CN104356846A - Low-temperature cured water-based paint with good adhesion and for glass door as well as preparation method of water-based paint - Google Patents
Low-temperature cured water-based paint with good adhesion and for glass door as well as preparation method of water-based paint Download PDFInfo
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- CN104356846A CN104356846A CN201410537598.8A CN201410537598A CN104356846A CN 104356846 A CN104356846 A CN 104356846A CN 201410537598 A CN201410537598 A CN 201410537598A CN 104356846 A CN104356846 A CN 104356846A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Inorganic Chemistry (AREA)
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Abstract
The invention discloses low-temperature cured water-based paint with good adhesion and for a glass door. The low-temperature cured water-based paint is characterized by being prepared from raw materials in parts by weight as follows: 28-32 parts of self-crosslinking water soluble acrylic acid resin, 30-33 parts of water soluble phenolic resin, 0.1-0.3 parts of liquid paraffin, 8-12 parts of modified propyl benzene emulsion, 0.6-1.2 parts of adipic dihydrazide, 1-2 parts of diacetone acrylamide, 1-3 parts of propanediol phenyl ether, 0.2-0.5 parts of bis (P, P-bis-ethylhexyl diphosphato) ethanediolato titanate, 0.3-0.5 parts of the leveling agent BYK-56, 0.3-0.5 parts of polypropylene oxide glycol, 0.3-0.5 parts of methyl 4-hydroxybenzoate, 1-2 parts of butylene glycol, 0.5-1.0 part of acetylene glycol, 0.2-0.5 parts of calcium carbonate, 0.2-0.3 parts of zinc oxide, 0.2-0.4 parts of an ultraviolet absorber, 1-2 parts of pigment and 10-15 parts of deionized water. The added modified propyl benzene emulsion of the water-based paint has the functions of sterilization, dust prevention, antistatic effect and the like; added adipic dihydrazide and diacetone acrylamide are subjected to cross-linking and curing at the room temperature, and the adhesion of the paint and the hardness of a paint film are improved; and the paint has excellent endurance capacity for a liquid such as water, ethanol and the like, does not contain a solvent such as benzene, ethyl acetate and the like or heavy metal, does not have bad odor and is green and environment-friendly, the cost is low, and a preparation method is simple.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, glass door use coating that particularly a kind of low-temperature curing sticking power is good and preparation method thereof.
Background technology
Along with the raising day by day of people's living standard, the pursuit of people to U.S. is more and more stronger, glass partition, glass bathrooms etc. will use glass door, as home decoration glass and glasswork, the demand in market is met with its distinctive gorgeous colorful decorative effect, but along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified, because current glass paint is mostly solvent based coating, the benzene to human body and bad environmental need be used during application, toluene, ethyl acetate etc. are containing benzene solvent, in addition, the bonding strength of some coating is low, less to the sticking power of various glass material product, and easily come off, duration of service is not long.Glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, aqueous glass paint has that better sticking power is good, ageing resistance is good, water tolerance and the advantage such as resistance to alcohol acidity is good, and safety and environmental protection, not containing objectionable impuritiess such as free TDI, benzene, toluene, ethyl acetate, can not damage HUMAN HEALTH, be brand-new environmental protection low-toxicity product.
Summary of the invention
The object of this invention is to provide good glass door use coating of a kind of low-temperature curing sticking power and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The glass door use coating that a kind of low-temperature curing sticking power is good, be made up of the raw material of following weight part: self-cross linking type water soluble acrylic resin 28-32, water soluble phenol resin 30-33, whiteruss 0.1-0.3, modification propyl benzene emulsion 8-12, adipic dihydrazide 0.6-1.2, diacetone-acryloamide(DAA) 1-2, propylene glycol phenylate 1-3, Di(dioctylpyrophosphato) ethylene titanate 0.2-0.5, flow agent BYK-560.3-0.5, polyoxypropyleneglycol 0.3-0.5, methyl p-hydroxybenzoate 0.3-0.5, butyleneglycol 1-2, acetylene ethylene glycol 0.5-1.0, calcium carbonate 0.2-0.5, zinc oxide 0.2-0.3, UV light absorber 0.2-0.4, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
The glass door use coating that a kind of low-temperature curing sticking power of the present invention is good, be made up of following concrete steps:
(1) deionized water, flow agent BYK-56, whiteruss, methyl p-hydroxybenzoate, butyleneglycol, polyoxypropyleneglycol mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol phenylate, acetylene ethylene glycol stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds self-cross linking type water soluble acrylic resin, water soluble phenol resin, modification propyl benzene emulsion, adipic dihydrazide, diacetone-acryloamide(DAA) stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds Di(dioctylpyrophosphato) ethylene titanate, pigment, calcium carbonate, zinc oxide uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
The invention has the advantages that: the modifying cinepazid emulsion that water-borne coatings of the present invention adds has sterilization, dust-proof, antistatic etc. effect, the adipic dihydrazide added and diacetone-acryloamide(DAA) room temperature crosslinking curing, improve sticking power and the hardness of paint film of coating, coating of the present invention is excellent to the tolerance of the liquid such as water and ethanol, not containing benzene, ethyl acetate equal solvent, not containing heavy metal, without unpleasant odor, environmental protection, preparation method is simple, and cost is low.
specific embodiments
Below by specific examples, the present invention is described in detail.
The glass door use coating that a kind of low-temperature curing sticking power is good, be made up of the raw material of following weight part (kilogram): self-cross linking type water soluble acrylic resin 30, water soluble phenol resin 32, whiteruss 0.2, modification propyl benzene emulsion 11, adipic dihydrazide 0.8, diacetone-acryloamide(DAA) 1, propylene glycol phenylate 3, Di(dioctylpyrophosphato) ethylene titanate 0.4, flow agent BYK-560.3, polyoxypropyleneglycol 0.3, methyl p-hydroxybenzoate 0.4, butyleneglycol 2, acetylene ethylene glycol 0.8, calcium carbonate 0.4, zinc oxide 0.3, UV light absorber 0.4, pigment 2, deionized water 15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part (kilogram): silane coupling agent KH5700.5, nano titanium oxide 3, nano zine oxide 2, vinylbenzene 26, butyl acrylate 52, methacrylic acid 12, N, N'-methylene-bisacrylamide 0.5, sodium lauryl sulphate 2, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 10, ammonium persulphate 0.5, ethyl acetate 15, distilled water 130; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use.The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
The glass door use coating that a kind of low-temperature curing sticking power of the present invention is good, be made up of following concrete steps:
(1) deionized water, flow agent BYK-56, whiteruss, methyl p-hydroxybenzoate, butyleneglycol, polyoxypropyleneglycol mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol phenylate, acetylene ethylene glycol stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds self-cross linking type water soluble acrylic resin, water soluble phenol resin, modification propyl benzene emulsion, adipic dihydrazide, diacetone-acryloamide(DAA) stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds Di(dioctylpyrophosphato) ethylene titanate, pigment, calcium carbonate, zinc oxide uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Paint adhesion experiment (frame method) of the present invention≤1 grade, water tolerance experiment (500h) is without exception, hardness of paint film is 3H, artificial ageing resistance experiment >=1000 hours without exception, resistance to boiling water experiment >=12 are hour unchanged, and salt fog resistance experiment >=24 hours is unchanged, and abrasion resistance is tested 10000 times and passed through, paint film without breakage, alcohol resistance experiment >=24 hours unchanged.
Claims (2)
1. the glass door use coating that a low-temperature curing sticking power is good, it is characterized in that, be made up of the raw material of following weight part: self-cross linking type water soluble acrylic resin 28-32, water soluble phenol resin 30-33, whiteruss 0.1-0.3, modification propyl benzene emulsion 8-12, adipic dihydrazide 0.6-1.2, diacetone-acryloamide(DAA) 1-2, propylene glycol phenylate 1-3, Di(dioctylpyrophosphato) ethylene titanate 0.2-0.5, flow agent BYK-560.3-0.5, polyoxypropyleneglycol 0.3-0.5, methyl p-hydroxybenzoate 0.3-0.5, butyleneglycol 1-2, acetylene ethylene glycol 0.5-1.0, calcium carbonate 0.2-0.5, zinc oxide 0.2-0.3, UV light absorber 0.2-0.4, pigment 1-2, deionized water 10-15,
Described modifying cinepazid emulsion is made up of the raw material of following weight part: silane coupling agent KH5700.3-0.6, nano titanium oxide 3-4, nano zine oxide 2-3, vinylbenzene 23-28, butyl acrylate 48-54, methacrylic acid 9-13, N, N'-methylene-bisacrylamide 0.4-0.8, sodium lauryl sulphate 2-4, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride 8-12, ammonium persulphate 0.5-1.0, ethyl acetate 10-15, distilled water 120-150; Nano titanium oxide, nano zine oxide and toluene are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH570 be heated to backflow, isothermal reaction 1-2 hour, filters and uses absolute ethanol washing three times to dry namely to obtain nano composite material for subsequent use; The distilled water of nano composite material and 50-70% is added in three mouthfuls of round-bottomed flasks that agitator, prolong are housed, raised temperature controls at 80 ° of about C, add residue distilled water, sodium lauryl sulphate and 10-30% Potassium Persulphate again, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride, vinylbenzene, butyl acrylate, methacrylic acid is added again after rapid stirring emulsification 20min, after isothermal reaction 45min, drip remaining Potassium Persulphate and N again, N'-methylene-bisacrylamide, lowers the temperature after isothermal reaction 3-4 hour, filters the benzene emulsion obtaining modification.
2. the glass door use coating that a kind of low-temperature curing sticking power is good according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-56, whiteruss, methyl p-hydroxybenzoate, butyleneglycol, polyoxypropyleneglycol mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol phenylate, acetylene ethylene glycol stirs 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds self-cross linking type water soluble acrylic resin, water soluble phenol resin, modification propyl benzene emulsion, adipic dihydrazide, diacetone-acryloamide(DAA) stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds Di(dioctylpyrophosphato) ethylene titanate, pigment, calcium carbonate, zinc oxide uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410537598.8A CN104356846A (en) | 2014-10-14 | 2014-10-14 | Low-temperature cured water-based paint with good adhesion and for glass door as well as preparation method of water-based paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410537598.8A CN104356846A (en) | 2014-10-14 | 2014-10-14 | Low-temperature cured water-based paint with good adhesion and for glass door as well as preparation method of water-based paint |
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| CN104356846A true CN104356846A (en) | 2015-02-18 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153843A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High toughness wear-resistant water-based paint special for automobile parts |
| CN105645788A (en) * | 2015-12-30 | 2016-06-08 | 曲少春 | Novel heat resistant coating and preparation method thereof |
| CN106280807A (en) * | 2016-08-29 | 2017-01-04 | 安徽省徽之尚机电科技有限公司 | A kind of preparation method of composite nano titanium dioxide antirust paint |
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2014
- 2014-10-14 CN CN201410537598.8A patent/CN104356846A/en active Pending
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| CN1908022A (en) * | 2006-08-11 | 2007-02-07 | 中山耐乐生物科技有限公司 | Process for preparing room temperature self-crosslinking acrylic ester emulsion modified by inorganic nano particle |
| CN102516436A (en) * | 2011-12-16 | 2012-06-27 | 佛山市南方包装有限公司 | Room-temperature self-crosslinkable styrene-acrylic emulsion resistant to ethanol dilution and preparation method for same |
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| 周万德等: "《甲醛衍生物手册》", 31 October 2010, 化学工业出版社 * |
| 邵谦等: "纳米TiO2/苯丙复合乳液的合成与表征", 《山东科技大学学报自然科学版》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153843A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High toughness wear-resistant water-based paint special for automobile parts |
| CN105645788A (en) * | 2015-12-30 | 2016-06-08 | 曲少春 | Novel heat resistant coating and preparation method thereof |
| CN106280807A (en) * | 2016-08-29 | 2017-01-04 | 安徽省徽之尚机电科技有限公司 | A kind of preparation method of composite nano titanium dioxide antirust paint |
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Application publication date: 20150218 |