CN101250345A - Method for preparing natural sliver paint - Google Patents

Method for preparing natural sliver paint Download PDF

Info

Publication number
CN101250345A
CN101250345A CNA2008100267657A CN200810026765A CN101250345A CN 101250345 A CN101250345 A CN 101250345A CN A2008100267657 A CNA2008100267657 A CN A2008100267657A CN 200810026765 A CN200810026765 A CN 200810026765A CN 101250345 A CN101250345 A CN 101250345A
Authority
CN
China
Prior art keywords
sliver
natural
preparation
emulsion
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2008100267657A
Other languages
Chinese (zh)
Other versions
CN101250345B (en
Inventor
刘春雨
黄广京
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN200810026765A priority Critical patent/CN101250345B/en
Publication of CN101250345A publication Critical patent/CN101250345A/en
Application granted granted Critical
Publication of CN101250345B publication Critical patent/CN101250345B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Paints Or Removers (AREA)

Abstract

The invention disclose a preparation process of natural rock slice paint, which is characterized in that the process comprises the following three technique steps that firstly mixing material to prepare half finished marbleized rock slice paint according to the traditional process, agitating cellulose fiber, water, auxiliary agent and emulsion into paste, then adding natural stone sand, preparing rock slices, mixing 40-45% powder material, emulsion, 25-33% water and 5-10% auxiliary agent into paste according to percentage by weight, making slices, baking and disintegrating into rock slice, and finally mixing half finished marbleized rock slice paint with rock slice in low speed to obtain finished product. The natural rock slice paint which is prepared by the preparing technique of the invention has the advantages of strong adhesion, beautiful decorativeness of natural rock slice, no dropping and cracking and the like.

Description

The preparation method of natural sliver paint
Technical field
The present invention relates to the technical field of fancy paint, more particularly relate to a kind of manufacture method of similar natural sliver paint.
Background technology
At present, decorative paint of a great variety, imitative stone material spray-painting coating also becomes the widely used kind of people, as Chinese patent application number is 200510057418.7, name is called a kind of imitative stone material sprayed coating, the applying date be the patent application of 2005.12.02, it relates to a kind of sprayed coating of imitative stone material.Coating is made up of base-material, auxiliary material, caking agent, surperficial paint vehicle, the consisting of of each component (following be weight part) base-material: jade powder+putty powder; Jade powder 80~120 orders wherein, 8~35 parts; Putty powder 200 orders, 45~60 parts; Auxiliary material: whitening agent and thickening material; 0.1~0.5 part in whitening agent; 0.2~0.6 part of thickening material; Caking agent: glue+Mierocrystalline cellulose+water soluble acrylic acid; Wherein glue is 7~25 parts; 0.3~10 part of Mierocrystalline cellulose; 1.0~7 parts of water soluble acrylic acids.This patent application hardness and marble, granite are suitable, and certain toughness is arranged, and being used for exterior wall has beautiful decoration, does not come off, ftractures, and soaks indeformable, nontoxic advantage.But it adopts the traditional technology preparation still can't reach the effect of right rock.Though someone invents out natural rock lacquer, the natural rock lacquer as the term suggests be outward appearance just as stone grouan, the texture of natural-like stones such as numb stone makes the more apparent nature gracefulness of building decoration, and is steady, the effect of style and random rock matter; Be modern high grade water-soluble paint for decoration, adopt natural granite raw material and the agent of the special thing salt binding of true qualities mat; Be applicable to cement wall, plank, the paper lament, glass, foam sprays on the materials such as glued board, and indoor and outdoor decoration, or industrial art, sculpture for city etc. all can use natural rock sheet lacquer, are subjected to the favorable comment and the recommendation of building decoration circle all over the world at large.Yet, in the preparation process of natural rock lacquer, except that the composition of raw materials factor, the prepared natural rock lacquer effect of coming out of different fabrication process conditions is different, and how preparing the technology and the preferable performance that embody the natural rock decorative effect is the problem that people inquire into.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, and a kind of technical indicator excellence is provided, the preparation method of a kind of natural sliver paint of the true stone effect of sliver shape that strong adhesion, advantage such as do not come off, do not ftracture have.
The technical solution that the present invention adopts in order to solve the problems of the technologies described above is as follows:
The preparation method of this natural sliver paint comprises following three processing steps:
(1), at first carry out the half-finished preparation of parian sliver paint:
Pick out starting material by traditional true mineral varnish earlier and comprise the special-purpose benzene emulsion of true mineral varnish, the color sand of natural thickness of all kinds and various auxiliary agent and water, by the technological process of production of the existing true mineral varnish production work in-process that feed intake, its proportioning (weight percent) is: special-purpose benzene emulsion: the 8-12% of true mineral varnish, each color sand: 70-80% of natural thickness, mixed aid 3-10%, tap water or deionized water: 5-10%, concrete technology is with Mierocrystalline cellulose, water, auxiliary agent, emulsion stirs pulping, add natural stone sand then, it is earlier with Mierocrystalline cellulose, water low speed disperseed 10-15 minute, add auxiliary agent middling speed dispersion 15-20 branch again and plant, stir the 15-20 branch behind the adding benzene emulsion and plant a pulping; Adding natural colour sand mixing 10-15 branch again plants; Promptly get parian sliver paint work in-process;
(2), the preparation of sliver
With elastic styrene acrylic emulsion as filmogen, lime carbonate, kaolin, talcum powder are made as filler and various auxiliary agent and tap water or deionized water and are pulpous state: according to the requirement toning of required sliver color, its weight percent proportioning: elasticity propionic acid emulsion: 20-30%, filler: 40-60%, mixed aid: 5-10%, tap water or deionized water: 30-40%; Work in-process are scraped on plastic paper through being up to the standards, build: slivers such as 3-5mm dry or dry again and are broken into 20-40 order sheet with crusher;
(3), make finished product
The dried rock sliver of parian sliver paint work in-process in above-mentioned first and second step is carried out proportioning: the dried rock sliver of parian sliver work in-process (weight percent): 90-95%: 5-10%, mix to stir and can pack through being up to the standards.
In above-mentioned second processing step, described film-making, dry water content in the process≤5%, the sliver that is broken into is the 20-8 order, thickness is between the 0.6-1.0mm.
In above-mentioned (one) processing step, be that elder generation disperses Mierocrystalline cellulose, water low speed 10-15 minute, add auxiliary agent middling speed dispersion 15-20 branch again and plant, stir the 15-20 branch after the adding emulsion and plant a pulping; The adding mixing 10-15 branch of natural stone sand is planted.
In the preparation process of the second processing step sliver, earlier water, auxiliary agent are disperseed 10 fens kinds with emulsion low speed, add 10 fens kinds of powder middling speed pulping then after, the ability film-making.
In the 3rd processing step, low speed mixing stirred to 8-15 minute when the work in-process in the first step mixed.
Described Mierocrystalline cellulose can adopt Natvosol (HEC), carboxymethyl cellulose (CMC) or methylcellulose gum (MC), wherein Natvosol (HEC) is because its outstanding premium properties, as the hot water or cold water all can dissolve, not have hot gelation, to the good conformability of salt and solvent.The most outstanding is to electrolytical dissolved salt; can be dissolved in the saturated brine of monovalence or polyvalent ion and do not lose its viscosity; HEC has performances such as good thickening, emulsification, dispersion, bonding, bonding, suspension, film forming, antimicrobial, water conservation, protection limbs, salt tolerant, thereby preferentially uses Natvosol (HEC).
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is: the present invention has adopted film-making to dry and be broken into the mode of sliver, makes the sliver paint of preparing have unique decorative effect, and it is quite analogous to natural rock; Simultaneously owing to make product have strong adhesion, beautiful decoration, advantage such as do not come off, do not ftracture, and the rock paint of prior art does not adopt above-mentioned film-making to dry and be broken into the technology of sliver, through experiment relatively, even if adopt identical prescription, also can't reach prepared effect and the performance that goes out of production technique of the present invention.
Description of drawings
Fig. 1 is preparation technology's schema of the present invention.
Embodiment
As shown in Figure 1, the preparation method of natural sliver paint of the present invention comprises following concrete steps:
One), at first carry out the half-finished preparation of parian sliver paint:
The parian sliver paint belongs to a kind of of SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS.Pick out starting material (the special-purpose benzene emulsion of true mineral varnish by traditional true mineral varnish earlier, the color sand of natural thickness of all kinds and various auxiliary agent and water) feed intake by the technological process of production of existing true mineral varnish and to produce work in-process (seeing process flow sheet) and carry out proportioning (weight percent): special-purpose benzene emulsion: the 8-12% of true mineral varnish, each color sand: 70-80% of natural thickness, various auxiliary agent 3-10%, tap water or deionized water: 5-10%, concrete technology is with Mierocrystalline cellulose, water, auxiliary agent, emulsion stirs pulping, add natural stone sand then, it is earlier with Mierocrystalline cellulose, water low speed disperseed 15 minutes, add the auxiliary agent middling speed again and disperse 20 fens kinds, stir 18 fens kind pulpings after the adding emulsion; The adding of natural stone sand mixes 13 fens kinds;
Two), the preparation of sliver
Requirement according to the construction technology and the appearance effect of parian sliver paint, through the approval that repeatedly experimental results show that and obtain each expert, select elastic styrene acrylic emulsion at last as filmogen, lime carbonate, kaolin, talcum powder are made as filler and various auxiliary agent and tap water or deionized water and is pulpous state: according to the requirement toning of client to the sliver color, production technique sees process flow sheet for details.Its weight percent proportioning: elasticity propionic acid emulsion: 20-30%, filler: 40-60%, various auxiliary agents: 5-10%, tap water or deionized water: 30-40%.Work in-process are scraped on plastic paper through being up to the standards, build: slivers such as 3-5mm dry or dry again and are broken into 20-40 order sheet with crusher.Concrete technology be with powder, emulsion, water, auxiliary agent mixing, wherein by weight percentage with behind powder 40-45%, emulsion 20-25%, water 25-33%, the auxiliary agent 5-10% mixing pulping, film-making, dries, and is broken into sliver; Earlier water, auxiliary agent are disperseed 10 fens kinds with emulsion low speed, add 10 fens kinds of powder middling speed pulping then after, the ability film-making.Described film-making, dry water content in the process≤5%, the sliver that is broken into is the 20-8 order, and thickness is between the 0.6-1.0mm.
Three), parian sliver paint
The dried rock sliver of parian sliver paint work in-process in above-mentioned first and second step is carried out proportioning: the dried rock sliver of parian sliver work in-process: 90-95%: 5-10%, low speed mixing stirs can pack through being up to the standards in 8-15 minute.
The half-finished quality control index of sliver pulping in the present invention's second processing step
The control project Controlling index
Outward appearance Do not have caking, be uniform state after the stirring
PH value 8.0-9.0
Viscosity (25 °) KU 105-110
Proportion (25 °) KU 1.20-1.30
Parian sliver paint semi-manufactured goods quality controlling index in the present invention's first processing step
The control project Controlling index
Outward appearance Do not have caking, be uniform state after the stirring
PH value 8.0-9.0
Viscosity (25 °) KU 96-105
Proportion (25 °) KU 1.40-1.60
The sliver paint that the present invention of employing such scheme prepares has strong adhesion, beautiful decoration, advantage such as do not come off, do not ftracture, processing condition in its technological process are to draw through testing repeatedly, adopt the solution of the present invention to have decorative effect preferably, the style elegance is outstanding, can be widely used in various buildings, serve as decorating inner and external walls coating.Dwelling house, villa, public building, aging blocks renewal and reform, garden feature, architectural decorative component etc. all can adopt natural sliver paint of the present invention to carry out spraying and decorating.
Parian natural sliver paint technical target of the product of the present invention and foundation:
Parian natural sliver paint construction technology process of the present invention
Processing base level → body of wall levelling → polishing maintenance cleaning → seal coat → do lattice seam → spraying parian sliver paint → polishing → cover clear finish.

Claims (8)

1, the preparation method of natural sliver paint is characterized in that, it comprises the steps:
(1), at first carries out the half-finished preparation of parian sliver paint
Pick out starting material by traditional true mineral varnish earlier and comprise the special-purpose benzene emulsion of true mineral varnish, the color sand of natural thickness of all kinds and various auxiliary agent and water, by the technological process of production of the existing true mineral varnish production work in-process that feed intake, its proportioning (weight percent) is: special-purpose benzene emulsion: the 8-12% of true mineral varnish, each color sand: 70-80% of natural thickness, mixed aid 3-10%, tap water or deionized water: 5-10%, concrete technology adds natural stone sand then and promptly gets parian sliver paint work in-process for Mierocrystalline cellulose, water, auxiliary agent, emulsion are stirred pulping;
(2), the preparation of sliver
With elastic styrene acrylic emulsion as filmogen, lime carbonate, kaolin, talcum powder are made as filler and various auxiliary agent and tap water or deionized water and are pulpous state: according to the requirement toning of required sliver color, its weight percent proportioning: elasticity propionic acid emulsion: 20-30%, filler: 40-60%, mixed aid: 5-10%, tap water or deionized water: 30-40%; Work in-process are scraped on plastic paper through being up to the standards, build: slivers such as 3-5mm dry or dry again and are broken into 20-40 order sheet with crusher;
(3), make finished product
The dried rock sliver of parian sliver paint work in-process in above-mentioned first and second step is carried out proportioning: the dried rock sliver of parian sliver work in-process (weight percent): 90-95%: 5-10%, mix to stir and can pack through being up to the standards.
2, the preparation method of natural sliver paint according to claim 1 is characterized in that, described film-making, dries water content in the process≤5%, and the sliver that is broken into is the 20-8 order, and thickness is between the 0.6-1.0mm.
3, the preparation method of natural sliver paint according to claim 1 and 2, it is characterized in that, in the half-finished preparation process of the first step parian sliver paint, earlier Mierocrystalline cellulose, water low speed were disperseed 10-15 minute, add auxiliary agent middling speed dispersion 15-20 branch again and plant, stir the 15-20 branch after the adding emulsion and plant a pulping; The adding mixing 10-15 branch of natural stone sand is planted.
4, the preparation method of natural sliver paint according to claim 1 and 2 is characterized in that, in second processing step, earlier general side, auxiliary agent and 10 fens kinds of emulsion low speed dispersion, add 10 fens kinds of powder middling speed pulping then after, the ability film-making.
5, the preparation method of natural sliver paint according to claim 1 and 2 is characterized in that, in the 3rd processing step, low speed mixing stirred to 8-15 minute.
6, the preparation method of natural sliver paint according to claim 1 and 2 is characterized in that, described Mierocrystalline cellulose adopts Natvosol (HEC), carboxymethyl cellulose (CMC) or methylcellulose gum (MC).
7, the preparation method of natural sliver paint according to claim 1 and 2 is characterized in that, parian sliver paint semi-manufactured goods quality controlling index is in the present invention's first processing step:
The control project Controlling index Outward appearance Do not have caking, be uniform state after the stirring PH value 8.0-9.0 Viscosity (25 °) KU 96-105 Proportion (25 °) KU 1.40-1.60
8, the preparation method of natural sliver paint according to claim 1 and 2 is characterized in that, the half-finished quality control index of sliver pulping in the present invention's second processing step
The control project Controlling index Outward appearance Do not have caking, be uniform state after the stirring PH value 8.0-9.0 Viscosity (25 °) KU 105-110 Proportion (25 °) KU 1.20-1.30
CN200810026765A 2008-03-12 2008-03-12 Method for preparing natural sliver paint Expired - Fee Related CN101250345B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200810026765A CN101250345B (en) 2008-03-12 2008-03-12 Method for preparing natural sliver paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200810026765A CN101250345B (en) 2008-03-12 2008-03-12 Method for preparing natural sliver paint

Publications (2)

Publication Number Publication Date
CN101250345A true CN101250345A (en) 2008-08-27
CN101250345B CN101250345B (en) 2012-10-03

Family

ID=39953955

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200810026765A Expired - Fee Related CN101250345B (en) 2008-03-12 2008-03-12 Method for preparing natural sliver paint

Country Status (1)

Country Link
CN (1) CN101250345B (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN103555082A (en) * 2013-11-08 2014-02-05 西北永新涂料有限公司 Real stone paint and preparation method thereof
CN104449169A (en) * 2014-12-31 2015-03-25 韦良 Preparation method of natural slice paint
CN105566991A (en) * 2015-12-17 2016-05-11 李许生 Preparation method of colored composite rock slices
CN105754394A (en) * 2016-05-09 2016-07-13 上海绿特丹保温工程有限公司 Reflective composite rock slice and production technology thereof
CN105780480A (en) * 2016-03-24 2016-07-20 李许生 Preparation method of flexible surface lining material
CN106363836A (en) * 2015-07-22 2017-02-01 广西启利新材料科技股份有限公司 Rock sheet prepared from plastic film
CN106700707A (en) * 2015-07-22 2017-05-24 广西启利新材料科技股份有限公司 Colored rock slice prepared from plastic blank
CN106750736A (en) * 2016-11-11 2017-05-31 社旗县王悦建筑材料销售有限公司 A kind of artificial sliver and preparation method thereof
CN107459276A (en) * 2017-07-04 2017-12-12 孟咸来 A kind of colorful dry granular piece preparation method of grinding stone for being used to manufacture stone-like coating
CN107603290A (en) * 2017-09-21 2018-01-19 苏州振振好新型建材科技有限公司 A kind of tough and tensile weather-proof exterior wall sliver paint
CN108715706A (en) * 2018-06-01 2018-10-30 湘江涂料科技有限公司 Elastic reflective insulation sliver and preparation method thereof and lacquer and preparation method thereof
CN110607085A (en) * 2019-10-08 2019-12-24 刘金江 Preparation process of water-based granite coating for building exterior wall
CN110654038A (en) * 2019-09-29 2020-01-07 刘金江 Preparation method of coating raw material rock slices
CN115340776A (en) * 2022-08-31 2022-11-15 中铁十二局集团有限公司勘测设计分公司 Water-based colorful and highly granite-imitated color stone paint texture coating and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103571254B (en) * 2013-06-20 2016-01-13 江门市华石涂料有限公司 A kind of compound sliver and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322078C (en) * 2005-10-25 2007-06-20 广州秀珀化工有限公司 Inorganic powder texture coating, and its applying method
CN100560667C (en) * 2006-02-23 2009-11-18 富思特制漆(北京)有限公司 Marble paint for building, making method and construction technology thereof
CN100558834C (en) * 2006-07-21 2009-11-11 华南理工大学 A kind of green powdered paint and preparation method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617071A (en) * 2012-03-23 2012-08-01 尚怀兴 High-gloss real stone lacquer and marble simulation lacquer
CN103555082A (en) * 2013-11-08 2014-02-05 西北永新涂料有限公司 Real stone paint and preparation method thereof
CN103555082B (en) * 2013-11-08 2015-06-17 西北永新涂料有限公司 Real stone paint and preparation method thereof
CN104449169A (en) * 2014-12-31 2015-03-25 韦良 Preparation method of natural slice paint
CN106363836A (en) * 2015-07-22 2017-02-01 广西启利新材料科技股份有限公司 Rock sheet prepared from plastic film
CN106700707A (en) * 2015-07-22 2017-05-24 广西启利新材料科技股份有限公司 Colored rock slice prepared from plastic blank
CN105566991A (en) * 2015-12-17 2016-05-11 李许生 Preparation method of colored composite rock slices
CN105780480A (en) * 2016-03-24 2016-07-20 李许生 Preparation method of flexible surface lining material
CN105754394A (en) * 2016-05-09 2016-07-13 上海绿特丹保温工程有限公司 Reflective composite rock slice and production technology thereof
CN106750736A (en) * 2016-11-11 2017-05-31 社旗县王悦建筑材料销售有限公司 A kind of artificial sliver and preparation method thereof
CN106750736B (en) * 2016-11-11 2018-04-06 社旗县王悦建筑材料销售有限公司 A kind of artificial sliver and preparation method thereof
CN107459276A (en) * 2017-07-04 2017-12-12 孟咸来 A kind of colorful dry granular piece preparation method of grinding stone for being used to manufacture stone-like coating
CN107603290A (en) * 2017-09-21 2018-01-19 苏州振振好新型建材科技有限公司 A kind of tough and tensile weather-proof exterior wall sliver paint
CN108715706A (en) * 2018-06-01 2018-10-30 湘江涂料科技有限公司 Elastic reflective insulation sliver and preparation method thereof and lacquer and preparation method thereof
CN108715706B (en) * 2018-06-01 2020-11-13 湘江涂料科技有限公司 Elastic reflective heat-insulation rock slice and preparation method thereof, and stone-like paint and preparation method thereof
CN110654038A (en) * 2019-09-29 2020-01-07 刘金江 Preparation method of coating raw material rock slices
CN110607085A (en) * 2019-10-08 2019-12-24 刘金江 Preparation process of water-based granite coating for building exterior wall
CN115340776A (en) * 2022-08-31 2022-11-15 中铁十二局集团有限公司勘测设计分公司 Water-based colorful and highly granite-imitated color stone paint texture coating and preparation method thereof

Also Published As

Publication number Publication date
CN101250345B (en) 2012-10-03

Similar Documents

Publication Publication Date Title
CN101250345B (en) Method for preparing natural sliver paint
CN101942234B (en) Environment friendly dry powder emulsion paint and preparation method thereof
CN108841274B (en) Preparation method and construction process of multi-dimensional stone-like paint
CN102021985B (en) Thermal insulation textured decorative face brick for building outside wall
CN104559602A (en) Litchi surface stone-like paint and preparation method thereof
CN102617084A (en) Inorganic colorized decoration mortar and preparation method thereof
CN105541230B (en) Imitative stone material dry powder paint and its construction method
CN105693282A (en) Foamed ceramic decorative plate and preparation method thereof
CN102604492A (en) Preparation method of black sand primer paint assorted with ceramic tile simulated outer-wall coating
CN102863859A (en) Energy-saving marble-imitating paint preparation method and product thereof
CN102557557A (en) Decoration mortar for external wall thermal insulation system
CN106396576B (en) A kind of colored plaster decoration wall material and its preparation and application with self-cleaning function
CN105565744A (en) Natural micro-mineral powder
CN102719157A (en) Spraying rubber cement for decoration and preparation method thereof
CN106009793A (en) Dry powder textured paint
CN106396577B (en) A kind of white plaster decoration wall material and its preparation and application with self-cleaning function
CN105152590A (en) Method for producing lightweight artificial culture stone product by adopting high-humidity sludge
CN109233458A (en) A kind of aqueousance artificial granite coating and preparation method thereof
CN101798474A (en) Multi-angle reflect type coating and preparation method thereof
CN103420637B (en) true mineral varnish and preparation method thereof
CN101936060B (en) Method for manufacturing artistic decorative panel for wall surface
CN101899242B (en) Paint for making wood grains and method for preparing same
CN109970395A (en) A kind of wearable environment protection composite light lacquer and its manufacturing method
CN111574156A (en) Soft porcelain granite and one-step forming method thereof
CN2158901Y (en) Granite-imitation decorative plate

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121003

Termination date: 20130312