CN107139287B - A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time - Google Patents
A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time Download PDFInfo
- Publication number
- CN107139287B CN107139287B CN201710297785.7A CN201710297785A CN107139287B CN 107139287 B CN107139287 B CN 107139287B CN 201710297785 A CN201710297785 A CN 201710297785A CN 107139287 B CN107139287 B CN 107139287B
- Authority
- CN
- China
- Prior art keywords
- parts
- added
- mixed
- layer
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time, first smears one layer of primer in handicraft surface, and after cooling, 70 DEG C of bakings make its thawing, while baking, then applies last layer strengthening layer, cooling after the completion of smearing, waxing.Advantageous effect：One layer of primer first is smeared in handicraft surface, one layer of protective effect played to handicraft surface, after cooling, plastic, 70 DEG C of bakings, glue constantly melts, and while baking, then applies last layer strengthening layer, strengthens glue and first mixed with the primer of thawing, smeared.After cooling, strengthens, invigoration effect is played to handicraft surface; meanwhile primer avoids reinforcing glue corrosion penetration from entering in craftwork to playing layer protecting film to handicraft surface; the each small pore of craftwork is blocked, avoids damaging by worms, water oozes; simultaneously can be effectively with reinforcing glue bond, after cooling, surface is waxed; enhance glossiness, coating does not burn, high temperature resistance; timber burning point is promoted, and reduces combustion of wood performance.
Description
Technical field：
The present invention relates to a kind of wood furnitures to maintain field, and in particular under a kind of baking of wood furniture surface high-temp in short-term
Between fire-retardant method.
Background technology：
Timber is after the surface treatments such as colouring, repairing, and will wax glazing, it is therefore an objective to waterproof and dustproof, anti-on hand greasy
Deng.The method of waxing is that first several beeswaxs or microwax are cut into slices, are placed in tin, in addition some turpentine oil, then puts
It is slowly heated on electric rangette, notices that the excessively high turpentine oil of temperature can be on fire.After wax is completely melt, it is stained with thin cloth when slightly cooler
It is applied to woodcarving surface, then is wiped with strength with another piece of clean cloth until generating uniform gloss.This method is relatively suitble to
Precious wood, it is relatively also troublesome.Beginner is carved with general wood, and shoe polish, the method for the simplicity such as floor wax may be used
Glazing can also increase the gloss of wood, bright and original.
The percentage of desiccated wood essential element is：Carbon 50, hydrogen 6.2, oxygen 43；The timber each element that moisture content is 13%
Percentage is：Carbon 43.5, hydrogen 5.2, oxygen 38.3.The burning of timber will undergo the processes such as dry, thermal decomposition, charing, burning.Combustion
Point is 200 DEG C or more, 400 DEG C of self-ignition point or more.In addition, timber is there are one important characteristic --- low temperature spontaneous combustion, less than
It is heated for a long time under its ignition temperature, spontaneous combustion can also occur for timber.
Invention content：
A kind of another wood for being suitable for household is provided technical problem to be solved by the present invention lies in the prior art is overcome
Furniture surface high-temperature baking lower short time processed fire-retardant method.
The technical problems to be solved by the invention are realized using following technical scheme.
A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time, it is characterised in that：First in handicraft surface
One layer of primer is smeared, after cooling, 70 DEG C of bakings make its thawing, while baking, then apply last layer strengthening layer, after the completion of smearing,
It is cooling, waxing.
Further technology：The bottom preparation method is：
A reaction kettle for carrying blender is selected, then vegetable oil is added into reaction kettle and opens stirring；
Butadiene rubber is taken, A jellies are mixed to get with crosslinking agent, catalyst, tackifier and polypropylene；
Gelatin, rubber softener, octamethylcyclotetrasilazane are mixed 1 hour, temperature is 60 DEG C, is then heated to
70 DEG C, anti-aging agent is added, then be warming up to 80 DEG C, stirs 1 hour, obtain B jellies；
A is mixed with B jellies, vulcanizes 3-5 days in 20 DEG C of air, is subsequently placed in reaction kettle, 75-80 DEG C of reaction, 3
Hour；
Wait for above-mentioned steps after reaction, reaction kettle is cooled to 20-25 DEG C, by pentaerythrite, methanol and the second in raw material
Glycol is added thereto, and is stood 5-10 hours after stirring evenly, is obtained auxiliary material one；
E-42 epoxy resin and diethylenetriamine are mixed；
Mixed solvent and ethyl cyanoacetate are added in bottle, stirred；
It is heated to 81-86 DEG C, monochloroacetic acid is added, continues stirring 1 hour；
30 will be pressed in the environment of -60 DEG C to 60 DEG C of intermixture and ethylenediamine:1 ratio is mixed, and is stirred；
Room temperature is cooled to again, obtains auxiliary material two；
Auxiliary material one is mixed with microwax, takes moment adhesive that mixing is added, and is heated to 60 DEG C, heats duration 10 minutes, so
Postcooling is placed in 60% auxiliary material two, cooling, obtains primer.
Further technology：Constituent content is respectively needed for the primer preparation：50-53 parts of vegetable oil, 6-7 parts it is suitable
Buna, 3-5 part crosslinking agent, 3-5 parts of catalyst, 3-5 parts of tackifier, 6-9 parts of polypropylene, 26-29 parts of gelatin, 12-13 portions of rubbers
Gum softening agent, 5-11 parts of octamethylcyclotetrasilazanes, 1-2 parts of anti-aging agents, 6-9 parts of pentaerythrites, 5-7 parts of methanol, 9-12 parts of second
Glycol, 15-26 parts of E-42 epoxy resin, 4-7 parts of diethylenetriamines, 14-17 parts of ethyl cyanoacetates, 10-13 parts of monochloroacetic acids, 5-
8 parts of ethylenediamines, 23-25 parts of microwaxes, 10-16 parts of moment adhesives.
Further technology：Constituent content is respectively needed for the primer preparation：50 parts of vegetable oil, 6 parts of suitable fourth rubbers
Glue, 3 parts of crosslinking agents, 3 parts of catalyst, 3 parts of tackifier, 6 parts of polypropylene, 26 parts of gelatin, 12 parts of rubber softener, 5 parts of prestoxs
Cyclotetrasilazane, 1 part of anti-aging agent, 6 parts of pentaerythrites, 5 parts of methanol, 9 parts of ethylene glycol, 15 parts of E-42 epoxy resin, 4 parts of divinyls
Triamine, 14 parts of ethyl cyanoacetates, 10 parts of monochloroacetic acids, 5 parts of ethylenediamines, 23 parts of microwaxes, 10 parts of moment adhesives.
Further technology：Constituent content is respectively needed for the primer preparation：53 parts of vegetable oil, 7 parts of suitable fourth rubbers
Glue, 5 parts of crosslinking agents, 5 parts of catalyst, 5 parts of tackifier, 9 parts of polypropylene, 29 parts of gelatin, 13 parts of rubber softener, 11 parts of prestoxs
Cyclotetrasilazane, 2 parts of anti-aging agents, 9 parts of pentaerythrites, 7 parts of methanol, 12 parts of ethylene glycol, 26 parts of E-42 epoxy resin, 7 parts of diethyls
Alkene triamine, 17 parts of ethyl cyanoacetates, 13 parts of monochloroacetic acids, 8 parts of ethylenediamines, 25 parts of microwaxes, 16 parts of moment adhesives.
Further technology：The preparation method of the strengthening layer includes：
The dehydration alum weighed is put into drying oven, drying furnace temperature is risen to 120-150 DEG C, room temperature is down to after drying
Discharging, pulverizes and sieves, is mixed with dioctyl phthalate, gained mixture is named as component A；
By starch and water, proportion 1:13, it is added in flask；Stirring, is added sodium hydroxide, and heating four-hole boiling flask is warming up to
It 90-95 DEG C, reacts 40-50 minutes；Oxidation diisopropylbenzene (DIPB) is added and water is kept stirring 20 minutes；It is cooled to 50-60 DEG C, oxidation two
Isopropylbenzene and water proportion are 1:1, insulation reaction 30-40 minutes；It with cold water mix, stirs evenly, gained liquid is named as component
B；
95% second alcohol and water is 1 by volume:4-1:8 are made into alcohol solution silane coupling agent are added, by polypropylene with
10 times of water mixing, mixed solution are placed in 200W-300W ultrasonic waves, are stirred lower heating hydrolysis 30min-1.5h and are made 80
DEG C~90 DEG C of transparent acidification hydrating solutions, name component C；
Cotton linter is added in chrysanthemum water under stiring, after stirring into serum, 40% caustic-soda aqueous solution, stearic acid is added,
Rapid stirring；Pentachlorophenol, waterglass, thiocarbamide, ethyl acetate, heating stirring are sequentially added, heating temperature is 190 DEG C, duration
10 minutes；70 DEG C are cooled to, casein is instilled, naturally cools to room temperature, filter to take liquid, obtain component D；
Component A, B, C and D are merged, polyvinyl alcohol, sodium phosphate are added, mixes, stirs evenly,.
Further technology：Constituent content is respectively needed for the strengthening layer preparation：10-16 parts of alum, 5-6 parts of neighbours
Dioctyl phthalate, 80-90 part starch, 7-9 parts of sodium hydroxides, 23-25 parts of cumyl peroxides, 95% second of 40-46 parts
Alcohol, 4-6 part silane coupling agent, 14-18 parts of polypropylene, 60-78 parts of cotton linters, 40% caustic-soda aqueous solution of 30-33 parts, 11-15 parts
Stearic acid, 5-9 part pentachlorophenol, 7-9 parts of waterglass, 1-2 parts of thiocarbamides, 3-6 parts of ethyl acetate, 1-2 parts of casein, 11-14 parts
Polyvinyl alcohol, 6-8 part sodium phosphate.
Further technology：Constituent content is respectively needed for the strengthening layer preparation：10 parts of alum, 5 parts of adjacent benzene two
Formic acid dioctyl ester, 80 parts of starch, 7 parts of sodium hydroxides, 23 parts of cumyl peroxides, 40 part of 95% ethyl alcohol, 4 parts it is silane coupled
Agent, 14 parts of polypropylene, 60 parts of cotton linters, 30 part of 40% caustic-soda aqueous solution, 11 parts of stearic acid, 5 parts of pentachlorophenols, 7 parts of waterglass,
1 part of thiocarbamide, 3 parts of ethyl acetate, 1 part of casein, 11 parts of polyvinyl alcohol, 6 parts of sodium phosphates.
Further technology：Constituent content is respectively needed for the strengthening layer preparation：16 parts of alum, 6 parts of adjacent benzene two
Formic acid dioctyl ester, 90 parts of starch, 9 parts of sodium hydroxides, 25 parts of cumyl peroxides, 46 part of 95% ethyl alcohol, 6 parts it is silane coupled
Agent, 18 parts of polypropylene, 78 parts of cotton linters, 33 part of 40% caustic-soda aqueous solution, 15 parts of stearic acid, 9 parts of pentachlorophenols, 9 parts of waterglass,
2 parts of thiocarbamides, 6 parts of ethyl acetate, 2 parts of casein, 14 parts of polyvinyl alcohol, 8 parts of sodium phosphates.
Advantageous effect：One layer of primer first is smeared in handicraft surface, one layer of protective effect is played to handicraft surface, it is cooling
Afterwards, plastic, 70 DEG C of bakings, glue constantly melts, and while baking, then applies last layer strengthening layer, the primer for strengthening glue and thawing is first
Mixing is smeared.After cooling, strengthens, invigoration effect is played to handicraft surface, meanwhile, primer to handicraft surface to playing one
Layer protective film avoids reinforcing glue corrosion penetration from entering in craftwork, blocks each small pore of craftwork, avoid damaging by worms, water oozes, together
When can effectively with strengthen glue bond, after cooling, surface waxing enhances glossiness, and coating does not burn, high temperature resistance, promotes timber combustion
Point, and reduce combustion of wood performance.
This product is used for following various wood technology product：
Juglans mandshurica：Its timber is glossy, and texture is straight or oblique, and structure is slightly thick, slow drying speed, is not easy warpage, timber toughness
Well, easy processing, cutting face are smooth.Bending, paint, bonding property are good, and nail is puted forth effort strong；Smear rear surface more satin, enhancing
Toughness, face is smooth, reduces rate of drying, and in lower 1 minute of 420 DEG C of environment of experiment, surface wax is melted, and strengthening layer is without influence, 2 points
Clock -3 minutes, strengthening layer is melted, and timber deformation, after 4 minutes, timber is natural.
Yellow pineapple：Its timber is glossy, and texture is straight, and structure is thick, and annual ring is obviously uniform, and material is soft, easy drying, processability
Can be good, wood color decorative pattern is very beautiful, and paint and bonding property are good, and nail is puted forth effort medium, is not easy to cleave；Rotproofness is good, is high
Grade furniture, glued board material；Rear surface more satin is smeared, moisture is lockked, rate of drying is reduced, tests 420 DEG C of environment lower 1 minute
Interior, surface wax is melted, and strengthening layer is without influence, and -3 minutes 2 minutes, strengthening layer was melted, timber deformation, and after 4 minutes, timber is certainly
So.
Toothed oak wood：Its specific gravity of wood is big, and quality is hard, contraction is big, intensity is high.Compact structure is not easy sawing, cutting face light
Sliding, easy to crack, buckling deformation is not easy drying.It is moisture-proof, wear-resistant, it is not easy to be glued, tinctorial property is good.Decoration wood floor at present
It is more with obtaining.Rear surface more satin is smeared, rate of drying is reduced, is tested in lower 1 minute of 420 DEG C of environment, surface wax is melted, and is strengthened
Layer is without influence, and -2 minutes 1 minute, strengthening layer was melted, and timber deformation, after 3 minutes, timber is natural.
China fir：Its material is light and soft, easily dry, shrinks small, does not warp and fracture, and endurance quality is good, easy processing, and section is relatively thick, intensity
In strong, easily splitting, bonding property is good, is southern each province's furniture, finishing with obtaining middle-grade timber the most universal.Smear rear surface more
Satin, case hardness are promoted to 104.8Mpa from 72.9.Rate of drying is reduced, is tested in lower 1 minute of 420 DEG C of environment, surface wax
Melt, strengthening layer is without influence, and -2 minutes 1 minute, strengthening layer was melted, and timber deformation, after 4 minutes, timber is natural.
Specific implementation mode：
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1：A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time, is first smeared in handicraft surface
One layer of primer, after cooling, 70 DEG C of bakings make its thawing, while baking, then apply last layer strengthening layer, cold after the completion of smearing
But, it waxes.
Further technology：The bottom preparation method is：
A reaction kettle for carrying blender is selected, then vegetable oil is added into reaction kettle and opens stirring；
Butadiene rubber is taken, A jellies are mixed to get with crosslinking agent, catalyst, tackifier and polypropylene；
Gelatin, rubber softener, octamethylcyclotetrasilazane are mixed 1 hour, temperature is 60 DEG C, is then heated to
70 DEG C, anti-aging agent is added, then be warming up to 80 DEG C, stirs 1 hour, obtain B jellies；
A is mixed with B jellies, vulcanizes 3-5 days in 20 DEG C of air, is subsequently placed in reaction kettle, 75-80 DEG C of reaction, 3
Hour；
Wait for above-mentioned steps after reaction, reaction kettle is cooled to 20-25 DEG C, by pentaerythrite, methanol and the second in raw material
Glycol is added thereto, and is stood 5-10 hours after stirring evenly, is obtained auxiliary material one；
E-42 epoxy resin and diethylenetriamine are mixed；
Mixed solvent and ethyl cyanoacetate are added in bottle, stirred；
It is heated to 81-86 DEG C, monochloroacetic acid is added, continues stirring 1 hour；
30 will be pressed in the environment of -60 DEG C to 60 DEG C of intermixture and ethylenediamine:1 ratio is mixed, and is stirred；
Room temperature is cooled to again, obtains auxiliary material two；
Auxiliary material one is mixed with microwax, takes moment adhesive that mixing is added, and is heated to 60 DEG C, heats duration 10 minutes, so
Postcooling is placed in 60% auxiliary material two, cooling, obtains primer.
Further technology：Constituent content is respectively needed for the primer preparation：50 parts of vegetable oil, 6 parts of suitable fourth rubbers
Glue, 3 parts of crosslinking agents, 3 parts of catalyst, 3 parts of tackifier, 6 parts of polypropylene, 26 parts of gelatin, 12 parts of rubber softener, 5 parts of prestoxs
Cyclotetrasilazane, 1 part of anti-aging agent, 6 parts of pentaerythrites, 5 parts of methanol, 9 parts of ethylene glycol, 15 parts of E-42 epoxy resin, 4 parts of divinyls
Triamine, 14 parts of ethyl cyanoacetates, 10 parts of monochloroacetic acids, 5 parts of ethylenediamines, 23 parts of microwaxes, 10 parts of moment adhesives.
Further technology：The preparation method of the strengthening layer includes：
The dehydration alum weighed is put into drying oven, drying furnace temperature is risen to 120-150 DEG C, room temperature is down to after drying
Discharging, pulverizes and sieves, is mixed with dioctyl phthalate, gained mixture is named as component A；
By starch and water, proportion 1:13, it is added in flask；Stirring, is added sodium hydroxide, and heating four-hole boiling flask is warming up to
It 90-95 DEG C, reacts 40-50 minutes；Oxidation diisopropylbenzene (DIPB) is added and water is kept stirring 20 minutes；It is cooled to 50-60 DEG C, oxidation two
Isopropylbenzene and water proportion are 1:1, insulation reaction 30-40 minutes；It with cold water mix, stirs evenly, gained liquid is named as component
B；
95% second alcohol and water is 1 by volume:4-1:8 are made into alcohol solution silane coupling agent are added, by polypropylene with
10 times of water mixing, mixed solution are placed in 200W-300W ultrasonic waves, are stirred lower heating hydrolysis 30min-1.5h and are made 80
DEG C~90 DEG C of transparent acidification hydrating solutions, name component C；
Cotton linter is added in chrysanthemum water under stiring, after stirring into serum, 40% caustic-soda aqueous solution, stearic acid is added,
Rapid stirring；Pentachlorophenol, waterglass, thiocarbamide, ethyl acetate, heating stirring are sequentially added, heating temperature is 190 DEG C, duration
10 minutes；70 DEG C are cooled to, casein is instilled, naturally cools to room temperature, filter to take liquid, obtain component D；
Component A, B, C and D are merged, polyvinyl alcohol, sodium phosphate are added, mixes, stirs evenly,.
Further technology：Constituent content is respectively needed for the strengthening layer preparation：10 parts of alum, 5 parts of adjacent benzene two
Formic acid dioctyl ester, 80 parts of starch, 7 parts of sodium hydroxides, 23 parts of cumyl peroxides, 40 part of 95% ethyl alcohol, 4 parts it is silane coupled
Agent, 14 parts of polypropylene, 60 parts of cotton linters, 30 part of 40% caustic-soda aqueous solution, 11 parts of stearic acid, 5 parts of pentachlorophenols, 7 parts of waterglass,
1 part of thiocarbamide, 3 parts of ethyl acetate, 1 part of casein, 11 parts of polyvinyl alcohol, 6 parts of sodium phosphates.
Embodiment 2：A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time, is first smeared in handicraft surface
One layer of primer, after cooling, 70 DEG C of bakings make its thawing, while baking, then apply last layer strengthening layer, cold after the completion of smearing
But, it waxes.
Further technology：The bottom preparation method is：
A reaction kettle for carrying blender is selected, then vegetable oil is added into reaction kettle and opens stirring；
Butadiene rubber is taken, A jellies are mixed to get with crosslinking agent, catalyst, tackifier and polypropylene；
Gelatin, rubber softener, octamethylcyclotetrasilazane are mixed 1 hour, temperature is 60 DEG C, is then heated to
70 DEG C, anti-aging agent is added, then be warming up to 80 DEG C, stirs 1 hour, obtain B jellies；
A is mixed with B jellies, vulcanizes 3-5 days in 20 DEG C of air, is subsequently placed in reaction kettle, 75-80 DEG C of reaction, 3
Hour；
Wait for above-mentioned steps after reaction, reaction kettle is cooled to 20-25 DEG C, by pentaerythrite, methanol and the second in raw material
Glycol is added thereto, and is stood 5-10 hours after stirring evenly, is obtained auxiliary material one；
E-42 epoxy resin and diethylenetriamine are mixed；
Mixed solvent and ethyl cyanoacetate are added in bottle, stirred；
It is heated to 81-86 DEG C, monochloroacetic acid is added, continues stirring 1 hour；
30 will be pressed in the environment of -60 DEG C to 60 DEG C of intermixture and ethylenediamine:1 ratio is mixed, and is stirred；
Room temperature is cooled to again, obtains auxiliary material two；
Auxiliary material one is mixed with microwax, takes moment adhesive that mixing is added, and is heated to 60 DEG C, heats duration 10 minutes, so
Postcooling is placed in 60% auxiliary material two, cooling, obtains primer.
Further technology：Constituent content is respectively needed for the primer preparation：53 parts of vegetable oil, 7 parts of suitable fourth rubbers
Glue, 5 parts of crosslinking agents, 5 parts of catalyst, 5 parts of tackifier, 9 parts of polypropylene, 29 parts of gelatin, 13 parts of rubber softener, 11 parts of prestoxs
Cyclotetrasilazane, 2 parts of anti-aging agents, 9 parts of pentaerythrites, 7 parts of methanol, 12 parts of ethylene glycol, 26 parts of E-42 epoxy resin, 7 parts of diethyls
Alkene triamine, 17 parts of ethyl cyanoacetates, 13 parts of monochloroacetic acids, 8 parts of ethylenediamines, 25 parts of microwaxes, 16 parts of moment adhesives.
Further technology：The preparation method of the strengthening layer includes：
The dehydration alum weighed is put into drying oven, drying furnace temperature is risen to 120-150 DEG C, room temperature is down to after drying
Discharging, pulverizes and sieves, is mixed with dioctyl phthalate, gained mixture is named as component A；
By starch and water, proportion 1:13, it is added in flask；Stirring, is added sodium hydroxide, and heating four-hole boiling flask is warming up to
It 90-95 DEG C, reacts 40-50 minutes；Oxidation diisopropylbenzene (DIPB) is added and water is kept stirring 20 minutes；It is cooled to 50-60 DEG C, oxidation two
Isopropylbenzene and water proportion are 1:1, insulation reaction 30-40 minutes；It with cold water mix, stirs evenly, gained liquid is named as component
B；
95% second alcohol and water is 1 by volume:4-1:8 are made into alcohol solution silane coupling agent are added, by polypropylene with
10 times of water mixing, mixed solution are placed in 200W-300W ultrasonic waves, are stirred lower heating hydrolysis 30min-1.5h and are made 80
DEG C~90 DEG C of transparent acidification hydrating solutions, name component C；
Cotton linter is added in chrysanthemum water under stiring, after stirring into serum, 40% caustic-soda aqueous solution, stearic acid is added,
Rapid stirring；Pentachlorophenol, waterglass, thiocarbamide, ethyl acetate, heating stirring are sequentially added, heating temperature is 190 DEG C, duration
10 minutes；70 DEG C are cooled to, casein is instilled, naturally cools to room temperature, filter to take liquid, obtain component D；
Component A, B, C and D are merged, polyvinyl alcohol, sodium phosphate are added, mixes, stirs evenly,.
Further technology：Constituent content is respectively needed for the strengthening layer preparation：16 parts of alum, 6 parts of adjacent benzene two
Formic acid dioctyl ester, 90 parts of starch, 9 parts of sodium hydroxides, 25 parts of cumyl peroxides, 46 part of 95% ethyl alcohol, 6 parts it is silane coupled
Agent, 18 parts of polypropylene, 78 parts of cotton linters, 33 part of 40% caustic-soda aqueous solution, 15 parts of stearic acid, 9 parts of pentachlorophenols, 9 parts of waterglass,
2 parts of thiocarbamides, 6 parts of ethyl acetate, 2 parts of casein, 14 parts of polyvinyl alcohol, 8 parts of sodium phosphates.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (1)
1. a kind of wood furniture surface high-temp toasts fire-retardant method of lower short time, it is characterised in that：First applied in handicraft surface
Smear one layer of primer, after cooling, 70 DEG C of bakings make its thawing, while baking, then apply last layer strengthening layer, cold after the completion of smearing
But, it waxes；
Bottom preparation method is：
A reaction kettle for carrying blender is selected, then vegetable oil is added into reaction kettle and opens stirring；
Butadiene rubber is taken, A jellies are mixed to get with crosslinking agent, catalyst, tackifier and polypropylene；
Gelatin, rubber softener, octamethylcyclotetrasilazane are mixed 1 hour, temperature is 60 DEG C, then heats to 70
DEG C, anti-aging agent is added, then be warming up to 80 DEG C, stirs 1 hour, obtain B jellies；
A is mixed with B jellies, vulcanizes 3-5 days in 20 DEG C of air, is subsequently placed in reaction kettle, 75-80 DEG C of reaction, 3 is small
When；
After waiting for step reaction, reaction kettle is cooled to 20-25 DEG C, and pentaerythrite, methanol and the ethylene glycol in raw material are added
Wherein, 5-10 hours are stood after stirring evenly, obtains auxiliary material one；
E-42 epoxy resin and diethylenetriamine are mixed；
Mixed solvent and ethyl cyanoacetate are added in bottle, stirred；
It is heated to 81-86 DEG C, monochloroacetic acid is added, continues stirring 1 hour；
30 will be pressed in the environment of -60 DEG C to 60 DEG C of intermixture and ethylenediamine:1 ratio is mixed, and is stirred；
Room temperature is cooled to again, obtains auxiliary material two；
Auxiliary material one is mixed with microwax, takes moment adhesive that mixing is added, and is heated to 60 DEG C, heating duration 10 minutes is then cold
But it is placed in 60% auxiliary material two, it is cooling, obtain primer；
Constituent content is respectively needed for primer preparation：50 parts of vegetable oil, 6 parts of butadiene rubbers, 3 parts of crosslinking agents, 3 parts of catalysis
Agent, 3 parts of tackifier, 6 parts of polypropylene, 26 parts of gelatin, 12 parts of rubber softener, 5 parts of octamethylcyclotetrasilazanes, 1 part of anti-aging agent,
6 parts of pentaerythrites, 5 parts of methanol, 9 parts of ethylene glycol, 15 parts of E-42 epoxy resin, 4 parts of diethylenetriamines, 14 parts of ethyl cyanoacetates,
10 parts of monochloroacetic acids, 5 parts of ethylenediamines, 23 parts of microwaxes, 10 parts of moment adhesives；
The preparation method of strengthening layer includes：
The dehydration alum weighed is put into drying oven, drying furnace temperature is risen to 120-150 DEG C, being down to room temperature after drying goes out
Material, pulverizes and sieves, is mixed with dioctyl phthalate, gained mixture is named as component A；
By starch and water, proportion 1:13, it is added in flask；Stirring, is added sodium hydroxide, and heating four-hole boiling flask is warming up to 90-
It 95 DEG C, reacts 40-50 minutes；Oxidation diisopropylbenzene (DIPB) is added and water is kept stirring 20 minutes；It is cooled to 50-60 DEG C, oxidation two is different
Propyl benzene and water proportion are 1:1, insulation reaction 30-40 minutes；It with cold water mix, stirs evenly, gained liquid is named as component B；
95% second alcohol and water is 1 by volume:4-1:8 are made into alcohol solution silane coupling agent are added, by polypropylene and 10 times
Water mixing, mixed solution is placed in 200W-300W ultrasonic waves, stir lower heating hydrolysis 30min-1.5h be made 80 DEG C~
90 DEG C of transparent acidification hydrating solutions, name component C；
Cotton linter is added in chrysanthemum water under stiring, after stirring into serum, 40% caustic-soda aqueous solution, stearic acid is added, rapidly
Stirring；Pentachlorophenol, waterglass, thiocarbamide, ethyl acetate, heating stirring are sequentially added, heating temperature is 190 DEG C, and duration 10 divides
Clock；70 DEG C are cooled to, casein is instilled, naturally cools to room temperature, filter to take liquid, obtain component D；
Component A, B, C and D are merged, polyvinyl alcohol, sodium phosphate are added, mixes, stirs evenly,；
Constituent content is respectively needed for strengthening layer preparation：10 parts of alum, 5 parts of dioctyl phthalates, 80 parts of starch, 7
Part sodium hydroxide, 23 parts of cumyl peroxides, 40 part of 95% ethyl alcohol, 4 parts of silane coupling agents, 14 parts of polypropylene, 60 portions of cottons are short
Suede, 30 part of 40% caustic-soda aqueous solution, 11 parts of stearic acid, 5 parts of pentachlorophenols, 7 parts of waterglass, 1 part of thiocarbamide, 3 parts of ethyl acetate, 1
Part casein, 11 parts of polyvinyl alcohol, 6 parts of sodium phosphates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710297785.7A CN107139287B (en) | 2017-04-29 | 2017-04-29 | A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710297785.7A CN107139287B (en) | 2017-04-29 | 2017-04-29 | A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107139287A CN107139287A (en) | 2017-09-08 |
| CN107139287B true CN107139287B (en) | 2018-10-02 |
Family
ID=59774929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710297785.7A Active CN107139287B (en) | 2017-04-29 | 2017-04-29 | A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107139287B (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040105938A1 (en) * | 2002-11-29 | 2004-06-03 | Universidad De Conception | Accelerated petrifaction process for lignocellulose materials |
| CN101326249A (en) * | 2005-11-08 | 2008-12-17 | 拉克西米·C·古普塔 | Methods for applying fire retardant systems, compositions and uses |
| CN102953535B (en) * | 2012-10-26 | 2015-06-03 | 浙江未来家木业有限公司 | Glazed floor board processing technology |
| CN103331791A (en) * | 2013-07-12 | 2013-10-02 | 三棵树涂料股份有限公司 | Novel hard environment-friendly wood wax oil and preparation method thereof |
| CN103802182B (en) * | 2014-03-13 | 2015-11-18 | 魏根成 | Plywood single board strengthening composition for modifying and preparation method thereof |
| JP2016030768A (en) * | 2014-07-25 | 2016-03-07 | 西本 孝一 | Burning inhibitor, burning inhibition method of combustible material and combustible material containing burning inhibitor |
-
2017
- 2017-04-29 CN CN201710297785.7A patent/CN107139287B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107139287A (en) | 2017-09-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101831255B (en) | Method for preparing modified starch adhesive for timber | |
| CN103911033A (en) | Special environment-friendly paint prepared by using raw lacquer as biomass base for furniture and cabinets | |
| CN104277579B (en) | The low smell environmental printing of a kind of waterproof ink and preparation method thereof | |
| WO2017066905A1 (en) | Fluorine-containing (meth)acrylate polymer and preparation method therefor | |
| CN106753229A (en) | A kind of lacquer wood raw lacquer colored drawing return repairs adhesive | |
| CN107139287B (en) | A kind of wood furniture surface high-temp toasts fire-retardant method of lower short time | |
| CN102161868A (en) | Water-based treatment agent for vulcanized shoes and preparation method thereof | |
| CN104312265B (en) | Molten color inhibition plastic printing ink of a kind of environment-friendly type alcohol and preparation method thereof | |
| CN107096701A (en) | Strengthen the method for the wooden articles for use surface acid resistance corrosion of furniture | |
| CN106867430A (en) | A kind of high-strength integrated timber makeup glue | |
| CN103849312A (en) | Shellac for increasing heat resistance of varnish, and modification method thereof | |
| CN105199285A (en) | Toughened cyanoacrylate composition | |
| CN113787790B (en) | Energy-saving decorative plate and preparation method thereof | |
| CN107083189A (en) | It is a kind of to strengthen the method for the anti-outdoor high temperature deformation of wood furniture | |
| CN107163843A (en) | It is a kind of to strengthen the method for the natural cracking resistance of Wood craft | |
| CN107142042A (en) | Furniture paint reinforcing quick-drying primer and preparation method thereof | |
| CN105085858B (en) | A kind of preparation method of bio-modification high temperature resistant polyurethane glue | |
| CN107033782A (en) | A kind of wood product surface does old rear corrosion resistant clear coat and preparation method thereof | |
| CN110105874A (en) | A kind of violin oil paint and its methods for making and using same | |
| CN111057424A (en) | Preparation method of high-adhesion wiping-resistant leather finishing agent | |
| CN106010270A (en) | Method for preparing rosin pentaerythritol ester for hot melt adhesive rod | |
| CN101328511A (en) | Carzy horse polished brushed resin for processing leather surface and preparing method thereof | |
| CN107722924B (en) | A kind of glucose-lignin resin crosslinking agent and its preparation method and application | |
| CN107129724A (en) | A kind of woodwork underwater paint quick-drying anti-dropout powder and preparation method thereof | |
| CN107418470A (en) | Furniture paint strengthens anti-dropout primer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |