CN102732138B - One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet - Google Patents
One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet Download PDFInfo
- Publication number
- CN102732138B CN102732138B CN201210245926.8A CN201210245926A CN102732138B CN 102732138 B CN102732138 B CN 102732138B CN 201210245926 A CN201210245926 A CN 201210245926A CN 102732138 B CN102732138 B CN 102732138B
- Authority
- CN
- China
- Prior art keywords
- dispersion
- nano
- nanometer
- powder
- dispersing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn - After Issue
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to one and shield infrared and the full wave Synolac nano transparent insulating coating of ultraviolet and preparation method, this coating comprises Synolac 35% ~ 80%, aminoresin 0 ~ 20%, nano ATO dispersion 10% ~ 30%, nanometer LaB
6dispersion 1% ~ 10%, nanometer WO
3dispersion 1% ~ 15%, flow agent 0.05% ~ 1%, defoamer 0.05% ~ 1% and solvent 5% ~ 20%.Its preparation method is: nano ATO dispersion, nanometer LaB
6dispersion, nanometer WO
3dispersion, is added drop-wise in Synolac by formulation weight ratio, dispersed with stirring 15min ~ 30min, then adds aminoresin, flow agent, defoamer and solvent, stirs and obtains nano transparent insulating coating.This coating is applicable on building glass, vehicle glass and cement surface heat insulation, both economical and practical, again can full-shield ultraviolet and infrared rays, heat-proof quality highly significant.
Description
Technical field
The present invention relates to function nano novel material, be specifically related to a kind of shield the infrared and ultraviolet of sunlight full wave, based on Synolac, the transparent heat insulating dope that is composited by multiple Nano Rare-earth Materials and metal oxide and preparation method thereof, particularly relate to a kind of transparent heat insulating dope be coated on various glass, plastics, metal and cement surface.
Background technology
China is energy consumption big country, the energy of annual consumption is equivalent to 1,500,000,000 tons of standard coals, wherein about 30% is building consumption, does not adopt the building glass of power-saving technology, when summer, the heat energy of the sun directly can be radiated city from window-glass, when winter, indoor heat can be radiated outdoor in ultrared mode again, all to maintain summer and winter indoor comfort temperature, need to be realized by air-conditioning or heating arrangement, a large amount of energy must be consumed.China's buildings unit surface energy consumption is more than 3 times of western developed country, and glass port energy waste accounts for about 50% of whole building energy consumption, namely the annual energy by glass port loss about 2.25 hundred million tons of standard coals, are equivalent to 21 pipe of reinforced concrete at Three Gorges Power Station annual electricity generating capacities.Simultaneously along with Economic development and growth in the living standard, air-conditioning, heating installation amount constantly increase, and the ratio of building energy consumption just constantly rises.And high performance selectively masking material can make glass have selectivity through function to spectrum, can through most of visible ray under not affecting the prerequisite of daylighting, infrared light, far red light, UV-light can be stopped again, block thermal radiation, thus reduce the energy consumption of air-conditioning or heating arrangement, reach energy-conservation object.
The radiation wave band scope that the sun arrives ground is approximately 200nm ~ 2500nm, wherein 200nm ~ 400nm is ultraviolet, 400nm ~ 800nm is visible ray, 800nm ~ 2500nm is near infrared ray, and near infrared can be divided into short wavelength-NIR (800nm ~ 1100nm) and long wave near infrared (1100nm ~ 2500nm), human eye only has direct perception to visible ray, so will reach energy-conservation object, just need to shield infrared rays and ultraviolet as much as possible, allow visible light-transmissive only.
Multiple Nano Rare-earth Materials is due to its special construction, there is higher taboo bandwidth sum conductivity, thus there are the photoelectric properties of a series of uniqueness, different Nano Rare-earth Materials has higher transmitance in visible region, but the infrared rays of different Nano Rare-earth Materials to different-waveband has different reflectivity, can absorb ultraviolet again, be excellent spectral correctiontechnique simultaneously.
ITO, ATO are as shielding material for the many employings of existing transparent heat-insulated technology, but this bi-material can only have shielding effect to long wave near infrared, does not significantly intercept short wavelength-NIR and ultraviolet, so energy-saving effect is limited.
Summary of the invention
In order to overcome above shortcoming, the invention provides the transparent heat insulating dope that a kind of transparent heat-insulated composite nano material system be made up of nano rare earth, metal oxide is completely newly prepared from, nano material after composite, it all has good shield effectiveness to whole near infrared ray of solar radiation and ultraviolet, thus greatly improves energy-saving effect.
In nano material selected by the present invention, nano antimony tin oxide is at 1300nm ~ 2500nm(long wave near infrared ray) between have good shielding effect; Nanometer lanthanum hexaborane is at 200nm ~ 400nm(ultraviolet) and 800nm ~ 1300nm(short wavelength-NIR line) there is extraordinary shielding effect, but can not absorb too many visible ray; Nanometer tungsten oxide to human body have harm, wavelength is at 200nm ~ 400nm, electromagnetic radiation X-ray between ultraviolet and gamma-rays has good shielding effect, simultaneous oxidation tungsten all has certain shielding effect to long wave, short wavelength-NIR line, high to visible light transmissivity, therefore, in order to shield all ultraviolets and near infrared ray, reach high visible light transmissivity again, above-mentioned three kinds of materials are composite in proportion can very perfectly reach this object simultaneously.
The present invention adopts three kinds of composite Nano rare earths, metal oxide is insulation agent, can shield all ultraviolets and near infrared ray; Employing synthetic alkyd resin is film forming matter, improve the hardness of film, gloss, sticking power, the transparency and weathering resistance, propose and a kind ofly economical and practical there is again excellent thermal insulation and the nano transparent insulating coating be coated on various building glass, vehicle glass, resin, plastics, metal and cement surface of good transparency.
In order to solve technical problem recited above, the present invention takes following technical scheme: the present invention relates to one and shield the infrared and full wave Synolac nano transparent insulating coating of ultraviolet, by weight percentage, its basic recipe is: Synolac 35% ~ 80%, aminoresin 0 ~ 20%, nano ATO dispersion 10% ~ 30%, nanometer LaB
6dispersion 1% ~ 10%, nanometer WO
3dispersion 1% ~ 15%, flow agent 0.05% ~ 1%, defoamer 0.05% ~ 1% and solvent 5% ~ 20%.
Wherein, Synolac of the present invention selects the combination of one or more of the long oil alkyd of good weatherability, medium oil alkyd, short oil-ity alcohol acid resin or modified alkyd resin.
Aminoresin selects propyl carbinol etherified amino resins or isopropylcarbinol etherified amino resins.
Nano ATO dispersion selects the nano ATO solvent slurry that particle diameter is 30nm ~ 80nm, solid content is 15% ~ 30%.
Nanometer LaB
6dispersion selects that particle diameter is 30nm ~ 80nm, solid content is the nanometer LaB of 15% ~ 30%
6solvent slurry.
Nanometer WO
3dispersion selects that particle diameter is 30nm ~ 80nm, solid content is the nanometer WO of 15% ~ 30%
3solvent slurry.
Flow agent selects the combination of one or more of acrylate copolymer, fluorine richness acrylate copolymer or Siloxane-Oxyalkylene Copolymers polymkeric substance.
Defoamer selects non-silicon ketofatty acid polymkeric substance, modified polypropene acid polymer, Soxylat A 25-7 or modified polyorganosiloxane.
The combination of one or more of alcohols, ester class, ketone, hydro carbons and ether organic solvent selected by solvent.
Nano ATO dispersion of the present invention, nanometer LaB
6dispersion, nanometer WO
3dispersion, its basic recipe is: nano-powder 15% ~ 30%, dispersion agent 2% ~ 12%, solvent 40% ~ 70%.Wherein dispersion agent of the present invention is polynary acid group copolymer dispersion agent, macromolecule polyurethane block copolymer dispersant and the combination of one or more containing negatively charged ion affinity groups polyester copolymer dispersion agent; The combination of one or more of alcohols, ester class, hydro carbons and ether organic solvent selected by solvent.
Nano-dispersed preparation process of the present invention is as follows: by formulation weight percentages, the solvent, the dispersion agent that add formula ratio successively stir, then slowly nano-powder is added while stirring, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is approximately 13h ~ 15h, obtains that solid content is 15% ~ 30%, median (D50) is at 40nm ~ 80nm nano pulp.The Nanodispersion of this technique dispersion preparation, particle size distribution is even, and highly stable, and long preservative period under normal temperature, all has good consistency with most film-forming resin.
The shielding of the present invention's one is infrared and ultraviolet full wave Synolac nano transparent insulating coating preparation technology is as follows: by formulation weight percentages, obtained nano ATO dispersion, nanometer LaB6 dispersion, nanometer WO3 dispersion, be added drop-wise in Synolac by formulation weight than successively, dispersed with stirring 15min ~ 30min, add aminoresin, flow agent, defoamer and solvent by formula rate again, be uniformly mixed filtration i.e. obtained one and shield the infrared and full wave Synolac nano transparent insulating coating of ultraviolet.
Principle of the present invention: all ultraviolets and near infrared composite nano materials can be shielded be coated in glass (or other ground) surface by having by a kind of carrier, thus make glass (or other ground) have heat insulating function, there are again high visible light transmissivity, full-shield ultraviolet and infrared rays, high adhesive force and hardness, excellent weathering resistance.
Result of implementation of the present invention: with reference to concerned countries standard, the fundamental property of nano transparent insulating coating of the present invention is detected, result shows the coating hardness that coating of the present invention formed can reach 4H level, and sticking power is 0 grade, and thermotolerance, water tolerance, weathering resistance are good.The present invention adopts nano ATO/WO
3/ LaB
6compound system is as the UV-visible-infrared of the heat insulating coat of lagging material through spectrum, and light transmission average transmittances in visible-range is greater than 80%; Transmitance at 380nm ~ 400nm place is 0%, and the transmitance at 800nm ~ 1000nm place is 1%, and the transmitance at 1000nm ~ 2000nm place is 2%, that is, coating intercepts ultraviolet and infrared rays completely, only has visible light-transmissive coating, so effect of heat insulation highly significant.If compare with the heat-proof quality of blank glass, the glass then scribbling composite Nano transparent heat insulating dope detects that the temperature in test box reduces by 10 DEG C ~ 13 DEG C, and therefore composite Nano transparent heat insulating dope of the present invention has strong adhesion, hardness is high, transmittance good, the feature of full-shield ultraviolet and infrared rays and heat-proof quality highly significant.
Accompanying drawing explanation
Fig. 1 is that the thermal insulating coating of the embodiment of the present invention contrasts schematic diagram with the UV-visible-infrared adopting the nano transparent insulating coating of ATO lagging material to apply the rear coating formed on the market through spectrum.
Embodiment
Describe the present invention below in conjunction with embodiment, but the invention is not restricted to given example.
Nano ATO dispersion technique of the present invention is as follows: dimethylbenzene 30%, Virahol 36%, dispersion agent (BYK-111) 2%, dispersion agent (Tech-6202) 7%, nano ATO powder 25%.Add the solvent of formula ratio, dispersion agent stirring successively, then slowly nano-powder is added while stirring, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is approximately 13h ~ 15h, obtains the nano ATO dispersion that median at about 75nm, solid content is 25%.
Nanometer LaB of the present invention
6dispersion technique is as follows: dimethylbenzene 30%, Virahol 42%, dispersion agent (BYK-111) 2%, dispersion agent (HSM-7161) 6%, nanometer LaB
6powder 20%.Add the solvent of formula ratio, dispersion agent stirring successively, then slowly nano-powder is added while stirring, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is approximately 13h ~ 15h, and obtaining median at about 70nm, solid content is the nanometer LaB of 20%
6dispersion.
Nanometer WO of the present invention
3dispersion technique is as follows: Virahol 75%, dispersion agent (Solseperse20000 or Tech-5163HC) 5%, nanometer WO
3powder 20%.Add the solvent of formula ratio, dispersion agent stirring successively, then slowly nano-powder is added while stirring, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is approximately 13h ~ 15h, and obtaining median at about 75nm, solid content is the nanometer WO of 20%
3dispersion.
Prepare material according to the component formula of table 1 to implement.
Table 1: four embodiment component formula mass parts
| Material name | Example 1 | Example 2 | Example 3 | Example 4 |
| Long oil alkyd | 50 | 50 | — | — |
| Short oil-ity alcohol acid resin | — | — | 50 | — |
| Modified alkyd resin | — | — | — | 55 |
| Butanol etherification aminoresin | 15 | — | 12 | 10 |
| Isopropylcarbinol etherified amino resins | — | 15 | — | — |
| 25% nano ATO dispersion | 15 | 15 | 18 | 15 |
| 20% nanometer LaB 6Dispersion | 3 | 3 | 3 | 3 |
| 20% nanometer WO 3Dispersion | 7 | 7 | 8 | 7 |
| Flow agent BYK-306 | 0.2 | 0.2 | 0.2 | 0.2 |
| Adhesion promoter | 0.5 | 0.5 | 0.5 | 0.2 |
| Defoamer | 0.3 | 0.3 | 0.3 | 0.3 |
| Mixed solvent | 9.0 | 9.0 | 8.0 | 9.3 |
embodiment 1:
In paint mixing bucket, first add Synolac according to example in table 11 formula ratio, then stir and slowly drip nano ATO dispersion, nanometer LaB
6dispersion, nanometer WO
3dispersion, dispersed with stirring 20min ~ 30min, add aminoresin, flow agent, adhesion promoter, defoamer and solvent by formula ratio again, be uniformly mixed rear filtration i.e. obtained one and shield the infrared and full wave Synolac nano transparent insulating coating of ultraviolet.
Embodiment 2, embodiment 3, embodiment 4 preparation technology is with reference to embodiment 1.
According to relevant national standard, detect the fundamental property of nanometer transparent Synolac thermal insulating coating of the present invention, test result is as shown in table 2.
Table 2 nanometer transparent Synolac thermal insulating coating fundamental property test result
| Test event | Test result | Testing standard |
| Paint film appearance, color | Micro-indigo plant, transparent, smooth | GB1927-79 |
| Hardness (pencil) | ≥4H | GB/T6739-1996 |
| Sticking power, level (drawing circle method) | 0 | GB/T1720-79 |
| Shock strength, cm | 50 | GB/T1732-93 |
| Snappiness, mm | 2 | GB/T1731-93 |
| Water tolerance, immersion 48h | Without considerable change | GB/T1733-93 |
| Thermotolerance, 100 DEG C of baking 3h | Paint film without bubbling, wrinkling, cracking, variable color | GB/T1735-79 |
The present invention adopts nano ATO/WO
3/ LaB
6compound system contrasts through spectrum with the UV-visible-infrared adopting the nano transparent insulating coating of ATO lagging material to apply the rear coating formed on the market as the nano transparent insulating coating of lagging material, as shown in Figure 1, wherein, lower curve is the curve of nano ATO/WO3/LaB6 Synolac transparent heat insulating dope; Upper curve is the curve of common nano ATO transparent heat insulating dope, coating light transmission of the present invention in visible-range average transmittances about 70%, transmitance at 200nm ~ 380nm place is 0%, transmitance at 800nm ~ 2000nm place is 1%, that is, coating intercepts ultraviolet and infrared rays completely, only has visible light-transmissive coating, so effect of heat insulation highly significant.If compare with the heat-proof quality of blank glass, the glass then scribbling composite Nano transparent heat insulating dope detects that the temperature-averaging in test box reduces by 12 DEG C, and therefore composite Nano transparent heat insulating dope of the present invention has strong adhesion, hardness is high, transmittance good, the feature of full-shield ultraviolet and infrared rays and heat-proof quality highly significant.
Although the present invention has been explained in detail and has quoted embodiment as proof, for those of ordinary skill in the art, the various schemes obviously can made according to above-mentioned explanation, amendment and change, within the scope that all should be included in claim.
Claims (5)
1. one kind shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet, it is characterized in that: by weight percentage, it consists of: long oil alkyd 50.0%, butanol etherification aminoresin 15.0%, nano ATO dispersion 15.0%, nanometer LaB
6dispersion 3.0%, nanometer WO
3dispersion 7.0%, BYK-306 flow agent 0.2%, adhesion promoter 0.5%, defoamer 0.3%, mixed solvent 9.0%;
Wherein, described nano ATO dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 36%, BYK-111 wetting dispersing agent 2%, Tech-6202 wetting dispersing agent 7%, nano ATO powder 25%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains the nano ATO dispersion that particle diameter is 30nm-80nm, solid content is 25%;
Described nanometer LaB
6dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 42%, BYK-111 wetting dispersing agent 2%, HSM-7161 wetting dispersing agent 6%, nanometer LaB
6powder 20%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer LaB of 20%
6dispersion;
Described nanometer WO
3dispersion, by weight percentage, it consists of: Virahol 75%, Solseperse20000 or Tech-5163HC wetting dispersing agent 5%, nanometer WO
3powder 20%; Its preparation technology is as follows: by formula ratio successively solvent, wetting dispersing agent stirring, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer WO of 20%
3dispersion.
2. one kind shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet, it is characterized in that: by weight percentage, it consists of: long oil alkyd 50.0%, isopropylcarbinol etherified amino resins 15.0%, nano ATO dispersion 15.0%, nanometer LaB
6dispersion 3.0%, nanometer WO
3dispersion 7.0%, BYK-306 flow agent 0.2%, adhesion promoter 0.5%, defoamer 0.3%, mixed solvent 9.0%;
Wherein, described nano ATO dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 36%, BYK-111 wetting dispersing agent 2%, Tech-6202 wetting dispersing agent 7%, nano ATO powder 25%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains the nano ATO dispersion that particle diameter is 30nm-80nm, solid content is 25%;
Described nanometer LaB
6dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 42%, BYK-111 wetting dispersing agent 2%, HSM-7161 wetting dispersing agent 6%, nanometer LaB
6powder 20%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer LaB of 20%
6dispersion;
Described nanometer WO
3dispersion, by weight percentage, it consists of: Virahol 75%, Solseperse20000 or Tech-5163HC wetting dispersing agent 5%, nanometer WO
3powder 20%; Its preparation technology is as follows: by formula ratio successively solvent, wetting dispersing agent stirring, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer WO of 20%
3dispersion.
3. one kind shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet, it is characterized in that: by weight percentage, it consists of: short oil-ity alcohol acid resin 50.0%, butanol etherification aminoresin 12.0%, nano ATO dispersion 18.0%, nanometer LaB
6dispersion 3.0%, nanometer WO
3dispersion 8.0%, BYK-306 flow agent 0.2%, adhesion promoter 0.5%, defoamer 0.3%, mixed solvent 8.0%;
Wherein, described nano ATO dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 36%, BYK-111 wetting dispersing agent 2%, Tech-6202 wetting dispersing agent 7%, nano ATO powder 25%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains the nano ATO dispersion that particle diameter is 30nm-80nm, solid content is 25%;
Described nanometer LaB
6dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 42%, BYK-111 wetting dispersing agent 2%, HSM-7161 wetting dispersing agent 6%, nanometer LaB
6powder 20%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer LaB of 20%
6dispersion;
Described nanometer WO
3dispersion, by weight percentage, it consists of: Virahol 75%, Solseperse20000 or Tech-5163HC wetting dispersing agent 5%, nanometer WO
3powder 20%; Its preparation technology is as follows: by formula ratio successively solvent, wetting dispersing agent stirring, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer WO of 20%
3dispersion.
4. shield the infrared and full wave Synolac nano transparent insulating coating of ultraviolet, it is characterized in that: by weight percentage, it consists of: modified alkyd resin 55.0%, butanol etherification aminoresin 10.0%, nano ATO dispersion 15.0%, nanometer LaB
6dispersion 3.0%, nanometer WO
3dispersion 7.0%, BYK-306 flow agent 0.2%, adhesion promoter 0.2%, defoamer 0.3%, mixed solvent 9.3%;
Wherein, described nano ATO dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 36%, BYK-111 wetting dispersing agent 2%, Tech-6202 wetting dispersing agent 7%, nano ATO powder 25%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains the nano ATO dispersion that particle diameter is 30nm-80nm, solid content is 25%;
Described nanometer LaB
6dispersion, by weight percentage, it consists of: dimethylbenzene 30%, Virahol 42%, BYK-111 wetting dispersing agent 2%, HSM-7161 wetting dispersing agent 6%, nanometer LaB
6powder 20%; Its preparation technology is as follows: add solvent, wetting dispersing agent stirring successively by formula ratio, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer LaB of 20%
6dispersion;
Described nanometer WO
3dispersion, by weight percentage, it consists of: Virahol 75%, Solseperse20000 or Tech-5163HC wetting dispersing agent 5%, nanometer WO
3powder 20%; Its preparation technology is as follows: by formula ratio successively solvent, wetting dispersing agent stirring, then under agitation slowly nano-powder is added, high speed dispersion 30min after powder adds, open nano-level grinder, carry out circular grinding, milling time is 13 ~ 15h, obtains that particle diameter is 30nm-80nm, solid content is the nanometer WO of 20%
3dispersion.
5. the infrared and full wave Synolac nano transparent insulating coating of ultraviolet of one shielding as described in claim 1,2,3 or 4, is characterized in that: described defoamer is at least one of non-silicon ketofatty acid polymkeric substance, modified polypropene acid polymer, Soxylat A 25-7 or modified polyorganosiloxane; Described mixed solvent is the combination of one or more of alcohols, ester class, ketone, hydro carbons, ether organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210245926.8A CN102732138B (en) | 2012-07-16 | 2012-07-16 | One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210245926.8A CN102732138B (en) | 2012-07-16 | 2012-07-16 | One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102732138A CN102732138A (en) | 2012-10-17 |
| CN102732138B true CN102732138B (en) | 2016-01-27 |
Family
ID=46988462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210245926.8A Withdrawn - After Issue CN102732138B (en) | 2012-07-16 | 2012-07-16 | One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102732138B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103387762B (en) * | 2013-08-13 | 2015-07-08 | 武汉羿阳科技有限公司 | Solvent type transparent nanometer thermal insulation sizing agent and application method thereof |
| CN103992706A (en) * | 2014-04-14 | 2014-08-20 | 马鞍山博诺环保科技有限公司 | Intelligent temperature control all-band-shielding nanometer transparent thermal insulation coating material and preparation process thereof |
| WO2016121842A1 (en) * | 2015-01-27 | 2016-08-04 | 住友金属鉱山株式会社 | Near-infrared ray absorbing microparticle dispersion solution, production method thereof, counterfeit-preventing ink composition using said near-infrared ray absorbing microparticle dispersion solution, and anti-counterfeit printed matter using said near-infrared ray absorbing microparticles |
| CN106085096A (en) * | 2016-07-25 | 2016-11-09 | 吴舒晨 | A kind of based on amino resins creep into drilling rod protective coating and preparation method thereof |
| CN109486380A (en) * | 2018-09-27 | 2019-03-19 | 合众（佛山）化工有限公司 | A kind of PEEK acid modified alcoholic full-shield infrared ray and ultraviolet light water transparent heat insulation paint |
| CN113087966B (en) * | 2021-03-30 | 2022-04-26 | 浙江华帅特新材料科技有限公司 | Infrared absorber dispersion liquid, transparent heat-insulating organic glass and method for producing the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101835647A (en) * | 2007-10-23 | 2010-09-15 | 住友金属矿山株式会社 | Solar-radiation-shielding material for vehicle window and window for vehicle |
| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
| CN102559025A (en) * | 2011-11-18 | 2012-07-11 | 上海沪正纳米科技有限公司 | Preparation method for high-performance transparent glass heat-insulating coating |
-
2012
- 2012-07-16 CN CN201210245926.8A patent/CN102732138B/en not_active Withdrawn - After Issue
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101835647A (en) * | 2007-10-23 | 2010-09-15 | 住友金属矿山株式会社 | Solar-radiation-shielding material for vehicle window and window for vehicle |
| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101899249A (en) * | 2009-05-25 | 2010-12-01 | 上海复甲新型材料科技有限公司 | Transparent thermal insulation anti-ultraviolet coating and preparation method thereof |
| CN102559025A (en) * | 2011-11-18 | 2012-07-11 | 上海沪正纳米科技有限公司 | Preparation method for high-performance transparent glass heat-insulating coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102732138A (en) | 2012-10-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102746781B (en) | Full-shielded infrared and ultraviolet polyurethane nanometer transparent heat insulating coating | |
| CN102732138B (en) | One shields the infrared and full wave Synolac nano transparent insulating coating of ultraviolet | |
| CN102732108B (en) | Aqueous self-cleaning transparent heat-insulated nano-dope capable of fully shielding infrared ray and ultraviolet ray | |
| CN102732144B (en) | A kind of water-based ultraviolet (UV) curable full-shield nano transparent insulating coating | |
| CN101186781B (en) | Transparent heat insulating dope and preparation method thereof | |
| CN105778608B (en) | A kind of graphene composite coating and preparation method thereof | |
| CN101550307A (en) | Transparent heat insulation coating material, preparation method and application thereof | |
| CN103387787A (en) | Organic/inorganic hybrid transparent heat-insulating coating material, and preparation method and application thereof | |
| CN103351757A (en) | Water-based transparent heat-insulating paint used for energy-saving doors and windows and preparation method thereof | |
| CN106700788A (en) | Nano environment-friendly and heat insulation transparent paint and preparation method thereof | |
| CN101445330A (en) | Transparent antiultraviolet glass paint | |
| CN102277058A (en) | Compound deep color water-based insulating exterior wall coating and preparation method thereof | |
| CN101519561A (en) | Method for preparing ultraviolet-screening, transparent, heat-insulation paint | |
| CN101550312A (en) | Transparent heat insulation coating of alkyd resin glass | |
| CN103992706A (en) | Intelligent temperature control all-band-shielding nanometer transparent thermal insulation coating material and preparation process thereof | |
| CN102993873B (en) | A kind of inner wall heat-preservation coating | |
| CN104275884A (en) | Heat insulation, thermal insulation, yellowing resistant transparent energy-saving plate and preparation method thereof | |
| CN105419531A (en) | Preparing method of superhigh-sunshine reflectance ratio coating | |
| CN113527928B (en) | Glass heat-insulating coating with high visible light transmittance and high infrared barrier rate | |
| CN104861762B (en) | A kind of clear glass heat-barrier material and its application | |
| CN103013262B (en) | A kind of inner wall heat-preservation coating | |
| CN109385163B (en) | PEEK modified acrylic acid water-based transparent heat-insulating coating capable of fully shielding infrared rays and ultraviolet rays | |
| CN104479481A (en) | Waterborne self-crosslinking acrylic resin thermal-insulation coating and preparation method thereof | |
| CN103102756B (en) | A kind of inner wall heat-preservation coating | |
| CN103013260B (en) | A kind of inner wall heat-preservation coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20160127 Effective date of abandoning: 20170522 |
|
| AV01 | Patent right actively abandoned |