CN103992740A - Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product - Google Patents
Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product Download PDFInfo
- Publication number
- CN103992740A CN103992740A CN201410178583.7A CN201410178583A CN103992740A CN 103992740 A CN103992740 A CN 103992740A CN 201410178583 A CN201410178583 A CN 201410178583A CN 103992740 A CN103992740 A CN 103992740A
- Authority
- CN
- China
- Prior art keywords
- whisker
- crystal whisker
- parts
- crystal
- raw lacquer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a method using raw lacquer as a matrix to cooperate with whisker to prepare a paint and a product, and relates to a method using the raw lacquer as a main raw material to to prepare an environmental friendly paint with excellent ecological performances and a corresponding product; the raw lacquer is used as the matrix to cooperate with a filling material to prepare the paint, the prepared paint contains the raw lacquer, the filling material, a diluent and other ingredients, the key technology is that the paint comprises 100 parts of the raw lacquer and 0.5 to 15 parts of basic magnesium sulfate whisker or magnesium hydroxide whisker or silicon dioxide whisker or magnesium borate whisker or aluminum borate whisker or magnesium oxide whisker or zinc oxide whisker or potassium titanate whisker or calcium sulfate whisker or calcium carbonate whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride whisker. When the whisker is used as the filling material to cooperate with the raw lacquer to use, the drying rate of a paint film can be increased by more than 31%. When the whisker is used as the filling material to cooperate with a coupling agent to use, the drying rate of the paint film can be further increased by more than 15%. The method has remarkable progress significance to solve low temperature seasonal construction and facilitate raw lacquer construction at room temperature.
Description
Technical field
The invention belongs to the friendly type polymeric material field of ecosystem environment, especially belong to a kind of and take raw lacquer as biomass-based high-molecular coating technology of preparing.
Background technology
Raw lacquer has another name called Rhus lacquer, state's paint, lacquer, lacquer, Chinese lacquer etc., is time-honored Chinese traditional coating, and its main chemical is laccol, is a kind of traditional natural high-quality coating, have the king's of coating good reputation.
Raw lacquer thinks to have at least more than 8000 at Chinese applicating history according to archaeology person, and someone thinks that this is the fifth-largest invention or the sixth-largest invention of ancient Chinese.Although raw lacquer is long in Chinese application, but because the execution conditions of raw lacquer are compared with modern chemical industry paint, be to have relatively high expectations, especially the construction period of raw lacquer is longer, and is subject to raw lacquer use procedure restricted by natural factor, drying conditions requires harsh, need to control certain temperature, humidity condition.While constructing in the winter time, drying property is poor, is difficult to polymerization film formation.And raw lacquer viscosity is large, construction technology is fastidious, demands strict technology, and can only adopt manual operations, is difficult to adopt the operation of mechanize mode, and the production cycle is long, and labour productivity is low.Meanwhile, raw lacquer also easily causes people's skin allergy, there is no so far the good recipe of radical cure raw lacquer allergy.These defects that raw lacquer itself exists, make people then other surrogates of searching, and development of new paint kind, nibbles Lacquer Market share.Cause being not easy to large-scale industrial production.
Raw lacquer, when north of China or use in winter, often, because room temperature is lower cannot and complete raw lacquer film forming, completes raw lacquer drying process fast.Especially, carry out indoor wall or other water and facilitate the raw lacquer of mobile equipment to cover with paint, lacquer, colour wash, etc. while constructing, how to improve the seasoning speed of raw lacquer under low temperature and low humidity condition, become a technical bottleneck of the industry.
In contemporary upholstery activity, people start to trend towards to be turned on by chemistry painting industry the lacquer of nontoxic non-environmental-pollution and study, and raw lacquer is the first-selected research object of this lacquer.
In addition, the snappiness of raw lacquer film is poor, i.e. the friability of paint film, and this is in raw lacquer application, to need the guardian technique bottleneck problem that solves.
Therefore be necessary take that raw lacquer studies into a kind of have nature, environmental protection, acidproof, corrosion-resistant, water-fast, oil resistant, the good high-molecular coating of wear resisting property as biomass-based, to meet people, day by day wait in expectation and return Piao and return genuine demand.
Summary of the invention
Object of the present invention
Be to provide a kind of good preparation method for coating and corresponding goods of environmental friendliness, ecological performance that raw lacquer is main raw material of take.
Realize invention technical scheme
scheme one
Take raw lacquer as matter basigamy closes the method that stopping composition is prepared coating, contain the compositions such as raw lacquer, stopping composition, thinner in this coating, its gordian technique is that described stopping composition is used the compositions such as whisker, thereby makes to contain the compositions such as whisker in this coating.
scheme two
A kind ofly take raw lacquer and be used in conjunction with the method that stopping composition is prepared coating as matter base, in this coating, contain the compositions such as raw lacquer, stopping composition, resin, thinner, its gordian technique be to this take in the coating that raw lacquer is raw material add and make it contain inorganic crystal whisker or/and compositions such as epoxy resin.
scheme three
A kind ofly take raw lacquer and be used in conjunction with the method that stopping composition is prepared coating as matter base, in this coating, contain the compositions such as raw lacquer, thinner, stopping composition, resin and coupling agent, its gordian technique be to this take in the coating that raw lacquer is raw material add and make it contain the compositions such as inorganic crystal whisker, epoxy resin, coupling agent.
scheme four
A kind ofly take raw lacquer and be used in conjunction with coating prepared by stopping composition as matter base, in this coating, contain the compositions such as raw lacquer, stopping composition, resin, thinner, its gordian technique be to this take in the coating that raw lacquer is raw material add and make it contain following any one composition:
Inorganic crystal whisker composition; Or
Inorganic crystal whisker and epoxy resin composition; Or
Inorganic crystal whisker and epoxy resin composition and coupling agent composition; Or
Inorganic crystal whisker and coupling agent composition.
scheme five
Take raw lacquer as matter basigamy closes a coating prepared by stopping composition, contain the compositions such as raw lacquer, stopping composition, thinner in this coating, its gordian technique is the quality component that adds in this coating and make it contain following any one formula:
Formula one,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and in silicon nitride crystal whisker arbitrarily multiple (two kinds to all, two or three or four kind or five kinds or six kinds or seven kinds or eight kinds or nine kinds or ten kinds or 11 kinds or 12 kinds or all
.down together) whisker composition is 0.5 part to 15 parts;
Formula three,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula four,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula five,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
By filling a prescription described in five in every 100 parts of this programme five
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula six,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
By filling a prescription described in six in every 100 parts of this programme five
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent.
scheme six
The coating that the raw lacquer of take must be prepared as matter basigamy synthetic, contains raw lacquer, stopping composition, thinner composition in this coating, its gordian technique is the quality component that adds in this coating and make it contain following any one formula:
Formula one,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
By filling a prescription described in one in every 100 parts of this programme six
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
By filling a prescription described in two in every 100 parts of this programme six
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula three,
100 parts, raw lacquer;
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
By filling a prescription described in three in every 100 parts of this programme six
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula four,
100 parts, raw lacquer;
1 part to 40 parts of epoxy resin;
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
By filling a prescription described in four in every 100 parts of this programme six
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent.
scheme seven
Aforementioned schemes one is carried out suitably processing and mixing to the raw lacquer, stopping composition, the thinner that contain in scheme six formula (also can adopt the formula of this programme seven promptings), and its guardian technique is to contain following method:
Step 1, preparation formula one is to arbitrary group of raw material in formula eight:
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula three,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula four,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula five,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
By filling a prescription described in five in every 100 parts of this programme seven
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula six,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
By filling a prescription described in six in every 100 parts of this programme seven
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula seven,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
By filling a prescription described in seven in every 100 parts of this programme seven
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Formula eight,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
By filling a prescription described in eight in every 100 parts of this programme seven
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent;
Step 2, whisker Preblend is prepared in whisker pre-treatment, according to formula, makes following different treatment:
whisker composition by formula one or formula two or formula three or formula four, mixes rear standby with part thinner with whisker composition;
coupling agent in formula five or six or seven or eight is put into thinner and be mixed into the solution shape that can spray, then spray in the whisker raw material under high-speed stirring state, standby after continuing to stir;
Step 3, raw lacquer pre-treatment raw lacquer:
Raw lacquer is filtered; With thinner, raw lacquer is diluted; If need to add other auxiliary agent, add other auxiliary agent;
If use refining raw lacquer, can refining raw lacquer not dealt with;
Step 4, coating mixes, and according to formula, makes following different treatment:
while containing epoxy resin in formula, with thinner, epoxy resin is diluted, the whisker Preblend of preparing with step 2 mixes, then with the raw lacquer of step 3 preparation mix take the coating that raw lacquer is matter base, during construction, according to covering with paint, lacquer, colour wash, etc. dense (glue), spend and need to add appropriate thinner;
in formula when the epoxy resin, the raw lacquer of whisker Preblend prepared by step 2 and step 3 preparation mix take the coating that raw lacquer is matter base, during construction, according to covering with paint, lacquer, colour wash, etc. dense (glue) degree, need interpolation thinner in right amount.
Weighting agent, except using crystal whisker materials, can also be used calcined kaolin powder etc.
Technique scheme has only been pointed out key formula and other operative technique, and other technology contents can be with reference to routine techniques, and with reference to embodiment content described later.
beneficial effect of the present invention
1. raw lacquer is combined to use with epoxy resin, even if do not add solidifying agent, also can make epoxy resin cure, and combine the significant associating of performance result of use while using, while especially using alcohol as thinner, effect is more obvious, and environmental protection more.Because raw lacquer and alcohol all can be prepared with biological method, no matter it is produced still all can not caused environmental pollution in use procedure.After adopting method shown in the present that raw lacquer and epoxy resin are used in conjunction with, use summer and autumn temperature (25 ℃ ± 5 ℃, humidity 80% ± 10%) are lower, even if mismatch solidifying agent such as using ethylenediamines, shorten the time of drying of more alone raw lacquer more than 2 to 4 times; When suitably adding ethylenediamines solidifying agent, shorten the time of drying of more alone raw lacquer more than 4-10 times.After adopting method shown in the present that raw lacquer and epoxy resin are used in conjunction with, use winter-spring season temperature (8 ℃ ± 5 ℃, humidity 70% ± 10%) is lower, even if mismatch solidifying agent such as using ethylenediamines, shorten the time of drying of more alone raw lacquer more than 3 to 4 times; When suitably adding ethylenediamines solidifying agent, shorten the time of drying of more alone raw lacquer more than 6-10 times.
When using whisker class to coordinate raw lacquer to use as stopping composition, the rate of drying of paint film can improve more than 31%.
When being used in conjunction with coupling agent, the rate of drying that can improve again paint film is more than 15%.
---for solving low temperature season construction and being convenient to the construction of raw lacquer normal temperature, there is marked improvement meaning.
2. formula shown in the present and method, by coating test standard detection, can improve 0.5 times to 1.5 times of the sticking power of paint film, even more than; Other performance of paint film: thermotolerance raising 32% to 117%, corrosive nature raising 24% to 119%, snappiness raising 37% to 107%, acidproof (diluted acid) performance raising 31% to 63%, oil resistance raising 22% to 67%, wear resisting property raising 28% to 108%.
Tensile strength and the shearing resistance of the paint film that coating prepared by the inventive method forms can improve 52% to 169%, can effectively solve raw lacquer snappiness defect, can effectively reduce the fragility of paint film.This has significant progressive for the toughness problem that solves raw lacquer.
Calcium sulfate crystal whiskers and other particle-filled dose are mixed for preparing raw lacquer coating, effect is better, as wastewaters with modified calcium sulfate whiskers is mixed as weighting agent with silica powder, epoxy resin, with only comparing as weighting agent by single wastewaters with modified calcium sulfate whiskers, tensile strength and the shearing resistance of the paint film that preparation forms can improve again 11% to 19%.Especially it is good that the raw lacquer coating of preparing with calcium sulfate crystal whiskers removes physicals apparent characteristic, and the ratio of performance to price is quite high.
3. because the cost of raw lacquer present stage is more expensive, source is also nervous, adds after stopping composition, and to reduce raw materials cost 8% to 30%, and painting quality not only do not decline, and the over-all properties of paint film is significantly improved.
4. (the section calcined kaolin powder of carrying only refers to calcined kaolin powder itself to use calcined kaolin powder, do not refer to other stopping composition composition) as stopping composition, being particularly useful for white purposes and wall covers with paint, lacquer, colour wash, etc., the opacifying power of paint film can improve 15% to 25%, tinctorial property (white) can improve 25 to 30%, thermotolerance raising 40% to 100%, corrosive nature raising 50% to 110%, snappiness raising 20% to 40%, acidproof (diluted acid) performance raising 40% to 60%, oil resistance raising 20% to 60%, wear resisting property raising 25% to 40%.1000 ℃ of calcined kaolin powder to 1400 ℃ of productions of the calcined kaolin powder that uses 500～700 ℃ of productions of calcination temperature range and calcination temperature range are compared as stopping composition of the present invention, except the kaolin powder of the kaolin powder higher temperatures calcining of low temperature calcination (take that to use the kaolin powder of low temperature calcination be stopping composition with using the kaolin powder of high-temperature calcination low 10 to 15 percentage points aspect wear resisting property, compare as stopping composition with not using the kaolin powder of calcining) outside, other aspect of performance is all to be used the kaolin powder of low temperature calcination to show excellently, generally differ 10 to 20 percentage points, go through the reduction of calcining temperature, the fuel cost of calcined kaolin powder also can reduce by 20% to 25%, and can reduce the maintenance cost that calciner Yin Gaowen easily causes.
5. adopt the present invention except adopting traditional " coating with lacquer decorations " technique, also can suitably increase dilution dosage and adorn (require the fineness of stopping composition reach 300 orders more than) raw lacquer coating for mechanical spray, this is also a progress.
In sum, the coating that raw lacquer is biomass-based preparation is take in the present invention, that a kind of natural, environmental protection, acidproof, corrosion-resistant, water-fast, oil resistant, wear resisting property all show the environmentally friendly coating of good polymer, and can meet the day by day anticipatory Piao of returning of people and return true demand, and realized goal of the invention.---for the purposes of expanding raw lacquer, there is marked improvement meaning.
Embodiment
Because having described comparatively detailed technology contents in aforesaid technical scheme, can meet technology can implement and operational condition, in order to save content length, content in technique scheme can be directly as the content in this embodiment, in order to make the present invention can reach the state of more managing phase, below some key details in specific implementation process is further disclosed.
about stopping composition and whisker
Whisker be one of a kind of stopping composition composition or stopping composition can only have this composition of whisker or stopping composition to only have inorganic crystal whisker this is a kind of; Stopping composition also can comprise other material outside whisker, as: the calcined kaolin powder in silicate industry, ceramics powder, common brick powder, blue bricks grey tile powder, glass powder etc.; Talcum powder, silica powder, Graphite Powder 99, terra alba etc.The fineness of stopping composition is larger, and effect is better.The ratio of stopping composition and raw lacquer, the ratio of pointing out, generally can also be recommended as 0.3-1: 1 in technical scheme.
In the present invention, use stopping composition or the whisker arriving with prompting, mainly refer to metal, pottery and macromolecular material class three major types, as the whisker of metal, oxide compound, carbide, halogenide, nitride, graphite and macromolecular compound manufacture.Although what adopt in title of the present invention and some content is " inorganic crystal whisker " concept, but be extended to natch " organic crystalline palpus " field, be can be with " organic crystalline must " replacements " inorganic crystal whisker " in the present invention, or " organic crystalline must " and " inorganic crystal whisker " be joined (connection) and closed use.
Based on cost consideration, keypoint recommendation is used calcium sulfate, calcium carbonate crystal whisker.Calcium sulfate crystal whiskers is a kind of good weighting agent with enhancing, toughness reinforcing, heat-resisting, high thixotropic.With calcium sulfate crystal whiskers and epoxy resin and raw lacquer connection (joining), close use, can greatly improve the performance of raw lacquer and epoxy resin, performance is addition trend, and while supporting the use coupling agent especially again, effect is more remarkable.
To the production of calcium sulfate crystal whiskers, can consider to prepare calcium sulfate crystal whiskers with reference to disclosed technology in CN200510047776.X patent (publication number CN1806551), this way preparation is simple, equipment requirements is low, and the calcium sulfate crystal whiskers of making can meet the service requirements of coating.
If paint film is had to special hardness requirement, can select whisker according to the Mohs' hardness of whisker, as the highest in the Mohs' hardness of silicon carbide and silicon nitride crystal whisker, just can emphasis selecting the two is stopping composition, is that cost is higher.
about raw lacquer
Can add biomass auxiliary material to raw lacquer and do pre-treatment, biomass auxiliary material is generally boiled wood oil, ripe oleum lini, perilla oil, Chinese catalpa oil, rosin, wood wax oil or dryness or semi-drying vegetables oil, animal oil.Suggestion is used boiled wood oil and ripe oleum lini to use in 7: 3 ratio proportionings.
Raw lacquer is produced paint by safe and comfortable paint, Hanzhong paint, entrance of the city paint, dam paint, Qinling Mountains paint and other areas, decocts dish mark more than 65%, and laccol content is more than 50%.
Raw lacquer is carried out to filtration treatment can be improved operating efficiency and improve painting quality.Can by the quality proportioning of raw lacquer with addition of activated protein (generally refer to animal serum albumen, sphaeroprotein, glycoprotein, water-soluble polypeptide or sericin, also can directly use traditional raw lacquer to coat with lacquer pig blood ox blood and other animality blood that decorations technique is used) 1%～5%.
The present invention can use refining raw lacquer.
about coupling agent
The invention reside in described " coupling agent ", be applicable to use titanate coupling agent, consumption can be 0.08% to 5% of stopping composition (as: whisker composition) quality, and recommended amounts is 0.2% to 3%; Technical scheme statement "
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With by filling a prescription described in seven in every 100 parts of this programme seven
the quality component of whisker composition is separately joined
0.1 part to 3 parts of coupling agent ", be normally interpreted as " 0.1 part to 3 parts of every 100 parts of alkali magnesium sulfate crystal whiskers or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker adapted coupling agent ".
Certainly, also can use silane coupling agent, zirconium ester coupling agent, aluminate coupling agent etc., especially, when stopping composition is the compositions such as silicon-dioxide, glass, graphite, talcum powder, carbon black, wood powder, silane coupling agent is used in suggestion.But because the wide accommodation of titanate coupling agent, price material benefit, so titanate coupling agent is used in suggestion.
Coupling agent claims again short stick or surface treatment agent, is a kind of material with both sexes structure.It is centered by titanium, and one end of molecule can be reacted with the chemical group on inorganics surface, forms firmly chemical bond; The other end group has close organic character, can be wound around with reactive organic molecule or physics, thereby the material that two kinds of character are differed widely firmly combines.
The inorganics of processing through titanate coupling agent be hydrophobic parent organically, in adding polymeric system, can promote bondingly, there is katalysis; Improve and disperse and rheological property; Improve shock strength, can not produce fragility; Improve mechanical property, improve loading level, reduce costs; Prevent from being separated, the effect such as anticorrosion, anti-oxidant, fire-retardant, it is a kind of multi-functional auxiliary agent with very large handiness, itself is coupling agent, also can do dispersion agent, wetting agent, tackiness agent, linking agent, catalyzer, is therefore of wide application.Coupler is used in conjunction with in raw lacquer coating, and the effect showing is quite good.Titanate coupling agent is used in conjunction with in the present invention, embodies good synergy with raw lacquer etc.---this is also important beneficial effect of the present invention.
Titanate coupling agent mainly contains Four types: 1) monoalkoxy type; 2) tetra-sodium type; 3) type that boils together; 4) corrdination type.
Titanate coupling agent has very large handiness and multifunctionality, itself is coupling agent, also can be dispersion agent, wetting agent, tackiness agent, linking agent, catalyzer etc., can also have concurrently antirust, anti-oxidant, fire-retardant etc. multi-functionally, therefore be of wide application, surpass other coupling agent.
The consumption of coupling agent, is generally the 0.5--3% of handled thing (typically referring to stopping composition) weight, and recommendation amount is 0.8---1.5%.Its consumption and effect are not proportional relations, measure too much coupling agent surplus and make on the contrary degradation, and very little,, because cladding not exclusively, effect is not remarkable for amount.So time need to test out optimum amount in application, accomplish not only economy but also effective.
Suggestion consumption parameter is as follows:
The consumption of titanate coupling agent is that hydroxyl or the proton that will make whole isopropoxies in coupling agent molecule and face, stopping composition provide react, and surface-area is larger, and the consumption of coupling agent just the more.
The in the situation that of low loading level, coupling agent consumption accounts for 0.6% of stopping composition amount;
The in the situation that of middle loading level, coupling agent consumption accounts for 1.0% of stopping composition amount;
The in the situation that of high filler loading capacity, coupling agent consumption accounts for the 1.5-2.0% of stopping composition amount;
The coarse particles that surface-area is little, as 0.2% of inorganics weight for the stopping composition such as glass;
Fine particle carbon black and some silicon-dioxide, with the 1.5-2.5% of its weight.
Titanate coupling agent using method:
Monoalkoxy type titanate coupling agent, as NGT-101, NGT-102, NGT-105, NGT-502, is applicable to stopping composition or the extremely low stopping composition of water ratio of dry production, and burnt phosphide type is applicable to inorganic fillings and the pigment containing a certain amount of free water as NGT-201.
Directly reinforced method: in proportion resin, stopping composition and coupling agent are carried out to mix and blend, until add other auxiliary agents to carry out mix and blend after stirring, this method effect is generally speaking not as good as method for pretreating.
Method for pretreating: first use anhydrous solvent, as dehydrated alcohol (raw spirit), Virahol etc., raw spirit is used in suggestion, and during for interior decoration, the safety performance of alcohol is even more ideal, and common solvent is 1:1 with the ratio of coupling agent; Under the condition of high-speed stirring inorganic fillings (whisker), the coupling agent having diluted is dripped or be sprayed to stopping composition surface, then being warming up to 75-150 ℃ continues to stir 10 minutes, now stopping composition surface element has formed unimolecular film, from wetting ability, become hydrophobic nature, comparatively stable, after solvent is dried and to be gone, add after other auxiliary agents and resin treatment moulding standby.
Also can adopt the pre-treatment of high-speed stirring heating means, can save solvent consumption, and treatment effect is good.The steps include: stopping composition to add in mixing tank, start and stir, (rotating speed is higher to be warmed up to 70 ℃ of-80 ℃ of left and right, more be conducive to coupling agent in the dispersion on stopping composition surface), then evenly add titanate coupling agent or coupling agent solution, can adopt dripping method or spraying, add rear continuation and stir 15 minutes (churning time is depending on rotating speed).
Select coupling agent to carry out surface treatment inorganic fillings, then with resin and other auxiliary agent mixing granulation, can reach best coupling effect.By the hydrophilic hydrophobic that becomes, nonhygroscopic through the stopping composition surface of coupling agent treatment, stable performance.
Certainly, also can, according to the practical situation of raw lacquer application, select corresponding using method.
Variant because of the physicochemical property of stopping composition, be applied to when of the present invention, please according to experimental result, to determine and add coupler consumption, in file of the present invention, only consumption, also general conventional ratio are recommended in prompting.
Because titanate coupling agent consumption is few, for making it bring into play due effect, must make it in stopping composition handled things such as (or) pigment, disperse equably, otherwise, do not reach coupling effect.
4. about thinner
Thinner of the present invention can be alcohol, or white oil of camphor, turps, rosin one kind of or more than one.Based on environmental protection, consider, alcohol is used in suggestion, because alcohol can be used agricultural crop straw to prepare with biological method as raw material, and alcohol is without any side effects, to environment, shows more friendlyly.
Thinner consumption according to cover with paint, lacquer, colour wash, etc. processing requirement with addition of, in the present invention, do not do ratio prompting.
about using PH adjusting control agent
In order to be beneficial to laccase, play a role, can in formula, use pH adjusting control agent, this pH adjusting control agent generally can be used pyridine, Ammoniom-Acetate or ammoniacal liquor one of them or more than one, adding proportion is generally 0.25% to 5% of material quantity, controls pH value in 5.0 to the 7.0 suitable growth potential of hydrogen that are laccase.Adding duration of service can be in the preprocessing process of raw lacquer, can be also that raw lacquer is when mix with stopping composition.
about epoxy resin and solidifying agent thereof
When using epoxy resin, if in the present invention with addition of ethylenediamines solidifying agent, for accelerating the dry of paint film, there is remarkable effect, but consider that quadrol is chemical product, may there is not too friendly suspicion to environment, can be with addition of solidifying agent.If with addition of solidifying agent, be generally suggestion according to the epoxy equivalent (weight) proportioning solidifying agent of epoxy resin as quadrol, how to join and please refer to relevant epoxy resin handbook.
Even if do not use solidifying agent, because there being the existence of raw lacquer composition, can impel epoxy resin cure, when raw lacquer and epoxy resin are used in conjunction with, present the effect that significantly improves drying varniss speed; When using whisker class material also to have remarkable speed-raising effect for being dried of paint film; When using coupling agent, for being dried of paint film, also there is significant booster action.---this is important very important progressive meaning of the present invention, also can say one of beneficial effect content.
performance Detection explanation
The detection of correlated performance, if no special instructions, generally drawn by coating test standard or the detection of respective performances examination criteria, as: the method for inspection can be with reference to national inspecting standards such as GB/T14703-2008, GB/T6739-1996, GB/T1761-1979, GB/T1735-1979.
other explanation
In the present invention, a guardian technique is exactly that preparation process is had relatively high expectations for mixing, mixes more evenly, and coating effect is unreasonable to be thought.
In the present invention, if no special instructions, correlation proportion is quality (weight) component.
Claims (10)
1. the raw lacquer of take must be prepared the method for coating as matter basigamy synthetic, contains raw lacquer, stopping composition, thinner composition in this coating, it is characterized in that the composition that described stopping composition contains is whisker composition.
2. take raw lacquer and close the method that inorganic crystal whisker is prepared coating as matter basigamy for one kind, in this coating, contain raw lacquer, stopping composition, resin, thinner composition, it is characterized in that to this take in the coating that raw lacquer is raw material add and make it contain inorganic crystal whisker or/and epoxy resin composition.
3. take raw lacquer and close the method that inorganic crystal whisker is prepared coating as matter basigamy for one kind, in this coating, contain raw lacquer, thinner, stopping composition, resin and coupling agent composition, it is characterized in that to this take in the coating that raw lacquer is raw material add and make it contain inorganic crystal whisker, epoxy resin, coupling agent composition.
4. take raw lacquer as matter basigamy closes a coating prepared by inorganic crystal whisker, contain raw lacquer, stopping composition, thinner composition, it is characterized in that this take in the coating that raw lacquer is raw material contain:
Inorganic crystal whisker composition; Or
Inorganic crystal whisker and epoxy resin composition; Or
Inorganic crystal whisker and epoxy resin composition and coupling agent composition; Or
Inorganic crystal whisker and coupling agent composition.
5. take raw lacquer as matter basigamy closes a coating prepared by inorganic crystal whisker, in this coating, contain raw lacquer, stopping composition, thinner composition, it is characterized in that the quality component that contains following any one formula in this coating:
Formula one,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula three,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula four,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula five,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula six,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent.
6. take raw lacquer as matter basigamy closes a coating prepared by inorganic crystal whisker, in this coating, contain raw lacquer, stopping composition, thinner composition, it is characterized in that the quality component that contains following any one formula in this coating:
Formula one,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula three,
100 parts, raw lacquer;
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula four,
100 parts, raw lacquer;
1 part to 40 parts of epoxy resin;
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent.
7. as claimed in claim 1ly a kind ofly take raw lacquer and must prepare the method for coating as matter basigamy synthetic, in formula, contain raw lacquer, stopping composition, thinner, it is characterized in that containing following method:
Step 1, preparation formula one is to arbitrary group of raw material in formula eight:
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula two,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula three,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Formula four,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Formula five,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
0.5 part to 25 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker;
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula six,
100 parts, raw lacquer; With
1 part to 40 parts of epoxy resin; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 25 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula seven,
100 parts, raw lacquer; With
0.5 part to 15 parts of alkali magnesium sulfate crystal whisker or magnesium hydroxide crystal whisker or silicon-dioxide whisker or magnesium borate crystal whisker or aluminium borate whisker or magnesia crystal whisker or ZnOw or potassium titanate crystal whisker or calcium sulfate crystal whiskers or calcium carbonate crystal whisker or silicon carbide whisker or zinc titanate whisker or silicon nitride crystal whisker; With
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Formula eight,
100 parts, raw lacquer; With
alkali magnesium sulfate crystal whisker or/and magnesium hydroxide crystal whisker or/and silicon-dioxide whisker or/and magnesium borate crystal whisker or/and aluminium borate whisker or/and magnesia crystal whisker or/and ZnOw or/and potassium titanate crystal whisker or/and calcium sulfate crystal whiskers or/and calcium carbonate crystal whisker or/and silicon carbide whisker or/and zinc titanate whisker or/and 0.5 part to 15 parts of multiple (two kinds to all) arbitrarily whisker composition in silicon nitride crystal whisker;
Quality component by every 100 parts of whisker compositions is separately joined
0.1 part to 3 parts of coupling agent;
Step 2, whisker Preblend is prepared in whisker pre-treatment, according to formula, makes following different treatment:
whisker composition by formula one or formula two or formula three or formula four, mixes rear standby with part thinner with whisker composition;
coupling agent in formula five or six or seven or eight is put into thinner and be mixed into the solution shape that can spray, then spray in the whisker raw material under high-speed stirring state, standby after continuing to stir;
Step 3, raw lacquer pre-treatment raw lacquer:
Raw lacquer is filtered; With thinner, raw lacquer is diluted; If need to add other auxiliary agent, add other auxiliary agent;
If use refining raw lacquer, can refining raw lacquer not dealt with;
Step 4, coating mixes, and according to formula, makes following different treatment:
while containing epoxy resin in formula, with thinner, epoxy resin is diluted, the whisker Preblend of preparing with step 2 mixes, then with the raw lacquer of step 3 preparation mix take the coating that raw lacquer is matter base, during construction, according to covering with paint, lacquer, colour wash, etc. dense (glue), spend and need to add appropriate thinner;
in formula when the epoxy resin, the raw lacquer of whisker Preblend prepared by step 2 and step 3 preparation mix take the coating that raw lacquer is matter base, during construction, according to covering with paint, lacquer, colour wash, etc. dense (glue) degree, need interpolation thinner in right amount.
8. a kind of as described in claim 3 or 7 be take raw lacquer as matter basigamy closes the method that inorganic crystal whisker is prepared coating, is described " coupling agent ", it is characterized in that this " coupling agent " is titanate coupling agent, and consumption is 0.2% to 3% of stopping composition quality.
9. a kind of as described in claim 1 or 2 or 3 or 7 be take raw lacquer and closed the method that inorganic crystal whisker is prepared coating as matter basigamy, in formula, use pH adjusting control agent, it is characterized in that: this pH adjusting control agent is pyridine, Ammoniom-Acetate or ammoniacal liquor one of them or more than one, adding proportion is generally 0.25% to 5% of material quantity, controls pH value between 5.0 to 7.0.
10. a kind of as described in claim 1 or 2 or 3 or 7 be take raw lacquer and closed the method that inorganic crystal whisker is prepared coating as matter basigamy, be described " thinner ", it is characterized in that this thinner is alcohol, or white oil of camphor, turps, rosin one kind of or more than one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410178583.7A CN103992740A (en) | 2014-04-28 | 2014-04-30 | Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410172208 | 2014-04-28 | ||
| CN201410172208.1 | 2014-04-28 | ||
| CN201410178583.7A CN103992740A (en) | 2014-04-28 | 2014-04-30 | Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103992740A true CN103992740A (en) | 2014-08-20 |
Family
ID=51307090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410178583.7A Pending CN103992740A (en) | 2014-04-28 | 2014-04-30 | Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103992740A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118356A (en) * | 2016-06-29 | 2016-11-16 | 铜陵青铜时代雕塑有限公司 | A kind of nano aluminum nitride modification high abrasion bronze sculpture Super hydrophobic anticorrosive paint and preparation method thereof |
| CN107523189A (en) * | 2017-09-12 | 2017-12-29 | 无锡市永兴金属软管有限公司 | A kind of effective impregnating fluid of wavy metal and preparation method thereof |
| CN109161296A (en) * | 2018-07-17 | 2019-01-08 | 常州大学 | A kind of anticorrosion epoxy resin coating and preparation method thereof suitable for natural gas line wall |
| CN111004532A (en) * | 2019-12-05 | 2020-04-14 | 安徽建筑大学 | Water-resistant non-stripping type interior wall latex paint |
| CN112778885A (en) * | 2021-01-08 | 2021-05-11 | 中国科学院青海盐湖研究所 | Super-hydrophobic coating material, preparation method thereof and super-hydrophobic coating |
| CN115851129A (en) * | 2022-12-07 | 2023-03-28 | 湖北坝漆文旅科技有限公司 | Corrosion-resistant raw lacquer coating and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789359A (en) * | 2005-12-28 | 2006-06-21 | 攀钢集团攀枝花钢铁研究院 | Raw lacquer and its preparation method |
-
2014
- 2014-04-30 CN CN201410178583.7A patent/CN103992740A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789359A (en) * | 2005-12-28 | 2006-06-21 | 攀钢集团攀枝花钢铁研究院 | Raw lacquer and its preparation method |
Non-Patent Citations (3)
| Title |
|---|
| 天津化工研究设计院: "《无机精细化学品手册》", 31 January 2001, 化学工业出版社 * |
| 孙秋菊: "《无机晶须填充改性聚合物的应用》", 31 December 2012, 科学出版社 * |
| 林宣益等: "《涂料用溶剂与助剂》", 30 June 2012, 化学工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118356A (en) * | 2016-06-29 | 2016-11-16 | 铜陵青铜时代雕塑有限公司 | A kind of nano aluminum nitride modification high abrasion bronze sculpture Super hydrophobic anticorrosive paint and preparation method thereof |
| CN107523189A (en) * | 2017-09-12 | 2017-12-29 | 无锡市永兴金属软管有限公司 | A kind of effective impregnating fluid of wavy metal and preparation method thereof |
| CN109161296A (en) * | 2018-07-17 | 2019-01-08 | 常州大学 | A kind of anticorrosion epoxy resin coating and preparation method thereof suitable for natural gas line wall |
| CN111004532A (en) * | 2019-12-05 | 2020-04-14 | 安徽建筑大学 | Water-resistant non-stripping type interior wall latex paint |
| CN112778885A (en) * | 2021-01-08 | 2021-05-11 | 中国科学院青海盐湖研究所 | Super-hydrophobic coating material, preparation method thereof and super-hydrophobic coating |
| CN115851129A (en) * | 2022-12-07 | 2023-03-28 | 湖北坝漆文旅科技有限公司 | Corrosion-resistant raw lacquer coating and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103897591A (en) | Preparation method of raw-lacquer-based wall coating and application technology thereof | |
| CN103992740A (en) | Method using raw lacquer as matrix to cooperate with whisker to prepare paint and product | |
| CN101942234B (en) | Environment friendly dry powder emulsion paint and preparation method thereof | |
| CN103911033A (en) | Special environment-friendly paint prepared by using raw lacquer as biomass base for furniture and cabinets | |
| CN101481584B (en) | Dry powder latex paint for inner wall and preparation thereof | |
| CN102408220B (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN103725051A (en) | Base material of inorganic coating and application of base material | |
| CN106905744B (en) | A kind of crack resistance type exterior wall powder of lacquer putty for use on | |
| CN108456475A (en) | A kind of high adhesion force Waterproof priming paint and its preparation method and application | |
| CN105907285B (en) | Super abrasive polyurethane floor coatings | |
| CN101638544A (en) | Coating for forming flexible imitation marble facing and preparation method thereof | |
| CN107522418B (en) | Wear-resisting artificial color sand of one kind and preparation method thereof | |
| CN101891411A (en) | Waterproofing gypsum agent preparation method | |
| CN106746901B (en) | A kind of concrete dyeing hardening sealant agent | |
| CN1357580A (en) | Production process of colar glaze guartz paint | |
| CN108706603A (en) | A kind of nano calcium hydroxide/nano kaoline nanocomposite and preparation method | |
| CN103897592A (en) | Method for preparing polymer material by taking raw lacquer as biomass base and polymer material prepared by using method | |
| CN110386788A (en) | A kind of JS cement base anti-counterfeit paint, Preparation method and use | |
| CN106916492B (en) | A kind of novel decorative powdery sliver interior wall coating and preparation method thereof | |
| CN106280789A (en) | A kind of double-component silicon third anticracking waterproof coating and preparation method thereof | |
| CN106147457A (en) | A kind of hair dryer antibiotic paint and preparation method thereof | |
| CN102617086A (en) | Novel dry powder emulsion paint | |
| CN109251644A (en) | A kind of polyureas floor coatings and its preparation, application method and carbamide resin | |
| CN105647248B (en) | A kind of basis material and its preparation method and application | |
| RU2384598C2 (en) | Composition for finishing of concrete and plastered surfaces |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140820 |