CN104074097B - A kind of computer color spray paper using surface modification coating and its preparation method - Google Patents
A kind of computer color spray paper using surface modification coating and its preparation method Download PDFInfo
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- CN104074097B CN104074097B CN201410290375.6A CN201410290375A CN104074097B CN 104074097 B CN104074097 B CN 104074097B CN 201410290375 A CN201410290375 A CN 201410290375A CN 104074097 B CN104074097 B CN 104074097B
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- color spray
- surface modification
- computer color
- paraffin wax
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Abstract
The present invention relates to a kind of computer color spray paper using surface modification coating and its preparation method, belong to technical field of polymer materials. The computer color spray paper using surface modification coating of the present invention comprises the following raw material according to weight parts: polyacrylic resin 35-50 part, polyethylene vinyl acetate resin 10-20 part, vinyl acetic monomer 80-110 part, polyacrylamide 10-19 part, polychlorostyrene second diene dimethylamine 4-12 part, white carbon black 20-40 part, titanium dioxide 5-10 part, dispersion agent 1-2 part, wetting agent 1-2 part, talcum powder 5-18 part, paraffin wax emulsions 10-20 part, casein food grade 5-15 part. The modified paint formula of the present invention is reasonable, design for color spray ink and pigment, the modification computer color spray paper using obtained by this modified paint, has better wettability power, that spraying ink is sprawled is suitable, have better color reductibility, the image of acquisition and color highly to be reduced the advantage such as former.
Description
Technical field
The present invention relates to a kind of paper surface modified paint and its preparation method, more specifically, the present invention relates to a kind of computer color spray paper using surface modification coating and its preparation method, belong to technical field of polymer materials.
Background technology
A large amount of employing computer color spray print paper is needed in fields such as advertisings. In order to obtain preferably printing effect, it is necessary to the surface of paper is carried out modification.
It is CN101870748A that State Intellectual Property Office discloses a publication number in 2010.10.27, name is called the patent of invention of " a kind of preparations and applicatio method of polyacrylic acid amide modifier for fly ash fiber paper making ", which disclose a kind of preparations and applicatio method of polyacrylic acid amide modifier for fly ash fiber paper making, it is characterized in that: first in aqueous phase, acroleic acid polymerization is become polyacrylic acid, again by N, N-dimethyl-1,3-propylene diamine joins and carries out amidation in the polyacrylic acid aqueous solution; Gained amidated products is warming up to 50 ~ 80 DEG C, adds bromination of n-butane and carry out season ammonium, obtain polyacrylic acid amide modifier. Then, being dispersed in water by coal ash fiber, add polyacrylic acid amide modifier, stir 10 ~ 15 minutes, add xylon slurry, after mixing, papermaking on sheet forming machine, obtains the paper containing coal ash fiber. Polyacrylic acid amide modifier prepared by aforesaid method can strengthen the bonding force between coal ash fiber and wood pulp cellulose, thus improves the intensity containing coal ash fiber paper.
It is CN101575826 that State Intellectual Property Office discloses a publication number in 2009.11.11, name is called the patent of invention of " water-borne coatings for finish foil ", which disclosing a kind of water-borne coatings for finish foil is the coating used in finish foil process for processing, this kind of water-borne coatings is the polyacrylic acid dispersion liquid also containing hydroxyl by vinylbenzene and acrylic ester copolymer, through the melamine resin of alcohol class etherificate, aliphatic polyester thing, organic modified polyorganosiloxane, polyether-modified polysiloxane, the oxide compound of inorganic silicon, polysiloxane polyether copolymer, aromatic sulphonic acid is mixed with in proportion, coat the surface of decorative paper, after short period of time baking-curing, just can obtain top coat of good performance.Produce simple, with low cost, environmental protection, covering with paint convenient, be conducive to solving in producing the supply of material inconvenience produced because of coating import and the higher problem of cost, be conducive to realizing the localization of water-borne coatings.
Disclosed in above-mentioned prior art patent, properties-correcting agent or coating are not all suitable for the modification on computer color spray paper using surface, cannot improve the performance of its paper for the feature of color spray pigment.
Summary of the invention
The present invention is intended to solve the problem of above-mentioned prior art, it is provided that a kind of computer color spray paper using surface modification coating, it is possible to the surface of computer color spray paper using is carried out modification, it is to increase the spraying property of paper.
In order to realize foregoing invention object, its concrete technical scheme is as follows:
A kind of computer color spray paper using surface modification coating, it is characterised in that: comprise the following raw material according to weight parts:
Polyacrylic resin 35-50 part
Polyethylene vinyl acetate resin 10-20 part
Vinyl acetic monomer 80-110 part
Polyacrylamide 10-19 part
Polychlorostyrene second diene dimethylamine 4-12 part
White carbon black 20-40 part
Titanium dioxide 5-10 part
Dispersion agent 1-2 part
Wetting agent 1-2 part
Talcum powder 5-18 part
Paraffin wax emulsions 10-20 part
Casein food grade 5-15 part.
Preferably, a kind of computer color spray paper using surface modification coating, it is characterised in that: comprise the following raw material according to weight parts:
Polyacrylic resin 39-42 part
Polyethylene vinyl acetate resin 12-17 part
Vinyl acetic monomer 85-100 part
Polyacrylamide 15-18 part
Polychlorostyrene second diene dimethylamine 6-10 part
White carbon black 25-38 part
Titanium dioxide 7-9 part
Dispersion agent 1.2-1.8 part
Wetting agent 1.5-1.9 part
Talcum powder 7-15 part
Paraffin wax emulsions 12-16 part
Casein food grade 7-13 part.
White carbon black of the present invention is thermal silica.
Paraffin wax emulsions of the present invention is the paraffin wax emulsions of 15%.
The preparation method of a kind of computer color spray paper using surface modification coating, it is characterised in that: comprise following processing step:
A, take polyacrylic resin by recipe requirements, polyethylene vinyl acetate resin, polyacrylamide, polychlorostyrene second diene dimethylamine, white carbon black, titanium dioxide, dispersion agent, wetting agent;
B, adding formula consumption 1/3 vinyl acetic monomer, dispersed with stirring is even, and then adds talcum powder, paraffin wax emulsions and casein food grade, and on closed two roller machine, grinding is evenly;
C, 2/3 vinyl acetic monomer adding remainder, fully mix and obtain computer color spray paper using surface modification coating.
The Advantageous Effects that the present invention brings:
The invention solves existing paper properties-correcting agent or modified paint is not all suitable for the modification on computer color spray paper using surface, the problem of the performance of its paper cannot be improved for the feature of color spray pigment. The computer color spray paper using surface modification formulation for coating material of the present invention is reasonable, design for color spray ink and pigment, the modification computer color spray paper using obtained by this modified paint, has better wettability power, that spraying ink is sprawled is suitable, have better color reductibility, the image of acquisition and color highly to be reduced the advantage such as former.
Embodiment
Embodiment 1
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 35 parts
Polyethylene vinyl acetate resin 10 parts
Vinyl acetic monomer 80 parts
Polyacrylamide 10 parts
Polychlorostyrene second diene dimethylamine 4 parts
White carbon black 20 parts
Titanium dioxide 5 parts
Dispersion agent 1 part
Wetting agent 1 part
Talcum powder 5 parts
Paraffin wax emulsions 10 parts
Casein food grade 5 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 2
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 50 parts
Polyethylene vinyl acetate resin 20 parts
Vinyl acetic monomer 110 parts
Polyacrylamide 19 parts
Polychlorostyrene second diene dimethylamine 12 parts
White carbon black 40 parts
Titanium dioxide 10 parts
Dispersion agent 2 parts
Wetting agent 2 parts
Talcum powder 18 parts
Paraffin wax emulsions 20 parts
Casein food grade 15 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 3
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 42.5 parts
Polyethylene vinyl acetate resin 15 parts
Vinyl acetic monomer 95 parts
Polyacrylamide 14.5 parts
Polychlorostyrene second diene dimethylamine 8 parts
White carbon black 30 parts
Titanium dioxide 7.5 parts
Dispersion agent 1.5 parts
Wetting agent 1.5 parts
Talcum powder 11.5 parts
Paraffin wax emulsions 15 parts
Casein food grade 10 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 4
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 39 parts
Polyethylene vinyl acetate resin 18.5 parts
Vinyl acetic monomer 88 parts
Polyacrylamide 17 parts
Polychlorostyrene second diene dimethylamine 6.5 parts
White carbon black 36 parts
Titanium dioxide 5.5 parts
Dispersion agent 1.4 parts
Wetting agent 1.7 parts
Talcum powder 15 parts
Paraffin wax emulsions 16 parts
Casein food grade 8.5 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 5
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 39 parts
Polyethylene vinyl acetate resin 12 parts
Vinyl acetic monomer 85 parts
Polyacrylamide 15 parts
Polychlorostyrene second diene dimethylamine 6 parts
White carbon black 25 parts
Titanium dioxide 7 parts
Dispersion agent 1.2 parts
Wetting agent 1.5 parts
Talcum powder 7 parts
Paraffin wax emulsions 12 parts
Casein food grade 7 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 6
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 42 parts
Polyethylene vinyl acetate resin 17 parts
Vinyl acetic monomer 100 parts
Polyacrylamide 18 parts
Polychlorostyrene second diene dimethylamine 10 parts
White carbon black 38 parts
Titanium dioxide 9 parts
Dispersion agent 1.8 parts
Wetting agent 1.9 parts
Talcum powder 15 parts
Paraffin wax emulsions 16 parts
Casein food grade 13 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 7
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 40.5 parts
Polyethylene vinyl acetate resin 14.5 parts
Vinyl acetic monomer 92.5 parts
Polyacrylamide 16.5 parts
Polychlorostyrene second diene dimethylamine 8 parts
White carbon black 31.5 parts
Titanium dioxide 8 parts
Dispersion agent 1.5 parts
Wetting agent 1.7 parts
Talcum powder 11 parts
Paraffin wax emulsions 14 parts
Casein food grade 10 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 8
A kind of computer color spray paper using surface modification coating, comprises the following raw material according to weight parts:
Polyacrylic resin 41.5 parts
Polyethylene vinyl acetate resin 16 parts
Vinyl acetic monomer 87 parts
Polyacrylamide 17 parts
Polychlorostyrene second diene dimethylamine 6.6 parts
White carbon black 27.3 parts
Titanium dioxide 7.2 parts
Dispersion agent 1.75 parts
Wetting agent 1.63 parts
Talcum powder 11.6 parts
Paraffin wax emulsions 13.7 parts
Casein food grade 12 parts.
Preferred:
Described white carbon black is thermal silica.
Described paraffin wax emulsions is the paraffin wax emulsions of 15%.
Embodiment 9
A preparation method for computer color spray paper using surface modification coating, comprises following processing step:
A, take polyacrylic resin by recipe requirements, polyethylene vinyl acetate resin, polyacrylamide, polychlorostyrene second diene dimethylamine, white carbon black, titanium dioxide, dispersion agent, wetting agent;
B, adding formula consumption 1/3 vinyl acetic monomer, dispersed with stirring is even, and then adds talcum powder, paraffin wax emulsions and casein food grade, and on closed two roller machine, grinding is evenly;
C, 2/3 vinyl acetic monomer adding remainder, fully mix and obtain computer color spray paper using surface modification coating.
Claims (5)
1. a computer color spray paper using surface modification coating, it is characterised in that: comprise the following raw material according to weight parts:
Polyacrylic resin 35-50 part
Polyethylene vinyl acetate resin 10-20 part
Vinyl acetic monomer 80-110 part
Polyacrylamide 10-19 part
Polychlorostyrene second diene dimethylamine 4-12 part
White carbon black 20-40 part
Titanium dioxide 5-10 part
Dispersion agent 1-2 part
Wetting agent 1-2 part
Talcum powder 5-18 part
Paraffin wax emulsions 10-20 part
Casein food grade 5-15 part.
2. a kind of computer color spray paper using surface modification coating according to claim 1, it is characterised in that: comprise the following raw material according to weight parts:
Polyacrylic resin 39-42 part
Polyethylene vinyl acetate resin 12-17 part
Vinyl acetic monomer 85-100 part
Polyacrylamide 15-18 part
Polychlorostyrene second diene dimethylamine 6-10 part
White carbon black 25-38 part
Titanium dioxide 7-9 part
Dispersion agent 1.2-1.8 part
Wetting agent 1.5-1.9 part
Talcum powder 7-15 part
Paraffin wax emulsions 12-16 part
Casein food grade 7-13 part.
3. a kind of computer color spray paper using surface modification coating according to claim 1 and 2, it is characterised in that: described white carbon black is thermal silica.
4. a kind of computer color spray paper using surface modification coating according to claim 1 and 2, it is characterised in that: described paraffin wax emulsions is the paraffin wax emulsions of 15%.
5. the preparation method of a kind of computer color spray paper using surface modification coating according to claim 1 and 2, it is characterised in that: comprise following processing step:
A, take polyacrylic resin by recipe requirements, polyethylene vinyl acetate resin, polyacrylamide, polychlorostyrene second diene dimethylamine, white carbon black, titanium dioxide, dispersion agent, wetting agent;
B, adding formula consumption 1/3 vinyl acetic monomer, dispersed with stirring is even, and then adds talcum powder, paraffin wax emulsions and casein food grade, and on closed two roller machine, grinding is evenly;
C, 2/3 vinyl acetic monomer adding remainder, fully mix and obtain computer color spray paper using surface modification coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410290375.6A CN104074097B (en) | 2014-06-26 | 2014-06-26 | A kind of computer color spray paper using surface modification coating and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410290375.6A CN104074097B (en) | 2014-06-26 | 2014-06-26 | A kind of computer color spray paper using surface modification coating and its preparation method |
Publications (2)
| Publication Number | Publication Date |
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| CN104074097A CN104074097A (en) | 2014-10-01 |
| CN104074097B true CN104074097B (en) | 2016-06-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410290375.6A Expired - Fee Related CN104074097B (en) | 2014-06-26 | 2014-06-26 | A kind of computer color spray paper using surface modification coating and its preparation method |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105586804B (en) * | 2015-09-28 | 2017-05-31 | 浙江帝龙新材料有限公司 | A kind of modified acrylic resin finish used for decorative paper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08296198A (en) * | 1995-04-27 | 1996-11-12 | Nitto Kogyo Co Ltd | Paper having increased paper strength and filter |
| CN101575826A (en) * | 2009-06-16 | 2009-11-11 | 张一帆 | Water paint for finish foil |
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
| CN103013248A (en) * | 2011-09-23 | 2013-04-03 | 陕西建设机械股份有限公司 | Sealing coating for cluster cable coating layer |
| JP5308223B2 (en) * | 2009-04-24 | 2013-10-09 | 大王製紙株式会社 | Coated paper |
-
2014
- 2014-06-26 CN CN201410290375.6A patent/CN104074097B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08296198A (en) * | 1995-04-27 | 1996-11-12 | Nitto Kogyo Co Ltd | Paper having increased paper strength and filter |
| JP5308223B2 (en) * | 2009-04-24 | 2013-10-09 | 大王製紙株式会社 | Coated paper |
| CN101575826A (en) * | 2009-06-16 | 2009-11-11 | 张一帆 | Water paint for finish foil |
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
| CN103013248A (en) * | 2011-09-23 | 2013-04-03 | 陕西建设机械股份有限公司 | Sealing coating for cluster cable coating layer |
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| CN104074097A (en) | 2014-10-01 |
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