CN104341947A - Bactericidal anticorrosive paint for glass sliding doors and preparation method thereof - Google Patents
Bactericidal anticorrosive paint for glass sliding doors and preparation method thereof Download PDFInfo
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- CN104341947A CN104341947A CN201410537647.8A CN201410537647A CN104341947A CN 104341947 A CN104341947 A CN 104341947A CN 201410537647 A CN201410537647 A CN 201410537647A CN 104341947 A CN104341947 A CN 104341947A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/32—Modified amine-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a bactericidal anticorrosive paint for glass sliding doors. The invention is characterized in that the paint is prepared from the following raw materials in parts by weight: 35-40 parts of high-hydroxymethyl methyl ether melamine formaldehyde resin, 20-23 parts of short-oil-length alkyd resin, 7-10 parts of modified pure acrylic emulsion, 1-3 parts of dipropylene glycol monomethyl ether, 0.3-0.5 part of tetraisopropyldi(dilauryl phosphite)titanate, 0.4-0.8 part of amide stearate, 0.3-0.5 part of leveling agent BYK-306, 0.3-0.5 part of aminopropyl triethoxy silane, 0.2-0.5 part of dimethyl polysiloxane defoaming agent, 0.3-0.6 part of methyl cellulose, 0.3-0.4 part of polyoxyethylene ethylene glycol alkylaryl ether, 0.6-1.2 parts of hydroxy phenyl methyl ester, 0.6-1.2 parts of silica sol, 1-2 parts of pigment and 10-15 parts of deionized water. The water-based glass paint has the advantages of favorable adhesive force, smooth paint film, favorable glossiness and favorable weather resistance; the added modified pure acrylic emulsion has the characteristics of excellent dirt resistance, excellent bactericidal property, excellent scrub resistance, excellent weather resistance and the like; the added hydroxy phenyl methyl ester has the bactericidal and anticorrosive functions, and does not have adverse effect on good health of people; and thus, when being used for home glass door decoration, the paint has the advantages of favorable decoration and protection effects, long service time and high practicality.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of glass sliding door coating with sterilization and anticorrosion type and preparation method thereof.
Background technology
Coating is applied to body surface can be formed and have protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material.The application of coating starts from prehistoric, and even to this day, paint field is also in development.Look around, coating is ubiquitous, its functional and ornamental leap various fields.Glass paint is the one of coating.It can be stable the surface sticking to glass wares, by distinct colors to glass wares carry out attractive in appearance and decoration function and efficacy.Conventional glass paint is divided into oil paint and water-borne coatings according to the kind of solvent, and oiliness is that water-based is using water as solvent using benzene, ester class as solvent.Glass paint is developed by solvent-borne type hydrotropisms, is the inexorable trend that the industries such as glass ornaments, artwork, Glass Containers and bottle adapt to environment protection requirement development, replaces traditional solvent-borne coating gradually, main flow field, occuping market.And along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified, the performances such as wear-resistant to it, anti-zoned quarter, weathering resistance propose requirements at the higher level, constantly substitute the application market of conventional inorganic paint coatings.
Summary of the invention
The object of this invention is to provide a kind of glass sliding door coating with sterilization and anticorrosion type and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of glass sliding door coating with sterilization and anticorrosion type, be made up of the raw material of following weight part: high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin 35-40, short oil-ity alcohol acid resin 20-23, modification pure-acrylic emulsion 7-10, dipropylene glycol monomethyl ether 1-3, tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester 0.3-0.5, stearic amide 0.4-0.8, flow agent BYK-3060.3-0.5, aminopropyl triethoxysilane 0.3-0.5, dimethyl polysiloxane defoamer 0.2-0.5, methylcellulose gum 0.3-0.6, polyoxyethylene glycol alkyl aryl ether 0.3-0.4, methyl hydroxybenzoate 0.6-1.2, silicon sol 0.6-1.2, pigment 1-2, deionized water 10-15,
Described modification pure-acrylic emulsion is made up of the raw material of following weight part: nano titanium oxide 3-5, nano silicon 2-4, nano-calcium carbonate 1-2, methyl methacrylate 50-56, butyl acrylate 43-48, methacrylic acid 1-3, silane coupling agent KH5701-2, ammonium persulphate 0.5-1.0, Sodium dodecylbenzene sulfonate 1-3, tributyl citrate 12-16, distilled water 100-130; Nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.Again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
A kind of glass sliding door coating with sterilization and anticorrosion type of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-306, dimethyl polysiloxane defoamer, polyoxyethylene glycol alkyl aryl ether, stearic amide, methyl hydroxybenzoate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monomethyl ether, aminopropyl triethoxysilane stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin, short oil-ity alcohol acid resin, modification pure-acrylic emulsion, methylcellulose gum stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester, silicon sol, pigment uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: aqueous glass paint sticking power of the present invention is good; paint film is smooth; glossiness is good, good weatherability, and the modification pure-acrylic emulsion of interpolation has the features such as excellent pollution resistance, bactericidal properties, scrub resistance and weathering resistance; the methyl hydroxybenzoate added has the effect of sterilization and anticorrosion; have no adverse effects to people are healthy, so coating of the present invention is as family glass door decoration use, decorative effect and protected effect good; duration of service is long, practical.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of glass sliding door coating with sterilization and anticorrosion type, be made up of the raw material of following weight part (kilogram): high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin 38, short oil-ity alcohol acid resin 22, modification pure-acrylic emulsion 8, dipropylene glycol monomethyl ether 3, tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester 0.4, stearic amide 0.6, flow agent BYK-3060.3, aminopropyl triethoxysilane 0.4, dimethyl polysiloxane defoamer 0.3, methylcellulose gum 0.3, polyoxyethylene glycol alkyl aryl ether 0.3, methyl hydroxybenzoate 1.2, silicon sol 1.2, pigment 2, deionized water 15,
Described modification pure-acrylic emulsion is made up of the raw material of following weight part (kilogram): nano titanium oxide 5, nano silicon 2, nano-calcium carbonate 1, methyl methacrylate 54, butyl acrylate 44, methacrylic acid 1, silane coupling agent KH5701, ammonium persulphate 0.5, Sodium dodecylbenzene sulfonate 1, tributyl citrate 15, distilled water 110; Nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.Again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
A kind of glass sliding door coating with sterilization and anticorrosion type of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-306, dimethyl polysiloxane defoamer, polyoxyethylene glycol alkyl aryl ether, stearic amide, methyl hydroxybenzoate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monomethyl ether, aminopropyl triethoxysilane stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin, short oil-ity alcohol acid resin, modification pure-acrylic emulsion, methylcellulose gum stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester, silicon sol, pigment uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Aqueous glass paint appearance of film of the present invention is normal, sticking power tests 1 grade, water tolerance experiment (GB/T1733-1993) >=240 hour, hardness 3H, abrasion resistance is tested: pass through for 1000 times, paint film is without breakage, alcohol resistance (60% ethanolic soln) >=100 hours nothing difference, wear resistance (0.5g/r)/mg5.8, resistance to boiling water experiment 12 hours is unchanged, solvent resistant test 12 hours unchanged.
Claims (2)
1. one kind has the glass sliding door coating of sterilization and anticorrosion type, it is characterized in that, be made up of the raw material of following weight part: high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin 35-40, short oil-ity alcohol acid resin 20-23, modification pure-acrylic emulsion 7-10, dipropylene glycol monomethyl ether 1-3, tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester 0.3-0.5, stearic amide 0.4-0.8, flow agent BYK-3060.3-0.5, aminopropyl triethoxysilane 0.3-0.5, dimethyl polysiloxane defoamer 0.2-0.5, methylcellulose gum 0.3-0.6, polyoxyethylene glycol alkyl aryl ether 0.3-0.4, methyl hydroxybenzoate 0.6-1.2, silicon sol 0.6-1.2, pigment 1-2, deionized water 10-15,
described modification pure-acrylic emulsion is made up of the raw material of following weight part: nano titanium oxide 3-5, nano silicon 2-4, nano-calcium carbonate 1-2, methyl methacrylate 50-56, butyl acrylate 43-48, methacrylic acid 1-3, silane coupling agent KH5701-2, ammonium persulphate 0.5-1.0, Sodium dodecylbenzene sulfonate 1-3, tributyl citrate 12-16, distilled water 100-130, nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use, again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
2. a kind of glass sliding door coating with sterilization and anticorrosion type according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-306, dimethyl polysiloxane defoamer, polyoxyethylene glycol alkyl aryl ether, stearic amide, methyl hydroxybenzoate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monomethyl ether, aminopropyl triethoxysilane stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds high methylol group type methyl-etherified terpolycyantoamino-formaldehyde resin, short oil-ity alcohol acid resin, modification pure-acrylic emulsion, methylcellulose gum stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds tetra isopropyl two (phosphorous acid two lauryl) titanic acid ester, silicon sol, pigment uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
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CN201410537647.8A CN104341947A (en) | 2014-10-14 | 2014-10-14 | Bactericidal anticorrosive paint for glass sliding doors and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105901015A (en) * | 2016-05-06 | 2016-08-31 | 陈昌 | Antibacterial metal oxide composite material and preparation method thereof |
CN106519827A (en) * | 2016-09-23 | 2017-03-22 | 安徽吉思特智能装备有限公司 | Self-cleaning fluorine-carbon heat-insulation radiation type coating material and preparation method thereof |
CN106634512A (en) * | 2016-12-13 | 2017-05-10 | 天长市银狐漆业有限公司 | Super-amphiphobic silver series anti-microbial compound hybridizing anti-corrosion coating |
CN106752819A (en) * | 2016-12-13 | 2017-05-31 | 天长市银狐漆业有限公司 | A kind of organic-inorganic hybrid polymer coating of modified particle modification |
CN107033759A (en) * | 2016-12-13 | 2017-08-11 | 天长市银狐漆业有限公司 | A kind of carbon black loadings molybdenum disulfide antifriction type super-amphiphobic hybridization coating |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105901015A (en) * | 2016-05-06 | 2016-08-31 | 陈昌 | Antibacterial metal oxide composite material and preparation method thereof |
CN105901015B (en) * | 2016-05-06 | 2018-05-11 | 徐海军 | A kind of antibacterial metal oxide composite and preparation method thereof |
CN106519827A (en) * | 2016-09-23 | 2017-03-22 | 安徽吉思特智能装备有限公司 | Self-cleaning fluorine-carbon heat-insulation radiation type coating material and preparation method thereof |
CN106634512A (en) * | 2016-12-13 | 2017-05-10 | 天长市银狐漆业有限公司 | Super-amphiphobic silver series anti-microbial compound hybridizing anti-corrosion coating |
CN106752819A (en) * | 2016-12-13 | 2017-05-31 | 天长市银狐漆业有限公司 | A kind of organic-inorganic hybrid polymer coating of modified particle modification |
CN107033759A (en) * | 2016-12-13 | 2017-08-11 | 天长市银狐漆业有限公司 | A kind of carbon black loadings molybdenum disulfide antifriction type super-amphiphobic hybridization coating |
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