CN103666156B - A kind of UV resistant copper sculpture paints with acrylic resin - Google Patents
A kind of UV resistant copper sculpture paints with acrylic resin Download PDFInfo
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- CN103666156B CN103666156B CN201310676008.5A CN201310676008A CN103666156B CN 103666156 B CN103666156 B CN 103666156B CN 201310676008 A CN201310676008 A CN 201310676008A CN 103666156 B CN103666156 B CN 103666156B
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Abstract
The present invention relates to a kind of paint, being specifically related to a kind of UV resistant copper sculpture acrylic resin paints, the present invention's paint is made up of the raw material of following weight portion: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2, 2-aminoethyl 17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylic glycidol ether 4-7, VTES 2-3, accelerant N a-22? 0.5-1.2, butyl titanate 2-3, IPD 1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12, the present invention's paint contains nano ceric oxide, then in conjunction with other raw materials, the paint hardness of preparation is high, good in optical property, and resistance to ultraviolet irradiation is aging, environmental corrosion resisting, stable in properties, long service life.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to a kind of UV resistant copper sculpture acrylic resin paint and preparation thereofTechnique.
Background technology
Copper sculpture is a class handicraft common in daily life, has higher artistic value and enjoying value, but,The copper sculpture art work is due to itself material character and put environment, easily occurs the problems such as oxide etch, and impact is beautifulSee and service life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and have certain to copper sculpture with paintRequirement, such as adhesive force, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, makes applicableThe paint of different use occasions, increases its artistic value.
Summary of the invention
The object of the invention is to, provide a kind of UV resistant copper sculpture acrylic resin to paint, to protect sculpture,To achieve these goals, the technical solution used in the present invention is as follows:
A kind of UV resistant copper sculpture paints with acrylic resin, it is characterized in that, material of the present invention is by following weight portionRaw material make: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2,2-Aminoethyl 17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylicGlycidol ether 4-7, VTES 2-3, accelerant N a-220.5-1.2, butyl titanate 2-3, isophoroneDiamines 1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, dimethylbenzene 10-12, butyl acetate 10-12.
Described auxiliary agent is made up of the raw material of following weight portion: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, diphenylguanidine TDM1-2, crosslinking agent TAC2-3, decanedioic acid sodium 1-2, APES 4-5, sodium phosphate trimer 1-2, sweetOil triacetate 35-40, vanadium diboride 1-2, n-propyl gallate 1-2, coix seed oil 2-3, epicatechin 1-2; Its preparation methodBe that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 DEG C, then take out, send intoIn the hydrochloric acid solution of 10-15%, soak 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powderBody; Gained powder mixes with other residual components, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds pulpingMaterial, to obtain final product.
Described a kind of UV resistant copper sculpture paints with acrylic resin, and its preparation technology is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris thirdOlefin(e) acid ester, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 DEG C, add phenyl glycidyl ether, acrylic glycidol ether,VTES, cumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute,Be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.
Compared with prior art, copper sculpture provided by the invention is painted and is possessed following advantage: added especially nanometer twoCerium oxide raw material, then in conjunction with other raw materials, effectively improved the performance of conventional acrylic resin material, the paint hardness makingHeight, good in optical property, resistance to ultraviolet irradiation is aging, environmental corrosion resisting, stable in properties, service time is long, and production technology letter relativelySingle, can be widely used in all kinds of bronze handicrafts.
Detailed description of the invention
Embodiment
The present embodiment paint is made up of following weight portion raw material: nano ceric oxide 3, potassium silicate 4, lithium metasilicate 2, acrylic acidResin 34, copper citrate 2,2-aminoethyl 17 alkenyl imidazolines 2, tri (propylene glycol) diacrylate 12, phenyl shrink sweetOil ether 2, acrylic glycidol ether 6, VTES 3, accelerant N a-221, butyl titanate 3, isophoroneDiamines 2, trimethylolpropane triacrylate 12, cumyl peroxide 2, DIMAPA 6, auxiliary agent 6, dimethylbenzene 12,Butyl acetate 12.
Described auxiliary agent is made up of the raw material of following weight portion: clay 12, diatomite 4, jade 3, sepiolite 3, promoterDTDM2, crosslinking agent TAC3, decanedioic acid sodium 2, APES 5, sodium phosphate trimer 2, triacetin 40, two boronChange vanadium 2, n-propyl gallate 2, coix seed oil 3, epicatechin 2; Its preparation method is that clay, diatomite, jade, sepiolite are sentEnter in calcining furnace and at 700-720 DEG C, calcine 3 hours, then, take out, send in 15% hydrochloric acid solution and soak 3 hours, filter,Obtain filter residue, clean with clear water, dry, grind to form 500 order powders; Gained powder mixes with other residual components, is heated to 60-70DEG C, stirring reaction 50 minutes, cooling, grind to form slurry, to obtain final product.
Described a kind of UV resistant copper sculpture paints with acrylic resin, and its preparation technology is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris thirdOlefin(e) acid ester, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, react 4 hours;
(2) material of step (1) is cooled to 70-85 DEG C, add phenyl glycidyl ether, acrylic glycidol ether,VTES, cumyl peroxide, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, stirring reaction is after 50 minutes, coldBut to room temperature, grind to form 40 μ m slurries, to obtain final product.
The performance test results of the present invention's paint is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a UV resistant copper sculpture paints with acrylic resin, it is characterized in that, this paint is by the raw material of following weight portionMake: nano ceric oxide 2-3, potassium silicate 3-4, lithium metasilicate 1-2, acrylic resin 30-34, copper citrate 1-2,2-aminoethyl17 alkenyl imidazoline 1-2, tri (propylene glycol) diacrylate 10-12, phenyl glycidyl ether 1-2, acrylic shrink sweetOil ether 4-7, VTES 2-3, accelerant N a-220.5-1.2, butyl titanate 2-3, IPD1-2, trimethylolpropane triacrylate 10-12, cumyl peroxide 1-2, DIMAPA 4-6, auxiliary agent 5-6, twoToluene 10-12, butyl acetate 10-12;
Described auxiliary agent is made up of the raw material of following weight portion: clay 10-12, diatomite 3-4, jade 2-3, sepiolite 2-3, shortEnter agent DTDM1-2, crosslinking agent TAC2-3, decanedioic acid sodium 1-2, APES 4-5, sodium phosphate trimer 1-2, sweetOil triacetate 35-40, vanadium diboride 1-2, n-propyl gallate 1-2, coix seed oil 2-3, epicatechin 1-2; Its preparation methodBe that clay, diatomite, jade, sepiolite are sent in calcining furnace and calcine 2-3 hour at 700-720 DEG C, then take out, send intoIn the hydrochloric acid solution of 10-15%, soak 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powderBody; Gained powder mixes with other residual components, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds pulpingMaterial, to obtain final product.
2. a kind of UV resistant copper sculpture as claimed in claim 1 paints with acrylic resin, and its preparation method is:
(1) by nano ceric oxide, tri (propylene glycol) diacrylate, butyl titanate, trimethylolpropane tris acrylic acidEster, auxiliary agent mix, and join in dimethylbenzene, butyl acetate solvent, are heated to 120-130 DEG C, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 DEG C, adds phenyl glycidyl ether, acrylic glycidol ether, etheneEthyl triethoxy silicane alkane, cumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, coolingTo room temperature, grind to form 20-60 μ m slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310676008.5A CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310676008.5A CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
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| Publication Number | Publication Date |
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| CN103666156A CN103666156A (en) | 2014-03-26 |
| CN103666156B true CN103666156B (en) | 2016-05-04 |
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| CN201310676008.5A Active CN103666156B (en) | 2013-12-07 | 2013-12-07 | A kind of UV resistant copper sculpture paints with acrylic resin |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038457A (en) * | 2015-07-29 | 2015-11-11 | 安徽鹏峰新型建材科技有限公司 | Ultraviolet light resistant paint for scaffolds |
| CN108441074A (en) * | 2018-03-31 | 2018-08-24 | 安徽天元塑业有限公司 | A kind of water-repellent paint of cementitious composite packaging bag |
| CN109159621A (en) * | 2018-09-07 | 2019-01-08 | 广东新合铝业新兴有限公司 | A kind of high durable aluminium alloy wood grain profile production technology and its aluminum profile of preparation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033356A (en) * | 2006-03-08 | 2007-09-12 | 盐城万成化学有限公司 | Gold paint and preparing process thereof |
| CN101182738A (en) * | 2006-11-13 | 2008-05-21 | 天津市世纪东方建筑景观雕塑技术开发中心 | Spraying method of cement emulation mineral varnish |
| CN101372597A (en) * | 2008-10-07 | 2009-02-25 | 俞岳兴 | Flash gold lacquer and preparation thereof |
| CN102898913A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Aqueous inorganic zinc rich paint |
-
2013
- 2013-12-07 CN CN201310676008.5A patent/CN103666156B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033356A (en) * | 2006-03-08 | 2007-09-12 | 盐城万成化学有限公司 | Gold paint and preparing process thereof |
| CN101182738A (en) * | 2006-11-13 | 2008-05-21 | 天津市世纪东方建筑景观雕塑技术开发中心 | Spraying method of cement emulation mineral varnish |
| CN101372597A (en) * | 2008-10-07 | 2009-02-25 | 俞岳兴 | Flash gold lacquer and preparation thereof |
| CN102898913A (en) * | 2012-10-24 | 2013-01-30 | 江苏纽克莱涂料有限公司 | Aqueous inorganic zinc rich paint |
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| CN103666156A (en) | 2014-03-26 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Acrylic resin paint for ultraviolet-resistant copper sculptures Effective date of registration: 20161209 Granted publication date: 20160504 Pledgee: Tongling Jinyu SME Credit Guarantee Center Pledgor: TONGLING XINJIUDING COPPER CULTURE INDUSTRY CO., LTD. Registration number: 2016340000105 |
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