CN107858828A - Quantum material coating, its preparation method, quantum material coated cloth - Google Patents
Quantum material coating, its preparation method, quantum material coated cloth Download PDFInfo
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- CN107858828A CN107858828A CN201711138832.XA CN201711138832A CN107858828A CN 107858828 A CN107858828 A CN 107858828A CN 201711138832 A CN201711138832 A CN 201711138832A CN 107858828 A CN107858828 A CN 107858828A
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- 239000000463 material Substances 0.000 title claims abstract description 72
- 239000004744 fabric Substances 0.000 title claims abstract description 38
- 239000011248 coating agent Substances 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 13
- 238000002604 ultrasonography Methods 0.000 claims description 9
- 239000004575 stone Substances 0.000 claims description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- 229910052613 tourmaline Inorganic materials 0.000 claims description 3
- 239000011032 tourmaline Substances 0.000 claims description 3
- 229940070527 tourmaline Drugs 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 2
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims description 2
- 239000010436 fluorite Substances 0.000 claims description 2
- 229910052629 lepidolite Inorganic materials 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 229910052590 monazite Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 229910052851 sillimanite Inorganic materials 0.000 claims description 2
- 239000010455 vermiculite Substances 0.000 claims description 2
- 229910052902 vermiculite Inorganic materials 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 229910052681 coesite Inorganic materials 0.000 abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 abstract description 4
- 230000036541 health Effects 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 3
- 230000002688 persistence Effects 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 206010001497 Agitation Diseases 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to fabric modifying field, and in particular to quantum material coating for coating the textiles such as cloth and preparation method thereof, and the cloth for coating to obtain using the quantum material coating.The quantum material coating is by following components and the product form of percentage by weight：Quantum material powder 25 35%, SiO2 10 20%, sodium lignin sulfonate 5 15%, ethanol 50 80%.The quantum material coating has good associativity with cloth, it is possible to increase the persistence in terms of quantum effects are played of quantum material coated cloth；Solid content can effectively be combined with fabric fibre in coating, while will not influence materials serve because of the problems such as quantum material is wrapped.The coated cloth obtained using foregoing quantum material coating preparation, suitable for being processed as a variety of specific health products, the application field of material is extensive, and market prospects are good.
Description
Technical field
The present invention relates to fabric modifying field, and in particular to for coat the textiles such as cloth quantum material coating and
Its preparation method, and the cloth for coating to obtain using the quantum material coating.
Background technology
With the progress of economic society and the raising of people's living standard, demand of the in the market for health product
It is stepped up.Quantum material is a kind of material with special physico-chemical property, has been widely used in field of health care products
(CN106673634A、CN106800409A、CN106698636A)。
Traditional quantum material product, is mostly scattered in the matrix materials such as resin by the dusty material with quantum activity
In.Among being largely wrapped in matrix resin due to quantum material, can not directly it be contacted with air and/or user, its amount
Sub- activation plays degree is extremely low, causes the waste of material.
To solve this problem, prior art proposes quantum material is applied to cloth (including fabric in the form of thin layer
And non-woven fabrics etc.) on, so as to obtain the cloth with quantum activity.In order to realize inorganic quantum material powder and cloth
Effectively combine, method disclosed in prior art includes：By quantum material with coupling agent etc. carry out surface it is modified, direct spraying with
Fabric face, but quantum material granule is much larger than string diameter, coupling agent is difficult to the former is effectively fixed；By quantum material
After material mixes with resin, fabric face is sprayed at, but this mode is deposited substantially or by quantum material using resin as carrier
The waste of material the problems such as.
The content of the invention
To solve problems of the prior art, the present invention proposes a kind of quantum material coating, and the coating does not have to resin
Carrier, effective combination can be formed with fabric, improve the quantum activity and durability of quantum material fabric.
Specifically, the quantum material coating is by following components and the product form of percentage by weight：
The present invention is with SiO2As inorganic bond, quantum material powder and sodium lignin sulfonate are glued together, the former
Playing and quantum activity effect is provided, the latter can be conjugated with fabric fibre by ring, firm combination is played in hydrogen bond and esterification etc.,
So as to which quantum material powder is fixed on fabric, without introducing resin matrix, the hair of quantum material activity is not interfered with
Wave.
The raw material of the quantum material powder is not particularly limited, as long as quantum material as known in the art can be made
It is raw mill into powder.Preferably, the quantum material be selected from di-iron trioxide, ferroso-ferric oxide, tourmaline, six ring stones,
Monazite, dodge keratite, six faceted pebbles, medical stone, magnesite, fluorite, quartz, red iron-stone, mica, lepidolite, vermiculite, wollastonite,
One or more in sillimanite, gangue, volcanic rock.
In order to further improve fixed effect of the quantum material powder on fabric, it is preferred to use compared with the powder of small particle.
Preferably, using modes such as ball millings, quantum material powder of the particle diameter at 1-20 μm is obtained.
On the other hand, there is provided the preparation method of the quantum material coating, comprise the following steps：
S1, quantum material powder, sodium lignin sulfonate mixed with ethanol, ultrasound mixes；
S2, tetraethyl orthosilicate is added into step S1 homomixtures, ultrasound mixes；
S3, sodium hydrate aqueous solution is added dropwise under the conditions of ultrasonic mixing；
S4, after being added dropwise, continue to be ultrasonically treated, then stop ultrasound and impose mechanical agitation, be cooled to room temperature, i.e.,
.
By method provided by the present invention, acted on using the high efficiency dispersion of ultrasound, quantum material powder can be prepared
End, sodium lignin sulfonate and SiO2Doping body, avoid SiO2It is the above two are fully wrapped around so that coating solid content has good
Fabric associativity.Additional heat is brought due to being ultrasonically treated, after hydrolyzing phase stopping supersound process, conversion mechanical agitation, can
System is gradually cooled down under admixture, prevent particle from drawing quenching and stopping mixing and undesirably reunite.
Preferably, the ultrasonic power is 400-800W, using large power supersonic, it is possible to achieve effectively scattered, anti-
Only reunite and wrap up.Further preferred step S1 is ultrasonically treated 20-30min, S2 and is ultrasonically treated 5-10min.
Preferably, in step S3, the addition of sodium hydroxide is the 0.05-0.5% of tetraethyl orthosilicate quality, in 10-
It is added dropwise in 15min.
Preferably, in step S4, continue to be ultrasonically treated 20-50min, mechanical agitation rotating speed is 200-500rpm.
Another further aspect, the present invention provide quantum material coated cloth, and it is coated on cloth by foregoing quantum material coating
Form.
Preferably, the coated weight of the quantum material coating is 50-100g/m2.The cloth is not particularly limited, can
To be non-woven fabrics, glue viscous fiber cloth, cotton etc..It is preferred that using cotton as base fabric, cotton fiber has tiny branch's fento, and it can
And sodium lignin sulfonate.
The beneficial effects of the present invention are：
1st, a kind of quantum material coating is provided, it has good associativity with cloth, it is possible to increase quantum material coats
The persistence in terms of quantum effects are played of cloth.
The 2nd, the preparation method of foregoing quantum material coating is provided, solid content in coating is effectively tied with fabric fibre
Close, while materials serve will not be influenceed because of the problems such as quantum material is wrapped.
3rd, the coated cloth obtained using foregoing quantum material coating preparation, suitable for being processed as a variety of specific health products,
The application field of material is extensive, and market prospects are good.
Embodiment
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described.Based on this
Embodiment in invention, the every other reality that those of ordinary skill in the art are obtained under the premise of creative work is not made
Example is applied, belongs to the scope of protection of the invention.
Embodiment 1
Prepare quantum material, by di-iron trioxide, ferroso-ferric oxide, tourmaline, medical stone, wollastonite and volcanic rock according to
0.5:0.5:2:1.5:0.5:0.1 mass ratio, put into ZOOKIN JM-1000 ball mills, grind 1h, obtain quantum material
Powder.
The foregoing quantum material powders of 300g, 150g sodium lignin sulfonates are added in JP-240ST type ultrasonic machines, added
800g ethanol, 30min is disperseed with 500W power ultrasonics.200g tetraethyl orthosilicates are then added, ultrasound point is continued with equal-wattage
Dissipate 5min.
The NaOH aqueous solution that 10mL concentration is 0.02g/mL is added dropwise into mixture, is added dropwise in 12min, and continue
After being ultrasonically treated 30min, room temperature is cooled to 500rpm mechanical agitations to system, produces quantum material coating.
Embodiment 2
With 500g/m2Cotton be base fabric, according to 50g/m2Coating weight, the quantum material that embodiment 1 is prepared applies
Material is sprayed on cloth cover, and horizontal obtains the cotton of quantum material coating after ethanol volatilization.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. quantum material coating, it is characterised in that by following components and the product form of percentage by weight：
2. quantum material coating according to claim 1, it is characterised in that the quantum material be selected from di-iron trioxide,
Ferroso-ferric oxide, tourmaline, six ring stones, monazite, dodge keratite, six faceted pebbles, medical stone, magnesite, fluorite, quartz, red iron-stone,
One or more in mica, lepidolite, vermiculite, wollastonite, sillimanite, gangue, volcanic rock.
3. quantum material coating according to claim 1, it is characterised in that the particle diameter of the quantum material powder is 1-20
μm。
4. the preparation method of quantum material coating according to claim 1, it is characterised in that comprise the following steps：
S1, quantum material powder, sodium lignin sulfonate mixed with ethanol, ultrasound mixes；
S2, tetraethyl orthosilicate is added into step S1 homomixtures, ultrasound mixes；
S3, sodium hydrate aqueous solution is added dropwise under the conditions of ultrasonic mixing；
S4, after being added dropwise, continue to be ultrasonically treated, then stop ultrasound and impose mechanical agitation, be cooled to room temperature, produce.
5. preparation method according to claim 4, it is characterised in that the ultrasonic power is 400-800W.
6. preparation method according to claim 5, it is characterised in that step S1 is ultrasonically treated at 20-30min, S2 ultrasound
Manage 5-10min.
7. preparation method according to claim 4, it is characterised in that in step S3, the addition of sodium hydroxide is positive silicon
The 0.05-0.5% of acetoacetic ester quality, is added dropwise in 10-15min.
8. preparation method according to claim 4, it is characterised in that in step S4, continue to be ultrasonically treated 20-50min, machine
Tool speed of agitator is 200-500rpm.
9. quantum material coated cloth, it is characterised in that it is to coat the quantum material coating described in claim any one of 1-3
In being formed on cloth.
10. quantum material coated cloth according to claim 9, it is characterised in that the coated weight of the quantum material coating
For 50-100g/m2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711138832.XA CN107858828A (en) | 2017-11-16 | 2017-11-16 | Quantum material coating, its preparation method, quantum material coated cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711138832.XA CN107858828A (en) | 2017-11-16 | 2017-11-16 | Quantum material coating, its preparation method, quantum material coated cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107858828A true CN107858828A (en) | 2018-03-30 |
Family
ID=61701939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711138832.XA Pending CN107858828A (en) | 2017-11-16 | 2017-11-16 | Quantum material coating, its preparation method, quantum material coated cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107858828A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108532015A (en) * | 2018-04-20 | 2018-09-14 | 唐山三友集团兴达化纤有限公司 | A kind of method and flame retardant viscose fiber preparing flame retardant viscose fiber based on self-assembling technique |
| CN108641465A (en) * | 2018-04-19 | 2018-10-12 | 浙江爱升婴童用品有限公司 | A kind of infrared antibacterial composite material of high-efficiency catalytic activity nano-negative ion, preparation method and application |
| CN109096893A (en) * | 2018-07-17 | 2018-12-28 | 合肥尚强电气科技有限公司 | A kind of weather-resistant coating preparation method of cable |
| CN110342918A (en) * | 2019-05-15 | 2019-10-18 | 中德道合科技有限公司 | A kind of crystallite new material and its application |
| CN113201932A (en) * | 2021-04-28 | 2021-08-03 | 常州市美尔娜服饰有限公司 | Volcanic fabric |
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Cited By (6)
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|---|---|---|---|---|
| CN108641465A (en) * | 2018-04-19 | 2018-10-12 | 浙江爱升婴童用品有限公司 | A kind of infrared antibacterial composite material of high-efficiency catalytic activity nano-negative ion, preparation method and application |
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| CN108532015B (en) * | 2018-04-20 | 2021-03-05 | 唐山三友集团兴达化纤有限公司 | Method for preparing flame-retardant viscose fiber based on self-assembly technology and flame-retardant viscose fiber |
| CN109096893A (en) * | 2018-07-17 | 2018-12-28 | 合肥尚强电气科技有限公司 | A kind of weather-resistant coating preparation method of cable |
| CN110342918A (en) * | 2019-05-15 | 2019-10-18 | 中德道合科技有限公司 | A kind of crystallite new material and its application |
| CN113201932A (en) * | 2021-04-28 | 2021-08-03 | 常州市美尔娜服饰有限公司 | Volcanic fabric |
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Application publication date: 20180330 |