CN104649610B - A kind of ceramic tile bond and application thereof - Google Patents
A kind of ceramic tile bond and application thereof Download PDFInfo
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- CN104649610B CN104649610B CN201410850942.9A CN201410850942A CN104649610B CN 104649610 B CN104649610 B CN 104649610B CN 201410850942 A CN201410850942 A CN 201410850942A CN 104649610 B CN104649610 B CN 104649610B
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Abstract
The invention discloses a kind of ceramic tile bond, consisting of of this binding agent: aqueous polymer resin 15% 30%, filler 65% 85%, photocatalysis catalyzer contact agent 10% 20%, thickening agent 0.2% 0.4%, hydrophober 0.2% 0.3%, defoamer 0.2% 0.3%, preservative 0.4% 0.6%, wetting dispersing agent 0.1% 0.3%, thixotropic agent 0.2% 0.5%, stable storage agent 0.5% 1.0%, brightener 1.0% 1.5% mill base 0 5%, remaining is water；Above-mentioned percentage ratio is mass percent.This binding agent solves because of the too high accumulation of salt in the surface soil problem of basicity, it is to avoid binding agent neutral and alkali composition is to glass material ceramic tile corrosion such as mosaics；Make the compactness of binding agent, glossiness increase simultaneously, possess stain resistant ability；Selected raw material is nontoxic, belongs to environmentally friendly machine, possesses great promotional value.
Description
Technical field
The invention belongs to building chemical field of material technology, be specifically related to a kind of ceramic tile bond, should
Material binding agent possesses neutrality, water-fast easy wiping, environment friendly and pollution-free feature.
Background technology
Along with the development of ceramics, ceramic tile is increasingly looked at by consumer parent as building and ornament materials.
Meanwhile, use more and more extensive as ornamental splendid high-grade mosaic.When ceramic tile or Marseille
Gram when interior decoration, it is required to use the surface realization of binding agent and architecture noumenon to fit tightly.
To this end, binding agent is in addition to requiring to have good adhesion strength, also require binding agent and ceramic tile or
Mosaic has good matching, and namely the composition of binding agent constitutes and can not produce tile material
Impact；Complete the gap between adjacent tiles to be entered after ceramic tile pastes further, since typically require
Row is repaired, and belongs to outer surface exposed layer at the gap filler filling the use of ceramic tile gap, is easily subject to the external world
The pollution of environment and erosion, thus cause the reduction of combination with decorative surfaces effect.Therefore, gap filler is generally wanted
Ask and possess stain resistance, the mildew resistance of excellence and be prone to scrubbing character.Traditional ceramic tile or mosaic
Binding agent and gap filler are mainly made up of cement base products or epoxy resin component.Cement based material
The basicity of binding agent and gap filler is higher, and accumulation of salt in the surface soil phenomenon easily occurs in long-time use, at ceramic tile surface
Or its gap produces color deposition, the aesthetic property of extreme influence decoration, it is often more important that work as combination with decorative surfaces
During for category of glass materials such as mosaics, mosaic surface will be produced by the highly basic composition in cement based adhesive
Raw serious corrosiveness so that it is lose decorative effect and even result in the generation of surface break-off；And
Although epoxy resin binding agent is not result in accumulation of salt in the surface soil phenomenon or category of glass is ostentatious comes off, but its
The processing step used and make is relatively complicated and material cost is higher, more seriously asphalt mixtures modified by epoxy resin
Lipid binding agent do not meets the requirement of environment-friendly materials containing toxic component, thus limits it in the market
Application.For being exposed to the gap filler of building surface, be necessarily required to after long-time use into
The cleaning of row pollutant, the gap filler of above two material is all difficulty with cleaning function；According to nothing
Machine gelling class material, such as the overbased material binding agent such as portland cement, aluminate cement, although have
It is beneficial to clean, but the reduction of ceramic tile cementation performance can be caused.And according to neutrality be gelled material, as
The gypsoide of different crystal forms is as binding agent or gap filler, owing to its resistance to water is very poor, it is easy to
Wet environment causes dissolve, destroy bond effect.So, a kind of resistance in the exploitation of building decoration field
Building material technology progress will be risen by aqueous scouring good, easy to clean, neutral binding agent and gap filler
To impetus.
Summary of the invention
For solving conventional cement base or epoxy resin ceramic tile bond and the defect of gap filler, the present invention grinds
Made one belongs to neutral, resistance to water good, anti-pollution ability strong, be prone to clean, anti-mildew and execute
Work simple process, surface effect environmental protection binding agent bright, non-dusting forms.Concrete technical scheme is:
A kind of ceramic tile bond, consisting of of this binding agent: aqueous polymer resin 15%-30%, filler
65%-85%, photocatalysis catalyzer contact agent 10%-20%, thickening agent 0.2%-0.4%, hydrophober
0.2%-0.3%, defoamer 0.2%-0.3%, preservative 0.4%-0.6%, wetting dispersing agent
0.1%-0.3%, thixotropic agent 0.2%-0.5%, stable storage agent 0.5%-1.0%, brightener
1.0%-1.5%, mill base 0-5%, remaining is water；Above-mentioned percentage ratio is mass percent.From viscous
The gelation of knot agent, environmental protection and practical application effect consider, aqueous polymer resin is emulsion-type tree
One in fat or solution resin, when selecting emulsion resin, selects acrylic emulsion, butylbenzene breast
In liquid, VAE emulsion, styrene-acrylic emulsion, tertiary acrylic emulsion, tertiary vinegar milk liquid, silicone acrylic emulsion a kind of or
Two kinds and above emulsion mixture, this material is in sides such as burst size of methanal, resistance to water and storage stabilities
There is higher performance in face.
The photocatalysis catalyzer contact agent used in above-mentioned formula is nano titanium oxide, and its reason is nano-silica
Change titanium and not only possess photocatalyst effect, and there is the effect of fungus and mildew resistance, the binding agent master of technical scheme
Apply in kitichen and toilet, easy breed bacteria and mouldy, therefore select suitable photocatalysis catalyst
Agent has vital effect to the realization of final effect.
In the selection of filler, for improving the compactness of surface effect, filler is ground calcium carbonate, light
One or both and thing mixed above in matter calcium carbonate, silica flour, Pulvis Talci, lithopone, and its
Particle size range is at 0-45 micron.
Described thickening agent be hydroxyethyl ether cellulose, alkali swelling type thickening agent, Acrylates thickening agent,
One or both and above mixture in polyurethanes thickening agent；Described hydrophober is that organosilicon is hated
One in water preparation, mineral oils hydrophober；Described thixotropic agent is in magnesium aluminum silicates, bentonite
A kind of；Described stable storage agent is pH adjusting agent, as sodium bicarbonate, sodium acetate or sodium phosphate have
PH adjusts function additive, or antioxidant, as aromatic amine, Hinered phenols, phosphorous acid esters resist
Oxidant；Described brightener is sulfonated melamine compound resin class brightener.
The ceramic tile bond of formula described in technical solution of the present invention can also be applied as gap filler.
In the binder formula that technical solution of the present invention is proposed, by selecting neutral enhanced water resistance resin solution
The accumulation of salt in the surface soil problem certainly brought because basicity is too high, it is achieved the neutralization of binding agent, it is to avoid the alkali in binding agent
Property composition to the corrosion of the glass material ceramic tile such as mosaic；Binding agent is increased by Fillers selection and Gradation Optimization
Compactness, improve adhesive surface glossiness so that it is possess higher stain resistant ability, hold very much
Easy cleaning, particularly overcomes the difficult shortcoming cleaned after tradition gap filler is stain；By other auxiliary agents and
Formulation optimization improves water-base resin resistance to water and easy scrubbing character.Utilize aqueous polymer resin flexibility higher,
Possesses the characteristic of superelevation elongation percentage, it is achieved that do not shrink and do not ftracture and the glass Mosaic class ceramic tile compatibility
Strong advantage；By adding preservative and antioxidant, arrive fungus-proof antisepsis effect, it is ensured that decoration
Permanence；The mill base splendid by selection dispersibility and wetting dispersing agent, make binding agent bright-colored
Uniformly, no color differnece, it is ensured that the aesthetic property of decoration；The selected cost of raw material is cheap, nontoxic,
Product packaging easy construction, without being again stirring for during use, reduces dust and noise pollution, belongs to ring
Guarantor's type product, possesses great promotional value.
Detailed description of the invention
For convenience of the understanding of technical solution of the present invention, now illustrate the concrete composition of this ceramic tile bond
Constitute and quality proportion relation.
Embodiment 1, selects styrene-butadiene emulsion 10 parts, styrene-acrylic emulsion 5 parts mixing composition waterborne polymeric tree
Fat, nano titanium oxide 10 parts is as photocatalysis catalyzer contact agent, nanometer grade calcium carbonate 30 parts, lightweight carbon
Acid calcium 30 parts, ultrafine quartz powder 10 parts mixing composition particle diameter is 15 microns of fillers；Acrylic thickener
0.3 part, organosilicon moisture repellent 0.2 part, mineral oil antifoam agent 0.3 part, preservative 0.5 part, acrylic acid
Salt wetting dispersing agent 0.2 part, aluminium-magnesium silicate thixotropic agent 0.4 part, stable storage agent 1.0 parts, light
Add mill base 0.7 part again after agent 1.4 parts mixing input stirred tank stirs and carry out mix and blend
Make ceramic tile bond.Above-mentioned number is mass fraction.
Embodiment 2, selects pure-acrylic emulsion 20 parts, nano titanium oxide 10 parts, utilizes lightweight carbonic acid
Calcium 25 parts, 20 parts of heavy carbonic acid, calcium Pulvis Talci 20 parts mixing composition particle diameter is 35 microns of fillers,
HEC0.3 part, organosilicon moisture repellent 0.3 part, organic silicon defoamer 0.2 part, sterilization antiseptic 0.5
Part, Acrylates wetting dispersing agent 0.2 part, organobentonite 0.3 part, stable storage agent 0.8
Part, brightener 1.2 parts, the material mixing of above-mentioned mass fraction puts in stirred tank and stirs
After add 1.2 parts of stirrings of mill base again and make ceramic tile bond.
Each composition in embodiment 1,2 can be replaced according to above narration.To embodiment 1,2
The binding agent constituted is according to " ceramic wall and floor bricks adhesive " (JG/T 547-2005), " ceramic wall and floor bricks
Gap filler " JC/T 1004-2007, " exterior wall coating material of synthetic resin emulsion " GB/T 9755-2001 with
And " wall facing mortar " JC/T 1024-2007 checks properties of product.Effect and parameter such as following table:
According to result of the test it can be seen that contrast with traditional ceramic tile bond or gap filler, this bonding
Agent can not only reach preferable adhesion strength, higher resistance to water, relatively low water absorption rate, and has
Stop the accumulation of salt in the surface soil, surface gloss high；Also there is superelevation elongation percentage, do not shrink, do not ftracture energy
Excellent compatibility is kept with ceramic tile；And this binding agent possesses high-wearing feature, splendid abrasion resistance,
Ensure bonding and the permanence of joint filling decoration.
The description of technique scheme only embodies the preferred technical solution of the present invention, based on the present invention
Embodiment, the technology of anyone other forms obtained on the premise of not making creative work
Scheme, and though its structure or done in form which kind of change, belong to protection scope of the present invention
Within.
Claims (6)
1. a ceramic tile bond, it is characterised in that consisting of of this binding agent: aqueous polymer resin 15%-30%, filler 65%-75%, nano titanium oxide 10%-20%, thickening agent 0.2%-0.4%, hydrophober 0.2%-0.3%, defoamer 0.2%-0.3%, preservative 0.4%-0.6%, wetting dispersing agent 0.1%-0.3%, thixotropic agent 0.2%-0.5%, stable storage agent 0.5%-1.0%, brightener 1.0%-1.5%, mill base 0-5%, remaining is water；Above-mentioned percentage ratio is mass percent；Wherein, described stable storage agent is pH adjusting agent or antioxidant.
Ceramic tile bond the most according to claim 1, it is characterized in that, aqueous polymer resin is the one in emulsion resin or solution resin, when selecting emulsion resin, select one or two kinds of and above emulsion mixture in acrylic emulsion, styrene-butadiene emulsion, VAE emulsion, styrene-acrylic emulsion, tertiary acrylic emulsion, tertiary vinegar milk liquid, silicone acrylic emulsion.
3. according to claim
1
Described
Ceramic tile bond, it is characterised in that filler is one or both and thing mixed above in ground calcium carbonate, precipitated calcium carbonate, silica flour, Pulvis Talci, lithopone, and its particle size range is at 0-45 micron.
4. according to claim
1
Described
Ceramic tile bond, it is characterised in that thickening agent is one or both and above mixture in hydroxyethyl ether cellulose, alkali swelling type thickening agent, Acrylates thickening agent, polyurethanes thickening agent；Described hydrophober is the one in organosilicon moisture repellent, mineral oils hydrophober；Described thixotropic agent is the one in magnesium aluminum silicates, bentonite；Described brightener is sulfonated melamine compound resin class brightener.
5. according to claim
1
Described
Ceramic tile bond, it is characterised in that being to have pH to adjust the auxiliary agent of function as the pH adjusting agent of stable storage agent, the described pH adjusting agent as stable storage agent is sodium bicarbonate, sodium acetate or sodium phosphate；Antioxidant is aromatic amine, Hinered phenols or phosphite antioxidant.
6. basis
Claim
1-5
Ceramic tile bond described in any one, it is characterised in that this ceramic tile bond is as the application of gap filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410850942.9A CN104649610B (en) | 2014-12-31 | 2014-12-31 | A kind of ceramic tile bond and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410850942.9A CN104649610B (en) | 2014-12-31 | 2014-12-31 | A kind of ceramic tile bond and application thereof |
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| Publication Number | Publication Date |
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| CN104649610A CN104649610A (en) | 2015-05-27 |
| CN104649610B true CN104649610B (en) | 2016-08-31 |
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| CN201410850942.9A Active CN104649610B (en) | 2014-12-31 | 2014-12-31 | A kind of ceramic tile bond and application thereof |
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| CN105174812A (en) * | 2015-09-19 | 2015-12-23 | 孙军 | Environment-friendly wall surface joint mixture and preparing method and using method thereof |
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| CN105254219A (en) * | 2015-09-19 | 2016-01-20 | 孙军 | Gap filler for polished tiles, and preparation method and use method thereof |
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| CN103214212B (en) * | 2013-04-17 | 2015-04-29 | 北京东方雨虹防水技术股份有限公司 | Paste tile adhesive and use thereof |
| CN104211357B (en) * | 2014-08-26 | 2016-04-06 | 德清扬泰建筑材料有限公司 | A kind of low alkalinity tile adhesives of improvement |
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Denomination of invention: Tile binder and application thereof Effective date of registration: 20161024 Granted publication date: 20160831 Pledgee: Beijing technology business factoring Ltd. Pledgor: Beijing Tianwei Baochen Chemical Product Co., Ltd. Registration number: 2016990000896 |
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