CN101899249A - Transparent thermal insulation anti-ultraviolet coating and preparation method thereof - Google Patents
Transparent thermal insulation anti-ultraviolet coating and preparation method thereof Download PDFInfo
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Abstract
The invention provides a transparent thermal insulation anti-ultraviolet coating and a preparation method thereof, belongs to the technical field chemical industry, materials and environmental protection and relates to the transparent thermal insulation anti-ultraviolet coating which can reduce the transmission of solar energy and ultraviolet and the preparation method thereof. The coating comprises nano-slurry with the thermal insulation anti-ultraviolet function and a film-forming substance, and is combined with the synergistic effects of a wetting dispersant and a hyper-dispersant for preparing the nano-slurry with high solid content and stable dispersion. The preparation process of the coating is simple and can greatly improve the solid content of the coating, ensure the optical effect of a paint film after coating, simultaneously organically combined powder with different functions and obtain the thermal insulation anti-ultraviolet functional coating with satisfactory effects. The coating has the characteristics of low transmission of ultraviolet and near infrared light of solar rays, high transmission of visible light and the like, and can be coated on glass, polycarbonate or organic glass and other transparent materials, and achieve the purposes of energy conservation and protection.
Description
Technical field
The invention belongs to chemical industry, material and environmental technology field.
Background technology
In order to reduce the radiation of sun power, reach purpose of energy saving, people adopt variety of way to change the light transmission of glass.The vehicle glass pad pasting can intercept solar irradiation, reduce each temperature surperficial and the interior air of car in the car, improve frame and take advantage of personnel's environment by bus, can reduce simultaneously the oil consumption of automobile, more same building energy conservation glass also reach the obstruct solar irradiation by metal-coated membrane (aluminium, silver etc.), reduce the purpose of air conditioning energy consumption.In recent years, it is found that some metal oxides have good optics barrier, as antimony tin (ATO) near infrared of wavelength 1400-2500nm had good barrier, tin indium oxide (ITO) has good barrier to the near infrared of wavelength 1100-2500nm, can intercept the near infrared light of 900-2500nm through the tin indium oxide (USP 5518810) of special processing.The part boride (EP 1008564, USP6620872, USP 6911654) can intercept near infrared light (800-1800nm) as lanthanum hexaborane (LaB6).Nano-powder such as titanium dioxide, zinc oxide, ferric oxide have good UV-light barrier in addition, can protect house decorative material to avoid ultraviolet radiation, increase the service life.Nano titanium oxide wherein particularly adopts the nano titanium oxide of elements such as doping iron, manganese, can intercept the ultraviolet ray of wavelength below 390nm.Another advantage that adopts inorganic anti-ultraviolet powder is its optical stability, organically can lose ultraviolet shielding function gradually in the uv-absorbing agent use, and there are not the problems referred to above in inorganic powder.
Because nano particle has very high specific surface area and surface free energy, be in the thermodynamic instability state, conglomerate very easily between the nano particle is difficult for homodisperse.The nano pulp of prior art for preparing exists easily that concentration is low, median size is big, easily anti-thick, visible region poor transparency, assemble easily when storing and disadvantage such as precipitation, effect of heat insulation is undesirable.The nano pulp functional nano powder concentration that being used for of CN101054455A and CN1563231A prepares coating is only about 2-15%, and is the highest also only 20%.It is very low that this method causes consolidating of coating to contain, because optical clear coating generally can only disposable application, the application twice are very big to the optical property influence, so wet film needs very thickly during application, just can be effective.The nano pulp method that provides the material preparation to contain 10-30% admittedly among the CN1903958A, but the nano pulp of embodiment contains admittedly also only 20%.The method of CN101230234A employing co-precipitation surface modification has prepared and has contained 40% nano-indium stannum oxide slurry admittedly, but complex process is difficult to obtain height and contains the stabilized nano slurry admittedly.The present invention utilizes two kinds of dispersion agent synergistic effects in the dispersion process of nano-powder, first kind is adopted wetting dispersing agent, and the nano powder physical efficiency is disperseed rapidly in process of lapping, and second kind is adopted hyper-dispersant, make scattered nano-powder that good stability be arranged, prevent secondary aggregation.Like this, not only can prepare the nano-dispersed slurry of high density, its stability reached more than 6 months.
Summary of the invention
The objective of the invention is by in coating, adding a certain amount of nano-powder and ultraviolet nano-powder of obstruct that intercepts the sunlight middle infrared (Mid-IR) that have, make this coating transparent, and can reduce solar energy and ultraviolet a kind of heat insulation anti-ultraviolet coating that sees through and preparation method thereof.
A kind of transparent thermal insulation anti-ultraviolet coating is characterized in that:
It is made up of nano pulp that contains heat insulation anti-ultraviolet function (10-80wt%) and filmogen (20-80wt%) institute mixed together,
Heat insulation anti-ultraviolet nanometer slurry wherein, solid content is 30-50wt%, includes heat insulating function material, anti-ultraviolet functional materials, and dispersion agent,
And by the nano pulp that heat insulating function material, anti-ultraviolet functional materials are formed, its size distribution is mainly at 10-200nm,
And dispersion agent comprises two kinds of wetting dispersing agent and hyper-dispersants, accounts for the 5-30wt% of nano-powder gross weight,
Filmogen wherein is polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, the 1-5 kind in these selected materials.
Further, described a kind of transparent thermal insulation anti-ultraviolet coating also has following technical characterictic:
Described nano pulp particle diameter, preferred median size is 50-150nm.
The described heat insulating function material that contains in the heat insulation anti-ultraviolet function nano slurry, be to have certain transmitance and the function powder of the lower transmitance in near-infrared region, be specially in antimony tin (ATO) nano-powder, tin indium oxide (ITO) nano-powder, lanthanum hexaborane (LaB6) nano-powder, the doping titanium dioxide alum nano-powder one or more at visible region.
Prevent the ultraviolet functional materials described containing in the heat insulation anti-ultraviolet function nano slurry, being a kind ofly to have preferably transmitance and there is the function powder of lower transmitance the ultraviolet region at visible region, specifically is nano TiO 2 powder, zinc oxide nano-powder, ferric oxide nano powder, these several nano-powders of cerium oxide nano-powder.
The described anti-ultraviolet functional materials that contains in the heat insulation anti-ultraviolet function nano slurry preferably has the nano titanium oxide of good doping iron of good ultraviolet barriering effect or manganese element.
The preparation method of this transparent thermal insulation anti-ultraviolet coating is as follows:
At first prepare transparent varnish, filmogen, and the nano pulp good with this varnish system consistency,
Transparent varnish wherein, for solvent, flow agent, defoamer, adhesion promoter etc. are deployed into the transparent varnish of single component or two-pack,
Filmogen wherein is polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, the 1-5 kind in these selected materials,
Nano pulp wherein, solid content is 30-50wt%, includes heat insulating function material, anti-ultraviolet functional materials, and dispersion agent;
Described transparent varnish and nano pulp are carried out thorough mixing, make described coating with transparent heat-insulated anti-ultraviolet function.
Further, the preparation method of described a kind of transparent thermal insulation anti-ultraviolet coating also includes following main points:
Described transparent varnish, filmogen and nano pulp have following component relation,
Filmogen 20-90
Nano pulp 10-80
Auxiliary agent 0.1-10
Solvent 0-50
Auxiliary agent wherein and solvent are the component of transparent varnish.
Described filmogen, can realize by polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, specifically can be preferably the good polyacrylic resin of weathering resistance, urethane resin, aminoresin and silicone resin and aqueous dispersions or emulsion by wherein one or more.
Selected filmogen can add solidifying agent at 0-200 ℃ of drying and forming-film.
The preparation method of described heat insulation anti-ultraviolet nanometer slurry, be in the heat insulating function powder, to add wetting dispersing agent and hyper-dispersant, dispersion medium, adopt abrasive method, grind back nano pulp concentration at 30-50wt%, median size is 10-200nm, preferred 10-100nm, wherein the composition of nano pulp and weight ratio are as follows:
Heat insulating function powder 20-40
Anti-ultraviolet function powder 10-30
Wetting dispersing agent 1.5-6
Hyper-dispersant 1.5-6
Dispersion medium 40-67
Described dispersion agent, be two kinds of the wetting dispersing agent, the hyper-dispersants that use in the nano pulp, has the stable and sterically hindered stable dual function of electrical charge rejection, as modified polyacrylate, modified poly ester class dispersion agent, fatty amine dispersion agent, according to selected resin system, can be aqueous dispersant, also can be the solvent borne dispersion agent.Two kinds of dispersant dosages account for the 5-30wt% of nano-powder gross weight respectively.
Described dispersion medium according to selected resin system, can be an aqueous dispersion medium, also can be the solvent borne dispersion agent, wherein organic solvent or mixed solvents such as solvent borne dispersion medium such as ethanol, butanols, dimethylbenzene, N-BUTYL ACETATE.
In use, adopt the method for showering, spraying or brushing that transparent thermal insulation anti-ultraviolet coating evenly is coated on the transparent substrate.
The invention has the advantages that:
The present invention utilizes the synergistic effect of wetting dispersing agent and hyper-dispersant, prepared nano pulp highly filled, stably dispersing, make coating preparation technology simple, the solids content of coating can improve greatly, the optical effect of the paint film after the assurance application, different function powder can be organically combined, thereby obtain the functional paint of heat insulation anti-ultraviolet satisfactory for result.This coating can directly be coated in the coating on the transparent substrates such as glass, polycarbonate, synthetic glass, polyester, these material surfaces had good adhesive, can directly be coated in material surface by construction technologies such as blade coating, showering, sprayings, make it have good infrared barrier and uv resistance energy.After this transparent heat-insulated anti-ultraviolet nanometer coating film forming, have the ultraviolet and the near infrared light transmitance of sunlight lowly, characteristics such as visible light transmissivity height can be applied on glass, polycarbonate, synthetic glass or other transparent material, reach energy-conservation and the protection purpose.
Description of drawings
Fig. 1 is the size distribution figure of nano pulp in a kind of transparent thermal insulation anti-ultraviolet coating of the present invention.
Embodiment
The explanation of Fig. 1:
As can be seen from Figure 1, the median size of nano pulp is 80nm, dispersion coefficient P.I=0.73.
Specific embodiment 1:
The preparation of the anti-ultraviolet nanometer slurry of water-borne heat-insulating of the present invention can be sent out according to following method:
Antimony tin 25
Nano titanium oxide 15
Wetting dispersing agent (Disperbyk-190) 4
Hyper-dispersant (Hyperdisper-5410) 4
Water 52
Wetting dispersing agent and hyper-dispersant are added to the water earlier, after stirring, under middling speed stirs, add above-mentioned powder, treat that these powders mix in water after, sand milling is 4 hours in sand mill, obtains the slurry about median size 90nm.
Specific embodiment 2:
The preparation of the heat insulation anti-ultraviolet nanometer slurry of pure dissolubility of the present invention can be according to following method:
Antimony tin 25
Nano titanium oxide 10
Wetting dispersing agent (ByK 160) 4
Hyper-dispersant (Hyperdisper-5410 polyester) 4
Ethanol 57
Join wetting dispersing agent (ByK 160) and hyper-dispersant (Hyperdisper-5410) in the ethanol earlier, after stirring, under middling speed stirs, add above-mentioned powder, treat that these powders mix in water after, sand milling is 8 hours in sand mill, obtains the slurry about median size 90nm.
Specific embodiment 3:
The preparation of solvent borne heat insulation nano slurry of the present invention can be according to following method:
Tin indium oxide (ITO) 25
Ferric oxide 10
Wetting dispersing agent (ByK 161) 4
Hyper-dispersant (BSK 32800SH) 5
Dimethylbenzene 56
Wetting dispersing agent and hyper-dispersant are joined earlier in the dimethylbenzene, after stirring, under middling speed stirs, add above-mentioned powder, treat that these powders mix in toluene after, sand milling is 8 hours in sand mill, obtains the slurry about median size 100nm.
Specific embodiment 4:
Of the present invention is that the preparation of water varnish can be according to following method:
Water soluble acrylic acid/polyurethane dispersing liquid 80
Dipropylene glycol monomethyl ether 6
Water 11
Defoamer (BYK-019) 0.9
Thickening material (RM-8W) 1.5
Wetting agent (H-140) 0.6
Above-mentioned materials is added by the prescription consumption, stir, obtain the varnish of certain viscosity with dispersion machine.
With above-mentioned water varnish and embodiment 1 waterborne nano slurry mixed by 100: 40, be coated on the glass baseplate, 10 microns of film thicknesses can obtain visible light transmissivity 73%, sun power transmittance 42%, the Clear coating of uv transmittance 8%.
Specific embodiment 5:
The preparation of pure dissolubility transparent heat insulation coating material of the present invention can be according to following method:
Silicone resin (admittedly containing 40%) 60
Embodiment 2 nano pulps 40
Defoamer (BYK-028) 0.4
Said components is mixed, be coated on the glass baseplate, but Air drying or in 80 ℃-120 ℃ down bakings 30 minutes, hardness 3H, 10 microns of film thicknesses, visible light transmissivity 68%, sun power transmittance 38%, the transparent heat-insulated coating of uv transmittance 11%.
Specific embodiment 6:
The preparation of solvent borne transparent heat insulation coating material of the present invention can be according to following method:
Acrylic resin 50
Embodiment 3 nano pulps 30
Flow agent (BYK-302) 0.5
Defoamer (BYK-071) 0.5
Said components is mixed, be sprayed on the clear polycarbonate base material, hardness reaches 2H, and 10 microns of film thicknesses can obtain visible light transmissivity 73%, sun power transmittance 40%, the Clear coating of uv transmittance 14%.
More than be the description of this invention and non-limiting, based on other embodiment of inventive concept, all among protection scope of the present invention.
Claims (13)
1. coating with transparent heat-insulated anti-ultraviolet function is characterized in that:
It is made up of nano pulp that contains heat insulation anti-ultraviolet function (10-80wt%) and filmogen (20-80wt%) institute mixed together,
Heat insulation anti-ultraviolet nanometer slurry wherein, solid content is 30-50wt%, includes heat insulating function material, anti-ultraviolet functional materials, and dispersion agent,
And by the nano pulp that heat insulating function material, anti-ultraviolet functional materials are formed, its size distribution is mainly at 10-200nm,
And dispersion agent comprises two kinds of wetting dispersing agent and hyper-dispersants, accounts for the 5-30wt% of nano-powder gross weight,
Filmogen wherein is polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, the 1-5 kind in these selected materials.
2. the coating with transparent heat-insulated anti-ultraviolet function according to claim 1 is characterized in that: described nano pulp particle diameter, preferred median size is 50-150nm.
3. the coating with transparent heat-insulated anti-ultraviolet function according to claim 1, it is characterized in that: the described heat insulating function material that contains in the heat insulation anti-ultraviolet function nano slurry, be to have certain transmitance and the function powder of the lower transmitance in near-infrared region, be specially in antimony tin (ATO) nano-powder, tin indium oxide (ITO) nano-powder, lanthanum hexaborane (LaB6) nano-powder, the doping titanium dioxide alum nano-powder one or more at visible region.
4. the coating with transparent heat-insulated anti-ultraviolet function according to claim 1, it is characterized in that: prevent the ultraviolet functional materials described containing in the heat insulation anti-ultraviolet function nano slurry, being a kind ofly to have preferably transmitance and there is the function powder of lower transmitance the ultraviolet region at visible region, specifically is nano TiO 2 powder, zinc oxide nano-powder, ferric oxide nano powder, these several nano-powders of cerium oxide nano-powder.
5. the coating with transparent heat-insulated anti-ultraviolet function according to claim 4, it is characterized in that: preferably have the nano titanium oxide of good doping iron of good ultraviolet barriering effect or manganese element, be used as the anti-ultraviolet functional materials in the heat insulation anti-ultraviolet function nano slurry.
6. preparation method with coating of transparent heat-insulated anti-ultraviolet function is characterized in that this method includes following steps:
At first prepare transparent varnish, filmogen, and the nano pulp good with this varnish system consistency,
Transparent varnish wherein, for solvent, flow agent, defoamer, adhesion promoter etc. are deployed into the transparent varnish of single component or two-pack,
Filmogen wherein is polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, the 1-5 kind in these selected materials,
Nano pulp wherein, solid content is 30-50wt%, includes heat insulating function material, anti-ultraviolet functional materials, and dispersion agent;
Described transparent varnish and nano pulp are carried out thorough mixing, make described coating with transparent heat-insulated anti-ultraviolet function.
7. preparation method according to claim 6 is characterized in that: described transparent varnish, filmogen and nano pulp have following component relation,
Filmogen 20-90
Nano pulp 10-80
Auxiliary agent 0.1-10
Solvent 0-50
Auxiliary agent wherein and solvent are the component of transparent varnish.
8. preparation method according to claim 6, it is characterized in that: filmogen wherein, can realize by polyacrylic resin, urethane resin, Synolac, aminoresin, polyester, silicone resin, inorganic silicate and their aqueous liquid dispersion or emulsion, specifically can be preferably the good polyacrylic resin of weathering resistance, urethane resin, aminoresin and silicone resin and aqueous dispersions or emulsion by wherein one or more.
9. preparation method according to claim 6 is characterized in that: selected filmogen can add solidifying agent at 0-200 ℃ of drying and forming-film.
10. preparation method according to claim 6, it is characterized in that: the preparation of heat insulation anti-ultraviolet nanometer slurry adds wetting dispersing agent and hyper-dispersant, dispersion medium in the heat insulating function powder, adopt abrasive method, grind back nano pulp concentration at 30-50wt%, median size is 10-200nm, preferred 10-100nm, wherein the composition of nano pulp and weight ratio are as follows
Heat insulating function powder 20-40
Anti-ultraviolet function powder 10-30
Wetting dispersing agent 1.5-6
Hyper-dispersant 1.5-6
Dispersion medium 40-67
11. heat insulation anti-ultraviolet nanometer slurry according to claim 6, it is characterized in that: dispersion agent is two kinds of the wetting dispersing agent, the hyper-dispersants that use in the nano pulp, has the stable and sterically hindered stable dual function of electrical charge rejection, as modified polyacrylate, modified poly ester class dispersion agent, fatty amine dispersion agent, according to selected resin system, can be aqueous dispersant, also can be the solvent borne dispersion agent, and two kinds of dispersant dosages account for the 5-30wt% of nano-powder gross weight respectively.
12. heat insulation anti-ultraviolet nanometer slurry according to claim 6, it is characterized in that: dispersion medium is according to selected resin system, it can be aqueous dispersion medium, also can be solvent borne dispersion agent, wherein organic solvent or mixed solvents such as solvent borne dispersion medium such as ethanol, butanols, dimethylbenzene, N-BUTYL ACETATE.
13. preparation method according to claim 6 is characterized in that: in use, adopt the method for showering, spraying or brushing that transparent thermal insulation anti-ultraviolet coating evenly is coated on the transparent substrate.
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2009
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