CN102533028A - Water-based, primer-free and high-performance exterior water coating - Google Patents
Water-based, primer-free and high-performance exterior water coating Download PDFInfo
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- CN102533028A CN102533028A CN2011104615942A CN201110461594A CN102533028A CN 102533028 A CN102533028 A CN 102533028A CN 2011104615942 A CN2011104615942 A CN 2011104615942A CN 201110461594 A CN201110461594 A CN 201110461594A CN 102533028 A CN102533028 A CN 102533028A
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Abstract
The invention discloses a water-based, primer-free and high-performance exterior water coating, which comprises the following components: nano silica sol, protective gel, acrylic acid emulsion, pigments, fillers, a pH modifier, a defoamer, a wetting agent, a dispersing agent, propylene glycol, a preservative agent, a film-forming additive, a leveling agent, a thickener, hydroxyethyl cellulose and a water softener. The invention has the following advantages that: the coating can be stored stably, no primer needs to be coated, and saltpetering and floating can be avoided; the coating has the toughness of an organic coating and the hardness of an inorganic coating, and the hardness of the coating is moderate; the coating has excellent acid resistance, alkali resistance, stain resistance, weather resistance and adhesion; and the water absorption of the substrate can be balanced, and the color retention performance of colored paint can be adopted to the largest extent.
Description
Technical field
This patent relates to Nano silica sol and ACRYLIC EMULSION Application of composite in exterior coating, processes the high performance outer wall paint that a kind of water-based is exempted to prime.
Background technology
Along with the fast development of construction industry, Highrise buildings is more and more, and the modern architecture exterior coating is had higher requirement.Most provinces and cities external wall has limited the use face brick at present, and it is good ornamental that this just requires the exterior wall coating material not only will have, and also should possess excellent resistance to weathering, contamination resistance, guarantor's light tint retention and anti-growing dim property.The external wall of building base material is mainly sand-cement slurry, concrete, and its basal plane decorative material is mainly cement based putty, and the equal alkalescence of this type of material is very strong.Therefore, must seal with alkali resistant priming paint after coating finish again.Yet there is following problem in this scheme: poor, the anti-contamination of (1) acid-fast alkali-proof is poor, weathering resistance is poor; (2) alkali resistant priming paint certainly exists pore because of containing color stuffing, passes in time, and the calcium ions and magnesium ions in the body of wall can ooze out through pore, causes the accumulation of salt in the surface soil to grow dim; (3) seal coat does not have opacifying power, and holiday causes the accumulation of salt in the surface soil to grow dim easily; (4) priming paint finish paint matching operation, the cycle is long, and the recruitment cost is high, and benefit is low.The problems referred to above have restricted common exterior coating promoting the use of on Highrise buildings, are difficult to meet the need of market.
To Nano silica sol-vinylformic acid compound be coating research for a long time, have very high using value.Number of patent application 200810010114.9 usefulness modified silicasols prepare water-borne coatings needs configuration finishing paint separately, is not the coating of our the high-efficient simple construction pursued.
Summary of the invention
The present invention makes a kind of Nano silica sol-ACRYLIC EMULSION composite exterior wall coating; The Nano silica sol uniform particles is distributed between the ACRYLIC EMULSION particle; Because the silicon oxide when analysing glue is active high; Nanoparticle is strong to the seepage force of base material, and tiny particle can be penetrated into the inside of base material through capillary action, and can with the alkaline matter Ca (OH) in the base material
2Reaction generates Calucium Silicate powder, and the synthesis result through mechanical snap and chemically bonded makes to film has stronger sticking power, and eliminates alkaline from root.After the film forming; Organic polymer is evenly distributed in the gap of silicon-oxygen-silicon inorganic coating, and remaining hydrophilic radical in the shielded inorganic coating makes and films when standing to cold and heat succeed each other; The contraction of coating obtains buffering; And making coating have certain elasticity, formed coating has the characteristic of inorganic paint and organic coating concurrently, remedies both deficiencies.
The present invention realizes that the technical scheme that above-mentioned performance is taked is:
It is film forming matter that this coating adopts Nano silica sol and ACRYLIC EMULSION, mainly comprises the component of following parts by weight:
In the above-mentioned water-borne coatings component Nano silica sol be in Shenzhen's Jiization chemical industry KH-Nano silica sol and the chemical industry CH83-120 of the Jiangsu League of Nations Nano silica sol any one;
In the above-mentioned water-borne coatings component protection glue be Henkel Dispersant 05 with Henkel Colorsperse 188A in any one;
In the above-mentioned water-borne coatings component ACRYLIC EMULSION be among DOW Chemical AC-808A and the BASF Acronal PA-237 any one;
Pigment is U.S. sharp to join in RCL-595 white titanium pigment and the R-706 of the Du Pont white titanium pigment any one in the above-mentioned water-borne coatings component;
Filler is talcum powder by weight ratio in the above-mentioned water-borne coatings component: kaolin: coarse whiting: wollastonite powder=1: 0.5: 2: 0.1-0.5;
Mierocrystalline cellulose is that any one is striden among the imperial 250HHBR in DOW Chemical QP-100MH and Asia in the above-mentioned water-borne coatings component;
In the above-mentioned water-borne coatings component skimmer be among Sheng Nuopuke NXZ and the B-943 of Ai Di section any one;
In the above-mentioned water-borne coatings component wetting agent be among DOW Chemical X-405 and the peaceful PE100 of section any one;
In the above-mentioned water-borne coatings component dispersion agent be Sheng Nuopuke Dispersant 5040 with golden source chemistry TCP-8045 in any one;
In the above-mentioned water-borne coatings component acid-base modifier be among the chemistry TCP-95 of DOW Chemical AMP-95 and golden source any one;
In the above-mentioned water-borne coatings component sanitas be among Shu Mei A26 and the Huffman D29 any one;
Thickening material is at least a among Sheng Nuopuke SN-636 and the Sheng Nuopuke SN-612NC in the above-mentioned water-borne coatings component.
In the above-mentioned water-borne coatings component flow agent be the peaceful DSX-2000 of section with the high chemical industry LS-200 of dimension in any one;
Film coalescence aid is Yi Shiman Texanol in the above-mentioned water-borne coatings component;
The preparation method that a kind of water-based of the present invention is exempted from the priming paint high performance outer wall paint comprises the steps:
1, the preparation of modified Nano silicon sol:
In 8-13 part Nano silica sol, add protection glue 0.5-1 part, 1000～1200 rev/mins, middling speed disperses 5-10min for use.
2, the preparation of coating:
A adds the soft water of formula ratio and the Mierocrystalline cellulose of formula ratio successively, and 1000～1200 rev/mins, middling speed disperses 10～15min transparent to dissolving fully.
The skimmer of the wetting agent of b input formula ratio, dispersion agent, acid-base modifier, Ucar 35,1/2 formula ratio, 1000～1200 rev/mins, middling speed is disperseed 5～10min.
C drops into formula ratio modified Nano silicon sol, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.
D drops into the pigment of formula ratio and the filler of formula ratio, and 2000～2300 rev/mins, high speed dispersion 15～20min is to fineness≤40 μ M.
E drops into the film coalescence aid of formula ratio, drops into the ACRYLIC EMULSION of formula ratio again, and 800～1000 rev/mins, middling speed is disperseed 5～10min.
The f paint: drop into the skimmer of residue 1/2 formula ratio, the sanitas of formula ratio, the flow agent of formula ratio and the thickening material of formula ratio, 500～600 rev/mins, 5～10min, the low speed mixing gets product.
High performance outer wall paint of exempting to prime of the present invention has following characteristics:
(1) snappiness that has organic coating concurrently and the hardness that inorganic paint is arranged, it is neither too hard, nor too soft to film;
(2) acidproof, alkaline-resisting, anti-contamination, weathering resistance are all very outstanding;
(3) superpower sticking power.On this coating application behind the wall with cement wall surface surface attachment not only, also form coordination reaction, basic unit is produced infiltration, very firmly;
(4) water-absorbent that can balanced base material can be brought into play the tint retention of colored paint to greatest extent.
(5) shelf-stable exempts to prime, and the Nano silica sol particle is strong to the seepage force of base material, and tiny particle can be penetrated into the inside of base material through capillary action, and can with the alkaline matter Ca (OH) in the base material
2Reaction generates Calucium Silicate powder, and making films has stronger sticking power, and eliminates alkalescence from root.
Embodiment
Through embodiment content of the present invention is done further explanation below, but the content that this part content does not limit the present invention in any way.
Embodiment 1 (weight part)
The preparation of 1 modified Nano silicon sol: in 9.3 parts of Nano silica sols, add 0.7 part in protection glue, 1000～1200 rev/mins, middling speed disperses 5-10min for use.
The preparation of 2 coating: a adds 21.7 parts of soft water and 0.1 part of Mierocrystalline cellulose successively, and 1000～1200 rev/mins, middling speed disperses 10～15min transparent to dissolving fully.B drops into 0.1 part of wetting agent, 0.6 part of dispersion agent, 0.1 part of acid-base modifier, 0.8 part of Ucar 35,0.15 part skimmer, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.C drops into 10 parts of modified Nano silicon sol, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.D drops into 17 parts of pigment and 30 parts of fillers, and 2000～2300 rev/mins, high speed dispersion 15～20min is to fineness≤40 μ M.E drops into 0.9 part of film coalescence aid, drops into 18 parts of ACRYLIC EMULSIONs again, and 800～1000 rev/mins, middling speed is disperseed 5～10min.The f paint: drop into 0.15 part of skimmer, 0.1 portion of sanitas, 0.1 part of flow agent, 0.2 part of thickening material, 500～600 rev/mins, 5～10min, the low speed mixing gets 100 parts of these coating.
Embodiment 2 (weight part)
The preparation of 1 modified Nano silicon sol: in 7.5 parts of Nano silica sols, add 0.5 part in protection glue, 1000～1200 rev/mins, middling speed disperses 5-10min for use.
The preparation of 2 coating: a adds 20.8 parts of soft water and 0.1 part of Mierocrystalline cellulose successively, and 1000～1200 rev/mins, middling speed disperses 10～15min transparent to dissolving fully.B drops into 0.1 part of wetting agent, 0.6 part of dispersion agent, 0.1 part of acid-base modifier, 0.7 part of Ucar 35,0.1 part of skimmer, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.C drops into 8 parts of modified Nano silicon sol, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.D drops into 15 parts of pigment and 32 parts of fillers, and 2000～2300 rev/mins, high speed dispersion 15～20min is to fineness≤40 μ M.E drops into 1 part of film coalescence aid, drops into 21 parts of ACRYLIC EMULSIONs again, and 800～1000 rev/mins, middling speed is disperseed 5～10min.The f paint: drop into 0.1 part of skimmer, 0.1 portion of sanitas, 0.1 part of flow agent, 0.2 part of thickening material, 500～600 rev/mins, 5～10min, the low speed mixing gets 100 parts of these coating.
Embodiment 3 (weight part)
The preparation of 1 modified Nano silicon sol: in 11.2 parts of Nano silica sols, add 0.8 part in protection glue, 1000～1200 rev/mins, middling speed disperses 5-10min for use.
The preparation of 2 coating: a adds 24.8 parts of soft water and 0.15 part of Mierocrystalline cellulose successively, and 1000～1200 rev/mins, middling speed disperses 10～15min transparent to dissolving fully.B drops into 0.1 part of wetting agent, 0.5 part of dispersion agent, 0.1 part of acid-base modifier, 0.7 part of Ucar 35,0.2 part of skimmer, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.C drops into 12 parts of modified Nano silicon sol, and 1000～1200 rev/mins, middling speed is disperseed 5～10min.D drops into 14 pigment and 30 parts of fillers, and 2000～2300 rev/mins, high speed dispersion 15～20min is to fineness≤40 μ M.E drops into 0.8 part of film coalescence aid, drops into 16 parts of ACRYLIC EMULSIONs again, and 800～1000 rev/mins, high speed dispersion 5～10min.The f paint: drop into 0.2 part of skimmer, 0.1 portion of sanitas, 0.1 part of flow agent, 0.25 part of thickening material, 500～600 rev/mins, 5～10min, the low speed mixing gets 100 parts of these coating.
Main raw material(s) title, technical indicator:
1.KH-Nano silica sol
Main chemical compositions: nanometer grade silica
SiO
2Content (%): 20
Median size (nanometer): 8-12
2.CH83-120 Nano silica sol
Main chemical compositions: nanometer grade silica
SiO
2Content (%): 20
Median size (nanometer): 8-10
3 Henkel Dispersant 05
Main chemical compositions: quarternary ammonium salt compound
Activeconstituents (%): 20
4. Henkel Colorsperse 188A
Main chemical compositions: quarternary ammonium salt compound
Activeconstituents (%): 20
5. DOW Chemical AC-808A
Main chemical compositions: pure acrylic acid emulsion
Solid content (%): 49.5
6. BASF Acronal PA-237
Main chemical compositions: pure acrylic acid emulsion
Solid content (%): 48
7. the U.S. sharp RCL-595 that joins
TiO
2Content (%)>=97
8. the R-706 of Du Pont
TiO
2Content (%)>=97
9. talcum powder
Fineness (order): 800-1500
10. kaolin
Fineness (order): 800-1500
11. coarse whiting
Fineness (order): 400-800
12. wollastonite powder
Fineness (order): 400-800
13. DOW Chemical QP-100MH
Main chemical compositions: hydroxyethyl ether cellulose
Viscosity (25 ℃ of mPaS): 4400-6000 (1%)
14. imperial 250HHBR is striden in the Asia
Main chemical compositions: hydroxyethyl ether cellulose
Viscosity (25 ℃ of mPaS): 3400-5000 (1%)
15. Sheng Nuopuke NXZ
Main chemical compositions: MO series mixture
Effective constituent (%): >=99
16. the B-943 of Ai Di section
Main chemical compositions: MO series mixture
Effective constituent (%): >=99
17. DOW Chemical X-405
Main chemical compositions: TX10
Effective constituent (%): 70
18. the peaceful PE100 of section
Main chemical compositions: TX10
Effective constituent (%): 99
19. golden source chemistry TCP-8045
Main chemical compositions: polyacrylic acid sodium salt
Effective constituent (%): 45
20. Sheng Nuopuke Dispersant 5040
Main chemical compositions: polyacrylic acid sodium salt
Effective constituent (%): 42
21. DOW Chemical AMP-95
Main chemical compositions: organic amine compound
Content (%): >=93
22. golden source chemistry TCP-95
Main chemical compositions: organic amine compound
Content (%): 90-95
23. the graceful Texanol of she scholar
Main chemical compositions: 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate
Effective constituent (%): >=99
24. Sheng Nuopuke SN-636
Main chemical compositions: acrylic ester polymer
Effective constituent (%): 30
25. Sheng Nuopuke SN-612NC
Main chemical compositions: non-ionic hydrophobic modified polyurethane
Effective constituent (%): 40
26. the peaceful DSX-2000 of section
Main chemical compositions: nonionic polyoxyalkylene type polyurethane
Effective constituent (%): 20
27. tie up high chemical industry LS-200
Main chemical compositions: nonionic polyoxyalkylene type polyurethane
Solid content (%): 20
28. Shu Mei A26
Main chemical compositions: chlormethylisothiazo,ine ketone and benzisothiazole alcohol/ketone mixtures
Effective constituent (%): 8
29. Huffman D29
Main chemical compositions: chlormethylisothiazo,ine ketone and benzisothiazole alcohol/ketone mixtures
Effective constituent (%): 9
30. Ucar 35 technical grade
With reference to exterior wall coating material of synthetic resin emulsion technical indicator (GB/T9755-2001), exterior wall inorganic architectural coatings technical indicator (JG/T26-2002) and building inside and outside wall are with performance test such as the following table of priming paint technical indicator (JG/T201-2007) to the water-borne coatings of the foregoing description preparation:
Claims (15)
1. high performance outer wall paint that water-based is exempted to prime mainly comprises the component of following parts by weight:
2. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described Nano silica sol be in Shenzhen's Jiization chemical industry KH-Nano silica sol and the chemical industry CH83-120 of the Jiangsu League of Nations Nano silica sol any one.
3. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described protection glue be Henkel Dispersant 05 with Henkel Colorsperse 188A in any one.
4. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that ACRYLIC EMULSION be among DOW Chemical AC-808A and the BASF Acronal PA-237 any one.
5. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime is characterized in that described pigment joins in RCL-595 white titanium pigment and the R-706 of the Du Pont white titanium pigment any one for U.S. sharp.
6. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime is characterized in that described filler weight proportioning is a talcum powder: kaolin: coarse whiting: wollastonite powder=1: 0.5: 2: 0.1-0.5.
7. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime is characterized in that described Mierocrystalline cellulose is that any one is striden among the imperial 250HHBR in DOW Chemical QP-100MH and Asia.
8. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described skimmer be among Sheng Nuopuke NXZ and the B-943 of Ai Di section any one.
9. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described wetting agent be among DOW Chemical X-405 and the peaceful PE100 of section any one.
10. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described dispersion agent be Sheng Nuopuke Dispersant 5040 with golden source chemistry TCP-8045 in any one.
11. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described acid-base modifier be among the chemistry TCP-95 of Tao Shi AMP-95 and golden source any one.
12. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described sanitas be among Shu Mei A26 and the Huffman D29 any one.
13. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime is characterized in that described thickening material is at least a among Sheng Nuopuke SN-636 and the Sheng Nuopuke SN-612NC.
14. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime, it is characterized in that described flow agent be the peaceful DSX-2000 of section with the high chemical industry LS-200 of dimension in any one.
15. the high performance outer wall paint that a kind of water-based according to claim 1 is exempted to prime is characterized in that described film coalescence aid is Yi Shiman Texanol.
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| CN2011104615942A CN102533028A (en) | 2011-12-29 | 2011-12-29 | Water-based, primer-free and high-performance exterior water coating |
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| CN103483883A (en) * | 2013-09-05 | 2014-01-01 | 鳄鱼制漆(上海)有限公司 | High-performance silica sol inorganic exterior wall coating |
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| CN103483883A (en) * | 2013-09-05 | 2014-01-01 | 鳄鱼制漆(上海)有限公司 | High-performance silica sol inorganic exterior wall coating |
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Application publication date: 20120704 |