CN104341914A - Dirt-resistant mold-resistant paint for glass doors and preparation method thereof - Google Patents

Dirt-resistant mold-resistant paint for glass doors and preparation method thereof Download PDF

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Publication number
CN104341914A
CN104341914A CN201410537677.9A CN201410537677A CN104341914A CN 104341914 A CN104341914 A CN 104341914A CN 201410537677 A CN201410537677 A CN 201410537677A CN 104341914 A CN104341914 A CN 104341914A
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water
emulsion
parts
paint
resistance
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Chinese (zh)
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张波
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FENGYANG HUIHENG TRADE Co Ltd
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FENGYANG HUIHENG TRADE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a dirt-resistant mold-resistant paint for glass doors. The invention is characterized in that the paint is prepared from the following raw materials in parts by weight: 45-54 parts of water-based acrylic acid emulsion, 12-14 parts of water-based fluorocarbon emulsion resin, 8-12 parts of modified styrene acrylic emulsion, 1-2 parts of water-based wax emulsion, 0.3-0.5 part of polyoxyethylene laurel ether, 0.2-0.4 part of amide stearate, 1-3 parts of dipropanediol monopropyl ether, 0.3-0.6 part of alkylol amine dipyrophosphoryl oxy hydroxy acetate titanate, 0.3-0.5 part of leveling agent BYK-3100, 0.3-0.6 part of propyl trimethoxy siloxane, 0.2-0.4 part of laurinol phenylacetate, 0.2-0.4 part of polyvinylpyrrolidone, 0.3-0.5 part of crystal whisker silicon, 0.5-1.0 part of hydroxy benzoyl propyl ester, 1-2 parts of pigment and 10-15 parts of deionized water. The water-based paint has the characteristics of excellent weather resistance, excellent water resistance, excellent dirt resistance, excellent mold resistance, excellent chemical resistance and the like; and the added modified styrene-acrylic emulsion enhances the bactericidal, dust-proof and antistatic actions of the paint. The paint is a pure water-based green safe environment-friendly paint, is harmless to human health, has the characteristics of no environmental pollution and favorable properties, and is worthy of popularization.

Description

A kind of resistance to mould glass door coating and preparation method thereof that bears dirty
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of resistance to mould glass door coating and preparation method thereof that bears dirty.
Background technology
Along with the raising day by day of people's living standard, the pursuit of people to U.S. is more and more stronger, glass partition, glass bathrooms etc. will use glass door, as home decoration glass and glasswork, the demand in market is met with its distinctive gorgeous colorful decorative effect, but along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified, because current glass paint is mostly solvent based coating, the benzene to human body and bad environmental need be used during application, toluene, ethyl acetate etc. are containing benzene solvent, in addition, the bonding strength of some coating is low, less to the sticking power of various glass material product, and easily come off, duration of service is not long.Glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, aqueous glass paint has that better sticking power is good, ageing resistance is good, water tolerance and the advantage such as resistance to alcohol acidity is good, and safety and environmental protection, not containing objectionable impuritiess such as free TDI, benzene, toluene, ethyl acetate, can not damage HUMAN HEALTH, be brand-new environmental protection low-toxicity product.
Summary of the invention
The object of this invention is to provide a kind of resistance to mould glass door coating and preparation method thereof that bears dirty.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of resistance to mould glass door coating that bears dirty, be made up of the raw material of following weight part: aqueous acrylic emulsion 48-54, water-base fluorocarbon emulsion resin 12-14, modification propyl benzene emulsion 8-12, water-borne wax emulsion 1-2, polyoxyethylene laurel ether 0.3-0.5, stearic amide 0.2-0.4, dipropylene glycol monopropyl ether 1-3, hydramine two pyrophosphoryl oxygen base oxyacetate titanate 0.3-0.6, flow agent BYK-3100.3-0.5, propyl trimethoxy siloxanes 0.3-0.6, Laurate alcohol ester phenylacetate 0.2-0.4, polyvinylpyrrolidone 0.2-0.4, silicon whisker 0.3-0.5, oxybenzene first propyl ester 0.5-1.0, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
A kind of resistance to mould glass door coating that bears dirty of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, oxybenzene first propyl ester, polyoxyethylene laurel ether, stearic amide, Laurate alcohol ester phenylacetate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, propyl trimethoxy siloxanes, polyvinylpyrrolidone stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous acrylic emulsion, water-base fluorocarbon emulsion resin, modification propyl benzene emulsion stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine two pyrophosphoryl oxygen base oxyacetate titanate, water-borne wax emulsion, pigment, silicon whisker uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
The invention has the advantages that: water-borne coatings of the present invention has the performance characteristics such as excellent weathering resistance, water tolerance, stain resistance, mildew resistance and chemical-resistant, the modifying cinepazid emulsion added improves the sterilization of coating, dust-proof, anlistatig effect, coating of the present invention is the green safety environmental protection coating material of water-based, be harmful to human health, environmentally safe, excellent property, is worthy to be popularized.
specific embodiments
Below by specific examples, the present invention is described in detail.
Bear dirty a resistance to mould glass door coating, is made up of the raw material of following weight part (kilogram): aqueous acrylic emulsion 52, water-base fluorocarbon emulsion resin 13, modification propyl benzene emulsion 10, water-borne wax emulsion 1, polyoxyethylene laurel ether 0.4, stearic amide 0.3, dipropylene glycol monopropyl ether 3, hydramine two pyrophosphoryl oxygen base oxyacetate titanate 0.4, flow agent BYK-3100.3, propyl trimethoxy siloxanes 0.3, Laurate alcohol ester phenylacetate 0.3, polyvinylpyrrolidone 0.4, silicon whisker 0.5, oxybenzene first propyl ester 0.8, pigment 2, deionized water 15;
Described modifying cinepazid emulsion is made up of the raw material of following weight part (kilogram): silane coupling agent KH5700.5, nano titanium oxide 3, nano zine oxide 2, vinylbenzene 26, butyl acrylate 52, methacrylic acid 12, N, N'-methylene-bisacrylamide 0.5, sodium lauryl sulphate 2, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 10, ammonium persulphate 0.5, ethyl acetate 15, distilled water 130; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
A kind of resistance to mould glass door coating that bears dirty of the present invention, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, oxybenzene first propyl ester, polyoxyethylene laurel ether, stearic amide, Laurate alcohol ester phenylacetate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, propyl trimethoxy siloxanes, polyvinylpyrrolidone stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous acrylic emulsion, water-base fluorocarbon emulsion resin, modification propyl benzene emulsion stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine two pyrophosphoryl oxygen base oxyacetate titanate, water-borne wax emulsion, pigment, silicon whisker uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Paint adhesion experiment (frame method) of the present invention≤1 grade, water tolerance experiment (600h) is without exception, hardness of paint film is 5H, artificial ageing resistance experiment >=800 hours is without exception, and resistance to boiling water experiment >=24 are hour unchanged, and salt fog resistance experiment >=24 hours is unchanged, abrasion resistance is tested 10000 times and is passed through, paint film without breakage, alcohol resistance experiment >=24 hours unchanged, cut resistance test 1 grade.

Claims (2)

1. the resistance to mould glass door coating that bears dirty, it is characterized in that, be made up of the raw material of following weight part: aqueous acrylic emulsion 48-54, water-base fluorocarbon emulsion resin 12-14, modification propyl benzene emulsion 8-12, water-borne wax emulsion 1-2, polyoxyethylene laurel ether 0.3-0.5, stearic amide 0.2-0.4, dipropylene glycol monopropyl ether 1-3, hydramine two pyrophosphoryl oxygen base oxyacetate titanate 0.3-0.6, flow agent BYK-3100.3-0.5, propyl trimethoxy siloxanes 0.3-0.6, Laurate alcohol ester phenylacetate 0.2-0.4, polyvinylpyrrolidone 0.2-0.4, silicon whisker 0.3-0.5, oxybenzene first propyl ester 0.5-1.0, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use; The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
2. a kind of resistance to mould glass door coating that bears dirty according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, oxybenzene first propyl ester, polyoxyethylene laurel ether, stearic amide, Laurate alcohol ester phenylacetate mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds dipropylene glycol monopropyl ether, propyl trimethoxy siloxanes, polyvinylpyrrolidone stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds aqueous acrylic emulsion, water-base fluorocarbon emulsion resin, modification propyl benzene emulsion stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds hydramine two pyrophosphoryl oxygen base oxyacetate titanate, water-borne wax emulsion, pigment, silicon whisker uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
CN201410537677.9A 2014-10-14 2014-10-14 Dirt-resistant mold-resistant paint for glass doors and preparation method thereof Pending CN104341914A (en)

Priority Applications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105820288A (en) * 2016-05-12 2016-08-03 上海保立佳新材料有限公司 Styrene-acrylic emulsion for building sealant and preparation method of styrene-acrylic emulsion
CN106346576A (en) * 2016-08-25 2017-01-25 阜南县永兴工艺品有限公司 High-weather-resistance straw treatment fluid and preparation method thereof
CN106380950A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Ultrahigh-durability fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106566442A (en) * 2016-10-28 2017-04-19 天长市永泰密封材料有限公司 Dustproof stain-resistant container water-based sealant and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH055076A (en) * 1990-12-14 1993-01-14 Nippon Paint Co Ltd Pigment dispersion base composition
CN101629031A (en) * 2009-08-17 2010-01-20 湖北大学 Photocatalytic functional coating and preparation method thereof
CN102212280A (en) * 2010-04-01 2011-10-12 东洋油墨制造股份有限公司 Antistatic coating composition
CN102585617A (en) * 2012-01-10 2012-07-18 江苏科技大学 Fluorocarbon modified styrene-acrylic coating, and preparation method thereof
CN103554348A (en) * 2013-10-23 2014-02-05 广东轻工职业技术学院 Polymer and preparation method and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH055076A (en) * 1990-12-14 1993-01-14 Nippon Paint Co Ltd Pigment dispersion base composition
CN101629031A (en) * 2009-08-17 2010-01-20 湖北大学 Photocatalytic functional coating and preparation method thereof
CN102212280A (en) * 2010-04-01 2011-10-12 东洋油墨制造股份有限公司 Antistatic coating composition
CN102585617A (en) * 2012-01-10 2012-07-18 江苏科技大学 Fluorocarbon modified styrene-acrylic coating, and preparation method thereof
CN103554348A (en) * 2013-10-23 2014-02-05 广东轻工职业技术学院 Polymer and preparation method and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105820288A (en) * 2016-05-12 2016-08-03 上海保立佳新材料有限公司 Styrene-acrylic emulsion for building sealant and preparation method of styrene-acrylic emulsion
CN106346576A (en) * 2016-08-25 2017-01-25 阜南县永兴工艺品有限公司 High-weather-resistance straw treatment fluid and preparation method thereof
CN106380950A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Ultrahigh-durability fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106566442A (en) * 2016-10-28 2017-04-19 天长市永泰密封材料有限公司 Dustproof stain-resistant container water-based sealant and preparation method thereof

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Application publication date: 20150211