CN101942234B - Environment friendly dry powder emulsion paint and preparation method thereof - Google Patents
Environment friendly dry powder emulsion paint and preparation method thereof Download PDFInfo
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- CN101942234B CN101942234B CN2009101840104A CN200910184010A CN101942234B CN 101942234 B CN101942234 B CN 101942234B CN 2009101840104 A CN2009101840104 A CN 2009101840104A CN 200910184010 A CN200910184010 A CN 200910184010A CN 101942234 B CN101942234 B CN 101942234B
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- dry powder
- emulsion paint
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- powder rubber
- friendly dry
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- 239000003973 paint Substances 0.000 title claims abstract description 64
- 239000000843 powder Substances 0.000 title claims abstract description 64
- 239000000839 emulsion Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000881 Modified starch Polymers 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims abstract description 9
- 239000004568 cement Substances 0.000 claims abstract description 9
- 239000004368 Modified starch Substances 0.000 claims abstract description 8
- 235000019426 modified starch Nutrition 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 7
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 claims abstract 2
- 238000012856 packing Methods 0.000 claims description 8
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 5
- 239000001038 titanium pigment Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000005083 Zinc sulfide Substances 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000010276 construction Methods 0.000 abstract description 12
- 238000005034 decoration Methods 0.000 abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 3
- 238000005336 cracking Methods 0.000 abstract description 2
- 238000005201 scrubbing Methods 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920003086 cellulose ether Polymers 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract 1
- 239000001023 inorganic pigment Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 239000002025 wood fiber Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 239000000975 dye Substances 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 240000003183 Manihot esculenta Species 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000009974 thixotropic effect Effects 0.000 description 2
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides environment friendly dry powder emulsion paint and a preparation method thereof. The environment friendly dry powder emulsion paint comprises the following substances in percentage by weight: 10-45% of white cement, 0.35-0.65% of cellulose ether, 40-75% of calcium carbonate, 3-25% of ash calcium, 0.1-0.5% of cassava modified starch, 0.1-2% of wood fiber, 0.1-1% of fluorescent whitening agent, 0-25% of redispersible emulsion powder, 0-30% of titanium white and 0-5% of inorganic pigment. The preparation method comprises the following steps: putting the substances in percentage into a blender, evenly mixing and packaging to obtain the finished product; adding water and evenly stirring for using; and realizing one-step forming from bottom to surface. The invention has the advantages of high strength, small possibility of cracking, no drop, no peeling, no hollowing, easy color, bright color, small possibility of color fading, scrubbing resistance, mildew resistance, environmental protection, non-pollution, low cost, simple and easy packaging, convenient transportation, simple construction and the like, and can be widely applied to decoration of interior and exterior walls of the buildings.
Description
Technical field
The invention belongs to the dry powder paint field, relate in particular to a kind of dry powder rubber-emulsion paint and preparation method thereof.
Background technology
The solvent-borne type rubber-emulsion paint of building decoration use is a liquid state on the existing market, is not easy to packing, transportation and storage, and storage and use liquid milk shellac varnish need be used a large amount of plastics or storage tank made of iron, and these storage tank costs are higher, waste resource, contaminate environment.
Existing rubber-emulsion paint when construction, whole process need 5 procedures, batch twice putty polishes corner angle with sand paper again, and then brushes priming paint one time earlier, brushes finish paint at last again one time, operation is loaded down with trivial details, takes a lot of work, time-consuming, expense material, cost is higher.Coating receives the influence of putty powder quality easily after construction, if the putty quality is unstable, coating can come off, peeling, hollowing, fades sometimes, influences attractive in appearancely, need bottom all be rooted out when serious, again construction.
Application number is 200610036625.9 one Chinese patent application file, discloses a kind of green powdered paint and preparation method thereof, and the whiteness of white cement in this formulation for coating material and wilkinite self has limitation, so whiteness is not enough, influences attractive in appearance; The whiteness deficiency makes its not easy coloring, and color is difficult to reach design effect; Because this coating does not contain the material of cracking resistance, so when body of wall produced hair line, coating also crackle can occur thereupon; Contain zeyssatite because of in this coating again, and zeyssatite has the porous particle structure, makes that the surfaces coated floor height is coarse,, be difficult to realize if require to do porcelain facing on the surface of coating.
Summary of the invention
To the shortcoming that prior art exists, the purpose of this invention is to provide a kind of novel environment friendly HS, high brightness, durable in use, be difficult for producing hair line, non-scale, the dry powder rubber-emulsion paint of hollowing, difficult drop-off not, replace the solvent-borne type rubber-emulsion paint.
Another object of the present invention is to provide the preparation method of this dry powder rubber-emulsion paint.
For achieving the above object, a kind of environment-friendly dry powder rubber-emulsion paint provided by the invention, form by the material of following weight percent:
White cement 10%～45%
Ether of cellulose 0.35%～0.65%
Lime carbonate 40%～75%
Ash calcium 3%～25%
Cassava modified starch 0.1%～0.5%
Wood fibre 0.1%～2%
White dyes 0.1%～1%
Redispersible latex powder 0%～25%
White titanium pigment 0%～30%
Mineral dye 0%～5%.
In the above-mentioned prescription, white cement mainly plays gains in strength and scrubbable effect, and optimum fineness is 300 orders～1000 orders, and preferable amount ranges is 10%-45%.
Ether of cellulose is the characteristic that can significantly improve the dry powder rubber-emulsion paint at aspects such as water conservation, thickening, slow setting, bleeds; Has the good stream property handed over; Improved the workability of dry powder rubber-emulsion paint, made the dry powder rubber-emulsion paint full, lubricious, its preferable usage quantity scope is 0.35%～0.65%.
Lime carbonate is a kind of widely used stopping composition, can improve the opacifying power of dry powder rubber-emulsion paint, plays the effect of drawing high, and reduces the cost of dry powder rubber-emulsion paint, and preferable fineness is 400 orders～1200 orders, and preferable amount ranges is 40%～75%.
Ash calcium is by the natural fat lime stone that is staple with CaCO3, after high-temperature calcination becomes unslaked lime (CaO), again through selected; Part digestion, and then pulverize through high speed selection by winnowing beater grinder and to form its apparent pure white exquisiteness; Be a kind of air hardening cementitious materials, can gain in strength that grey calcium powder adds in the dry powder rubber-emulsion paint; Along with coating film forming; Calcium hydroxide can generate calcium carbonate crystal and produce intensity with airborne CO2 reaction, and then in filming, can certain cohesiveness be provided for the dry powder rubber-emulsion paint, and gives significant water tolerance.It is low to be with grey calcium powder that main active filler has a cost, and characteristics such as water-tolerant, its preferable fineness are 400 orders～800 orders, and preferable amount ranges is 3%～25%.
Cassava modified starch is the tasteless pulverulent solids of a kind of white; Good stability has very strong suspension effect, and is acidproof, heat-resisting, viscosity is high; Can improve the rheological of dry powder rubber-emulsion paint; Strengthen tack and osmanthus wall sense, its preferable amount ranges is 0.1%～0.5%, and cassava modified starch also can substitute with pre-gelatinized starch.
Wood fibre is the organic fibre that the natural timber process is ground and chemical treatment obtains, and can improve the performance of optimizing the dry powder rubber-emulsion paint, improves the stability of production and the workability of construction; It has splitting resistance, moisture retention and thixotropic behavior, can effectively prevent be full of cracks, improves the precision and the cohesive strength of construction; And the minimizing skinning, can prevent the infiltration of moisture and rainwater again, can effectively prevent to drip and hang; Be uniformly dispersed, good leveling property, not sagging, anti-splashing, make that to smear constructing operation convenient, and color and luster is softer; Its preferable amount ranges is 0.1%～2%, also can substitute with polypropylene fibre.
White dyes can brighten and have the restraining effect to brightness reversion; Can absorb certain ultraviolet ray again, make the increase of reflected light quantity play the effect that adds light, thereby coatingsurface brightness is increased; Color is more clear, distinct, and its preferable amount ranges is 0.1%～1%.
Redispersible latex powder can improve workability, improve liquidity can, increase thixotroping with the anti-property of hanging down, improve force of cohesion, prolong the open hour and strengthen water-retentivity, its preferable amount ranges is 0%～25%.
White titanium pigment is a kind of good white powder pigment; Have good light scattering ability, thereby whiteness is good, tinting strength is high, strong covering power, has higher chemicalstability and better weather simultaneously; Its preferable amount ranges is 0%～30%, also can substitute with zinc sulfide white.
Mineral dye is in order to increase the ornamental of dry powder rubber-emulsion paint, can add color dye according to the decoration demand, also can not add, and its preferable amount ranges is 0%～5%, also can substitute with pigment dyestuff.
The preparation method of a kind of environment-friendly dry powder rubber-emulsion paint of the present invention is following:
Above-mentioned each component ratio is by weight percentage put into stirrer, mix the back packing and can make finished product.
During use; Earlier the environment-friendly dry powder rubber-emulsion paint is added water; Dry powder rubber-emulsion paint and water blended ratio are 10: 3.3～10: 7, can polish or spraying by blade coating after stirring, from hanging down to the face once shaped; Saved loaded down with trivial details operations such as need criticizing Puttying when traditional rubber-emulsion paint uses, construction technology is simple and efficient.
The present invention compared with prior art, its advantage and beneficial effect are:
(1) because the wood fibre that adds has splitting resistance, moisture retention and thixotropic behavior, the present invention is possessed cover the effect of hair line, coating is not easy to crack, do not come off, non-scale, hollowing not;
(2) added white dyes and white titanium pigment in the environment-friendly dry powder rubber-emulsion paint of the present invention, coatingsurface brightness is increased, whiteness is higher, and strong covering power is easy to paintedly, makes color more clear, distinct, and fugitive color is difficult for anti-yellow, beautiful lastingly;
(3) the various chemical assistants in no traditional rubber-emulsion paint among the present invention have no volatilization and irritating smell, and are environment friendly and pollution-free;
(4) the present invention is the solid state powder shape, and manufacturing cost has only 40%～70% of traditional rubber-emulsion paint, and packing cost has only 20%～50% of traditional rubber-emulsion paint, and pack simple and easy, convenient storage and transportation;
(5) the pure white exquisiteness of coatingsurface both can be done porcelain facing, the light of also can making mute;
(6) the present invention gets final product blade coating or spraying after Jia Shui stirs, and to the face once shaped, has saved the operation that needs Puttying when traditional rubber-emulsion paint uses the end of from, and construction technology is simple and efficient;
(7) the present invention also has advantages such as HS, scrubbing resistance, mildew-resistant, is the novel environment friendly decorative material for wall surface that replaces traditional putty and rubber-emulsion paint, can be widely used in the decoration of exterior wall in the buildings.
Embodiment
For a better understanding of the present invention, below in conjunction with embodiment the present invention is done further statement.
Embodiment 1
Each component concentration of environment-friendly dry powder rubber-emulsion paint of present embodiment is a white cement 21.4%, ether of cellulose 0.4%, lime carbonate 72.3%; Ash calcium 5%, cassava modified starch 0.1%, wood fibre 0.3%; White dyes 0.3%, redispersible latex powder 0.2% drops into stirrer by weight percentage with above-mentioned each component; After mixing, packing can make finished product environment-friendly dry powder rubber-emulsion paint.During construction, the environment-friendly dry powder rubber-emulsion paint is added water, ratio is the dry powder rubber-emulsion paint: water=10: 3.3, can use by blade coating after stirring.The white dry powder rubber-emulsion paint of present embodiment can be used for the decoration of inner wall of building.
Embodiment 2
Each component concentration of environment-friendly dry powder rubber-emulsion paint of present embodiment is a white cement 16.7%, ether of cellulose 0.6%, lime carbonate 70%, grey calcium 4%; Cassava modified starch 0.3%, wood fibre 0.5%, white dyes 0.6%; Redispersible latex powder 0.3%, white titanium pigment 5%, mineral dye 2%; Above-mentioned each component is dropped into stirrer by weight percentage, and after mixing, packing can make finished product environment-friendly dry powder rubber-emulsion paint.During construction, the environment-friendly dry powder rubber-emulsion paint is added water, ratio is the dry powder rubber-emulsion paint: water=10: 7 can spray after stirring.The colored dry powder rubber-emulsion paint of present embodiment can be used for the decoration of inner wall of building.
Embodiment 3
Each component concentration of environment-friendly dry powder rubber-emulsion paint of present embodiment is a white cement 30%, ether of cellulose 0.6%, lime carbonate 45%; Ash calcium 15%, cassava modified starch 0.3%, polypropylene fibre 1.2%; White dyes 0.8%, redispersible latex powder 1%, zinc sulfide white 6.1%; Above-mentioned each component is dropped into stirrer by weight percentage, and after mixing, packing can make finished product environment-friendly dry powder rubber-emulsion paint.During construction, the environment-friendly dry powder rubber-emulsion paint is added water, the back spraying that stirs gets final product, wherein the dry powder rubber-emulsion paint: water=10: 6.5.The white dry powder rubber-emulsion paint of present embodiment can be used for the skin spraying.
Embodiment 4
Each component concentration of environment-friendly dry powder rubber-emulsion paint of present embodiment is a white cement 28%, ether of cellulose 0.5%, lime carbonate 46.8%, grey calcium 3%; The cassava property handed over starch 0.2%, polypropylene fibre 1%, white dyes 0.6%; Redispersible latex powder 1.5%, zinc sulfide white 18%, mineral dye 0.4%; Above-mentioned each component is dropped into stirrer by weight percentage, and after mixing, packing can make finished product environment-friendly dry powder rubber-emulsion paint.During construction, the environment-friendly dry powder rubber-emulsion paint is added water, can use by blade coating after stirring, wherein the dry powder rubber-emulsion paint: water=10: 3.5.The colored dry powder rubber-emulsion paint of present embodiment can be used for the decoration of skin.
Bound value and interval value at each raw material can both realize the present invention, do not enumerate embodiment one by one at this, can realize the present invention preferably through above embodiment.
Claims (8)
1. environment-friendly dry powder rubber-emulsion paint is characterized in that being made up of the material of following weight percent:
2. a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: the fineness of said white cement is 300 orders～1000 orders.
3. a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: the fineness of said lime carbonate is 400 orders～1200 orders.
4. a kind of dry powder environment-friendly type emulsion paint according to claim 1 is characterized in that: said cassava modified starch also can be a pre-gelatinized starch.
5. a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: said wood fibre substitutes with polypropylene fibre.
6. a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: said white titanium pigment substitutes with zinc sulfide white.
7. a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: said grey calcium fineness is 400 orders～800 orders.
8. the preparation method of a kind of environment-friendly dry powder rubber-emulsion paint according to claim 1 is characterized in that: each component is mixed the input stirrer by weight percentage, and after stirring, packing promptly can be made into environment-friendly dry powder rubber-emulsion paint finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101840104A CN101942234B (en) | 2009-08-11 | 2009-08-11 | Environment friendly dry powder emulsion paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101840104A CN101942234B (en) | 2009-08-11 | 2009-08-11 | Environment friendly dry powder emulsion paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN101942234A CN101942234A (en) | 2011-01-12 |
| CN101942234B true CN101942234B (en) | 2012-02-01 |
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| CN2009101840104A Expired - Fee Related CN101942234B (en) | 2009-08-11 | 2009-08-11 | Environment friendly dry powder emulsion paint and preparation method thereof |
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| CN103086664A (en) * | 2013-01-08 | 2013-05-08 | 张立功 | Internal wall putty and production process thereof |
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| CN102617086A (en) * | 2012-03-04 | 2012-08-01 | 倪建东 | Novel dry powder emulsion paint |
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2009
- 2009-08-11 CN CN2009101840104A patent/CN101942234B/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103086664A (en) * | 2013-01-08 | 2013-05-08 | 张立功 | Internal wall putty and production process thereof |
| CN103086664B (en) * | 2013-01-08 | 2015-03-25 | 张立功 | Internal wall putty and production process thereof |
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| CN101942234A (en) | 2011-01-12 |
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