CN104342001A - Safe environment-friendly type water-based paint for glass and preparation method thereof - Google Patents
Safe environment-friendly type water-based paint for glass and preparation method thereof Download PDFInfo
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- CN104342001A CN104342001A CN201410537667.5A CN201410537667A CN104342001A CN 104342001 A CN104342001 A CN 104342001A CN 201410537667 A CN201410537667 A CN 201410537667A CN 104342001 A CN104342001 A CN 104342001A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention discloses a safe environment-friendly type water-based paint for glass, which is characterized by being prepared from the following raw materials in parts by weight: 30-35 parts of water-based polyurethane resin, 30-35 parts of low-methylated amino resin, 1-3 parts of ethylene glycol phenyl ether, 8-12 parts of modified styrene-acrylate emulsion, 0.3-0.6 part of titanium di(dioctylpyrophosphate) oxo-acetate, 0.2-0.5 part of polyether modified polyorganosiloxane, 1-3 parts of triethylene glycol monoethyl ether, 0.2-0.4 part of liquid paraffin, 0.1-0.3 part of triethanolamine oleate, 0.4-0.8 part of sodium oleate, 0.4-0.8 part of triethanolamine, 0.2-0.4 part of carbomer, 0.2-0.4 part of allantoin, 0.3-0.5 part of feldspar powder, 1-2 parts of pigments, and 10-15 parts of deionized water. The film formed by the water-based paint is flat and smooth, high in drying speed, and good in brightness, and has the characteristics of being high in weather resistance, scrubbing resistance and oxidization resistance, as well as high in sterilization and corrosiveness property and adhesive force, and the like. The added modified styrene-acrylate emulsion further improves the sterilization, dustproof and antistatic properties. The water-based paint is simple to operate, long in service life, environmentally friendly and safe, and strong in practicability.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of safe environment protection type glass use coating and preparation method thereof.
Background technology
Along with the raising day by day of people's living standard, the pursuit of people to U.S. is more and more stronger, glass partition, glass bathrooms etc. will use glass door, as home decoration glass and glasswork, the demand in market is met with its distinctive gorgeous colorful decorative effect, but along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified, because current glass paint is mostly solvent based coating, the benzene to human body and bad environmental need be used during application, toluene, ethyl acetate etc. are containing benzene solvent, in addition, the bonding strength of some coating is low, less to the sticking power of various glass material product, and easily come off, duration of service is not long.Glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, aqueous glass paint has that better sticking power is good, ageing resistance is good, water tolerance and the advantage such as resistance to alcohol acidity is good, and safety and environmental protection, not containing objectionable impuritiess such as free TDI, benzene, toluene, ethyl acetate, can not damage HUMAN HEALTH, be brand-new environmental protection low-toxicity product.
Summary of the invention
The object of this invention is to provide a kind of safe environment protection type glass use coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of safe environment protection type glass use coating, be made up of the raw material of following weight part: waterborne polyurethane resin 30-35, low methyl-etherified aminoresin 30-35, ethylene glycol phenyl ether 1-3, modification propyl benzene emulsion 8-12, two (dioctyl pyrophosphoryl bases) are containing fluoroacetic acid ester titanium 0.3-0.6, polyether-modified organopolysiloxane 0.2-0.5, Triethylene glycol ethyl ether 1-3, whiteruss 0.2-0.4, Emulphor FM 0.1-0.3, sodium oleate 0.4-0.8, trolamine 0.4-0.8, carbomer 0.2-0.4, wallantoin 0.2-0.4, Feldspar Powder 0.3-0.5, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
A kind of safe environment protection type glass use coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyether-modified organopolysiloxane, whiteruss, Emulphor FM, wallantoin mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds Triethylene glycol ethyl ether, trolamine, sodium oleate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds waterborne polyurethane resin, low methyl-etherified aminoresin, modification propyl benzene emulsion, carbomer stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds two (dioctyl pyrophosphoryl bases) successively containing fluoroacetic acid ester titanium, pigment, Feldspar Powder uniform stirring 20-30 minute;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
The invention has the advantages that: water-borne coatings paint film of the present invention is smooth, smooth, rate of drying is fast, glossiness is good, there are the features such as high weathering resistance, scrub resistance, oxidation-resistance, high sterilization and anticorrosion and sticking power, the modifying cinepazid emulsion added further increases the sterilization of coating, dust-proof, anlistatig effect, and the present invention is simple to operate, and duration of service is long, Environmental Safety, practical.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of safe environment protection type glass use coating, is made up of the raw material of following weight part (kilogram): waterborne polyurethane resin 32, low methyl-etherified aminoresin 33, ethylene glycol phenyl ether 3, modification propyl benzene emulsion 9, two (dioctyl pyrophosphoryl base) are containing fluoroacetic acid ester titanium 0.4, polyether-modified organopolysiloxane 0.4, Triethylene glycol ethyl ether 3, whiteruss 0.3, Emulphor FM 0.3, sodium oleate 0.6, trolamine 0.6, carbomer 0.4, wallantoin 0.4, Feldspar Powder 0.5, pigment 2, deionized water 15;
Described modifying cinepazid emulsion is made up of the raw material of following weight part (kilogram): silane coupling agent KH5700.5, nano titanium oxide 3, nano zine oxide 2, vinylbenzene 26, butyl acrylate 52, methacrylic acid 12, N, N'-methylene-bisacrylamide 0.5, sodium lauryl sulphate 2, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 10, ammonium persulphate 0.5, ethyl acetate 15, distilled water 130; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
A kind of safe environment protection type glass use coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyether-modified organopolysiloxane, whiteruss, Emulphor FM, wallantoin mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds Triethylene glycol ethyl ether, trolamine, sodium oleate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds waterborne polyurethane resin, low methyl-etherified aminoresin, modification propyl benzene emulsion, carbomer stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds two (dioctyl pyrophosphoryl bases) successively containing fluoroacetic acid ester titanium, pigment, Feldspar Powder uniform stirring 20-30 minute;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Paint adhesion experiment (frame method) of the present invention≤1 grade, water tolerance experiment (480h) is without exception, hardness of paint film is 2H, artificial ageing resistance experiment >=500 hours is without exception, and resistance to boiling water experiment >=12 are hour unchanged, and salt fog resistance experiment >=20 hours is unchanged, abrasion resistance is tested 10000 times and is passed through, paint film without breakage, alcohol resistance experiment >=24 hours unchanged, cut resistance test 1 grade.
Claims (2)
1. a safe environment protection type glass use coating, it is characterized in that, be made up of the raw material of following weight part: waterborne polyurethane resin 30-35, low methyl-etherified aminoresin 30-35, ethylene glycol phenyl ether 1-3, modification propyl benzene emulsion 8-12, two (dioctyl pyrophosphoryl bases) are containing fluoroacetic acid ester titanium 0.3-0.6, polyether-modified organopolysiloxane 0.2-0.5, Triethylene glycol ethyl ether 1-3, whiteruss 0.2-0.4, Emulphor FM 0.1-0.3, sodium oleate 0.4-0.8, trolamine 0.4-0.8, carbomer 0.2-0.4, wallantoin 0.2-0.4, Feldspar Powder 0.3-0.5, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use; The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
2. a kind of safe environment protection type glass use coating according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, polyether-modified organopolysiloxane, whiteruss, Emulphor FM, wallantoin mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds Triethylene glycol ethyl ether, trolamine, sodium oleate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds waterborne polyurethane resin, low methyl-etherified aminoresin, modification propyl benzene emulsion, carbomer stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds two (dioctyl pyrophosphoryl bases) successively containing fluoroacetic acid ester titanium, pigment, Feldspar Powder uniform stirring 20-30 minute;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
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Application Number | Priority Date | Filing Date | Title |
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CN201410537667.5A CN104342001A (en) | 2014-10-14 | 2014-10-14 | Safe environment-friendly type water-based paint for glass and preparation method thereof |
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CN201410537667.5A CN104342001A (en) | 2014-10-14 | 2014-10-14 | Safe environment-friendly type water-based paint for glass and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118444A (en) * | 2016-07-18 | 2016-11-16 | 天长市巨龙车船涂料有限公司 | A kind of self-drying type polyurethane antistatic paint |
CN106675282A (en) * | 2016-12-08 | 2017-05-17 | 安徽省阜阳闽安建材有限公司 | Adsorption and purification enhanced colored rock sheet inner wall coating with porous starch with synergic honeycomb-shaped manganese dioxide |
CN107699121A (en) * | 2017-09-19 | 2018-02-16 | 运研材料科技(上海)有限公司 | A kind of aqueous polyurethane coating and its film build method of resistance to butanone |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1914282A1 (en) * | 2006-10-17 | 2008-04-23 | Bayer MaterialScience AG | Aqueous coating of a binder mixture as base coat |
CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
CN103409019A (en) * | 2013-07-29 | 2013-11-27 | 重庆恒美涂料有限公司 | Water-based one-component glass paint raw material |
CN103965715A (en) * | 2013-01-29 | 2014-08-06 | 惠州市华昱美实业有限公司 | Water-based glass coating |
-
2014
- 2014-10-14 CN CN201410537667.5A patent/CN104342001A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1914282A1 (en) * | 2006-10-17 | 2008-04-23 | Bayer MaterialScience AG | Aqueous coating of a binder mixture as base coat |
CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
CN103965715A (en) * | 2013-01-29 | 2014-08-06 | 惠州市华昱美实业有限公司 | Water-based glass coating |
CN103409019A (en) * | 2013-07-29 | 2013-11-27 | 重庆恒美涂料有限公司 | Water-based one-component glass paint raw material |
Non-Patent Citations (1)
Title |
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朱万章等: "水性玻璃涂料的研制", 《上海涂料》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118444A (en) * | 2016-07-18 | 2016-11-16 | 天长市巨龙车船涂料有限公司 | A kind of self-drying type polyurethane antistatic paint |
CN106675282A (en) * | 2016-12-08 | 2017-05-17 | 安徽省阜阳闽安建材有限公司 | Adsorption and purification enhanced colored rock sheet inner wall coating with porous starch with synergic honeycomb-shaped manganese dioxide |
CN107699121A (en) * | 2017-09-19 | 2018-02-16 | 运研材料科技(上海)有限公司 | A kind of aqueous polyurethane coating and its film build method of resistance to butanone |
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