CN106867412A - A kind of preparation method of antimicrobial form artificial stone polishing fluid - Google Patents
A kind of preparation method of antimicrobial form artificial stone polishing fluid Download PDFInfo
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- CN106867412A CN106867412A CN201611248521.4A CN201611248521A CN106867412A CN 106867412 A CN106867412 A CN 106867412A CN 201611248521 A CN201611248521 A CN 201611248521A CN 106867412 A CN106867412 A CN 106867412A
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- artificial stone
- polishing fluid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F120/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/22—Esters containing halogen
Abstract
The invention discloses a kind of preparation method of antimicrobial form artificial stone polishing fluid, belong to polishing agent preparing technical field, the antimicrobial form polishing of artificial stone liquid is by following several into being grouped into：Gap filler, optical brightener, antiseptic, lubricant, anti-fouling agent, pH adjusting agent, surfactant, deionized water, the preparation method of the polishing fluid further comprises the preparation method of optical brightener, anti-fouling agent.The preparation method of polishing fluid of the present invention, raw material are common, step is concise, specification, low production cost, easily realize industrialized production, and obtained product has antibacterial and polishing performance concurrently, and market value is high.
Description
Technical field
The invention belongs to polishing fluid production technical field, and in particular to a kind of artificial stone's polishing fluid with anti-microbial property
Preparation method.
Background technology
Artificial stone is, with unsaturated polyester (UP) resin as adhesive, to be equipped with natural marble or calcite, dolomite, silicon
The inorganic powders such as sand, glass dust, and appropriate fire retardant, color etc., through dispensing mixing, porcelain casting, vibrocompression, extruding etc.
Method forming and hardening is made.Compared with lithotome, artificial stone has beautiful in colour, highly polished, color uniformity, resists
Press wear-resisting, good toughness, compact structure, sturdy and durable, light specific gravity, do not absorb water, resistant to corrosion weathering, aberration are small, colour-fast, radioactivity
Low advantage, the advantage with comprehensive utilization of resources has immeasurable effect in terms of environmental protection and energy saving, is also qualified
Building materials Green Product, it has also become the first-selected finishing material of modern architecture.Artificial stone when in use between long afterwards, it may appear that
Glossiness is decreased obviously, breed bacteria, generation are gone mouldy problem is, it is necessary to put into manpower and materials to stone material cleaning, sterilized, effect is but
It is undesirable.
At present, the polishing method to artificial stone mainly has physics to polish and two methods of chemical polishing.Physics polishing master
If being polished stone surface using sand paper, then glaze finish paint is coated, it is recovered light；Chemical polishing is mainly is thrown using some
Photo etching is surface-treated to artificial stone, its brightness and durability is all restored.Because the use of polishing agent is more convenient,
At present, the polishing agent on the market for artificial stone is widely loved by consumers.
Research for artificial stone's polishing agent prescription is also a lot.Such as patent of invention " polished bricks, stone material, artificial stone renovation
With polishing agent " (application number：2010101117991.3) disclose a kind of comprising compositions such as fluorine-containing auxiliary agent, nano silicons
Polishing agent, the polishing agent has the advantages that removal brick body surface foul, recovers stone material color and luster, improves durability；Patent of invention " one
Kind nanometer burnishing liquid, antiscuffing paste and preparation method thereof " (application number 201410746951.3) discloses one kind comprising organosilicon, silicon
The preparation method of colloidal sol, the polishing fluid of wax emulsion, has the advantages that to improve stone surface microstructure, reaches mirror effect；Hair
A kind of bright Patent Application Publication " stone polishing agent " (application number：201610275102.3) disclose it is a kind of by abrasive material, sodium oxalate,
Prodan, paraffin etc. can produce crystallizing layer into the polishing agent being grouped into stone surface, lift stone material glossiness.But almost
Polishing fluid function is all relatively simple, while smoothness, the brightness of stone surface is strengthened, without the corresponding function of increase.
The disclosure of background above technology contents is only used for auxiliary and understands inventive concept of the invention and technical scheme, and it is not
Necessarily belong in the prior art of present patent application, the applying date of the above in present patent application is being shown without tangible proof
In the case of disclosed, above-mentioned background technology should not be taken to evaluate the novelty and creativeness of the application.
The content of the invention
In order to overcome the deficiencies in the prior art, the present invention to provide a kind of preparation method of antimicrobial form artificial stone polishing fluid,
Wherein also include optical brightener, the preparation method of anti-fouling agent, the polishing fluid produced by the preparation method, antibacterial, polishing effect are good,
And effect is lasting.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of antimicrobial form artificial stone polishing fluid, in units of weight portion, including following raw material：3~18 parts of gap filler, increasing
6~22 parts of photo etching, 0.2~6 part of lubricant, 4~16 parts of anti-fouling agent, 0.3~3.6 part of pH adjusting agent, surfactant A 1~
7.5 parts, 0.5~4 part of antiseptic, 40~140 parts of deionized water.
Preferably, the gap filler is mixed by one or more in nano silicon, phosphate, carbonate or silicate
Compound is constituted.
Preferably, the optical brightener includes one or more breasts in Brazil wax, beeswax, plate wax or atoleine
The liquid changed.
Preferably, the lubricant is mixed by one or more in ethylene glycol, glycerine, dimethicone or amido silicon oil
Conjunction is formed.
Preferably, the anti-fouling agent includes butyl acrylate, methyl acrylate, acrylic acid, methacrylate, methyl-prop
One or more in the difluoro heptyl ester of olefin(e) acid ten, full-fluorine octyl sulfuryl fluoride or 20-800 viscosity hydroxy silicone oil are polymerized.
Preferably, the pH adjusting agent by triethanolamine, ammoniacal liquor, sodium hydroxide solution, hydrochloric acid one or more mixing
Form.
Preferably, the antiseptic by coated with polyethylene glycol Nano Silver, nano phase ag_2 o, nano titanium oxide, Nano-Zinc,
The liquid composition of one or more dispersed mixtures in nano zine oxide.
The present invention also provides a kind of preparation method of antimicrobial form artificial stone polishing fluid, comprises the following steps：
S1：Surfactant A is weighed, is added in the 500mL beakers for filling 50~200g deionized waters, 10000~
5~the 10min of ultrasonic activation of 60000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 40~60 DEG C of water-baths, in the stirring of 200~1000r/min rotating speeds
Under, sequentially add antiseptic in 60min, 5~40g silicon sol solutions, 3~24g biphosphate sodium salts, 20~80g optical brighteners,
5~40g anti-fouling agents, 1~10g glycerine, are sufficiently stirred for 60~180min；
S3：After in the beaker obtained by step S2 reactions after liquid cooling to room temperature, with triethanolamine adjust to pH value be 5~
7, that is, antimicrobial form artificial stone's polishing fluid is obtained.
Preferably, the preparation method of the optical brightener described in step S2, comprises the following steps：
A1：Brazil wax, beeswax, plate wax or atoleine are weighed, 3~9g of surfactant B adds tri- mouthfuls of 250mL
It is placed in flask in 70~95 DEG C of thermostat water baths, 5~30min of stirring reaction under 300~1000r/min rotating speeds；
A2：After the completion of step S1 reactions, speed of agitator is risen into 1000~3000r/min, 20 are slowly added dropwise in 60min
~60g deionized waters, react 60~180min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 100~600r/min, it is to be mixed
Stop reaction when reaction to reaction solution is cooled to room temperature, resulting solution is optical brightener.
Preferably, the preparation method of the anti-fouling agent described in step S2, comprises the following steps：
B1：Weigh in 0.1~2g surfactants C, 10~80g deionized waters addition 250mL there-necked flasks, slowly heat up
To 60~85 DEG C, be slowly added dropwise under 200~800r/min rotating speeds 10~30g butyl acrylates, methyl acrylate, acrylic acid,
One kind in methacrylate, dodecafluoroheptyl methacrylate, full-fluorine octyl sulfuryl fluoride or 20-800 viscosity hydroxy silicone oil
Or it is several；
B2：By 60~180min of step S1 gained mixed liquor stirring and emulsifyings；
B3：In 20min, to the ammonium persulfate aqueous solutions of 5~10mL 2% are added dropwise in step S2 gained mixed liquors, temperature is protected
Hold at 80~90 DEG C, continue to stop reaction after stirring 15~40min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
The invention has the advantages that：
(1) preparation method of the present invention, raw material sources are extensive, step simplicity, low production cost；
(2) the antimicrobial form artificial stone's polishing fluid prepared by preparation method of the present invention, with antibacterial, antifouling, increasing
The combination properties such as light, U.S. seam, use on artificial stone surface, can play the effect of long-acting anti-soil, antibacterial.
Specific embodiment
The present invention is described in further detail with reference to specific embodiment.It is emphasized that the description below is only
Only it is exemplary, rather than in order to limit the scope of the present invention and its application.
In embodiment, a kind of antimicrobial form artificial stone polishing fluid, in units of weight portion, including following raw material：Joint filling
3~18 parts of agent, 6~22 parts of optical brightener, 0.2~6 part of lubricant, 4~16 parts of anti-fouling agent, 0.3~3.6 part of pH adjusting agent, surface
1~7.5 part of activating agent A, 0.5~4 part of antiseptic, 40~140 parts of deionized water.
The gap filler is by one or more the mixture groups in nano silicon, phosphate, carbonate or silicate
Into.
The optical brightener includes that one or more emulsifications in Brazil wax, beeswax, plate wax or atoleine are formed
Liquid.
The lubricant is mixed by one or more in ethylene glycol, glycerine, dimethicone or amido silicon oil.
The anti-fouling agent includes butyl acrylate, methyl acrylate, acrylic acid, methacrylate, methacrylic acid ten
One or more in difluoro heptyl ester, full-fluorine octyl sulfuryl fluoride or 20-800 viscosity hydroxy silicone oil are polymerized.
The pH adjusting agent is mixed by one or more of triethanolamine, ammoniacal liquor, sodium hydroxide solution, hydrochloric acid.
The antiseptic is by coated with polyethylene glycol Nano Silver, nano phase ag_2 o, nano titanium oxide, Nano-Zinc, nano oxygen
Change the liquid composition of one or more dispersed mixtures in zinc.
The preparation method of the antimicrobial form artificial stone polishing fluid, comprises the following steps：
S1：Surfactant A is weighed, is added in the 500mL beakers for filling 50~200g deionized waters, 10000~
5~the 10min of ultrasonic activation of 60000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 40~60 DEG C of water-baths, in the stirring of 200~1000r/min rotating speeds
Under, sequentially add antiseptic in 60min, 5~40g silicon sol solutions, 3~24g biphosphate sodium salts, 20~80g optical brighteners,
5~40g anti-fouling agents, 1~10g glycerine, are sufficiently stirred for 60~180min；
S3：After in the beaker obtained by step S2 reactions after liquid cooling to room temperature, with triethanolamine adjust to pH value be 5~
7, that is, antimicrobial form artificial stone's polishing fluid is obtained.
The preparation method of the optical brightener described in step S2, comprises the following steps：
A1：Brazil wax, beeswax, plate wax or atoleine are weighed, 3~9g of surfactant B adds tri- mouthfuls of 250mL
It is placed in flask in 70~95 DEG C of thermostat water baths, 5~30min of stirring reaction under 300~1000r/min rotating speeds；
A2：After the completion of step S1 reactions, speed of agitator is risen into 1000~3000r/min, 20 are slowly added dropwise in 60min
~60g deionized waters, react 60~180min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 100~600r/min, it is to be mixed
Stop reaction when reaction to reaction solution is cooled to room temperature, resulting solution is optical brightener.
The preparation method of the anti-fouling agent described in step S2, comprises the following steps：
B1：Weigh in 0.1~2g surfactants C, 10~80g deionized waters addition 250mL there-necked flasks, slowly heat up
To 60~85 DEG C, be slowly added dropwise under 200~800r/min rotating speeds 10~30g butyl acrylates, methyl acrylate, acrylic acid,
One kind in methacrylate, dodecafluoroheptyl methacrylate, full-fluorine octyl sulfuryl fluoride or 20-800 viscosity hydroxy silicone oil
Or it is several；
B2：By 60~180min of step S1 gained mixed liquor stirring and emulsifyings；
B3：In 20min, to the ammonium persulfate aqueous solutions of 5~10mL 2% are added dropwise in step S2 gained mixed liquors, temperature is protected
Hold at 80~90 DEG C, continue to stop reaction after stirring 15~40min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
Embodiment 1：
A kind of antimicrobial form artificial stone polishing fluid, in units of weight portion, including following raw material：3 parts of gap filler, optical brightener
6 parts, 0.2 part of lubricant, 4 parts of anti-fouling agent, 0.3 part of pH adjusting agent, 1 part of surfactant, 0.5 part of antiseptic, deionized water 40
Part.
The gap filler is 2 parts of nano silicons and 1 part of phosphate composition.
The optical brightener is the liquid of 4 parts of Brazil waxs and 2 parts of beeswax emulsifications.
The lubricant is 0.1 part of ethylene glycol and 0.1 part of dimethicone mixing composition.
The anti-fouling agent is formed for butyl acrylate.
The pH adjusting agent is that 0.2 part of triethanolamine and 1 part of mixed in hydrochloric acid are formed.
The antiseptic is 0.3 part of coated with polyethylene glycol Nano Silver, 0.2 part of coated with polyethylene glycol nano titanium oxide dispersion
Mixture solution.
The surfactant A is sodium n-alkylbenzenesulfonate.
The preparation method of the antimicrobial form artificial stone polishing fluid, comprises the following steps：
S1：1 part of sodium n-alkylbenzenesulfonate is weighed, is added in the 500mL beakers for filling 50g deionized waters,
The ultrasonic activation 10min of 10000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 40 DEG C of water-baths, under the stirring of 200r/min rotating speeds, in 60min
Inside sequentially add 0.3 part of coated with polyethylene glycol Nano Silver, 0.2 part of coated with polyethylene glycol nano titanium oxide dispersed mixture molten
Liquid, 5g silicon sol solutions, 3g biphosphate sodium salts, 20g optical brighteners, 5g anti-fouling agents, 1g glycerine is sufficiently stirred for 60min；
S3：It is after after liquid cooling to room temperature in the beaker obtained by step S2 reactions, being adjusted to pH value with triethanolamine
5.5, that is, antimicrobial form artificial stone's polishing fluid is obtained.
The preparation method of the optical brightener described in step S2, comprises the following steps：
A1：4 parts of Brazil waxs and 2 parts of beeswaxs are weighed, sodium sulfate of polyethenoxy ether of fatty alcohol 3g adds tri- mouthfuls of 250mL
It is placed in flask in 70 DEG C of thermostat water baths, the stirring reaction 5min under 300r/min rotating speeds；
A2：After the completion of step S1 reactions, speed of agitator is risen into 1000/min, 20g deionizations are slowly added dropwise in 60min
Water, reacts 60min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 100r/min, reaction to be mixed
Stop reaction when being cooled to room temperature to reaction solution, resulting solution is optical brightener.
The preparation method of the anti-fouling agent described in step S2, comprises the following steps：
B1：Weigh in 0.1g lauroyl glutamates, 10g deionized waters addition 250mL there-necked flasks, be to slowly warm up to 60
DEG C, 10g butyl acrylates are slowly added dropwise under 200r/min rotating speeds；
B2：By step S1 gained mixed liquor stirring and emulsifyings 60min；
B3：In 20min, to the ammonium persulfate aqueous solutions of 5mL 2% are added dropwise in step S2 gained mixed liquors, temperature is maintained at
80 DEG C, continue to stop reaction after stirring 15min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
Embodiment 2
A kind of antimicrobial form artificial stone polishing fluid, in units of weight portion, including following raw material：18 parts of gap filler, add lustre to
22 parts of agent, 6 parts of lubricant, 16 parts of anti-fouling agent, 3.6 parts of pH adjusting agent, 7.5 parts of surfactant, 4 parts of antiseptic, deionized water
140 parts.
The gap filler is 12 parts of nano silicons and 6 parts of carbonate mixtures.
The optical brightener is the liquid composition of 14 parts of plate waxes and 8 parts of emulsifications of atoleine.
The lubricant is 4 parts of glycerine and 2 parts of amido silicon oil mixing compositions.
The anti-fouling agent is methacrylate polymers.
The pH adjusting agent is formed for 2.2 parts of ammoniacal liquor, 0.4 part of sodium hydroxide solution, 1 part of mixed in hydrochloric acid.
The antiseptic is 2 parts of coated with polyethylene glycol Nano Silvers, 2 parts of coated with polyethylene glycol Nano-Zinc dispersion mixing thing liquids
Body.
The surfactant A is lignosulfonates.
The preparation method of antimicrobial form artificial stone's polishing fluid, comprises the following steps：
S1：7.5 parts of lignosulfonates are weighed, is added in the 500mL beakers for filling 200g deionized waters,
The ultrasonic activation 5min of 60000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 60 DEG C of water-baths, under the stirring of 1000r/min rotating speeds, in 60min
Inside sequentially add 2 parts of coated with polyethylene glycol Nano Silvers, 2 parts of coated with polyethylene glycol Nano-Zinc dispersed mixture liquid, 40g Ludox
Solution, 24g biphosphate sodium salts, 80g optical brighteners, 40g anti-fouling agents, 10g glycerine is sufficiently stirred for 180min；
S3：It is after after liquid cooling to room temperature in the beaker obtained by step S2 reactions, being adjusted to pH value with triethanolamine
6.8, that is, antimicrobial form artificial stone's polishing fluid is obtained.
The preparation method of the optical brightener described in step S2, comprises the following steps：
A1：14 parts of plate waxes and 8 parts of atoleines are weighed, dispersing agent MF 9g is placed in 95 in addition 250mL there-necked flasks
In DEG C thermostat water bath, the stirring reaction 30min under 1000r/min rotating speeds；
A2：Step S1 reaction after the completion of, speed of agitator is risen into 3000r/min, be slowly added dropwise in 60min 60g go from
Sub- water, reacts 180min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 600r/min, reaction to be mixed
Stop reaction when being cooled to room temperature to reaction solution, resulting solution is optical brightener.
The preparation method of the anti-fouling agent described in step S2, comprises the following steps：
B1：Weigh in 2g aliphatic alcohol polyethenoxies (3) ether, 80g deionized waters addition 250mL there-necked flasks, slowly heat up
To 85 DEG C, 30g methacrylates are slowly added dropwise under 800r/min rotating speeds；
B2：By step S1 gained mixed liquor stirring and emulsifyings 180min；
B3：In 20min, to the ammonium persulfate aqueous solutions of 10mL 2% are added dropwise in step S2 gained mixed liquors, temperature keeps
At 90 DEG C, continue to stop reaction after stirring 40min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
Embodiment 3
A kind of antimicrobial form artificial stone polishing fluid, in units of weight portion, including following raw material：10 parts of gap filler, add lustre to
16 parts of agent, 2.6 parts of lubricant, 10 parts of anti-fouling agent, 2.2 parts of pH adjusting agent, 4 parts of surfactant, 2.5 parts of antiseptic, deionization
80 parts of water.
The gap filler is 6 parts of nano silicons, 2 parts of phosphate, 2 parts of carbonate mixtures.
The optical brightener is 10 parts of Brazil waxs, the liquid of 6 parts of atoleines emulsification.
The lubricant is 1.2 parts of glycerine, 0.8 part of dimethicone and 0.6 part of amido silicon oil mixture.
The anti-fouling agent is dodecafluoroheptyl methacrylate polymer.
The pH adjusting agent is 1.2 parts of triethanolamines, 0.2 part of sodium hydroxide solution, 0.8 part of hydrochloric acid mixture.
The antiseptic is dispersion mixing thing liquid in 2 parts of coated with polyethylene glycol nano phase ag_2 os and 0.5 part of nano zine oxide
Body.
The surfactant A is alkylphenol-polyethenoxy (7) ether.
The preparation method of antimicrobial form artificial stone's polishing fluid, comprises the following steps：
S1：4 parts of alkylphenol-polyethenoxy (7) ethers are weighed, is added in the 500mL beakers for filling 120g deionized waters,
The ultrasonic activation 8min of 30000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 50 DEG C of water-baths, under the stirring of 600r/min rotating speeds, in 60min
Dispersed mixture liquid in 2 parts of coated with polyethylene glycol nano phase ag_2 os and 0.5 part of nano zine oxide is inside sequentially added, 25g silicon is molten
Sol solution, 16g biphosphate sodium salts, 50g optical brighteners, 26g anti-fouling agents, 8g glycerine is sufficiently stirred for 120min；
S3：It is after after liquid cooling to room temperature in the beaker obtained by step S2 reactions, being adjusted to pH value with triethanolamine
6.5, that is, antimicrobial form artificial stone's polishing fluid is obtained.
The preparation method of the optical brightener described in step S2, comprises the following steps：
A1：Weigh 10 parts of Brazil waxs, 6 parts of atoleines, sldium lauryl sulfate 5g, in addition 250mL there-necked flasks
It is placed in 85 DEG C of thermostat water baths, the stirring reaction 20min under 600r/min rotating speeds；
A2：Step S1 reaction after the completion of, speed of agitator is risen into 2000r/min, be slowly added dropwise in 60min 40g go from
Sub- water, reacts 100min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 400r/min, reaction to be mixed
Stop reaction when being cooled to room temperature to reaction solution, resulting solution is optical brightener.
The preparation method of the anti-fouling agent described in step S2, comprises the following steps：
B1：Weigh in 1.6g heavy alkylbenzene sulfonates, 50g deionized waters addition 250mL there-necked flasks, be to slowly warm up to 70
DEG C, 20g dodecafluoroheptyl methacrylates are slowly added dropwise under 500r/min rotating speeds；
B2：By step S1 gained mixed liquor stirring and emulsifyings 120min；
B3：In 20min, to the ammonium persulfate aqueous solutions of 8mL 2% are added dropwise in step S2 gained mixed liquors, temperature is maintained at
85 DEG C, continue to stop reaction after stirring 25min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
In order to beneficial effects of the present invention are described in more detail, verified by following contrast experiment：
One piece of area of certain family is chosen for 4m2, rectangular artificial marble kitchen countertop be sample, the mesa surfaces mill
Damage, soiled condition are uniform.The table top is evenly dividing two parts A and B for area equation, midfeather 10cm.A table tops are used
Once, B table tops are polished using commercially available polishing fluid 20mL for the polishing fluid 20mL polishings that the methods described of the embodiment of the present invention 1 is prepared from
Once, tested immediately, recorded, randomly selected 0.2m on table top2Sampling experimental；The marble countertop was through routine use 10 days
Afterwards, test, record and sampling experimental are re-started.
The experimental data of record table top A and B, it is as shown in the table：
As can be seen here, the polishing fluid for being prepared using the method for the invention, can lift and keep artificial stone surface light
Brightness, kill stone surface bacterium and long-acting suppression bacteria breed.
The specific implementation of the invention is not to be limited to these illustrations for above content, is led for technology belonging to the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the claims of the present invention by being submitted to determine should be all considered as belonging to.
Claims (10)
1. a kind of antimicrobial form artificial stone polishing fluid, it is characterised in that in units of weight portion, including following raw material：Gap filler 3
~18 parts, 6~22 parts of optical brightener, 0.2~6 part of lubricant, 4~16 parts of anti-fouling agent, 0.3~3.6 part of pH adjusting agent, surface-active
1~7.5 part of agent A, 0.5~4 part of antiseptic, 40~140 parts of deionized water.
2. antimicrobial form artificial stone polishing fluid according to claim 1, it is characterised in that the gap filler is by nano-silica
One or more mixtures composition in SiClx, phosphate, carbonate or silicate.
3. antimicrobial form artificial stone polishing fluid according to claim 1, it is characterised in that the optical brightener includes cohune
The liquid of one or more emulsifications in palmitic acid wax, beeswax, plate wax or atoleine.
4. antimicrobial form artificial stone polishing fluid according to claim 1, it is characterised in that the lubricant by ethylene glycol,
One or more in glycerine, dimethicone or amido silicon oil are mixed.
5. antimicrobial form artificial stone polishing fluid according to claim 1, it is characterised in that the anti-fouling agent includes acrylic acid
Butyl ester, methyl acrylate, acrylic acid, methacrylate, dodecafluoroheptyl methacrylate, full-fluorine octyl sulfuryl fluoride or 20-
One or more in 800 viscosity hydroxy silicone oil are polymerized.
6. antimicrobial form polishing of artificial stone liquid according to claim 1, it is characterised in that the pH adjusting agent is by three ethanol
One or more of amine, ammoniacal liquor, sodium hydroxide solution, hydrochloric acid are mixed.
7. antimicrobial form polishing of artificial stone liquid according to claim 1, it is characterised in that the antiseptic is by polyethylene glycol bag
Cover one or more dispersed mixtures in Nano Silver, nano phase ag_2 o, nano titanium oxide, Nano-Zinc, nano zine oxide and
Into liquid composition.
8. the preparation method of the antimicrobial form artificial stone's polishing fluid according to any one of claim 1~7, it is characterised in that
Comprise the following steps：
S1：Surfactant is weighed, is added in the 500mL beakers for filling 50~200g deionized waters, 10000~
5~the 10min of ultrasonic activation of 60000Hz frequencies；
S2：Beaker obtained by step S1 reactions is placed in 40~60 DEG C of water-baths, under the stirring of 200~1000r/min rotating speeds,
Sequentially add antiseptic in 60min, 5~40g silicon sol solutions, 3~24g biphosphate sodium salts, 20~80g optical brighteners, 5~
40g anti-fouling agents, 1~10g glycerine, are sufficiently stirred for 60~180min；
S3：After after liquid cooling to room temperature in the beaker obtained by step S2 reactions, it is 5~7 to be adjusted to pH value with triethanolamine, i.e.,
Antimicrobial form artificial stone's polishing fluid is obtained.
9. the preparation method of antimicrobial form artificial stone polishing fluid according to claim 8, it is characterised in that institute in step S2
The preparation method of the optical brightener stated, comprises the following steps：
A1：Brazil wax, beeswax, plate wax or atoleine are weighed, 3~9g of surfactant B adds 250mL there-necked flasks
In be placed in 70~95 DEG C of thermostat water baths, 5~30min of stirring reaction under 300~1000r/min rotating speeds；
A2：After the completion of step S1 reactions, speed of agitator is risen into 100~3000r/min, 20~60g is slowly added dropwise in 60min
Deionized water, reacts 60~180min；
A3：After the completion of step S2 reactions, water bath device is removed, speed of agitator is adjusted to 100~600r/min, reaction to be mixed
Stop reaction when being cooled to room temperature to reaction solution, resulting solution is optical brightener.
10. the preparation method of antimicrobial form artificial stone polishing fluid according to claim 8, it is characterised in that step S2 institutes
The preparation method of the anti-fouling agent stated, it is characterised in that comprise the following steps：
B1：Weigh in 0.1~2g surfactants C, 10~80g deionized waters addition 250mL there-necked flasks, be to slowly warm up to 60
~85 DEG C, 10~30g butyl acrylates, methyl acrylate, acrylic acid, methyl are slowly added dropwise under 200~800r/min rotating speeds
One kind or several in acrylate, dodecafluoroheptyl methacrylate, full-fluorine octyl sulfuryl fluoride or 20-800 viscosity hydroxy silicone oil
Kind；
B2：By 60~180min of step S1 gained mixed liquor stirring and emulsifyings；
B3：In 20min, to the ammonium persulfate aqueous solutions of 5~10mL 2% are added dropwise in step S2 gained mixed liquors, temperature is maintained at
80~90 DEG C, continue to stop reaction after stirring 15~40min, liquid to be mixed obtains anti-fouling agent after being cooled to room temperature.
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| CN107828341A (en) * | 2017-11-17 | 2018-03-23 | 枣庄市博源人造石有限公司 | A kind of antimicrobial form artificial stone polishing fluid and preparation method thereof |
| CN108003794A (en) * | 2017-12-11 | 2018-05-08 | 合众（佛山）化工有限公司 | A kind of ceramic polished liquid of photocatalyst type |
| CN108084886A (en) * | 2017-12-11 | 2018-05-29 | 合众（佛山）化工有限公司 | A kind of ceramic polished liquid of durable antibiotic |
| CN110016294A (en) * | 2019-04-15 | 2019-07-16 | 广西利升石业有限公司 | A kind of antibacterial polishing fluid and preparation method thereof based on stone polishing |
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| CN110387192A (en) * | 2019-07-16 | 2019-10-29 | 佛山欧神诺陶瓷有限公司 | A kind of ceramic polishing liquid and preparation method thereof that can generate anion |
| CN110587491A (en) * | 2019-09-28 | 2019-12-20 | 深圳市佰石特石业有限公司 | Marble leather surface treatment process |
| CN115491130A (en) * | 2022-10-08 | 2022-12-20 | 中建海龙科技有限公司 | Antibacterial artificial stone polishing solution and preparation method thereof |
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| CN107828341A (en) * | 2017-11-17 | 2018-03-23 | 枣庄市博源人造石有限公司 | A kind of antimicrobial form artificial stone polishing fluid and preparation method thereof |
| CN108003794A (en) * | 2017-12-11 | 2018-05-08 | 合众（佛山）化工有限公司 | A kind of ceramic polished liquid of photocatalyst type |
| CN108084886A (en) * | 2017-12-11 | 2018-05-29 | 合众（佛山）化工有限公司 | A kind of ceramic polished liquid of durable antibiotic |
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| CN110128168A (en) * | 2019-05-17 | 2019-08-16 | 广东极米新材料科技有限公司 | A kind of ceramic tile gloss renovation agent and preparation method thereof |
| CN110128168B (en) * | 2019-05-17 | 2021-06-01 | 广东极米新材料科技有限公司 | Ceramic tile gloss repairing agent and preparation method thereof |
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| CN110387192A (en) * | 2019-07-16 | 2019-10-29 | 佛山欧神诺陶瓷有限公司 | A kind of ceramic polishing liquid and preparation method thereof that can generate anion |
| CN110587491A (en) * | 2019-09-28 | 2019-12-20 | 深圳市佰石特石业有限公司 | Marble leather surface treatment process |
| CN115491130A (en) * | 2022-10-08 | 2022-12-20 | 中建海龙科技有限公司 | Antibacterial artificial stone polishing solution and preparation method thereof |
| CN115785821A (en) * | 2022-11-17 | 2023-03-14 | 佛山市雅伦高科石业有限公司 | Stone polishing agent and preparation method thereof |
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