CN109181545A - A kind of granitic lacquer of high emulation and its preparation process - Google Patents
A kind of granitic lacquer of high emulation and its preparation process Download PDFInfo
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- CN109181545A CN109181545A CN201810934752.3A CN201810934752A CN109181545A CN 109181545 A CN109181545 A CN 109181545A CN 201810934752 A CN201810934752 A CN 201810934752A CN 109181545 A CN109181545 A CN 109181545A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of granitic lacquers of high emulation, including below according to the raw material of parts by weight: 80-95 parts of water, 150-170 parts of lacquer lotion, 5-10 parts of cellulose, 15-30 parts of coalescing agent, color sand 200-400 parts, 3-7 parts of thickener, 5-8 parts of bacteriostatic agent of mixing, 20-40 parts of propylene glycol, 50-80 parts of magnesium stearate, 70-90 parts of silicone acrylic emulsion, 8-20 parts of super-fine zinc dust；Lacquer mixed stability obtained by the present invention is good；Easy construction, spraying property be good, drying and forming-film when do not crack, film has hardness after drying and forming-film；Adhesive force and the good magnesium stearate of weatherability have excellent lubrication stably dispersing effect.
Description
Technical field
The present invention relates to technical field of coatings, the granitic lacquer of specifically a kind of high emulation and its preparation process.
Background technique
It is base-material that mineral varnish, which is by one or more synthetic resin emulsions, a small amount of coalescing agent is added as binding material,
Using the natural colour sand of different gradation or artificial sand as aggregate, it is quantitatively adding dispersing agent, defoaming agent, fungicide, multifunctional assistant, increasing
A series of auxiliary agents such as thick dose add a kind of decorative effect that quantitative deionized water is prepared and exactly like marble, granite etc.
The high-quality of stone material, high performance building coating.Lacquer is to form pattern and match volume, reaches sufficiently high hardness, and
Assign a kind of coating of coating lithotome color.
But most lacquers currently on the market are there are texture perception is poor, the deficiencies such as imitation stone fidelity is low；In addition,
Lacquer multiselect uses styrene-acrylic emulsion as film forming matter in the market, and a large amount of ethylene glycol is added to improve the freeze proof of lacquer
Property, so that such product has the shortcomings that weatherability is poor, VOC content is high, the feature of environmental protection is poor more, it is difficult to meet the needs of client；With
Raising of the people to coating for internal and external wall cosmetic requirement, lacquer is with its unique appearance and performance increasingly by everybody
Like, many high-end residentials, garden even high buildings and large mansions all propose to cover with paint, lacquer, colour wash, etc. and the natural stone appearances such as natural granite, marble
Very similar lacquer requires stronger hardness, waterproof, ageing-resistant etc. in aspect of performance.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide a kind of granitic lacquer of high emulation and its preparation process
The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 80-95 parts of water, lacquer lotion
150-170 parts, 5-10 parts of cellulose, 15-30 parts of coalescing agent, color sand 200-400 parts of mixing, 3-7 parts of thickener, bacteriostatic agent 5-
8 parts, 20-40 parts of propylene glycol, 50-80 parts of magnesium stearate, 70-90 parts of silicone acrylic emulsion, 8-20 parts of super-fine zinc dust.
As a further solution of the present invention: including below according to the raw material of parts by weight: 83-90 parts of water, lacquer lotion
155-160 parts, 6-9 parts of cellulose, 18-25 parts of coalescing agent, color sand 260-300 parts of mixing, 4-6 parts of thickener, bacteriostatic agent 6-7
Part, propylene glycol 28-38,55-70 parts of magnesium stearate, 76-80 parts of silicone acrylic emulsion, 12-17 parts of super-fine zinc dust.
As further scheme of the invention: the mixing color sand is by the color sand of different-grain diameter, mountain flour and artificial imitative stone
What particle was constituted, wherein the color sand is by the artificial color sand of 15-30 mesh, the artificial color sand of 40-80 mesh and natural colour sand, 80-120
Mesh natural colour sand, 120-130 mesh natural colour sand be composed, the artificial color sand of the 40-80 mesh and 40-80 mesh natural colour sand
Mass ratio be 2:5-8:3.
As further scheme of the invention: the mountain flour is the natural stone-powder of 160 mesh of 65-120 part, described artificial imitative
20-50 parts of stone particle
As further scheme of the invention: the coalescing agent is in 12 type coalescing agent of ethylene glycol phenyl ether and alcohol ester
One kind.
As further scheme of the invention: the bacteriostatic agent is inorganic fungicide.
As further scheme of the invention: the thickener is that polyurethane thickener is synthesis macromolecule, preferably
Polyethylene glycol oxide.
The preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.5-9 by S4, then addition amine neutralizer, adds mixing color sand, thickener and magnesium stearate, heating
Stirring 20-30 minutes to get
As further scheme of the invention: in step S1, mixing speed 90-120r/min is stirred 15 minutes.
As further scheme of the invention: in step S4, heating temperature is 60-85 DEG C.
Compared with prior art, the beneficial effects of the present invention are: lacquer mixed stability obtained by the present invention is good；It applies
Work is easy, spraying property is good, drying and forming-film when do not crack, film has hardness after drying and forming-film；Adhesive force and weatherability are well hard
Fatty acid magnesium has excellent lubrication stably dispersing effect, and loose webs thixotropy structure is introduced in mineral varnish, can prevent from expecting
Particle sedimentation, improves the stability of mineral varnish；Magnesium stearate, which also has, simultaneously urges stemness, can promote the rate of drying of mineral varnish.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 80 parts of water, lacquer lotion 150-
Part, 5 parts of cellulose, 15 parts of coalescing agent, 200 parts of color sand of mixing, 3 parts of thickener, 5 parts of bacteriostatic agent, 20 parts of propylene glycol, stearic acid
50 parts of magnesium, 70 parts of silicone acrylic emulsion, 8 parts of super-fine zinc dust.
The mixing color sand is made of the color sand of different-grain diameter, mountain flour and artificial imitative stone particle, wherein the color sand is
It is composed of the natural colour sand of the artificial color sand of 15 mesh, the artificial color sand of 40 mesh and natural colour sand, 80 mesh natural colour sands, 120 mesh,
The mass ratio of the artificial color sand of 40 mesh and 40 mesh natural colour sands is 2:5, and the mountain flour is the natural stone-powder of 65 part of 160 mesh, institute
State artificial 20 parts of imitative stone particle.
The coalescing agent is ethylene glycol phenyl ether；The bacteriostatic agent is inorganic fungicide, and the thickener is polyurethane
Thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
In the present embodiment, the preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.5 by S4, then addition amine neutralizer, is added mixing color sand, thickener and magnesium stearate, heating and is stirred
Mix 20 minutes to get.
In step S1, mixing speed 90r/min is stirred 15 minutes, and in step S4, heating temperature is 60 DEG C.
Embodiment 2
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 95 parts of water, lacquer lotion 170
Part, 10 parts of cellulose, 30 parts of coalescing agent, 400 parts of color sand of mixing is 7 parts of thickener, 8 parts of bacteriostatic agent, 40 parts of propylene glycol, stearic
80 parts of sour magnesium, 90 parts of silicone acrylic emulsion, 20 parts of super-fine zinc dust.
The mixing color sand is made of the color sand of different-grain diameter, mountain flour and artificial imitative stone particle, wherein the color sand is
It is composed of the natural colour sand of the artificial color sand of 30 mesh, the artificial color sand of 80 mesh and natural colour sand, 120 mesh natural colour sands, 130 mesh
, the mass ratio of the artificial color sand of 80 mesh and 80 mesh natural colour sands is 8:3, and the mountain flour is the natural stone of 120 part of 160 mesh
Powder, artificial 20 parts of the imitative stone particle.
The coalescing agent is ethylene glycol phenyl ether；The bacteriostatic agent is inorganic fungicide, and the thickener is polyurethane
Thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
In the present embodiment, the preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.6 by S4, then addition amine neutralizer, is added mixing color sand, thickener and magnesium stearate, heating and is stirred
Mix 20 minutes to get.
In step S1, mixing speed 120r/min is stirred 15 minutes, and in step S4, heating temperature is 85 DEG C
Embodiment 3
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 83 parts of water, lacquer lotion 155
Part, 6 parts of cellulose, 18 parts of coalescing agent, 260 parts of color sand of mixing, 4 parts of thickener, 6 parts of bacteriostatic agent, propylene glycol 28, magnesium stearate
55 parts, 76 parts of silicone acrylic emulsion, 12 parts of super-fine zinc dust.
The mixing color sand is made of the color sand of different-grain diameter, mountain flour and artificial imitative stone particle, wherein the color sand is
It is composed of the natural colour sand of the artificial color sand of 15 mesh, the artificial color sand of 40 mesh and natural colour sand, 80 mesh natural colour sands, 120 mesh,
The mass ratio of the artificial color sand of 40 mesh and 40 mesh natural colour sands is 2:5, and the mountain flour is the natural stone-powder of 65 part of 160 mesh, institute
State artificial 20 parts of imitative stone particle.
The coalescing agent is 12 type coalescing agent of alcohol ester；The bacteriostatic agent is inorganic fungicide, and the thickener is
Polyurethane thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
In the present embodiment, the preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.7 by S4, then addition amine neutralizer, is added mixing color sand, thickener and magnesium stearate, heating and is stirred
Mix 20 minutes to get.
In step S1, mixing speed 100r/min is stirred 15 minutes, and in step S4, heating temperature is 80 DEG C
Embodiment 4
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 90 parts of water, lacquer lotion 160
Part, 9 parts of cellulose, 25 parts of coalescing agent, 300 parts of color sand of mixing, 6 parts of thickener, 7 parts of bacteriostatic agent, propylene glycol 38, magnesium stearate
70 parts, 80 parts of silicone acrylic emulsion, 17 parts of super-fine zinc dust.
The mixing color sand is made of the color sand of different-grain diameter, mountain flour and artificial imitative stone particle, wherein the color sand is
It is composed of the natural colour sand of the artificial color sand of 30 mesh, the artificial color sand of 80 mesh and natural colour sand, 120 mesh natural colour sands, 130 mesh
, the mass ratio of the artificial color sand of 80 mesh and 80 mesh natural colour sands is 8:3, and the mountain flour is the natural stone of 120 part of 160 mesh
Powder, artificial 50 parts of the imitative stone particle.
The coalescing agent is ethylene glycol phenyl ether；The bacteriostatic agent is inorganic fungicide, and the thickener is polyurethane
Thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
In the present embodiment, the preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 9 by S4, then addition amine neutralizer, adds mixing color sand, thickener and magnesium stearate, heating stirring
30 minutes to get.
In step S1, mixing speed 100r/min is stirred 15 minutes, and in step S4, heating temperature is 85 DEG C
Embodiment 5
A kind of granitic lacquer of high emulation, including below according to the raw material of parts by weight: 85 parts of water, lacquer lotion 158
Part, 8 parts of cellulose, 20 parts of coalescing agent, 280 parts of color sand of mixing, 5 parts of thickener, 6.5 parts of bacteriostatic agent, propylene glycol 33, stearic acid
65 parts of magnesium, 78 parts of silicone acrylic emulsion, 15 parts of super-fine zinc dust.
The mixing color sand is made of the color sand of different-grain diameter, mountain flour and artificial imitative stone particle, wherein the color sand is
It is composed of the natural colour sand of the artificial color sand of 30 mesh, the artificial color sand of 80 mesh and natural colour sand, 120 mesh natural colour sands, 130 mesh
, the mass ratio of the artificial color sand of 80 mesh and 80 mesh natural colour sands is 8:3, and the mountain flour is the natural stone of 120 part of 160 mesh
Powder, artificial 50 parts of the imitative stone particle.
The coalescing agent is 12 type coalescing agent of alcohol ester；The bacteriostatic agent is inorganic fungicide, and the thickener is
Polyurethane thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
In the present embodiment, the preparation method of the granitic lacquer of high emulation, steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.8 by S4, then addition amine neutralizer, is added mixing color sand, thickener and magnesium stearate, heating and is stirred
Mix 25 minutes to get.
In step S1, mixing speed 100r/min is stirred 15 minutes, and in step S4, heating temperature is 85 DEG C.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of granitic lacquer of high emulation, which is characterized in that including below according to the raw material of parts by weight: water 80-95
Part, 150-170 parts of lacquer lotion, 5-10 parts of cellulose, 15-30 parts of coalescing agent, color sand 200-400 parts is mixed, thickener
3-7 parts, 5-8 parts of bacteriostatic agent, 20-40 parts of propylene glycol, 50-80 parts of magnesium stearate, 70-90 parts of silicone acrylic emulsion, super-fine zinc dust 8-20
Part.
2. the granitic lacquer of high emulation according to claim 1, which is characterized in that including below according to parts by weight
Raw material: 83-90 parts of water, 155-160 parts of lacquer lotion, 6-9 parts of cellulose, 18-25 parts of coalescing agent, mix color sand 260-
300 parts, 4-6 parts of thickener, 6-7 parts of bacteriostatic agent, propylene glycol 28-38,55-70 parts of magnesium stearate, 76-80 parts of silicone acrylic emulsion, surpass
Thin 12-17 parts of zinc powder.
3. the granitic lacquer of high emulation according to claim 2, which is characterized in that the mixing color sand is by difference
What color sand, mountain flour and the artificial imitative stone particle of partial size were constituted, wherein the color sand is by the artificial color sand of 15-30 mesh, 40-80 mesh
Artificial color sand and natural colour sand, 80-120 mesh natural colour sand, 120-130 mesh natural colour sand be composed, the 40-80 mesh
The mass ratio of artificial color sand and 40-80 mesh natural colour sand is 2:5-8:3.
4. the granitic lacquer of high emulation according to claim 3, which is characterized in that the mountain flour is 65-120 parts
The natural stone-powder of 160 mesh, artificial 20-50 parts of the imitative stone particle.
5. the granitic lacquer of high emulation according to claim 1, which is characterized in that the coalescing agent is second two
One of 12 type coalescing agent of alcohol phenyl ether and alcohol ester.
6. the granitic lacquer of high emulation according to claim 1, which is characterized in that the bacteriostatic agent is inorganic kills
Microbial inoculum.
7. the granitic lacquer of high emulation according to claim 1, which is characterized in that the thickener is polyurethane
Thickener is synthesis macromolecule, preferably polyethylene glycol oxide.
8. a kind of preparation process of the granitic lacquer of high emulation as claimed in claim 1, which is characterized in that
Steps are as follows:
S1, the cellulose solution that cellulose and a part of water are first mixed into 5%；
S2,5% cellulose solution is added in remaining water, after stirring a period of time, coalescing agent and bacteriostatic agent is added；
S3, lacquer lotion, silicone acrylic emulsion, propylene glycol and super-fine zinc dust is added into mixture again；
PH value is adjusted to 8.5-9 by S4, then addition amine neutralizer, adds mixing color sand, thickener and magnesium stearate, heating
Stirring 20-30 minutes to get.
9. the preparation process of the granitic lacquer of high emulation according to claim 8, which is characterized in that step S1
In, mixing speed 90-120r/min is stirred 15 minutes.
10. the preparation process of the granitic lacquer of high emulation according to claim 8, which is characterized in that step S4
In, heating temperature is 60-85 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810934752.3A CN109181545A (en) | 2018-08-16 | 2018-08-16 | A kind of granitic lacquer of high emulation and its preparation process |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810934752.3A CN109181545A (en) | 2018-08-16 | 2018-08-16 | A kind of granitic lacquer of high emulation and its preparation process |
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| CN109181545A true CN109181545A (en) | 2019-01-11 |
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| CN201810934752.3A Pending CN109181545A (en) | 2018-08-16 | 2018-08-16 | A kind of granitic lacquer of high emulation and its preparation process |
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Cited By (4)
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| CN111732372A (en) * | 2020-06-28 | 2020-10-02 | 江苏春之声装饰材料有限公司 | High-weather-resistance anti-cracking stone-like paint for wall and preparation method thereof |
| CN113621260A (en) * | 2021-09-02 | 2021-11-09 | 浙江曼得丽涂料有限公司 | Acrylic magic color rock particle stone-like paint and preparation method thereof |
| CN113956739A (en) * | 2021-11-29 | 2022-01-21 | 广东美家美福科技有限公司 | Granite coating and preparation process thereof |
| CN114292557A (en) * | 2021-12-29 | 2022-04-08 | 亚士漆(上海)有限公司 | Finishing-free real stone paint and preparation method and application thereof |
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| CN111732372A (en) * | 2020-06-28 | 2020-10-02 | 江苏春之声装饰材料有限公司 | High-weather-resistance anti-cracking stone-like paint for wall and preparation method thereof |
| CN113621260A (en) * | 2021-09-02 | 2021-11-09 | 浙江曼得丽涂料有限公司 | Acrylic magic color rock particle stone-like paint and preparation method thereof |
| CN113956739A (en) * | 2021-11-29 | 2022-01-21 | 广东美家美福科技有限公司 | Granite coating and preparation process thereof |
| CN114292557A (en) * | 2021-12-29 | 2022-04-08 | 亚士漆(上海)有限公司 | Finishing-free real stone paint and preparation method and application thereof |
| CN114292557B (en) * | 2021-12-29 | 2022-12-09 | 亚士漆(上海)有限公司 | Finishing-free stone-like paint and preparation method and application thereof |
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Application publication date: 20190111 |