CN103740190B - A kind of rare earth nano insulating mold coating for high-transparent glass and preparation method thereof - Google Patents
A kind of rare earth nano insulating mold coating for high-transparent glass and preparation method thereof Download PDFInfo
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- CN103740190B CN103740190B CN201310741219.2A CN201310741219A CN103740190B CN 103740190 B CN103740190 B CN 103740190B CN 201310741219 A CN201310741219 A CN 201310741219A CN 103740190 B CN103740190 B CN 103740190B
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Abstract
The invention discloses a kind of rare earth nano insulating mold coating for high-transparent glass, calculate by mass percentage, by the fluorine carbon emulsion 70%-90% of hydroxyl acrylic modification, nano-indium stannum oxide water slurry (ITO) 5%-15%, pure water 5%-15%, cerium oxide 0.05%-0.2%, dispersion agent 0.1%-0.8% and film coalescence aid 0.1%-0.8% form; A kind of preparation method of rare earth nano insulating mold coating for high-transparent glass first adds the fluorine carbon emulsion of hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.The present invention has high transmission rate.
Description
Technical field
The invention belongs to technical field of coatings, relate to a kind of rare earth nano insulating mold coating for high-transparent glass and preparation method thereof.
Background technology
The paint film of the heat insulating reflecting coating using nano-indium stannum oxide (ITO) or nano antimony tin oxide (ATO) to make in the market there will be the not high problem of transparency, affects the transmitance of visible ray.
Summary of the invention
The object of the invention is to, a kind of rare earth nano insulating mold coating for high-transparent glass with high transmission rate and preparation method thereof is provided.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: a kind of rare earth nano insulating mold coating for high-transparent glass, calculate by mass percentage, by the fluorine carbon emulsion 70%-90% of hydroxyl acrylic modification, nano-indium stannum oxide water slurry (ITO) 5%-15%, pure water 5%-15%, cerium oxide 0.05%-0.2%, dispersion agent 0.1%-0.8% and film coalescence aid 0.1%-0.8% form;
Calculate by mass percentage, nano-indium stannum oxide water slurry (ITO) is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%;
Cerium oxide is nanoscale cerium;
First add the fluorine carbon emulsion of hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.
Need add solidifying agent when the present invention uses to stir, solidifying agent is the mixed solvent of HDI solidifying agent or HDI solidifying agent and propandiol butyl ether, and the ratio of coating and solidifying agent is 5:1, is then sprayed on coated article surface.
Embodiment
Embodiments of the invention: unit is kg.
Embodiment one:
Rare earth nano insulating mold coating for high-transparent glass consists of the following composition:
The fluorine carbon emulsion 70 of hydroxyl acrylic modification
Nano-indium stannum oxide water slurry 10
Pure water 18.95
Cerium oxide 0.05
Dispersion agent 0.2
Film coalescence aid 0.8
Solidifying agent consists of the following composition:
2547 (HDI solidifying agent) 40
Propandiol butyl ether 60
Nano-indium stannum oxide water slurry (ITO) is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%; In sand milling stirring dispersion machine, add deionized water, dispersion agent, wetting agent, thickening material etc. stir, add through drying nano-indium stannum oxide (ITO) powder, high speed dispersion sand milling 6 ~ 8h, obtain homogeneous, stable water slurry, pH is adjusted to be 7.5-8.0, the nano-indium stannum oxide water slurry of obtained nano-ITO content 13%.
First add the fluorine carbon emulsion of hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.
Solidifying agent need be added when the present invention uses stir.
Stir for 5:1 adds solidifying agent according to the ratio of coating and solidifying agent during use, be then sprayed on coated article surface.
Effect: gained film visible transmission compares: >=70%, sheltering coefficient: 0.75.
Embodiment two
Rare earth nano insulating mold coating for high-transparent glass consists of the following composition:
The fluorine carbon emulsion 80 of hydroxyl acrylic modification
Nano-indium stannum oxide water slurry 10
Pure water 8.9
Cerium oxide 0.1
Dispersion agent 0.2
Film coalescence aid 0.8
Solidifying agent consists of the following composition:
2547 (HDI solidifying agent) 40
Propandiol butyl ether 60
Nano-indium stannum oxide water slurry (ITO) is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%; In sand milling stirring dispersion machine, add deionized water, dispersion agent, wetting agent, thickening material etc. stir, add through drying nano-indium stannum oxide (ITO) powder, high speed dispersion sand milling 6 ~ 8h, obtain homogeneous, stable water slurry, pH is adjusted to be 7.5-8.0, the nano-indium stannum oxide water slurry of obtained nano-ITO content 13%.
First add the fluorine carbon emulsion of hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.
Solidifying agent need be added when the present invention uses stir,
Stir for 5:1 adds solidifying agent according to the ratio of coating and solidifying agent during use, be then sprayed on coated article surface.
Effect: gained film visible transmission compares: >=75%, sheltering coefficient: 0.76.
Embodiment three
Rare earth nano insulating mold coating for high-transparent glass consists of the following composition:
The fluorine carbon emulsion 85 of hydroxyl acrylic modification
Nano-indium stannum oxide water slurry 10
Pure water 3.85
Cerium oxide 0.15
Dispersion agent 0.2
Film coalescence aid 0.8
Solidifying agent consists of the following composition:
2547 (HDI solidifying agent) 40
Propandiol butyl ether 60
Nano-indium stannum oxide water slurry (ITO) is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%; In sand milling stirring dispersion machine, add deionized water, dispersion agent, wetting agent, thickening material etc. stir, add through drying nano-indium stannum oxide (ITO) powder, high speed dispersion sand milling 6 ~ 8h, obtain homogeneous, stable water slurry, pH is adjusted to be 7.5-8.0, the nano-indium stannum oxide water slurry of obtained nano-ITO content 13%.
First add the fluorine carbon emulsion of hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.
Solidifying agent need be added when the present invention uses stir,
Stir for 5:1 adds solidifying agent according to the ratio of coating and solidifying agent during use, be then sprayed on coated article surface.
Effect: gained film visible transmission compares: >=80%, sheltering coefficient: 0.77.
Embodiment four
Rare earth nano insulating mold coating for high-transparent glass consists of the following composition:
The fluorine carbon emulsion 80 of hydroxyl acrylic modification
Nano-indium stannum oxide water slurry 10
Pure water 8.8
Cerium oxide 0.2
Dispersion agent 0.2
Film coalescence aid 0.8
Solidifying agent consists of the following composition:
2547 (HDI solidifying agent) 100
Nano-indium stannum oxide water slurry (ITO) is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%; In sand milling stirring dispersion machine, add deionized water, dispersion agent, wetting agent, thickening material etc. stir, add through drying nano-indium stannum oxide (ITO) powder, high speed dispersion sand milling 6 ~ 8h, obtain homogeneous, stable water slurry, pH is adjusted to be 7.5-8.0, the nano-indium stannum oxide water slurry of obtained nano-ITO content 13%.
First add the fluorine carbon emulsion of hydroxyl acrylic modification, then add auxiliary agent, then add pure water high speed dispersion 10-20 minute, nano-indium stannum oxide water slurry and nanoscale cerium are added respectively, after sufficient dispersed with stirring is even
Stir for 5:1 adds solidifying agent according to the ratio of coating and solidifying agent during use, be then sprayed on coated article surface.
Effect: gained film visible transmission compares: >=80%, sheltering coefficient: 0.77.
Claims (2)
1. a rare earth nano insulating mold coating for high-transparent glass, it is characterized in that: calculate by mass percentage, this rare earth nano insulating mold coating for high-transparent glass is by the fluorine carbon emulsion 70%-85% of hydroxyl acrylic modification, nano-indium stannum oxide water slurry ITO5%-15%, pure water 5%-15%, cerium oxide 0.05%-0.2%, dispersion agent 0.1%-0.8% and film coalescence aid 0.1%-0.8% form;
Calculate by mass percentage, described nano-indium stannum oxide water slurry ITO is made up of nano-indium stannum oxide 13%, deionized water 83.1%-84%, dispersion agent 2%, wetting agent 0.1%, thickening material 0.2%, defoamer 0.2%, anticorrosion and bactericidal agent 0.2% and pH adjusting agent 0.2%-1%;
Described cerium oxide is nanoscale cerium.
2. the preparation method of a rare earth nano insulating mold coating for high-transparent glass as claimed in claim 1, it is characterized in that: the fluorine carbon emulsion first adding hydroxyl acrylic modification, then dispersion agent and film coalescence aid is added, add pure water again with the speed high speed dispersion 10-20 minute of 800 revs/min, nano-indium stannum oxide water slurry and cerium oxide are added respectively, stirs fully with after the Rate Dispersion 10-20 of 800 revs/min minute.
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| CN104312310B (en) * | 2014-10-16 | 2016-08-24 | 衢州市万能达清洗有限公司 | A kind of heat exchanger environmental protection and energy saving method of inhibiting corrosion |
| CN104449206A (en) * | 2014-10-23 | 2015-03-25 | 安徽省实防新型玻璃科技有限公司 | Thermal insulating sterilization type coating for glass doors and preparation method of thermal insulating sterilization type coating |
| CN104497736A (en) * | 2014-12-16 | 2015-04-08 | 深圳市东维丰电子科技股份有限公司 | Double-component transparent glass thermal-insulating coating and preparation method thereof |
| CN113817379A (en) * | 2021-09-27 | 2021-12-21 | 天津包钢稀土研究院有限责任公司 | Natural distribution lanthanum-cerium oxide reflective heat-insulation coating and preparation method thereof |
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| WO2007126432A1 (en) * | 2006-03-27 | 2007-11-08 | Georgia Tech Research Corporation | Superhydrophobic surface and method for forming same |
| CN101265031A (en) * | 2008-04-18 | 2008-09-17 | 张家港市润和科技有限公司 | Aqueous glass heat insulation paint and preparation method thereof |
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