CN104356827B - A kind of nano stone surface conditioning agent and preparation method thereof - Google Patents
A kind of nano stone surface conditioning agent and preparation method thereof Download PDFInfo
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- CN104356827B CN104356827B CN201410642762.1A CN201410642762A CN104356827B CN 104356827 B CN104356827 B CN 104356827B CN 201410642762 A CN201410642762 A CN 201410642762A CN 104356827 B CN104356827 B CN 104356827B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of nano stone surface conditioning agent, it includes component A and B component, counts by weight, and described component A includes following raw material：12 parts of 5wt% 10wt% oxalate solutions, 35 parts of 5wt% 10wt% silicate fluoride solutions, 69 parts of 30wt% 50wt% pure-acrylic emulsions, 49 parts of water；Described B component includes following raw material：12 parts of 35 parts of 15wt% 20wt% acrylic resins aqueous isopropanol, Tissuemat E or microwax, 36 parts of solvent.The component of A, B two in nano stone surface conditioning agent of the present invention is nano material, with infiltration adhesion property well, successively grinding and polishing treatment is carried out with component A, B component, the blending crystallizing layer that can be formed component A, the specular layer formation formed with B component is firmly combined with, hard surface, glossiness is greatly improved, is conducive to improving the persistence of stone surface high gloss.
Description
Technical field
The invention belongs to building stone field, and in particular to a kind of nano stone surface conditioning agent and preparation method thereof.
Background technology
Due to the improvement of people's living standards, to the decoration of living environment, also gradually concern is got up, then various buildings
Inner-outer wall, ground and table top have largely used the materials such as granite, marble, artificial stone and polished bricks, microlite.Due to these
There is photosensitiveness high after material processing so that this building seems steady, elegant, clean.
But, these ornamental stone materials are chronically exposed in air, and what is had is even chronically at the public field that People are hurrying to and fro
Institute, such as square, hotel lobby etc., cause stone surface to be damaged, it is serious have impact on the overall planarization of stone material, glossiness,
Dicoration, therefore surface to this kind of stone material manually protected, and realizes that the decoration of long period is necessary.
At present, in world wide Italy, Spain in terms of stone material application and protection all in rank first.Stone
Material care field has substantial amounts of conserving material, and spread in performance is uneven, using more or import, such as K2, K3,
The series stone material mirror surface treatment agent such as NCL2510, price general charged is all higher.And some domestic mirror surface treatment materials can also be processed out
Mirror effect, but film strength is poor so that and it can not effectively keep minute surface for a long time.
The content of the invention
The technical problems to be solved by the invention are directed to the deficiency of above-mentioned prior art presence and provide a kind of nanometer stone
Material surface conditioning agent, can improve stone surface structure, improve glossiness, and minute surface can be kept not to be worn the long period.
The present invention is to solve the problems, such as that used technical scheme set forth above is：
A kind of nano stone surface conditioning agent, including component A and B component, count by weight, and described component A includes
Following raw material：1-2 parts of 5wt%-10wt% oxalate solutions, 3-5 parts of 5wt%-10wt% silicate fluoride solutions, 30wt%-
6-9 parts, water 4-9 parts of 50wt% pure-acrylic emulsions；Described B component includes following raw material：15wt%-20wt% acrylic resins are different
Propanol solution 3-5 parts, Tissuemat E or microwax 1-2 parts, solvent 3-6 parts.
By such scheme, described oxalates is one or two mixing in any proportion in sodium oxalate and potassium oxalate
Thing.
By such scheme, described fluosilicate is pressed for one or more in prodan, magnesium fluosilicate, aluminum fluosilicate
The mixture of arbitrary proportion.
By such scheme, described Tissuemat E weight average molecular weight is 2000-5000.
By such scheme, described microwax weight average molecular weight is 500-1000.
By such scheme, described solvent is one or more in isopropanol, ethyl acetate, butyl acetate by any ratio
The mixture of example.
By such scheme, the acrylic resin is the one kind or two in commercially available BR-116, or DM-810 acrylic resins
Person's mixture in any proportion.
By such scheme, the pure-acrylic emulsion be commercially available AcronalDS-6266ap, or BA-201 pure-acrylic emulsions one kind
Or both mixture in any proportion.
Present invention also offers the preparation method of above-mentioned nano stone surface conditioning agent, including following two steps：
(1) component A is prepared：Following raw material is weighed by weight：1-2 parts of 5wt%-10wt% oxalate solutions, 5wt%-
3-5 parts of 10wt% silicate fluoride solutions, 6-9 parts, water 4-9 parts of 30wt%-50wt% pure-acrylic emulsions；Then by oxalate solution,
40-50 DEG C is warming up to after silicate fluoride solution mixing, adds pure-acrylic emulsion and water, the lower reaction 15min-45min of stirring to obtain final product A
Component；
(2) B component is prepared：Following raw material is weighed by weight：15wt%-20wt% acrylic resin aqueous isopropanols 3-
5 parts, Tissuemat E or microwax 1-2 parts, solvent 3-6 parts；Then acrylic resin aqueous isopropanol is heated to 60-80 DEG C,
Stirring is lower to add Tissuemat E or microwax, insulation reaction 4-6h to be cooled to room temperature and add solvent, 15min-45min to obtain final product B
Component.
The application process of nano stone surface conditioning agent of the present invention, it is characterised in that：Clearing up the stone of greasy dirt
Material surface, first carries out grinding and polishing treatment with component A, then grinding and polishing treatment is carried out with B component, and component A, the consumption of B component are respectively 40-
80g/m2、20-30g/m2, you can form firm, wear-resisting specular layer in stone surface.Wherein, grinding and polishing treatment uses multi-functional stone
Material processor or retreading machine, coordinate hundred clean pads to carry out grinding and polishing.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, nano stone surface conditioning agent of the present invention includes the component of A, B two, and the component of A, B two is nano material, has
There is infiltration adhesion property well, carry out grinding and polishing treatment with component A, B component successively, the blending crystallizing layer that can be formed component A,
The specular layer formation formed with B component is firmly combined with, hard surface, so as to greatly improve glossiness, is conducive to improving stone material
The persistence of surface high gloss；
2nd, the oxalates that contains in component A, fluosilicate can be with the carbonate on surface or silicic acid in the process of stone grinder
Reactant salt, so that stone material exposes new surface, while the polyacrylic acid tree being ground in the material for getting off and pure-acrylic emulsion
Fat forms blending crystal and is received in the recess and micro chink of stone material together, forms smooth, smooth, closely knit blending crystallization
Layer；
3rd, acrylic resin, the wherein high-precision wax such as Tissuemat E or microwax, acrylic resin master are mainly turned into B component
Play a part of to add lustre to, the high-precision wax such as Tissuemat E or microwax is mainly the wearability and intensity for increasing specular layer, while
Also certain enhanced shine can be played, the effect of B component is the blending crystallizing layer for further enhancing component A formation, in grinding
Effect can form one layer of wear-resisting high rigidity, film layer of high glaze in stone surface, imitate the finer and close minute surface that reaches of stone surface
Really, the specular layer of high gloss is formed；
4th, simple production process, it is easy to industrialized production.
Specific embodiment
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention is not
It is limited only to the following examples.
Embodiment 1
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The sodium oxalate solution of 5g 5wt%, the sodium fluoride solution of 15g 5wt%, the AcronalDS-6266ap of 30g 30wt%
Pure-acrylic emulsion and 20g water；Described B component includes following raw material：15g 15wt%BR-116 acrylic resins aqueous isopropanol,
5g microwaxes (weight average molecular weight Mw=500), 15g isopropanols.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：Heated up after the sodium fluoride solution of the sodium oxalate solution of 5g 5wt%, 15g 5wt% is mixed
To 40 DEG C, the AcronalDS-6266ap pure-acrylic emulsions and 20g water stirring reaction 30min of 30g 30wt% are added, obtain final product component A
70g；
(2) B component is prepared：15g 15wt%BR-116 acrylic resin aqueous isopropanols are warming up to 60 DEG C, under stirring
5g microwaxes (Mw=500), insulation reaction 4h are added, room temperature is cooled to and is added 15g isopropanols, stir 30min, obtain final product B component
35g。
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 40g/m2、20g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
Embodiment 2
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The sodium oxalate solution of 10g 10wt%, the sodium fluoride solution of 25g 10wt%, the BA-201 pure-acrylic emulsions of 45g 50wt%
With 45g water；Described B component includes following raw material：25g 20wt%DM-810 acrylic resins aqueous isopropanol, 10g crystallites
Wax (weight average molecular weight Mw=1000), 30g ethyl acetate.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：After the sodium fluoride solution of the sodium oxalate solution of 10g 10wt%, 25g 10wt% is mixed
50 DEG C are warming up to, the BA-201 pure-acrylic emulsions and 45g water stirring reaction 15min of 45g 50wt% is added, component A 125g is obtained final product；
(2) B component is prepared：25g 20wt%DM-810 acrylic resin aqueous isopropanols are warming up to 80 DEG C, under stirring
10g microwaxes (Mw=1000), insulation reaction 4h are added, room temperature is cooled to and is added 30g ethyl acetate, stir 15min, obtain final product B
Component 65g.
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 80g/m2、30g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
Embodiment 3
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The Potassium Oxalate Solution of 10g 10wt%, the magnesium fluosilicate solution of 5g 10wt%, 10g 10wt% sodium fluoride solutions, 10g
The AcronalDS-6266ap pure-acrylic emulsions and 45g water of 10wt% aluminum fluosilicate solutions, 45g 50wt%；Described B component bag
Include following raw material：25g 20wt%DM-810 acrylic resins aqueous isopropanol, 10g Tissuemat Es (weight average molecular weight Mw=
2000), 10g ethyl acetate, 10g isopropanols, 10g butyl acetates.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：By the Potassium Oxalate Solution of 10g 10wt%, the magnesium fluosilicate solution of 5g 10wt%, 10g
50 DEG C are warming up to after 10wt% sodium fluoride solutions, the mixing of 10g 10wt% aluminum fluosilicate solutions, add 45g 50wt%'s
AcronalDS-6266ap pure-acrylic emulsions and 45g water stirring reaction 45min, obtain final product component A 125g；
(2) B component is prepared：25g 20wt%DM-810 acrylic resin aqueous isopropanols are warming up to 80 DEG C, under stirring
10g Tissuemat Es (Mw=2000), insulation reaction 5h are added, room temperature is cooled to and is added 10g ethyl acetate, 10g isopropanols, 10g
Butyl acetate, stirs 45min, obtains final product B component 65g.
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 60g/m2、25g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
Embodiment 4
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The Potassium Oxalate Solution of 10g 10wt%, the aluminum fluosilicate solution of 25g 10wt%, pure third breasts of BA-201 of 25g 50wt%
The AcronalDS-6266ap pure-acrylic emulsions and 45g water of liquid, 20g50wt%；Described B component includes following raw material：10g
20wt%BR-116 acrylic resins aqueous isopropanol and 15gDM-810 acrylic resins aqueous isopropanol, 10g Tissuemat Es
(weight average molecular weight Mw=5000), 30g isopropanols.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：After the aluminum fluosilicate solution of the Potassium Oxalate Solution of 10g 10wt%, 25g 10wt% is mixed
50 DEG C are warming up to, BA-201 pure-acrylic emulsions, the AcronalDS-6266ap pure-acrylic emulsions of 20g50wt% of 25g 50wt% is added
With 45g water stirring reaction 30min, component A 125g is obtained final product；
(2) B component is prepared：By 10g 20wt%BR-116 acrylic resins aqueous isopropanols and 15gDM-810 acrylic acid
Resin aqueous isopropanol is warming up to 80 DEG C, and stirring is lower to add 10g Tissuemat Es (Mw=5000), insulation reaction 6h to be cooled to room
Temperature adds 30g isopropanols, stirs 30min, obtains final product B component 65g.
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 60g/m2、25g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
Embodiment 5
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The Potassium Oxalate Solution of 3g 8wt%, the sodium oxalate solution of 3g 8wt%, the aluminum fluosilicate solution of 12g 7wt%, 9g 7wt%
Magnesium fluosilicate, the pure-acrylic emulsion of 35g 40wt% and 30g water；Described B component includes following raw material：20g 17wt% propylene
Acid resin aqueous isopropanol, 5g Tissuemat Es (Mw=3500) and 5g microwaxes, 15g isopropanols, 15g butyl acetates.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：By the Potassium Oxalate Solution of 3g 8wt%, the sodium oxalate solution of 3g 8wt%, 12g 7wt%
Be warming up to 45 DEG C after aluminum fluosilicate solution, the magnesium fluosilicate of 9g 7wt%, mixing, add 35g 40wt% pure-acrylic emulsion and
30g water stirring reaction 30min, obtain final product component A 92g；
(2) B component is prepared：20g 17wt% acrylic resin aqueous isopropanols are warming up to 70 DEG C, stirring is lower to add 5g
Tissuemat E (Mw=3500) and 5g microwaxes, insulation reaction 5h are cooled to room temperature and add 15g isopropanols, 15g butyl acetates,
Stirring 30min, obtains final product B component 60g.
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 60g/m2、25g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
Embodiment 6
A kind of nano stone surface conditioning agent, is made up of component A and B component mixing, and described component A includes following original
Material：The Potassium Oxalate Solution of 10g 5wt%, the magnesium fluosilicate solution of 25g 10wt%, the pure-acrylic emulsion and 45g of 45g 40wt%
Water；Described B component includes following raw material：25g 15wt% acrylic resins aqueous isopropanol, 10g Tissuemat Es (Mw=
4000), 30g isopropanols.
The preparation method of above-mentioned nano stone surface conditioning agent, comprises the following steps：
(1) component A is prepared：It is warming up to after the magnesium fluosilicate solution of the potassium oxalate of 10g 5wt%, 25g 10wt% is mixed
45 DEG C, the pure-acrylic emulsion and 45g water stirring reaction 30min of 45g 40wt% are added, obtain final product component A 125g；
(2) B component is prepared：25g 15wt% acrylic resin aqueous isopropanols are warming up to 65 DEG C, stirring is lower to add 10g
Tissuemat E (Mw=4000), insulation reaction 6h is cooled to room temperature and adds 30g isopropanols, stirs 30min, obtains final product B component 65g.
Above-mentioned nano stone surface conditioning agent application process is：The stone surface of greasy dirt is being cleared up, according to first component A
The order of B component uses multifunctional stone processor or retreading machine afterwards, coordinates hundred clean pads to carry out grinding and polishing, component A, the use of B component
Amount is respectively 60g/m2、25g/m2, you can stone surface formed firmly, the specular layer of hard wear resistant.
1st, the droplet measurement of above-mentioned nano stone surface conditioning agent prepared by embodiment of the present invention 1-6
Granularity survey is carried out with Britain's Malvern nanometer laser particle size analyzer to nano stone surface conditioning agent prepared by embodiment
Examination, testing result see the table below 1.
The testing graininess result of table 1.
From the testing result of upper table 1, the nano stone surface conditioning agent A, the particle diameter of B component obtained by embodiment are in 1-
Between 100nm, belong to nano material, with good intensity, infiltration adhesion property, component A can be broken with stone surface well
The carbonate or silicate reaction of damage, make it expose new surface, while be ground the chip for getting off can be with pure-acrylic emulsion one
Rise in inserting stone material micro chink, form smooth closely knit blending crystallizing layer；On this basis, nanometer acrylic resin, polyethylene
The high-precision wax such as wax or microwax can further improve wearability, intensity and the glossiness of minute surface.
2nd, the application test of above-mentioned nano stone surface conditioning agent prepared by embodiment of the present invention 1-6：
Stone surface process test：Untreated stone material glossiness at 5-20 °, by above-described embodiment 1-6 gained nano stone
The component A of surface conditioning agent is applied to stone surface, using multifunctional stone processor or retreading machine, coordinates hundred clean pads to be ground
Throw, then B component is applied to stone surface, using multifunctional stone processor or retreading machine, coordinate hundred clean pads to carry out grinding and polishing, process
The testing result of stone surface same day glossiness as shown in table 2, the light behind one week, one month is used in public situations such as hotels afterwards
Damp degree testing result is equally listed in Table 2 below.
The glossiness testing result of the different stone surface treatment of table 2.
From the testing result of upper table 2, the gloss of the different stone surfaces processed through nano stone surface conditioning agent of the present invention
Degree is significantly improved, just after treatment glossiness all more than 85 °, with good mirror effect；And over time, make
With under state, the different stone surfaces abrasion processed by surface conditioning agent of the present invention is less, and in one month, glossiness changes all
Within 10 °, it is seen that it has hardness and wearability higher.
The above is only the preferred embodiment of the present invention, it is noted that come for one of ordinary skill in the art
Say, without departing from the concept of the premise of the invention, can also make some modifications and variations, these belong to of the invention
Protection domain.
Claims (10)
1. a kind of nano stone surface conditioning agent, it is characterised in that it is made up of component A and B component, counts by weight, described
Component A be made up of following raw material：1-2 parts of 5wt%-10wt% oxalate solutions, 5wt%-10wt% silicate fluoride solutions 3-5
Part, 6-9 parts, water 4-9 parts of 30wt%-50wt% pure-acrylic emulsions；Described B component is made up of following raw material：15wt%-20wt%
3-5 parts of acrylic resin aqueous isopropanol, Tissuemat E or microwax 1-2 parts, solvent 3-6 parts；
The application process of described nano stone surface conditioning agent：Stone surface after greasy dirt is cleared up, is first ground with component A
Throwing is processed, then grinding and polishing treatment is carried out with B component, and component A, the consumption of B component are respectively 40-80g/m2、20-30g/m2, you can
Stone surface forms firm, wear-resisting specular layer.
2. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that described oxalates is oxalic acid
One or two mixtures in any proportion in sodium and potassium oxalate.
3. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that described fluosilicate is fluorine
One or more mixtures in any proportion in sodium metasilicate, magnesium fluosilicate, aluminum fluosilicate.
4. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that described Tissuemat E weight is equal
Molecular weight is 2000-5000.
5. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that described microwax is divided equally again
Son amount is 500-1000.
6. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that described solvent be isopropanol,
One or more mixtures in any proportion in ethyl acetate, butyl acetate.
7. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that the acrylic resin is city
Sell BR-116, or one or both of DM-810 acrylic resins mixture in any proportion.
8. a kind of nano stone surface conditioning agent according to claim 1, it is characterised in that the pure-acrylic emulsion is commercially available
AcronalDS-6266ap, or BA-201 pure-acrylic emulsions one or both mixture in any proportion.
9. the preparation method of one of claim 1-8 described nano stone surface conditioning agent, it is characterised in that including following step
Suddenly：
(1) component A is prepared：Following raw material is weighed by weight：1-2 parts of 5wt%-10wt% oxalate solutions, 5wt%-
3-5 parts of 10wt% silicate fluoride solutions, 6-9 parts, water 4-9 parts of 30wt%-50wt% pure-acrylic emulsions；Then by oxalate solution,
40-50 DEG C is warming up to after silicate fluoride solution mixing, adds pure-acrylic emulsion and water, the lower reaction 15min-45min of stirring to obtain final product A
Component；
(2) B component is prepared：Following raw material is weighed by weight：3-5 parts of 15wt%-20wt% acrylic resin aqueous isopropanols,
Tissuemat E or microwax 1-2 parts, solvent 3-6 parts；Then acrylic resin aqueous isopropanol is heated to 60-80 DEG C, stirring
It is lower to add Tissuemat E or microwax, insulation reaction 4-6h to be cooled to room temperature and add solvent, 15min-45min to obtain final product B component.
10. the application process of one of claim 1-8 described nano stone surface conditioning agent, it is characterised in that：In cleaning oil
Stone surface after dirt, first carries out grinding and polishing treatment with component A, then grinding and polishing treatment, component A, the consumption of B component are carried out with B component
Respectively 40-80g/m2、20-30g/m2, you can form firm, wear-resisting specular layer in stone surface.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694003A (en) * | 2015-03-17 | 2015-06-10 | 高飞 | Anti-fouling waterproof stone-like coating |
| CN105315008A (en) * | 2015-10-16 | 2016-02-10 | 江苏名和集团有限公司 | Concrete surface reinforcing sealant and preparation method thereof |
| CN107964372A (en) * | 2016-10-20 | 2018-04-27 | 佛山市高明区(中国科学院)新材料专业中心 | A kind of stone material crystal face agent and preparation method thereof |
| CN110157338A (en) * | 2019-07-03 | 2019-08-23 | 郑州石宝宝科技有限公司 | A kind of surface coating formula antiscuffing paste for lithotome |
| CN110551450B (en) * | 2019-10-24 | 2021-05-04 | 湖南柯盛新材料有限公司 | Decorative stone brightening agent and preparation method and application thereof |
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| CN101343191A (en) * | 2008-08-26 | 2009-01-14 | 浙江大学 | Permeation type hydraulic stone cultural relics reinforcing material and reinforcing method |
| CN101607833A (en) * | 2009-07-23 | 2009-12-23 | 浙江大学 | The reinforcement material of permeable hydraulic degraded loose rocks and reinforcement means |
| CN102180702A (en) * | 2010-12-29 | 2011-09-14 | 广东新粤建材有限公司 | Stone surface treating agent, preparation method thereof and stone surface treating method |
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2014
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101343191A (en) * | 2008-08-26 | 2009-01-14 | 浙江大学 | Permeation type hydraulic stone cultural relics reinforcing material and reinforcing method |
| CN101607833A (en) * | 2009-07-23 | 2009-12-23 | 浙江大学 | The reinforcement material of permeable hydraulic degraded loose rocks and reinforcement means |
| CN102180702A (en) * | 2010-12-29 | 2011-09-14 | 广东新粤建材有限公司 | Stone surface treating agent, preparation method thereof and stone surface treating method |
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