CN102719157B - Spraying rubber cement for decoration and preparation method thereof - Google Patents
Spraying rubber cement for decoration and preparation method thereof Download PDFInfo
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- CN102719157B CN102719157B CN201210161231.1A CN201210161231A CN102719157B CN 102719157 B CN102719157 B CN 102719157B CN 201210161231 A CN201210161231 A CN 201210161231A CN 102719157 B CN102719157 B CN 102719157B
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Abstract
The present invention discloses a spraying rubber cement for decoration and a preparation method thereof. The spraying rubber cement is prepared from raw materials by weight as follows: from 3 to 5 % of cellulose; from 40 to 50 % of water; from 1 to 2 % of glycerol; from 1 to 3 % of liquid paraffin; from 1 to 3 % of calcium halophosphate fluorescent powder; from 5 to 10 % of an emulsion; from 8 to 15 % of nanometer level calcium carbonate powder and from 25 to 40 % of soluble glass. The emulsion is an aqueous acrylic acid emulsion or a styrene acrylic emulsion. The spraying rubber cement is detected according to national quality standards and all detect items are qualified. The spraying rubber cement has excellent comprehensive properties, such as cohesive strength, water resistance property, acid resistance property, alkaline resistance property, salt fog resistance property and the like; the spraying cement is healthy and eco-friendly; the spraying cement has bright layer colors and strong third dimension; the spraying cement has no obstruction in spraying; and the spraying cement has a low production cost.
Description
Technical field
The present invention relates to a kind of finishing spraying rubber cement, particularly relate to a kind of finishing spraying rubber cement and preparation method thereof, be mainly used in construction work internal wall finishing.
Background technology
In general, interior wall coating is after having plastered.After wall puzzles, carry out render and set, when second, basal plane can be put down substantially.Because the requirement of interior wall is higher than exterior wall, so higher to the requirement meeting of planeness, so generally all can criticize putty, the effect of putty is to make metope more smooth.Generally, putty can be criticized Liang Zhi tri-roads.First bottoming, uses the slightly putty of a bit, and second starts levelling, can use choice refreshments.Whether San road depending on circumstances will be criticized.Every batch of one putty all should be polished, particularly together last.After polishing is good, remove floating dust, start priming, after priming paint parches, go up again twice finish paint.
Visible, after construction work indoor wall plaster, often need putty levelling and coating ornamental surface, to reach effect attractive in appearance, that decorate, and realize the functions such as moistureproof.Wall decoration workload in fitting-out work is large, occupies fitting-out work cost ratio large, and labor strength is large, significant to decoration company.
The constructional method of coating generally has brush, rolls, sprays, criticizes four kinds.Brush is material-saving, but more time-consuming.The effect everyway rolling is the comparison golden mean of the Confucian school, is not material-saving, neither effect best, but comparatively speaking, this is the form of construction work that cost performance is higher.The effect of spray is relatively good, but not too easily repairs.The effect of criticizing is best, but takes material most.Spraying is by spray gun or dish formula spraying gun, by means of pressure or centrifugal force, is dispersed into even and fine droplet, is applied over the coating process on coated article surface.Spraying operation production efficiency is high, is applicable to handwork and industrial automation and produces.With respect to other constructional methods, can save a large amount of manually, and speed up the work, and can ensure the quality of products, but spraying there is higher requirement to coating.
Chinese invention patent 200510057418.7 discloses a kind of sprayed coating of imitative stone material.This coating is made up of base-material, auxiliary material, caking agent, surperficial paint vehicle, the consisting of of each component (being weight part below) base-material: jade powder+putty powder; Wherein jade powder 80～120 orders, 8～35 parts; Putty powder 200 orders, 45～60 parts; Auxiliary material: whitening agent and thickening material; 0.1～0.5 part, whitening agent; 0.2～0.6 part of thickening material; Caking agent: glue+Mierocrystalline cellulose+water soluble acrylic acid; Wherein 7～25 parts, glue; 0.3～10 part of Mierocrystalline cellulose; 1.0～7 parts of water soluble acrylic acids.The hardness of this coating and marble, granite are suitable, and have certain toughness, have beautiful decoration for exterior wall, do not come off, ftracture, and soak indeformable, nontoxic advantage.This sprayed coating is mainly used for preparing the material of imitative stone material, and its decorative effect is mainly the effect that represents stone material, not for replacing putty and decorative paint.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of spraying rubber cement that can direct spraying, can directly with gunite machine, pulp spraying be coated on plaster metope, make metope there is stereoscopic sensation, colored beautiful, economic technology simple, without coating, good decorating effect, whole synthesis performance is good.
The object of the invention is achieved through the following technical solutions:
Spraying rubber cement for a kind of finishing, by mass percentage, its composition of raw materials is as follows:
A, Mierocrystalline cellulose 3-5%
B, water 40-50%
C, glycerol 1-2%
D, whiteruss 1-3%
E, halogen calcium phosphate fluoressent powder 1-3%
F, emulsion 5-10%
G, nanometer grade calcium carbonate powder 8-15%
H, water glass 25-40%
Described emulsion is aqueous acrylic emulsion or benzene emulsion.
For further realizing the object of the invention, the consumption of described water glass is preferably 30-35%.
The consumption of described silicone modified styrene-acrylate emulsion is preferably 6-8%.
Described aqueous acrylic emulsion is preferably 996AD or BLJ-998AD; Described benzene emulsion is preferably A-62,3099 or BLJ-816 benzene emulsion.
The median size of described nanometer grade calcium carbonate powder is preferably 60-70nm.
Described Mierocrystalline cellulose is selected Mierocrystalline cellulose or the methylcellulose gum (MC) of sodium carboxymethyl-cellulose (CMC).
The preparation method of spraying rubber cement for described finishing, comprises the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 20-30 hour;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, silicone modified styrene-acrylate emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
Described aqueous acrylic emulsion is selected Acrylic Ester Emulsion Modified by Organ ic-siloxanes; In organic-silane-modified acrylic ester (organic siloxane modified acrylic acid emulsion) macromolecular chain on Siliciumatom connect alkyl and be subject to after thermooxidizing, what generate is highly cross-linked more stable Si-O-Si key, can prevent its main chain break degraded, and Si-O-Si bond energy and ground tight bond, improve carbonaceous layer and the ground sticking power in the time of high temperature, therefore can effectively improve the easy deciduous of carbonaceous layer.Aqueous acrylic emulsion can be selected the 996AD of the rich Industrial Co., Ltd. of Ahmedabad, the BLJ-998AD of Shanghai Bao Lijia Chemical Co., Ltd..
Benzene emulsion is selected the Shanghai BLJ-816 of Bao Lijia Chemical Co., Ltd. benzene emulsion, the Shanghai A-62 of Zhen Zhou chemistry painting industry company limited benzene emulsion, the federal Chemical Co., Ltd. in Nantong 3099 benzene emulsions; The federal Chemical Co., Ltd. in Nantong 3099 benzene emulsions have excellent water tolerance, scrub resistance, anti-stain characteristic compared with common phenylpropyl alcohol.There is good color developing and tint retention and levelling brushing property preferably with the exterior coating that these product are made.
With respect to prior art, tool of the present invention has the following advantages and beneficial effect:
(1) the present invention is directly coated in pulp spraying in plaster aspect and (does not re-use coating) with gunite machine, makes surface have stereoscopic sensation and good decorative effect.
(2) product of the present invention detects according to state quality standard, and all test items are qualified.
(3) excellent combination property such as product of the present invention spraying rubber cement cohesive strength, water resistance, acid resistance, alkaline resistance properties and salt fog resistance, and health environment-friendly, figure layer color is beautiful, and stereoscopic sensation is strong, sprays accessiblely, and cost is low.
Embodiment
In order further to understand the present invention, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these are described is for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
Embodiment 1
A kind of inner wall of building decoration type putty, by mass percentage, decoration type putty is made up of 35% A component and 65% B component; Wherein the raw materials quality per-cent formula of A component and B component is as follows:
Formula:
Spraying rubber cement for a kind of finishing, by mass percentage, its composition of raw materials is as follows:
A, Mierocrystalline cellulose 3.5%
B, water 45%
C, glycerol 1.5%
D, whiteruss 2.5%
E, halogen calcium phosphate fluoressent powder 1.5%
F, emulsion 6%
G, nanometer grade calcium carbonate powder 10%
H, water glass 30%
The median size of nanometer grade calcium carbonate powder is 60-70nm
Mierocrystalline cellulose is selected the Mierocrystalline cellulose of sodium carboxymethyl-cellulose (CMC).
Emulsion is selected the federal Chemical Co., Ltd. in Nantong 3099 benzene emulsions.
The median size of nanometer grade calcium carbonate powder is 60-70nm.
The preparation method of spraying rubber cement for this finishing, comprises the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 20 hours;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, silicone modified styrene-acrylate emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
After the spraying rubber cement spraying that the present embodiment makes, appearance stereoscopic sensation is strong, and color is beautiful.Humidity is under 50-80% condition, and spraying rubber cement performance prepared by the present embodiment detects according to the standard of table 1, the finishing obtaining by the performance test results of spraying rubber cement film in table 1:
Table 1
The present embodiment detects according to state quality standard, and all test items are qualified.The excellent combination properties such as spraying rubber cement cohesive strength, water resistance, acid resistance, alkaline resistance properties and salt fog resistance that the present embodiment obtains, and health environment-friendly, figure layer color is beautiful, and stereoscopic sensation is strong, sprays accessiblely, and cost is low.
Embodiment 2
Spraying rubber cement for a kind of finishing, by mass percentage, its composition of raw materials is as follows:
A, Mierocrystalline cellulose 5%
B, water 40%
C, glycerol 2%
D, whiteruss 3%
E, halogen calcium phosphate fluoressent powder 3%
F, emulsion 10%
G, nanometer grade calcium carbonate powder 10%
H, water glass 27%
The median size of nanometer grade calcium carbonate powder is 60-70nm
Mierocrystalline cellulose is selected methylcellulose gum (MC).
Emulsion is selected the Shanghai BLJ-816 of Bao Lijia Chemical Co., Ltd. benzene emulsion.
The preparation method of spraying rubber cement for this finishing, comprises the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 25 hours;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, silicone modified styrene-acrylate emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
After the spraying rubber cement spraying that the present embodiment makes, appearance stereoscopic sensation is strong, and color is beautiful.Humidity is under 50-80% condition, and spraying rubber cement performance prepared by the present embodiment detects according to the standard of table 1, the finishing obtaining by the performance test results of spraying rubber cement film in table 2:
Table 2
The present embodiment detects according to state quality standard, and all test items are qualified.The excellent combination properties such as spraying rubber cement cohesive strength, water resistance, acid resistance, alkaline resistance properties and salt fog resistance that the present embodiment obtains, and health environment-friendly, figure layer color is beautiful, and stereoscopic sensation is strong, sprays accessiblely, and cost is low.
Embodiment 3
A kind of inner wall of building decoration type putty, by mass percentage, decoration type putty is made up of 35% A component and 65% B component; Wherein the raw materials quality per-cent formula of A component and B component is as follows: formula:
Spraying rubber cement for a kind of finishing, by mass percentage, its composition of raw materials is as follows:
A, Mierocrystalline cellulose 3%
B, water 41%
C, glycerol 1%
D, whiteruss 1%
E, halogen calcium phosphate fluoressent powder 1%
F, emulsion 5%
G, nanometer grade calcium carbonate powder 8%
H, water glass 40%
The median size of nanometer grade calcium carbonate powder is 60-70nm
Mierocrystalline cellulose is selected the Mierocrystalline cellulose of sodium carboxymethyl-cellulose (CMC).
Emulsion is aqueous acrylic emulsion, selects the 996AD of the rich Industrial Co., Ltd. of Ahmedabad.
The median size of nanometer grade calcium carbonate powder is 60-70nm.
The preparation method of spraying rubber cement for this finishing, comprises the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 30 hours;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, silicone modified styrene-acrylate emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
After the spraying rubber cement spraying that the present embodiment makes, appearance stereoscopic sensation is strong, and color is beautiful.Humidity is under 50-80% condition, and spraying rubber cement performance prepared by the present embodiment detects according to the standard of table 1, the finishing obtaining by the performance test results of spraying rubber cement film in table 3:
Table 3
The present embodiment detects according to state quality standard, and all test items are qualified.The excellent combination properties such as spraying rubber cement cohesive strength, water resistance, acid resistance, alkaline resistance properties and salt fog resistance that the present embodiment obtains, and health environment-friendly, figure layer color is beautiful, and stereoscopic sensation is strong, sprays accessiblely, and cost is low.
Claims (6)
1. a spraying rubber cement for finishing, is characterized in that: by mass percentage, its composition of raw materials is as follows:
A, Mierocrystalline cellulose 3 ?5%
B, water 40 ?50%
C, glycerol 1 ?2%
D, whiteruss 1 ?3%
E, halogen calcium phosphate fluoressent powder 1 ?3%
F, emulsion 5 ?10%
G, nanometer grade calcium carbonate powder 8 ?15%
H, water glass 25 ?40%
Described emulsion is aqueous acrylic emulsion or benzene emulsion;
Described aqueous acrylic emulsion is 996AD or BLJ-998AD;
Described benzene emulsion is A-62,3099 or BLJ-816 benzene emulsion;
When preparation, comprise the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 20 ?30 hours;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
2. spraying rubber cement for finishing according to claim 1, is characterized in that: by mass percentage, the consumption of described water glass be 30 ?35%.
3. spraying rubber cement for finishing according to claim 1, is characterized in that: by mass percentage, the consumption of described benzene emulsion be 6 ?8%.
4. spraying rubber cement for finishing according to claim 1, is characterized in that: the median size of described nanometer grade calcium carbonate powder be 60 ?70nm.
5. spraying rubber cement for finishing according to claim 1, is characterized in that: described Mierocrystalline cellulose is selected Mierocrystalline cellulose or the methylcellulose gum of sodium carboxymethyl-cellulose.
6. the finishing preparation method who sprays rubber cement described in claim 1, is characterized in that comprising the steps:
(1) take Mierocrystalline cellulose, glycerol, water glass and water by formula, mix, react at normal temperatures 20 ?30 hours;
(2) take whiteruss, halogen calcium phosphate fluoressent powder, emulsion and nanometer grade calcium carbonate powder by formula, mix;
(3) step (2) gained mixture is added in step (1) products therefrom and mixed under agitation condition.
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| CN103343005B (en) * | 2013-07-13 | 2015-05-13 | 上海洞舟实业有限公司 | High-stability carbon nanometer fluorescence dye |
| CN104327628A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Fluorescent paint for glass doors, and its preparation method |
| CN106189630A (en) * | 2016-07-29 | 2016-12-07 | 上海轩颂建筑科技有限公司 | A kind of rendering technique of wall face figure floriation |
| CN115537095A (en) * | 2022-04-13 | 2022-12-30 | 安徽宏飞钓具有限公司 | Luminous multi-section flexible bionic bait and preparation method thereof |
| CN115093729B (en) * | 2022-07-26 | 2024-01-02 | 富思特新材料科技发展股份有限公司 | Self-luminous pollution-resistant fireproof material and preparation method and application thereof |
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| CN1358805A (en) * | 2000-12-14 | 2002-07-17 | 华中师范大学 | Aqueous inorganic copper-imitated paint and operation method |
| CN1793246A (en) * | 2005-12-31 | 2006-06-28 | 上海申真阿里佳托涂料有限公司 | Anion inorganic nano wall covering |
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Address after: 510640 2A, 2 floor, soil and fertilizer monitoring building, five Academy of Agricultural Sciences, five mountain road, Guangzhou, Guangdong Patentee after: Guangdong Dragon King Jiayuan Decoration Engineering Limited by Share Ltd Address before: 510640 soil and fertilizer monitoring building, five Academy of Agricultural Sciences, five mountain road, Tianhe District, Guangdong Patentee before: Guangzhou Jinglong Decoration Engineering Co.,Ltd. |
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Effective date of registration: 20200102 Address after: 510638 Guangdong city of Guangzhou province Tianhe District five road, building 1, SFI monitoring Patentee after: Guangdong Jing Long Construction Group Co., Ltd. Address before: 510640 Guangdong city of Guangzhou province Tianhe District five road, SFI monitoring building 2 floor 2A Patentee before: Guangdong Dragon King Jiayuan Decoration Engineering Limited by Share Ltd |