CN105199606B - A kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material and preparation method thereof - Google Patents
A kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material and preparation method thereof Download PDFInfo
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- CN105199606B CN105199606B CN201510708014.3A CN201510708014A CN105199606B CN 105199606 B CN105199606 B CN 105199606B CN 201510708014 A CN201510708014 A CN 201510708014A CN 105199606 B CN105199606 B CN 105199606B
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Abstract
The invention discloses imitative baked wheaten cake stone material water burnt-in sand environmental protection coating material of a kind of high stability and preparation method thereof, the coating is made up of base paint, Protection glue, continuous phase and mortar, and wherein the weight ratio of base paint, Protection glue and continuous phase is 12：0.35‑0.75：0.5 0.75, the weight ratio of the mortar and the base paint, Protection glue and continuous phase gross weight is 1：1.Mortar and continuous phase have chiltern texture in the coating, and spraying effect has stone material permeability and high emulation, can directly spray the imitative bush-hammered face effect for burning stone material without intermediate base layer bottoming, one-shot forming, save construction and material cost.And emulsion is made using special silane grafting process and without soap body system, film is existing good for machine ground sealing, there is excellent weather resistance and stability again, due to special silane group, make the colorful color tablets in water burnt-in sand coating that there is certain toughness, effectively prevent color tablets from wearing, because emulsion is free of APEO, meet environment protection requirement.
Description
Technical field
The present invention relates to building coating preparation field, and in particular to there is one kind excellent stability and height to imitate fired slab
Water burnt-in sand environmental protection coating material of stone material and preparation method thereof.
Background technology
The progress of society causes modern to improve constantly the understanding of surrounding environment, cherishes the earth, protects ours
Health, this idea that goes back to nature just increasingly are advocated by modern, pursued.Therefore the harmonious coexistence that Nature and Man occupies makes
Obtain selection of the people to construction material parian paint and be driven onto safety and environmental protection.The excellent properties of water-soluble colorful coating and stone material
High simulation quality assigns its wide application field, and water-soluble colorful coating obtains the favor of client with its unique effect.
As living standard improves constantly, people can not be satisfied with original straight-shade coating again, imitate stone, individual character
Changing design will be more and more, and the splendid water burnt-in sand coating of decorative effect undoubtedly turns into the optimal selection of designer and client.
Fired slab stone material is favored by designer in recent years with its serious texture, durable quality, various color.
Burning stone material processing technology has the shortcomings that certain and limitation：First, burning matte can only make to the stone material of granite class mostly
With；Second, stone material, after high temperature is burnt, surface ruptures, weatherability declines, some whites it is granite fired after
Matte highlights iron rust freckle；Third, stone material burns technique for the theories such as low-carbon stone material, energy consumption is larger, does not meet environmental protection
It is required that.Burn stone material using the shortcomings that be also it will be apparent that one be expensive price, two be construction it is complicated, three be that deadweight is high
Difficulty is combined with insulation, many users is hung back.
In order to reach fired slab stone effect, some domestic companies are typically achieved the goal using following two modes：First,
Using texture or true mineral varnish as substrate, then in surface spraying water-soluble colorful coating.But such way can cause pass of constructing
Increase, increase human cost, and due to water-soluble colorful coating color dot merged well with substrate cause it is final
For color dot as floating over substrate, the natural effect for imitating stone is poor.2nd, water-soluble colorful coating and true mineral varnish are mixed and made into coating.This
Kind way has certain improvement compared with for the first on construction pass, but is also acquired a certain degree of difficulty in production technology, such as due to
Water-soluble colorful coating color dot poor toughness, mutability is broken when being mixed with true mineral varnish, bleeding, and stores and upper there is also easy layering and tie
The phenomenon of block.
Compared with traditional true mineral varnish, water burnt-in sand coating is better than true mineral varnish in the stability of color.Water burnt-in sand coating it is more
The raw material of kind of color can realize by industrialized production, and the color of true mineral varnish places one's entire reliance upon the color of natural colour sand,
Fewer and fewer now with natural colour sand resource, the uncontrollability of color significantly impacts the development of true mineral varnish.Water burnt-in sand coating
It is the product of a new generation, it is easier than traditional true mineral varnish method in construction, as common multicolor finish construction method, no
Need intermediate base layer bottoming directly to spray the imitative bush-hammered face effect for burning stone material, save construction and material cost.Simultaneously
Because the color dot in water burnt-in sand coating and continuous phase contain true stone particle, third dimension and material sense are stronger, can create almost
With the baked wheaten cake stone effect as former stone so that final spraying effect is more true to nature, and fidelity can reach 100%.
And fidelity and stability are always two big short slabs of imitative fired slab stone substrate coating, and the choosing of building stone-like coating
Select developing direction.Water burnt-in sand coating not only has decoration protective effect, and construction is simple saves man-hour.Existing water burnt-in sand applies
Material is granulated difficult, the stirring frangible bleeding of color dot in production technology, and poor storage stability, imitation stone effect are not true to nature enough.
The content of the invention
Based on the problems of above-mentioned prior art, the present invention provides a kind of high stability imitative baked wheaten cake stone material water burnt-in sand ring
Friendly coating and preparation method thereof, the spraying effect of the coating have the permeability and high emulation of stone material, one-shot forming, saved significantly
About construction and material cost, simple production process, product storage stability is good.
In order to solve the above technical problems, the present invention provides, a kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material, should
Coating is made up of base paint, Protection glue, continuous phase and mortar, wherein, the weight ratio of the base paint, Protection glue and continuous phase
For 1-2：0.35-0.75：0.5-0.75, the weight ratio of the mortar and the base paint, Protection glue and continuous phase gross weight
For 1：1；
The base paint is made up of following raw material by weight：
The Protection glue is made up of following raw material by weight：
Deionized water 923-933
Protect rubber powder 65-75
Cellulose 2；
The continuous phase is made up of following raw material by weight：
The mortar is made up of following raw material by weight：
In above-mentioned coating, the cellulose in the base paint is using in hydroxyethyl cellulose, hydroxypropyl methyl cellulose
The mixture of any one or two kinds；
Cellulose in the Protection glue and mortar uses hydroxyethyl cellulose.
In above-mentioned coating, dispersant in the base paint using any one in Quadrafos, polyacrylate or
The mixture that two kinds of person.
In above-mentioned coating, defoamer in the base paint, continuous phase and mortar is using mineral oil defoaming agent, organic
The mixture of any one or two kinds in silicon defoaming agent.
In above-mentioned coating, the thickener in the continuous phase and mortar is increased using alkali swelling type thickener, association type
Any mixture of any one or two kinds in thick dose.
In above-mentioned coating, the antifreezing agent in the base paint, continuous phase and mortar is using ethylene glycol, propane diols
In any one or two kinds mixture.
In above-mentioned coating, the coalescents in the base paint, continuous phase and mortar are using alcohol ester 12, second two
The mixture of any one or two kinds in alcohol butyl ether.
In above-mentioned coating, the rutile titanium white powder rutile titanium dioxide in the base paint；
The pure acrylic latex in the continuous phase and mortar uses pure acrylate copolymer emulsion.
The embodiment of the present invention also provides a kind of high stability the imitative preparation method for burning stone material water burnt-in sand environmental protection coating material, and it is special
Sign is, for preparing coating of the present invention, including：
Base paint, Protection glue, continuous phase and mortar are prepared respectively by composition of raw materials of the present invention, are recycled and are made
Base paint, Protection glue, continuous phase and mortar prepare coating finished product, wherein,
Prepare base paint：
By deionized water in basic raw materials for varnish and cellulose, dispersant, defoamer, bactericide, pH adjusting agent, antifreezing agent and
Coalescents are added to that stirrer for mixing is uniform, add rutile titanium white powder 800-1000r/min rotating speed at a high speed point
Dissipate the rotating speed moderate-speed mixer for uniformly, being then separately added into pure acrylic latex, antiseepage toner, protective agent 400-600r/min again
20min, is eventually adding defoamer, bactericide and quartz sand and stirs and obtain base paint；
Prepare Protection glue：
Deionized water in Protection glue raw material, protection rubber powder, cellulose are added to stirrer for mixing stirring, stirring speed
Spend for 800-1000r/min, it is Protection glue to stir the colourless transparent solution obtained after 60-120min；
Prepare continuous phase：
Deionized water in continuous phase raw material and bactericide, defoamer, antifreezing agent, coalescents and pH adjusting agent are added
Stirrer for mixing is uniform, then adds organic-silicon-modified emulsion and thickener 200-300r/min rotating speed stirring at low speed
15min obtains continuous phase；
Prepare mortar：
By the deionized water in mortar raw material and cellulose, dispersant, defoamer, bactericide, pH adjusting agent, antifreezing agent
It is uniform that stirrer for mixing is added to coalescents, is then separately added into pure acrylic latex and thickener 200-300 again
Rotating speed stirring at low speed 15min, be eventually adding after quartz sand stirs and obtain mortar；
Prepare coating finished product：
It is by weight 1-2：0.35-0.75：0.5-0.75 ratio takes base paint obtained above, Protection glue and continuous
Phase, first base paint, Protection glue and continuous phase are stirred, then will be with the base paint, Protection glue and continuous phase gross weight
For 1：1 mortar is added thereto the packaging that stirs and obtains the imitative baked wheaten cake stone material water burnt-in sand environmental protection coating material finished product of high stability.
Beneficial effects of the present invention are：Mortar and continuous phase have chiltern texture in the coating so that the spraying of coating
Effect has a permeability and high emulation of stone material, while it is imitative in terms of construction not need intermediate base layer bottoming directly to spray
The bush-hammered face effect of stone material is burnt, one-shot forming, greatlys save construction and material cost.And the emulsion used in the coating is adopted
It is made with special silane grafting process and without soap body system, film is existing good for machine ground sealing, has again excellent
Weatherability and stability, simultaneously because carry special silane group, make the obtained imitative base burnt in stone material water burnt-in sand coating
The color tablets that plinth paint makes have certain toughness, effectively prevent color tablets to be worn, simultaneously because emulsion is free of APEO, also meet
The environment protection requirement of low emission.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, rather than whole embodiments.Based on embodiments of the invention, ordinary skill
The every other embodiment that personnel are obtained under the premise of creative work is not made, belongs to protection scope of the present invention.
The coating and preparation method of the present invention are described further with reference to specific embodiment.
Embodiment one
The present embodiment provides that a kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material, by base paint, Protection glue, continuous
Phase and mortar, are formed, its preparation method is by weight proportion：Base paint, Protection glue, continuous phase and mortar are first prepared respectively
Material, finally prepares coating finished product again, specifically includes that (the dosage unit of following raw materials being related to is:Kilogram)：
A:The preparation of base paint：
Each raw material of base paint is taken by upper table, by the material rate in base paint formulation by deionized water, cellulose, scattered
It is uniform that agent, defoamer, bactericide, pH adjusting agent, antifreezing agent and coalescents are added to stirrer for mixing, adds rutile
Titanium dioxide is uniformly dispersed at a high speed with 800-1000r/min rotating speed, be then separately added into again pure acrylic latex, antiseepage toner,
Protective agent 400-600r/min rotating speed moderate-speed mixer 20min, is eventually adding defoamer, bactericide and quartz sand and stirs
Obtain base paint.
B:The preparation of Protection glue：
| Deionized water | 923 |
| Protect rubber powder | 75 |
| Hydroxyethyl cellulose | 2 |
Each raw material of glue is fetched protection by upper table, the deionized water in Protection glue raw material, protection rubber powder, cellulose are once added
Stirred to stirrer for mixing, mixing speed 800-1000r/min, stir the colourless transparent solution obtained after 60-120min
As Protection glue.
C：The preparation of continuous phase：
Take each raw material of continuous phase by upper table, by the deionized water in continuous phase raw material, bactericide, defoamer, antifreezing agent, into
It is uniform that film auxiliary agent and pH adjusting agent are added to stirrer for mixing, is then separately added into organic-silicon-modified emulsion again and thickener is used
200-300r/min rotating speed stirring at low speed 15min obtains continuous phase.
D:The preparation of mortar：
Take each raw material of mortar by upper table, by mortar raw material by deionized water, cellulose, dispersant, defoamer, kill
It is uniform that microbial inoculum, pH adjusting agent, antifreezing agent and coalescents are added to stirrer for mixing, is then separately added into pure acrylic acid breast again
The rotating speed stirring at low speed 15min of liquid and thickener 200-300r/min, is eventually adding after quartz sand stirs and obtains sand
Slurry.
It is prepared by coating finished product：
| Base paint | 220 |
| Protection glue | 140 |
| Continuous phase | 140 |
| Mortar | 500 |
Base paint obtained above, Protection glue and continuous phase are pressed into the dosage in upper table, stirred, then by mortar
The imitative baked wheaten cake stone material water burnt-in sand environmental protection coating material finished product of high stability is obtained after being added thereto the packaging that stirs.
Embodiment two
The present embodiment provides that a kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material, by base paint, Protection glue, continuous
Mutually formed by weight proportion with mortar, its preparation method is：Base paint, Protection glue, continuous phase and mortar are first prepared respectively,
Coating finished product is finally prepared again, specifically includes that (the dosage unit of following raw materials being related to is:Kilogram)：
A:The preparation of base paint：
| Deionized water | 185 |
| Hydroxyethyl cellulose | 5 |
| Hydroxyethyl cellulose | 4 |
| Dispersant | 1.5 |
| Coalescents | 10 |
| Antifreezing agent | 5 |
| Rutile titanium white powder | 5 |
| PH conditioning agents | 1.5 |
| Pure acrylic latex | 300 |
| Bactericide | 3 |
| Protective agent | 60 |
| Antiseepage toner | 3 |
| Defoamer | 3 |
| Quartz sand | 404 |
The specific preparation process of above-mentioned base paint is the same as embodiment one.
B:The preparation of Protection glue：
| Deionized water | 933 |
| Protect rubber powder | 65 |
| Hydroxyethyl cellulose | 2 |
The specific preparation process of above-mentioned Protection glue is the same as embodiment one.
C：The preparation of continuous phase：
| Deionized water | 375 |
| PH conditioning agents | 0.5 |
| Coalescents | 30 |
| Antifreezing agent | 30 |
| Defoamer | 2 |
| Bactericide | 1.5 |
| Organic-silicon-modified emulsion | 580 |
| Thickener | 30 |
The specific preparation process of above-mentioned continuous phase is the same as embodiment one.
D:The preparation of mortar：
| Deionized water | 100 |
| Hydroxyethyl cellulose | 1.5 |
| PH conditioning agents | 0.5 |
| Coalescents | 7 |
| Antifreezing agent | 7 |
| Defoamer | 2 |
| Bactericide | 2 |
| Pure acrylic latex | 200 |
| Thickener | 30 |
| Quartz sand | 650 |
The specific preparation process of above-mentioned mortar is the same as embodiment one.
The preparation of coating finished product：
The specific preparation process of above-mentioned coating finished product is the same as embodiment one.
Mortar and continuous phase have chiltern texture in the water burnt-in sand environmental protection coating material of the present invention, and there is spraying effect stone material to lead to
Permeability and high emulation, it can directly spray the imitative bush-hammered face effect for burning stone material, one-shot forming, section without intermediate base layer bottoming
About construction and material cost.And emulsion is made using special silane grafting process and without soap body system, existing good pair of film
In machine ground sealing, there is excellent weather resistance and stability again, due to special silane group, making in water burnt-in sand coating
Colorful color tablets have certain toughness, effectively prevent color tablets from wearing, and because emulsion is free of APEO, meet environment protection requirement.Tool
Have and store the characteristics of imitating fired slab stone material with pelleting stability and height, production granulation not bleeding can be reached, color dot is not easy
Broken, storage is not easy to be layered, the requirement of construction is simple, while also has the fidelity of height.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can readily occur in,
It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims
Enclose and be defined.
Claims (9)
1. a kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that the coating by base paint, Protection glue,
Continuous phase and mortar composition, wherein, the weight ratio of the base paint, Protection glue and continuous phase is 1-2：0.35-0.75：0.5-
0.75, the weight ratio of the mortar and the base paint, Protection glue and continuous phase gross weight is 1：1；
The base paint is made up of following raw material by weight：
Cellulose in the base paint is using any one in hydroxyethyl cellulose, hydroxypropyl methyl cellulose or two kinds
Mixture；
The Protection glue is made up of following raw material by weight：
Deionized water 923-933
Protect rubber powder 65-75
Cellulose 2；
The continuous phase is made up of following raw material by weight：
The mortar is made up of following raw material by weight：
2. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Cellulose in Protection glue and mortar uses hydroxyethyl cellulose.
3. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Dispersant in base paint is using any one in Quadrafos, polyacrylate or two kinds of mixture.
4. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Defoamer in base paint, continuous phase and mortar using any one in mineral oil defoaming agent, organic silicon defoamer or
The mixture that two kinds of person.
5. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Thickener in continuous phase and mortar is using any one in alkali swelling type thickener, association thickener or two kinds
Any mixture.
6. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
The antifreezing agent in base paint, continuous phase and mortar is using any one in ethylene glycol, propane diols or two kinds
Mixture.
7. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Coalescents in base paint, continuous phase and mortar using any one in alcohol ester 12, butyl glycol ether or
The mixture that two kinds of person.
8. a kind of high stability according to claim 1 is imitative to burn stone material water burnt-in sand environmental protection coating material, it is characterised in that described
Rutile titanium white powder rutile titanium dioxide in base paint；
The pure acrylic latex in the base paint and mortar uses pure acrylate copolymer emulsion.
9. the imitative preparation method for burning stone material water burnt-in sand environmental protection coating material of a kind of high stability, it is characterised in that for preparing right
It is required that the coating described in 1 to 8 any one, including：
Composition of raw materials as described in any one of claim 1 to 8 prepares base paint, Protection glue, continuous phase and mortar respectively, then
Coating finished product is prepared using obtained base paint, Protection glue, continuous phase and mortar, wherein,
Prepare base paint：
By deionized water in basic raw materials for varnish and cellulose, dispersant, defoamer, bactericide, pH adjusting agent, antifreezing agent and film forming
Auxiliary agent is added to that stirrer for mixing is uniform, and the rotating speed for adding rutile titanium white powder 800-1000r/min is scattered equal at a high speed
It is even, pure acrylic latex, antiseepage toner, protective agent 400-600r/min rotating speed moderate-speed mixer are then separately added into again
20min, is eventually adding defoamer, bactericide and quartz sand and stirs and obtain base paint；
Prepare Protection glue：
Deionized water in Protection glue raw material, protection rubber powder, cellulose are added to stirrer for mixing stirring, mixing speed is
800-1000r/min, it is Protection glue to stir the colourless transparent solution obtained after 60-120min；
Prepare continuous phase：
Deionized water in continuous phase raw material and bactericide, defoamer, antifreezing agent, coalescents and pH adjusting agent are added and stirred
It is well mixed in machine, then adds organic-silicon-modified emulsion and thickener 200-300r/min rotating speed stirring at low speed
15min obtains continuous phase；
Prepare mortar：
By the deionized water in mortar raw material and cellulose, dispersant, defoamer, bactericide, pH adjusting agent, antifreezing agent and into
Film auxiliary agent is added to that stirrer for mixing is uniform, is then separately added into turning for pure acrylic latex and thickener 200-300 again
Fast stirring at low speed 15min, is eventually adding after quartz sand stirs and obtains mortar；
Prepare coating finished product：
It is by weight 1-2：0.35-0.75：0.5-0.75 ratio takes base paint, Protection glue and continuous phase obtained above,
First base paint, Protection glue and continuous phase are stirred, will be then 1 with the base paint, Protection glue and continuous phase gross weight：
1 mortar is added thereto the packaging that stirs and obtains the imitative baked wheaten cake stone material water burnt-in sand environmental protection coating material finished product of high stability.
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590425B (en) * | 2016-11-17 | 2019-07-19 | 济南好饰家化工有限公司 | Imitative bush-hammered face water burnt-in sand multicolor finish and preparation method and the application on insulation board |
| CN108948843A (en) * | 2018-07-13 | 2018-12-07 | 宁波大宝涂料有限公司 | The colorful hot glue of water burnt-in sand joins 5D nest mineral varnish |
| CN109635391B (en) * | 2018-11-30 | 2022-10-28 | 中国航空工业集团公司沈阳飞机设计研究所 | Simulation method of bicontinuous phase composite material |
| CN111484777A (en) * | 2019-01-28 | 2020-08-04 | 嘉兴市威纳建材有限公司 | High-solid-content cross-linking reaction sand-coated colorful stone-like paint and preparation method thereof |
| CN110003796A (en) * | 2019-02-09 | 2019-07-12 | 东阳市富士星涂料有限公司 | A kind of novel aqueous multicolor finish |
| CN110358384B (en) * | 2019-06-14 | 2023-07-14 | 河北晨阳工贸集团有限公司 | Sand-in-water multicolor paint and preparation method thereof |
| CN114085584B (en) * | 2021-12-20 | 2022-05-13 | 亚士创能科技(上海)股份有限公司 | Litchi surface multicolor paint and preparation method and application thereof |
| CN117229659A (en) * | 2023-09-15 | 2023-12-15 | 浙江瑞迪新材料股份有限公司 | High-texture sand-in-water coating and preparation method thereof |
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| CN102719162A (en) * | 2012-06-20 | 2012-10-10 | 浙江博星化工涂料有限公司 | Water-based artificial granite paint |
| CN104312351A (en) * | 2014-11-17 | 2015-01-28 | 广西启利新材料科技股份有限公司 | Sand-in-water colorful imitation stone paint |
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| CN102719162A (en) * | 2012-06-20 | 2012-10-10 | 浙江博星化工涂料有限公司 | Water-based artificial granite paint |
| CN102701640A (en) * | 2012-06-25 | 2012-10-03 | 吉林科龙建筑节能科技股份有限公司 | Water-based colorful architectural coating and preparation method thereof |
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