CN103911033A - Special environment-friendly paint prepared by using raw lacquer as biomass base for furniture and cabinets - Google Patents
Special environment-friendly paint prepared by using raw lacquer as biomass base for furniture and cabinets Download PDFInfo
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- CN103911033A CN103911033A CN201410171816.0A CN201410171816A CN103911033A CN 103911033 A CN103911033 A CN 103911033A CN 201410171816 A CN201410171816 A CN 201410171816A CN 103911033 A CN103911033 A CN 103911033A
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Abstract
The invention provides a special environment-friendly paint prepared by using a raw lacquer as a biomass base for furniture and cabinets and aims at providing a furniture and cabinet paint which is mainly prepared from raw lacquer, is environment-friendly and has excellent ecological properties. The environment-friendly paint comprises components such as the raw lacquer, a filler, a diluent and auxiliaries; the environment-friendly paint is technically characterized in that every 100 parts of raw lacquer is blended with 0.5-10 parts of magnesium salt whiskers. The high temperature resistance and the oil resistance of the raw lacquer for a cabinet are remarkably improved; when a traditional raw lacquer is applied to a cabinet tabletop, the high temperature requirement of the traditional raw lacquer hardly reaches the special heat resistance requirement of the cabinet tabletop, and the modern chemical paint cannot be comparable with the traditional raw lacquer in term of the heat resistance; consequently, the modern cabinet tabletops are seldom coated with the paint. The special environment-friendly paint completely overcomes the shortcoming; especially, as the paint is added with basic magnesium sulfate whiskers are added to the special environment-friendly paint, the heat resistance of the paint is obviously improved, and the comprehensive cost caused by use of the basic magnesium sulfate whiskers is not higher than the cost caused by use of the raw lacquer according to the traditional technology.
Description
Technical field
The invention belongs to chemical industry biotechnology and product material field, especially belong to a kind of taking special product of China raw lacquer as biomass-based polymer furniture and the biological paint of cabinet development and utilization technology.
Background technology
Raw lacquer has another name called Rhus lacquer, state's paint, lacquer, lacquer, Chinese lacquer etc., is time-honored Chinese traditional coating, and its main chemical is laccol, is a kind of traditional natural high-quality coating, have the king's of coating good reputation, belongs to Chinese special product.
Raw lacquer thinks to have at least more than 8000 at Chinese applicating history according to archaeology person, and someone thinks that this is the fifth-largest invention or the sixth-largest invention of ancient Chinese.Although raw lacquer is long in Chinese application, but because the execution conditions of raw lacquer are to have relatively high expectations compared with modern chemical industry paint, especially the construction period of raw lacquer is longer, and is subject to raw lacquer use procedure restricted by natural factor, drying conditions requires harsh, need to control certain temperature, humidity condition.While construction in the winter time, drying property is poor, is difficult to polymerization film formation.And raw lacquer viscosity is large, construction technology is fastidious, demands strict technology, and can only adopt manual operations, is difficult to adopt the operation of mechanize mode, and the production cycle is long, and labour productivity is low.Meanwhile, raw lacquer also easily causes people's skin allergy, there is no so far the good recipe of radical cure raw lacquer allergy.
Raw lacquer, in the time of north of China or use in winter, often, because room temperature is lower cannot and complete raw lacquer film forming, completes raw lacquer drying process fast.Especially, carry out indoor wall or other water and facilitate the raw lacquer of mobile equipment to cover with paint, lacquer, colour wash, etc. while construction, how to improve the seasoning speed of raw lacquer under low temperature and low humidity condition, become a technical bottleneck of the industry.
In contemporary upholstery activity, people start to trend towards to be turned on by chemistry painting industry the lacquer of nontoxic non-environmental-pollution and study, and raw lacquer is the first-selected research object of this lacquer.But, because:
The snappiness of raw lacquer film is poor, i.e. the friability of paint film, and this is the technical bottleneck problem that needs solution in raw lacquer application;
Cabinet is for its oil-proofness and high temperature resistantly have a particular requirement, and general chemical industry paint and common raw lacquer are all difficult to meet its this particular requirement;
Raw lacquer can only adopt traditional " coating with lacquer decorations " skill conventionally, be difficult to adopt modern spraying coating process, because adopt modern spraying coating process to be easy to cause thickness of paint layer deficiency, if spraying number of times is too much, and the thickness of each spraying is blocked up, be easy to cause occurring the sagging phenomenon of enamelled coating.
Because of above-mentioned these defects that raw lacquer itself exists, make people then other surrogates of searching, the novel paint coating variety of exploitation, is nibbling Lacquer Market share; Cause being not easy to large-scale industrial production., modern it is found that and feel after the great environmental protection impact that modern chemical industry paint brings to the mankind, again eye having been paid close attention to Chinese traditional raw lacquer, is to wish raw lacquer to develop as furniture and cabinet and use and paint very much.
Therefore be necessary to study into a kind of have nature, environmental protection, acidproof, corrosion-resistant, water-fast, oil resistant, the good polymer paint vehicle of wear resisting property taking raw lacquer as biomass-based, day by day wait in expectation and return Piao and return genuine demand to meet people.
Summary of the invention
Object of the present invention
Be to provide furniture and the cabinet that a kind of environmental friendliness, ecological performance taking raw lacquer as main raw material is good to paint with biological.
Realize invention technical scheme
Scheme one
Taking raw lacquer as biomass-based furniture and the cabinet special environment protection paint prepared, this environmental protection paint contains the compositions such as raw lacquer, stopping composition, thinner and assistant agent, and its guardian technique reference mark is that every 100 parts of raw lacquer are joined 0.5 part to 10 parts of magnesium salt whisker.
Scheme two
Taking raw lacquer as biomass-based furniture and the cabinet special environment protection paint prepared, this environmental protection paint contains the compositions such as raw lacquer, stopping composition, resin, thinner and assistant agent, and its guardian technique reference mark is that every 100 parts of raw lacquer join: 0.5 part to 10 parts of magnesium salt whisker, 1 part-20 parts of epoxy resin.
Scheme three
Taking raw lacquer as biomass-based furniture and the cabinet special environment protection paint prepared, this environmental protection paint contains raw lacquer, stopping composition, thinner and assistant agent etc., and its guardian technique reference mark is that every 100 parts of raw lacquer join 0.5 part to 10 parts of magnesium salt whisker; Separately join 0.5 part to 8 parts of coupling agent in the ratio of every 100 parts of magnesium salt whiskers.
Scheme four
Taking raw lacquer as biomass-based furniture and the cabinet special environment protection paint prepared, this environmental protection paint contains raw lacquer, stopping composition, resin, thinner and assistant agent etc., and its guardian technique point is that every 100 parts of raw lacquer join: 0.5 part to 10 parts of magnesium salt whisker, 1 part-20 parts of epoxy resin; Separately join 0.5 part to 10 parts of coupling agent according to the ratio of every 100 parts of magnesium salt whiskers.
Implement when such scheme, below further the key details of its technology of refinement have:
1. " magnesium salt whisker " described in such scheme, suggestion is used alkali magnesium sulfate crystal whisker, and every 100 parts of raw lacquer are joined 1 part to 5 parts of alkali magnesium sulfate crystal whisker.
2. above-mentioned " coupling agent ", suggestion is used titanate coupling agent, and every 100 parts of stopping composition are joined 0.5 part to 3 parts of titanate coupling agent.
3. " stopping composition " described in above-mentioned, suggestion use calcined kaolin or/and not stone flour or/and quartz powder/or/and talcum powder.Use is technical requirements routinely.If fineness can reach nanomaterial grade, technique effect is even more ideal.
4. " thinner " described in above-mentioned, suggestion is used alcohol, or white oil of camphor, turps, rosin one kind of or more than one.Usage quantity is technical requirements routinely.Thinner consumption adds according to construction process requirement.
5. " assistant agent " described in such scheme, suggestion use biomass auxiliary material or/and solidifying agent or/and pigment, especially described " the biomass auxiliary material " of suggestion is " being boiled wood oil, ripe oleum lini, perilla oil, Chinese catalpa oil, rosin, wood wax oil or dryness or semi-drying vegetables oil, animal oil or and animal serum albumen, sphaeroprotein, glycoprotein, water-soluble polypeptide or sericin "; " solidifying agent " is " quadrol ".Usage quantity is technical requirements routinely.
Technique scheme has only been pointed out key formula and its operative technique, and other technology contents can be with reference to routine techniques, and with reference to embodiment content described later.
beneficial effect of the present invention
1. formula shown in the present and method, by coating test standard detection, can improve 0.5 times to 1.5 times of the sticking power of paint film, even more than; Other performance of paint film: heat-resisting (high temperature) property raising 95% to 189%, corrosive nature raising 24% to 119%, snappiness raising 37% to 107%, acidproof (diluted acid) performance raising 31% to 63%, oil resistance raising 22% to 67%, wear resisting property raising 28% to 108%.This feature is especially used high temperature resistant, the oil-proofness problem of raw lacquer to bring the progress of utmost point significance for solving cabinet, use traditional raw lacquer in the time of cupboard panel, often be difficult to reach the special thermotolerance requirement of cupboard panel due to high temperature resistant requirement, and cannot paint with raw lacquer, especially cannot be compared with the resistance toheat of traditional raw lacquer as for modern chemical industry paint, cause modern people's cupboard panel seldom to make to paint.The present invention can solve this defect completely, and after especially adding alkali magnesium sulfate crystal whisker, its thermotolerance significantly increases, and uses the comprehensive cost of alkali magnesium sulfate crystal whisker not exceed the cost that uses raw lacquer by conventional art.
Because of significantly improving of wear resisting property, also there is unusual effect for the wearing quality that strengthens furniture and cabinet.
While adopting this technology, use with diameter be 0.5 to 1.2um, length is 20 to 100um alkali magnesium sulfate crystal whisker material filling, high-speed stirring is distributed in existing raw lacquer formula (to be generally less than 5%) according to a certain percentage, just can be uniformly dispersed completely through being stirred in 15 minutes, paint viscosity can double.After stirring, coating state is uniform and smooth state, without caking; Construction thickness is brought up to 0.7-1.0 mm from original 0.4mm, and sag prevention performance improves.Test its performance, cohesive strength is brought up to 1.5MPa from 0.67 MPa, and water tolerance, cold-hot cycle performance all significantly improve.In high temperature resistant experiment; find whisker add improved fire prevention raw lacquer at expanded foamed process floating coat and charring layer the intensity in jet flames; avoided overflowing in decomposition reaction a large amount of gas or powerful jet flames impacts and causes charring layer structural damage; avoid expansion sag of protecting coating; keep and increased structural integrity and the structural strength of charring layer and inorganic layer; thereby improve the time of flameproof protection, more effectively protected base material to avoid the destruction of high temperature.
2. raw lacquer is combined to use with epoxy resin, even if do not add solidifying agent, also can make epoxy resin cure, and combine the significant associating of performance result of use while use, while especially using alcohol as thinner, effect is more obvious, and environmental protection more.Because raw lacquer and alcohol all can be prepared with biological method, no matter it is produced still all can not caused environmental pollution in use procedure.After adopting method shown in the present that raw lacquer and epoxy resin are used in conjunction with, use summer and autumn temperature (25 DEG C ± 5 DEG C, humidity 80% ± 10%) are lower, even if mismatch solidifying agent such as using ethylenediamines, shorten the time of drying of more alone raw lacquer more than 2 to 4 times; In the time suitably adding ethylenediamines solidifying agent, shorten the time of drying of more alone raw lacquer more than 4-10 times.After adopting method shown in the present that raw lacquer and epoxy resin are used in conjunction with, use winter-spring season temperature (8 DEG C ± 5 DEG C, humidity 70% ± 10%) is lower, even if mismatch solidifying agent such as using ethylenediamines, shorten the time of drying of more alone raw lacquer more than 3 to 4 times; In the time suitably adding ethylenediamines solidifying agent, shorten the time of drying of more alone raw lacquer more than 6-10 times.
In the time using whisker class to coordinate raw lacquer to use as stopping composition, the rate of drying of paint film can improve more than 31%.
In the time being used in conjunction with coupling agent, the rate of drying that can improve again paint film is more than 15%.
the rate of drying of above-mentioned increase raw lacquer film,there is marked improvement meaning for solving low temperature season construction and being convenient to the construction of raw lacquer normal temperature.
Tensile strength and the shearing resistance of the paint film that coating prepared by the inventive method forms can improve 52% to 132%, can effectively solve raw lacquer snappiness defect, can effectively reduce the fragility of paint film.
3. because the cost of raw lacquer present stage is more expensive, source is also nervous, adds after stopping composition, and to reduce raw materials cost 8% to 30%, and painting quality not only do not decline, and the over-all properties of paint film is significantly improved.
4. adopt the present invention except adopting traditional " coating with lacquer decorations " technique, also can suitably increase dilution dosage (requires more than the fineness of stopping composition reaches 300 orders for mechanical spray decorations, fineness is thinner, effect is unreasonable to be thought) raw lacquer coating, solve raw lacquer and can only adopt the technical bottleneck problem of traditional " coating with lacquer decorations " skill.
In sum, the coating of the present invention taking raw lacquer as biomass-based preparation, that a kind of natural, environmental protection, acidproof, corrosion-resistant, water-fast, oil resistant, wear resisting property all show good traditional, environmentally friendly furniture and cabinet environmental protection paint, and can meet the day by day anticipatory Piao of returning of people and return true demand, and realize goal of the invention.---there is marked improvement meaning for the purposes of expanding raw lacquer.
Embodiment
Because having described comparatively detailed technology contents in aforesaid technical scheme, technology implementation and operational condition can be met, in order to save content length, content in technique scheme can be directly as the content in this embodiment, in order to make the present invention can reach more preferably state, below some key details in specific implementation process is further disclosed.
about stopping composition and whisker
Stopping composition of the present invention, comprises in fact: calcined kaolin or/and not stone flour or/and quartz powder/or/and outside talcum powder, magnesium salt whisker, can also comprise other stopping composition.The fineness of stopping composition is larger, and effect is better, receives level if can reach, and the technique effect of performance is the most desirable.The ratio of stopping composition and raw lacquer, the ratio of pointing out, can also be recommended as 0.3-1: 1 in technical scheme.
about raw lacquer
Can add biomass auxiliary material to raw lacquer and do pre-treatment, biomass auxiliary material is generally boiled wood oil, ripe oleum lini, perilla oil, Chinese catalpa oil, rosin, wood wax oil or dryness or semi-drying vegetables oil, animal oil.Suggestion is used boiled wood oil and ripe oleum lini to use in 7: 3 ratio proportionings.
Raw lacquer paints and other are regionally produced paint by safe and comfortable paint, Hanzhong paint, entrance of the city paint, dam paint, the Qinling Mountains, decocts and coils mark more than 65%, and laccol content is more than 50%.
Raw lacquer is carried out to filtration treatment can be improved operating efficiency and improve painting quality.Can by the quality proportioning of raw lacquer with addition of activated protein (generally refer to animal serum albumen, sphaeroprotein, glycoprotein, water-soluble polypeptide or sericin, also can directly use traditional raw lacquer coat with lacquer decorations technique use pig blood ox blood and other animality blood) 1%～5%.
The present invention can use refining raw lacquer.Also can adopt send out in lower technical scheme process:
Formula contains: raw lacquer: 92%, and bovine serum albumin: 5%, pyridine: 3%.In enzyme reactor, by the raw lacquer through filtering, at normal temperatures, pass into oxygen, add 5% bovine serum albumin, 3% pyridine, insulation reaction 8 hours, stirring velocity is controlled at 50/min～60/min, then in the dehydration that heats up, moisture content is controlled at 5%, visual inspection, raw lacquer becomes color of soy sauce by brown color, gets product.
about coupling agent
The invention reside in described " coupling agent ", be applicable to use titanate coupling agent, consumption except by aforementioned schemes can, can also be 0.1% to 8% of stopping composition (as: whisker composition) quality, recommended amounts is 0.2% to 3%.
Certainly, also can use silane coupling agent, zirconium ester coupling agent, aluminate coupling agent etc., because the wide accommodation of titanate coupling agent, price material benefit, so suggestion is used titanate coupling agent.
Coupling agent claims again short stick or surface treatment agent, is a kind of material with both sexes structure.It is centered by titanium, and one end of molecule can be reacted with the chemical group on inorganics surface, forms firmly chemical bond; The other end group has close organic character, can be wound around with reactive organic molecule or physics, thereby the material that two kinds of character are differed widely firmly combines.
Through the inorganics of titanate coupling agent processing be hydrophobic parent organically, in polymeric system, can promote bondingly when adding, there is katalysis; Improve and disperse and rheological property; Improve shock strength, can not produce fragility; Improve mechanical property, improve loading level, reduce costs; Prevent from being separated, the effect such as anticorrosion, anti-oxidant, fire-retardant, it is a kind of multi-functional auxiliary agent with very large handiness, itself is coupling agent, also can do dispersion agent, wetting agent, tackiness agent, linking agent, catalyzer, is therefore of wide application.Coupler is used in conjunction with in raw lacquer coating, and the effect showing is quite good.Titanate coupling agent is used in conjunction with in the present invention, embodies good synergy with raw lacquer etc.---this is also important beneficial effect of the present invention.
Titanate coupling agent mainly contains Four types: 1) monoalkoxy type; 2) tetra-sodium type; 3) type that boils together; 4) corrdination type.
Titanate coupling agent has very large handiness and multifunctionality, itself is coupling agent, also can be dispersion agent, wetting agent, tackiness agent, linking agent, catalyzer etc., can also have concurrently antirust, anti-oxidant, fire-retardant etc. multi-functionally, therefore be of wide application, surpass other coupling agent.
The consumption of coupling agent, is generally the 0.5-3% of handled thing (typically referring to stopping composition) weight, and recommendation amount is 0.8-1.5%.Its consumption and effect are not proportional relations, measure too much coupling agent surplus and make on the contrary degradation, and very little,, because cladding not exclusively, effect is not remarkable for amount.So time need to test out optimum amount in application, accomplish not only economy but also effective.
Suggestion consumption parameter is as follows:
The consumption of titanate coupling agent is that hydroxyl or the proton that will make whole isopropoxies in coupling agent molecule and face, stopping composition provide react, and surface-area is larger, and the consumption of coupling agent just the more.
The in the situation that of low loading level, coupling agent consumption accounts for 0.6% of stopping composition amount;
The in the situation that of middle loading level, coupling agent consumption accounts for 1.0% of stopping composition amount;
The in the situation that of high filler loading capacity, coupling agent consumption accounts for the 1.5-2.0% of stopping composition amount;
Titanate coupling agent using method:
Monoalkoxy type titanate coupling agent, as NGT-101, NGT-102, NGT-105, NGT-502, is applicable to stopping composition or the extremely low stopping composition of water ratio of dry production, and burnt phosphide type is applicable to inorganic fillings and the pigment containing a certain amount of free water as NGT-201.
Directly reinforced method: in proportion resin, stopping composition and coupling agent are carried out to mix and blend, until add other auxiliary agents to carry out mix and blend after stirring, this method effect is generally speaking not as good as method for pretreating.
Method for pretreating: first use anhydrous solvent, as dehydrated alcohol (raw spirit), Virahol etc., suggestion is used raw spirit, and during for interior decoration, the safety performance of alcohol is even more ideal, and common solvent is 1:1 with the ratio of coupling agent; Under the condition of high-speed stirring inorganic fillings (whisker), the coupling agent having diluted is dripped or be sprayed to stopping composition surface, then being warming up to 75-150 DEG C continues to stir 10 minutes, now stopping composition surface element has formed unimolecular film, become hydrophobic nature from wetting ability, comparatively stable, after solvent is dried and is gone, add after other auxiliary agents and resin treatment moulding for subsequent use.
Also can adopt the pre-treatment of high-speed stirring heating means, can save solvent consumption, and treatment effect is good.The steps include: stopping composition to add in mixing tank, start and stir, (rotating speed is higher to be warmed up to 70 DEG C of-80 DEG C of left and right, more be conducive to the dispersion of coupling agent on stopping composition surface), then evenly add titanate coupling agent or coupling agent solution, can adopt dripping method or spraying, add rear continuation and stir 15 minutes (churning time is depending on rotating speed).
Select coupling agent to carry out surface treatment inorganic fillings, then with resin and other auxiliary agent mixing granulation, can reach best coupling effect.By the hydrophilic hydrophobic that becomes, nonhygroscopic through the stopping composition surface of coupling agent treatment, stable performance.
Certainly, also can, according to the practical situation of raw lacquer application, select corresponding using method.
Variant because of the physicochemical property of stopping composition, being applied to time of the present invention, please to determine and add coupler consumption according to experimental result, in file of the present invention, only consumption, also general conventional ratio are recommended in prompting.
Because titanate coupling agent consumption is few, for making it bring into play due effect, must make it in stopping composition handled things such as (or) pigment, disperse equably, otherwise, do not reach coupling effect.
4. about thinner
Thinner of the present invention can be alcohol, or white oil of camphor, turps, rosin one kind of or more than one.Consider based on environmental protection, suggestion is used alcohol, because alcohol can use agricultural crop straw to prepare as raw material biological method, and alcohol is without any side effects, shows more friendlyly to environment.
Thinner consumption according to cover with paint, lacquer, colour wash, etc. processing requirement with addition of, in the present invention, do not do ratio prompting.
about using PH adjusting control agent
Play a role in order to be beneficial to laccase, can in formula, use pH adjusting control agent, this pH adjusting control agent generally can use pyridine, Ammoniom-Acetate or ammoniacal liquor one of them or more than one, adding proportion is generally 0.25% to 5% of material quantity, controls pH value in 5.0 to the 7.0 suitable growth potential of hydrogen that are laccase.Adding duration of service can be in the preprocessing process of raw lacquer, can be also that raw lacquer is while mixing with stopping composition.
about epoxy resin and solidifying agent thereof
In the time using epoxy resin, if in the present invention with addition of ethylenediamines solidifying agent, there is remarkable effect for accelerating the dry of paint film, but consider that quadrol is chemical product, may there is not too friendly suspicion to environment, can be with addition of solidifying agent.If with addition of solidifying agent, be generally suggestion according to the epoxy equivalent (weight) proportioning solidifying agent of epoxy resin as quadrol, how to join and please refer to relevant epoxy resin handbook.
Even if do not use solidifying agent, because there being the existence of raw lacquer composition, can impel epoxy resin cure, in the time that raw lacquer and epoxy resin are used in conjunction with, present the effect that significantly improves drying varniss speed; When using whisker class material also to have remarkable speed-raising effect for being dried of paint film; In the time using coupling agent, also there is significant booster action for being dried of paint film.---this is important very important progressive meaning of the present invention, also can say one of beneficial effect content.
performance Detection explanation
The detection of correlated performance, if no special instructions, generally to detect institute by coating test standard or respective performances examination criteria to draw, as: the method for inspection can be with reference to national inspecting standards such as GB/T14703-2008, GB/T6739-1996, GB/T1761-1979, GB/T1735-1979.
other explanation
In the present invention, a guardian technique is exactly that preparation process is had relatively high expectations for mixing, mixes more evenly, and coating effect is unreasonable to be thought.
In the present invention, if no special instructions, correlation proportion is quality (weight) component.
Claims (10)
1. the furniture taking raw lacquer as biomass-based preparation and a cabinet special environment protection paint, this environmental protection paint contains raw lacquer, stopping composition, thinner and assistant agent, it is characterized in that (quality component): every 100 parts of raw lacquer are joined 0.5 part to 10 parts of magnesium salt whisker.
2. furniture and the cabinet special environment protection paint taking raw lacquer as biomass-based preparation, this environmental protection paint contains raw lacquer, stopping composition, resin, thinner and assistant agent, it is characterized in that (quality component) every 100 parts of raw lacquer join: 0.5 part to 10 parts of magnesium salt whisker, 1 part-20 parts of epoxy resin.
3. furniture and the cabinet special environment protection paint taking raw lacquer as biomass-based preparation, this environmental protection paint contains raw lacquer, stopping composition, thinner and assistant agent, it is characterized in that (quality component) every 100 parts of raw lacquer join 0.5 part to 10 parts of magnesium salt whisker, separately join 0.5 part to 8 parts of coupling agent in the ratio of every 100 parts of magnesium salt whiskers.
4. furniture and the cabinet special environment protection paint taking raw lacquer as biomass-based preparation, this environmental protection paint contains raw lacquer, stopping composition, resin, thinner and assistant agent, it is characterized in that (quality component) every 100 parts of raw lacquer join: 0.5 part to 10 parts of magnesium salt whisker, 1 part-20 parts of epoxy resin, separately join 0.5 part to 10 parts of coupling agent according to the ratio of every 100 parts of magnesium salt whiskers.
5. " magnesium salt whisker " as claimed in claim 1 or 2 or 3 or 4, it is a kind of alkali magnesium sulfate crystal whisker to it is characterized in that (quality component), every 100 parts of raw lacquer are joined 1 part to 5 parts of alkali magnesium sulfate crystal whisker.
6. " coupling agent " as claimed in claim 1 or 2 or 3 or 4, it is a kind of titanate coupling agent to it is characterized in that (quality component), every 100 parts of stopping composition are joined 0.5 part to 3 parts of titanate coupling agent.
7. " stopping composition " as claimed in claim 1 or 2 or 3 or 4, it is characterized in that its can be calcined kaolin or/and not stone flour or/and quartz powder/or/and talcum powder.
8. " thinner " as claimed in claim 1 or 2 or 3 or 4, is characterized in that it can be alcohol, or white oil of camphor, turps, rosin one kind of or more than one.
9. " assistant agent " as claimed in claim 1 or 2 or 3 or 4, it is characterized in that its refer to biomass auxiliary material or/and solidifying agent or/and pigment.
10. " biomass auxiliary material is or/and solidifying agent " as claimed in claim 9, is characterized in that " biomass auxiliary material " refers to " being boiled wood oil, ripe oleum lini, perilla oil, Chinese catalpa oil, rosin, wood wax oil or dryness or semi-drying vegetables oil, animal oil or and animal serum albumen, sphaeroprotein, glycoprotein, water-soluble polypeptide or sericin "; " solidifying agent " refers to " quadrol ".
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| CN107474593A (en) * | 2017-07-25 | 2017-12-15 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze surface varnish |
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| CN110565446A (en) * | 2019-08-30 | 2019-12-13 | 祝恒 | Mechanized manufacturing method of novel environment-friendly device combining woody fiber or herbaceous fiber and lacquer |
| CN110776828A (en) * | 2019-11-29 | 2020-02-11 | 福州大学 | Dendritic polyamide-amine modified raw lacquer coating and preparation method thereof |
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