylic glycidol ether 4-7, VTES 2-3, accelerant N a-22? 0.5-1.2, butyl titanate 2-3, IPD 1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12, the present invention's paint contains nano ceric oxide, then in conjunction with other raw materials, the paint hardness of preparation is high, good in optical property, and resistance to ultraviolet irradiation is aging, environmental corrosion resisting, stable in properties, long service life.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to a kind of UV resistant copper sculpture acrylic resin paint and preparation thereofTechnique.
Background technology
Copper sculpture is a class handicraft common in daily life, has higher artistic value and enjoying value, but,The copper sculpture art work is due to itself material character and put environment, easily occurs the problems such as oxide etch, and impact is beautifulSee and service life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and have certain to copper sculpture with paintRequirement, such as adhesive force, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, makes applicableThe paint of different use occasions, increases its artistic value.
Summary of the invention
The object of the invention is to, provide a kind of UV resistant copper sculpture acrylic resin to paint, to protect sculpture,To achieve these goals, the technical solution used in the present invention is as follows:
A kind of UV resistant copper sculpture paints with acrylic resin, it is characterized in that, material of the present invention is by following weight portionRaw material make: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2,2-Aminoethyl 17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylicGlycidol ether 4-7, VTES 2-3, accelerant N a-220.5-1.2, butyl titanate 2-3, isophoroneDiamines 1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12.
Described auxiliary agent is made up of the raw material of following weight portion: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, diphenylguanidine TDM1-2, crosslinking agent TAC2-3, decanedioic acid sodium 1-2, APES 4-5, sodium phosphate trimer 1-2, sweetOil triacetate 35-40, vanadium diboride 1-2, n-propyl gallate 1-2, coix seed oil 2-3, epicatechin 1-2; Its preparation methodBe that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 DEG C, then take out, send intoIn the hydrochloric acid solution of 10-15%, soak 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powderBody; Gained powder mixes with other residual components, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds pulpingMaterial, to obtain final product.
Described a kind of UV resistant copper sculpture paints with acrylic resin, and its preparation technology is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris thirdOlefin(e) acid ester, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 DEG C, add phenyl glycidyl ether, acrylic glycidol ether,VTES, cumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute,Be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.
Compared with prior art, copper sculpture provided by the invention is painted and is possessed following advantage: added especially nanometer twoCerium oxide raw material, then in conjunction with other raw materials, effectively improved the performance of conventional acrylic resin material, the paint hardness makingHeight, good in optical property, resistance to ultraviolet irradiation is aging, environmental corrosion resisting, stable in properties, service time is long, and production technology letter relativelySingle, can be widely used in all kinds of bronze handicrafts.
Detailed description of the invention
Embodiment
The present embodiment paint is made up of following weight portion raw material: nano ceric oxide 3, potassium silicate 4, lithium metasilicate 2, acrylic acidResin 34, copper citrate 2,2-aminoethyl 17 alkenyl imidazolines 2, tri (propylene glycol) diacrylate 12, phenyl shrink sweetOil ether 2, acrylic glycidol ether 6, VTES 3, accelerant N a-221, butyl titanate 3, isophoroneDiamines 2, trimethylolpropane triacrylate 12, cumyl peroxide 2, DIMAPA 6, auxiliary agent 6, dimethylbenzene 12,Butyl acetate 12.
Described auxiliary agent is made up of the raw material of following weight portion: clay 12, diatomite 4, jade 3, sepiolite 3, promoterDTDM2, crosslinking agent TAC3, decanedioic acid sodium 2, APES 5, sodium phosphate trimer 2, triacetin 40, two boronChange vanadium 2, n-propyl gallate 2, coix seed oil 3, epicatechin 2; Its preparation method is that clay, diatomite, jade, sepiolite are sentEnter in calcining furnace and at 700-720 DEG C, calcine 3 hours, then, take out, send in 15% hydrochloric acid solution and soak 3 hours, filter,Obtain filter residue, clean with clear water, dry, grind to form 500 order powders; Gained powder mixes with other residual components, is heated to 60-70DEG C, stirring reaction 50 minutes, cooling, grind to form slurry, to obtain final product.
Described a kind of UV resistant copper sculpture paints with acrylic resin, and its preparation technology is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris thirdOlefin(e) acid ester, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, react 4 hours;
(2) material of step (1) is cooled to 70-85 DEG C, add phenyl glycidyl ether, acrylic glycidol ether,VTES, cumyl peroxide, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, stirring reaction is after 50 minutes, coldBut to room temperature, grind to form 40 μ m slurries, to obtain final product.
The performance test results of the present invention's paint is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a UV resistant copper sculpture paints with acrylic resin, it is characterized in that, this paint is by the raw material of following weight portionMake: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2,2-aminoethyl17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylic shrink sweetOil ether 4-7, VTES 2-3, accelerant N a-220.5-1.2, butyl titanate 2-3, IPD1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, twoToluene 10-12, butyl acetate 10-12;
Described auxiliary agent is made up of the raw material of following weight portion: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, shortEnter agent DTDM1-2, crosslinking agent TAC2-3, decanedioic acid sodium 1-2, APES 4-5, sodium phosphate trimer 1-2, sweetOil triacetate 35-40, vanadium diboride 1-2, n-propyl gallate 1-2, coix seed oil 2-3, epicatechin 1-2; Its preparation methodBe that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 DEG C, then take out, send intoIn the hydrochloric acid solution of 10-15%, soak 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powderBody; Gained powder mixes with other residual components, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds pulpingMaterial, to obtain final product.
2. a kind of UV resistant copper sculpture as claimed in claim 1 paints with acrylic resin, and its preparation method is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris acrylic acidEster, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 DEG C, adds phenyl glycidyl ether, acrylic glycidol ether, etheneEthyl triethoxy silicane alkane, cumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, coolingTo room temperature, grind to form 20-60 μ m slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310676008.5A CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310676008.5A CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
Publications (2)
| Publication Number | Publication Date |
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| CN103666156A CN103666156A (en) | 2014-03-26 |
| CN103666156B true CN103666156B (en) | 2016-05-04 |
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| CN201310676008.5A Active CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038457A (en) * | 2015-07-29 | 2015-11-11 | 安徽鹏峰新型建材科技有限公司 | Ultraviolet light resistant paint for scaffolds |
| CN108441074A (en) * | 2018-03-31 | 2018-08-24 | 安徽天元塑业有限公司 | A kind of water-repellent paint of cementitious composite packaging bag |
| CN109159621A (en) * | 2018-09-07 | 2019-01-08 | 广东新合铝业新兴有限公司 | A kind of high durable aluminium alloy wood grain profile production technology and its aluminum profile of preparation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033356A (en) * | 2006-03-08 | 2007-09-12 | 盐城万成化学有限公司 | Gold paint and preparing process thereof |
| CN101182738A (en) * | 2006-11-13 | 2008-05-21 | 天津市世纪东方建筑景观雕塑技术开发中心 | Spraying method of cement emulation mineral varnish |
| CN101372597A (en) * | 2008-10-07 | 2009-02-25 | 俞岳兴 | Flash gold lacquer and preparation thereof |
| CN102898913A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Aqueous inorganic zinc rich paint |
-
2013
- 2013-12-07 CN CN201310676008.5A patent/CN103666156B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033356A (en) * | 2006-03-08 | 2007-09-12 | 盐城万成化学有限公司 | Gold paint and preparing process thereof |
| CN101182738A (en) * | 2006-11-13 | 2008-05-21 | 天津市世纪东方建筑景观雕塑技术开发中心 | Spraying method of cement emulation mineral varnish |
| CN101372597A (en) * | 2008-10-07 | 2009-02-25 | 俞岳兴 | Flash gold lacquer and preparation thereof |
| CN102898913A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Aqueous inorganic zinc rich paint |
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| CN103666156A (en) | 2014-03-26 |
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Denomination of invention: Acrylic resin paint for ultraviolet-resistant copper sculptures Effective date of registration: 20161209 Granted publication date: 20160504 Pledgee: Tongling Jinyu SME Credit Guarantee Center Pledgor: TONGLING XINJIUDING COPPER CULTURE INDUSTRY CO., LTD. Registration number: 2016340000105 |
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