CN104327689A - Acid-resistant water-resistant aqueous paint for glass sliding doors and preparation method thereof - Google Patents
Acid-resistant water-resistant aqueous paint for glass sliding doors and preparation method thereof Download PDFInfo
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- CN104327689A CN104327689A CN201410537624.7A CN201410537624A CN104327689A CN 104327689 A CN104327689 A CN 104327689A CN 201410537624 A CN201410537624 A CN 201410537624A CN 104327689 A CN104327689 A CN 104327689A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
Disclosed acid-resistant water-resistant aqueous paint for glass sliding doors is characterized by being prepared from the following raw materials in parts by weight: 50-54 parts of aqueous alkyd resins, 13-16 parts of aqueous saturated resin, 0.2-0.4 part of aqueous silane coupling agent KH460, 1-3 parts of di(propylene glycol) propyl ether, 7-10 parts of modified pure acrylic emulsion, 0.2-0.4 part of alcohol amine fatty acid titanate, 0.3-0.5 parts of a levelling agent L-330, 0.3-0.5 part of 3-aminopropyltriethoxysilane, 0.2-0.4 part of octylphenol polyoxyethylene ether, 0.2-0.4 part of polydimethylsiloxane antifoaming agent, 0.2-0.4 part of sodium alginate, 0.2-0.4 part of fumed silica, 0.5-1.0 parts of mica powder, 1-2 parts of aluminium oxide fine powder, 2-4 parts of a pigment, 2-4 parts of propylene glycol, and 10-15 parts of deionized water. The aqueous paint for glass has the performances of resisting acids and resisting water, is long in service life, free of adverse smells and free of lead, mercury and other heavy metals, and accords with technological requirement of environment-friendly paint, and by adding the modified pure acrylic emulsion, the aqueous paint for glass is improved in anti-fouling performance, sterilization performance, scrubbing resistance, weatherability and other performances, is prolonged in service life and improved in quality.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of acidproof water-fast glass sliding door use coating and preparation method thereof.
Background technology
Glass paint is the one of coating.It can be stable the surface sticking to glass wares, by distinct colors to glass wares carry out attractive in appearance and decoration function and efficacy.Conventional glass paint is divided into oil paint and water-borne coatings according to the kind of solvent, and oiliness is that water-based is using water as solvent using benzene, ester class as solvent.Glass paint is developed by solvent-borne type hydrotropisms, is the inexorable trend that the industries such as glass ornaments, artwork, Glass Containers and bottle adapt to environment protection requirement development, replaces traditional solvent-borne coating gradually, main flow field, occuping market.And along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified, the performances such as wear-resistant to it, anti-zoned quarter, weathering resistance propose requirements at the higher level, constantly substitute the application market of conventional inorganic paint coatings.
Summary of the invention
The object of this invention is to provide a kind of acidproof water-fast glass sliding door use coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of acidproof water-fast glass sliding door use coating, be made up of the raw material of following weight part: aqueous alkide resin 50-54, water-based saturated resin 13-16, aqueous silane coupling agent KH4600.2-0.4, dipropylene glycol monopropyl ether 1-3, modification pure-acrylic emulsion 7-10, hydramine lipid acid titanic acid ester 0.2-0.4, flow agent L-3300.3-0.5, aminopropyl triethoxysilane 0.3-0.5, polyoxyethylene octylphenol ether 0.2-0.4, dimethyl polysiloxane defoamer 0.2-0.4, sodium alginate 0.2-0.4, aerosil 0.2-0.4, mica powder 0.5-1.0, aluminum oxide fine powder 1-2, pigment 2-4, propylene glycol 2-4, deionized water 10-15,
Described modification pure-acrylic emulsion is made up of the raw material of following weight part: nano titanium oxide 3-5, nano silicon 2-4, nano-calcium carbonate 1-2, methyl methacrylate 50-56, butyl acrylate 43-48, methacrylic acid 1-3, silane coupling agent KH5701-2, ammonium persulphate 0.5-1.0, Sodium dodecylbenzene sulfonate 1-3, tributyl citrate 12-16, distilled water 100-130; Nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.Again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
The glass sliding door use coating of a kind of uv blocking radiation of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent L-330, dimethyl polysiloxane defoamer, polyoxyethylene octylphenol ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, aminopropyl triethoxysilane, propylene glycol stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous alkide resin, water-based saturated resin, modification pure-acrylic emulsion, sodium alginate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds aqueous silane coupling agent KH460, hydramine lipid acid titanic acid ester, aerosil, pigment, aluminum oxide fine powder, mica powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: aqueous glass paint of the present invention has acidproof water-fast performance, long service life, without unpleasant odor, the heavy metals such as not leaded, mercury, meet the technical requirements of environmental protection coating material, the modification pure-acrylic emulsion added improve coating the performance such as pollution resistance, bactericidal properties, scrub resistance and weathering resistance, extend the time limit of service of coating, improve the quality of coating.
specific embodiments
Below by specific examples, the present invention is described in detail.
An acidproof water-fast glass sliding door use coating, is made up of the raw material of following weight part (kilogram): aqueous alkide resin 52, water-based saturated resin 15, aqueous silane coupling agent KH4600.4, dipropylene glycol monopropyl ether 3, modification pure-acrylic emulsion 8, hydramine lipid acid titanic acid ester 0.4, flow agent L-3300.4, aminopropyl triethoxysilane 0.4, polyoxyethylene octylphenol ether 0.4, dimethyl polysiloxane defoamer 0.3, sodium alginate 0.3, aerosil 0.3, mica powder 1.0, aluminum oxide fine powder 2, pigment 3, propylene glycol 4, deionized water 14;
Described modification pure-acrylic emulsion is made up of the raw material of following weight part (kilogram): nano titanium oxide 5, nano silicon 2, nano-calcium carbonate 1, methyl methacrylate 54, butyl acrylate 44, methacrylic acid 1, silane coupling agent KH5701, ammonium persulphate 0.5, Sodium dodecylbenzene sulfonate 1, tributyl citrate 15, distilled water 110; Nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.Again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
The glass sliding door use coating of a kind of uv blocking radiation of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent L-330, dimethyl polysiloxane defoamer, polyoxyethylene octylphenol ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, aminopropyl triethoxysilane, propylene glycol stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous alkide resin, water-based saturated resin, modification pure-acrylic emulsion, sodium alginate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds aqueous silane coupling agent KH460, hydramine lipid acid titanic acid ester, aerosil, pigment, aluminum oxide fine powder, mica powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Aqueous glass paint appearance of film of the present invention is normal, sticking power tests 1 grade, water tolerance experiment (GB/T1733-1993) >=240 hour, hardness 5H, abrasion resistance is tested: pass through for 1000 times, and paint film is without breakage, and alcohol resistance (60% ethanolic soln) >=100 hours nothings are peculiar, wear resistance (0.5g/r)/mg5.0, resistance to boiling water experiment 12 hours is unchanged.
Claims (2)
1. an acidproof water-fast glass sliding door use coating, it is characterized in that, be made up of the raw material of following weight part: aqueous alkide resin 50-54, water-based saturated resin 13-16, aqueous silane coupling agent KH4600.2-0.4, dipropylene glycol monopropyl ether 1-3, modification pure-acrylic emulsion 7-10, hydramine lipid acid titanic acid ester 0.2-0.4, flow agent L-3300.3-0.5, aminopropyl triethoxysilane 0.3-0.5, polyoxyethylene octylphenol ether 0.2-0.4, dimethyl polysiloxane defoamer 0.2-0.4, sodium alginate 0.2-0.4, aerosil 0.2-0.4, mica powder 0.5-1.0, aluminum oxide fine powder 1-2, pigment 2-4, propylene glycol 2-4, deionized water 10-15,
Described modification pure-acrylic emulsion is made up of the raw material of following weight part: nano titanium oxide 3-5, nano silicon 2-4, nano-calcium carbonate 1-2, methyl methacrylate 50-56, butyl acrylate 43-48, methacrylic acid 1-3, silane coupling agent KH5701-2, ammonium persulphate 0.5-1.0, Sodium dodecylbenzene sulfonate 1-3, tributyl citrate 12-16, distilled water 100-130; Nano titanium oxide, nano silicon, nano-calcium carbonate and tributyl citrate are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20 minute by preparation method, and the silane coupling agent KH570 slowly adding 30% is heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use;
Again by butyl acrylate, it is for subsequent use that methyl methacrylate and methacrylic acid mix formation monomer mixed solution in other beaker, fully dissolve post-heating to 60 ° of C by being added in Sodium dodecylbenzene sulfonate and distilled water in there-necked flask simultaneously, add nano composite material again, the monomer mixed solution rapid stirring emulsification of 10-30% 30 minutes, add ammonium persulphate raised temperature to 80 ° about C again, isothermal reaction is after 45 minutes, remaining monomer mixed solution is slowly added in flask, guarantee to drip in 2 hours to terminate, insulation 2-3 hour, insulation terminates rear cooling and is adjusted to the pure-acrylic emulsion that neutrality can obtain modification.
2. the glass sliding door use coating of a kind of uv blocking radiation according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent L-330, dimethyl polysiloxane defoamer, polyoxyethylene octylphenol ether mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, aminopropyl triethoxysilane, propylene glycol stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous alkide resin, water-based saturated resin, modification pure-acrylic emulsion, sodium alginate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds aqueous silane coupling agent KH460, hydramine lipid acid titanic acid ester, aerosil, pigment, aluminum oxide fine powder, mica powder uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410537624.7A CN104327689A (en) | 2014-10-14 | 2014-10-14 | Acid-resistant water-resistant aqueous paint for glass sliding doors and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410537624.7A CN104327689A (en) | 2014-10-14 | 2014-10-14 | Acid-resistant water-resistant aqueous paint for glass sliding doors and preparation method thereof |
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| CN104327689A true CN104327689A (en) | 2015-02-04 |
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| CN201410537624.7A Pending CN104327689A (en) | 2014-10-14 | 2014-10-14 | Acid-resistant water-resistant aqueous paint for glass sliding doors and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106747647A (en) * | 2016-12-30 | 2017-05-31 | 周益铭 | A kind of preparation method of cement concrete pavement curing agent |
| CN107384071A (en) * | 2017-07-19 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of high durable dip-coating sealing wax and preparation method thereof |
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| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102226054A (en) * | 2011-06-14 | 2011-10-26 | 德美建筑材料（太原）工程有限公司 | Sunlight reflective insulation paint |
| CN102924990A (en) * | 2012-10-16 | 2013-02-13 | 上海瑞冕新材料科技有限公司 | Transparent antireflection coating liquid and preparation method and application thereof |
| CN103382334A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Alkyd modified acrylic acid emulsion paint with high weatherability |
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2014
- 2014-10-14 CN CN201410537624.7A patent/CN104327689A/en active Pending
Patent Citations (6)
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| JP2008007718A (en) * | 2006-06-30 | 2008-01-17 | Toyobo Co Ltd | Alkyd resin, resin composition for water-based alkyd coating and method for producing them |
| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102226054A (en) * | 2011-06-14 | 2011-10-26 | 德美建筑材料（太原）工程有限公司 | Sunlight reflective insulation paint |
| CN102924990A (en) * | 2012-10-16 | 2013-02-13 | 上海瑞冕新材料科技有限公司 | Transparent antireflection coating liquid and preparation method and application thereof |
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| 邵谦等: "纳米TiO_2/苯丙复合乳液的合成与表征", 《山东科技大学学报(自然科学版)》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106747647A (en) * | 2016-12-30 | 2017-05-31 | 周益铭 | A kind of preparation method of cement concrete pavement curing agent |
| CN107384071A (en) * | 2017-07-19 | 2017-11-24 | 河北晨阳工贸集团有限公司 | A kind of high durable dip-coating sealing wax and preparation method thereof |
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Application publication date: 20150204 |