Summary of the invention
An object of the present invention is to provide waterborne edge sealing paint, improves the fillibility of waterborne edge sealing paint, rate of drying and hardness.
Another object of the present invention is to the preparation method that described waterborne edge sealing paint is provided.
Waterborne edge sealing paint provided by the invention, comprises the raw material of following weight part: water-base resin 100 ~ 250 parts, redispersable latex powder 50 ~ 150 parts, film coalescence aid 10 ~ 25 parts, wollastonite 100 ~ 250 parts and filler 400 ~ 550 parts.
Waterborne edge sealing paint of the present invention, preferably, comprises the raw material of following weight part: water-base resin 125 ~ 200 parts, redispersable latex powder 80 ~ 120 parts, film coalescence aid 15 ~ 22 parts, wollastonite 150 ~ 200 parts and filler 440 ~ 500 parts.
Waterborne edge sealing paint of the present invention, more preferably, comprises the raw material of following weight part: water-base resin 150 ~ 180 parts, redispersable latex powder 80 ~ 100 parts, film coalescence aid 17 ~ 22 parts, wollastonite 150 ~ 200 parts and filler 440 ~ 460 parts.
The above-mentioned waterborne edge sealing paint of the present invention, also comprises: in-can preservation sterilant, wetting dispersing agent, defoamer, thickening material and water.
The present invention adds in-can preservation sterilant again, wetting dispersing agent, defoamer, the effect of thickening material respectively: in-can preservation sterilant mainly plays the effect preventing coating products rotten because of bacteria breed in tank; Wetting dispersing agent mainly plays wetting filler, reduces the viscosity of coating, better can disperse opaque filler in coating system, and suppress coating to flocculate; Defoamer Main Function is the bubble that elimination coating produces in production, construction process; The effect of thickening material is adjusting coating viscosity.
Waterborne edge sealing paint provided by the invention, comprise the raw material of following weight part: water-base resin 100 ~ 250 parts, redispersable latex powder 50 ~ 150 parts, film coalescence aid 10 ~ 25 parts, wollastonite 100 ~ 250 parts, filler 400 ~ 550 parts, 1 ~ 4 part, in-can preservation sterilant, wetting dispersing agent 5 ~ 15 parts, defoamer 3 ~ 10 parts, thickening material 1 ~ 5 part and 0 ~ 150 part, water.
Waterborne edge sealing paint of the present invention, preferably, comprise the raw material of following weight part: water-base resin 125 ~ 200 parts, redispersable latex powder 80 ~ 120 parts, film coalescence aid 15 ~ 22 parts, wollastonite 150 ~ 200 parts, filler 440 ~ 500 parts, 1 ~ 4 part, in-can preservation sterilant, wetting dispersing agent 8 ~ 10 parts, defoamer 4 ~ 8 parts, thickening material 1 ~ 5 part and 50 ~ 118 parts, water.
Waterborne edge sealing paint of the present invention, more preferably, comprise the raw material of following weight part: water-base resin 150 ~ 180 parts, redispersable latex powder 80 ~ 100 parts, film coalescence aid 17 ~ 22 parts, wollastonite 150 ~ 200 parts, filler 440 ~ 460 parts, 3 parts, in-can preservation sterilant, wetting dispersing agent 8 ~ 9 parts, defoamer 6 parts, thickening material 3 ~ 3.5 parts and 60 ~ 97 parts, water.
Wherein, described water-base resin is: solids content is the watersoluble polyurethane acrylic acid dispersion liquid of 30 ~ 40%.Solids content preferably 32 ~ 36%.
Wherein, described redispersable latex powder is selected from: one or more in ethene and vinyl acetate copolymerized rubber powder (Vac/E), acrylate and styrene copolymerized rubber powder (A/S), vinyl acetate and ethene and higher aliphatic vinyl acetate terpolymer rubber powder (Vac/E/VeoVa) and vinyl acetate homopolymerization rubber powder (Pvac).
Wherein, described film coalescence aid is selected from: dipropylene (DPnB), butyl (DB) and 2, one or more two kinds in 2,4-trimethylammonium-1,3 pentanediol mono isobutyrate and tripropylene glycol butyl ether (TPnB).
Wherein, described wollastonite is: coating level wollastonite powder.
Wherein, described filler is selected from: one or more in talcum powder, fine particle calcium carbonate, coarse whiting and transparent powder.
Wherein, described in-can preservation sterilant is: formaldehyde condensation products is or/and isothiazolinone mixture.
Wherein, described wetting dispersing agent is selected from: one or more in sodium polyacrylate salt, modified polypropene acid solution class and modified polycarboxylic acid salt.
Wherein, described defoamer is selected from: one or more in polysiloxane-polyether copolymer emulsion class, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class and mineral oil base class.
Wherein, described thickening material is selected from: one or more of acrylic acid or the like, polyurethanes and cellulose ethers.
Wherein, described water is: deionized water.
The preparation method of described waterborne edge sealing paint provided by the invention, comprises the following steps: stir after being mixed stage by stage by the raw material of described ratio, and adjustment stormer viscosity, to 90 ~ 95KU/25 DEG C, to obtain final product.
The preparation method of described waterborne edge sealing paint provided by the invention, by raw materials used difference, mixes stage by stage and stirs, and particularly, comprises the following steps:
1) described water-base resin is weighed in dispersion cylinder, starts to stir;
2) claim standard by in-can preservation sterilant and wetting dispersing agent in described ratio, add under whipped state in dispersion cylinder;
3) defoamer and film coalescence aid are first weighed in container in described ratio, join in dispersion cylinder under whipped state after mixing;
4) under agitation add redispersable latex powder, wollastonite and filler in described ratio, disperse under whipped state;
5) add thickening material and water in described ratio, stir and adjust stormer viscosity to 90 ~ 95KU/25 DEG C, to obtain final product.
In above-mentioned preparation method:
Step 1) and step 2) stirring velocity be low speed, namely 200 ~ 600 revs/min.Preferably 500 revs/min.
Step 3) stirring velocity be middling speed, namely 601 ~ 1000 revs/min.Preferably 800 revs/min.
Step 4) stirring velocity when adding redispersable latex powder, wollastonite and filler is middling speed, namely 601 ~ 1000 revs/min.Preferably 800 revs/min.
Step 4) add the dispersion stirring velocity after redispersable latex powder, wollastonite and filler at a high speed, namely 1001 ~ 1500 revs/min.Preferably 1200 revs/min.
Step 4) jitter time be 15 ~ 30 minutes.
Step 5) stirring velocity be middling speed, namely 601 ~ 1000 revs/min.Preferably 800 revs/min.
Step 5) churning time be 2 ~ 15 minutes.Preferably 5 minutes.
Waterborne edge sealing paint solids content of the present invention is up to 75%, and 40 ~ 48 minutes time of polishing, dry 24 hours hardness can reach HB, and within 48 hours, hardness can reach H, and after dry, paint film is smooth does not subside.Zero VOC content (being 30 ~ 41g/L under different ingredients), without free TDI.Drying can there will not be at upper surface construction PU, NC equal solvent type coating end problem of stinging in 24 hours, has good solvent resistance.
In order to allow the waterborne edge sealing paint of this invention, there is above feature, technological core adopts water-free redispersable latex powder to be main body filmogen, collocation water-base resin, and be aided with wollastonite (being also a kind of filler in fact), thus reach this waterborne edge sealing paint while environmental protection, features such as there is ultra-high solids, fast drying, hardness is high, slump resistance is good can also be reached.Redispersable latex powder is the multipolymer of ethene, vinyl acetate etc., using polyvinyl alcohol as protective colloid, is a kind of water-soluble redispersible powder, has excellent anti-saponifiability and water-repellancy, and has good adhesive property; Water-base resin, especially aromatic urethane acrylic dispersions then have excellent perviousness, drying property and hardness.The main composition of wollastonite is CaSiO
3or CaOSiO
2, it is containing SiO
251.75%, CaO 48.25%, Chang Hantie, manganese, magnesium.Wollastonite is a kind of triclinic(crystalline)system, thin platelike crystal, inorganic needle-like mineral, aggregate radially or threadiness.Have glass and pearliness, water absorbability is less than 4%.Oil absorbency is low, specific conductivity is low, insulativity is better.Hardness 4.5 ~ 5.5, density 2.75 ~ 3.10g/cm3.Wollastonite is nontoxic, resistance to chemical attack, thermostability and dimensional stabilizing are good, mechanical property and electrical property excellent and there is certain strengthening action.There is very high whiteness simultaneously.Coating level wollastonite powder is applied to the toughness and wearing quality that can improve coating after in waterborne edge sealing paint, keep coating surface smooth with and good glossiness, improve anti-scrubbing and weathering resistance performance, reduce the oil number of coating and keep alkalescence, there is resistance to corrosion.Make coating can obtain better physical strength, increase weather resistance, increase adherence and corrosion resistance, also make waterborne edge sealing paint have good fraction of coverage and sticking power.
Compared with prior art, the present invention does not use the reagent such as rutile titanium white powder, mill base, wetting agent and stearic acid zinc powder, inherently reduces cost.And filler of the present invention has certain opacifying power, watersoluble polyurethane acrylic acid dispersion liquid, this has added the tensio-active agent of certain content in synthesis time, and has well substrate wetting; The resin adopted and redispersable latex powder all have good drying property and grinability, and filler content is up to more than 60, so do not add Zinic stearas all have good grinability.Be enough to replace raw material of the prior art, and reach better effect further.
The preparation method of waterborne edge sealing paint of the present invention is simple, easily operates, and harmless to operator.Only need the water of interpolation 5% to adjust rare directly to construct afterwards during use, mode comprises brushing, roller coat and spraying.Totally there is excellent sag resistance and fillibility.
In a word, waterborne edge sealing paint of the present invention, compared to the prior art, has following features: 1) endanger minimum to environment and people and animals; 2) high solids content, high fillibility, hardness is excellent does not sink; 3) sticking power that closure is good, fabulous, compact in paint film do not ftracture, and can support the use with various finish paint; 4) quick-drying, easily polishing, not scab paper, easy construction.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Be to illustrate that raw material of the present invention has availability to the buying situation of various raw material below, and should be used for limiting scope of the present invention.
Described water-base resin refers to that solids content is the watersoluble polyurethane acrylic acid dispersion liquid of 30 ~ 40%: the such as NeoRez R-9407 of DSM company (DSM), and this water-base resin is aqueous aromatic urethane acrylic dispersions; The UC84 of A Erbai Dinke company (ALBERDINGK BOLEY GmbH), this water-base resin is water-based aliphatic polyurethane acrylic copolymer dispersion liquid.
Product Yi Laitai (Elotex) 50E100S (primary chemical group is Vac/E), Yi Laitai (Elotex) EV2000 (type is Vac/E/VeoVa) that described redispersable latex powder is produced as national of the United States's starch chemical company (Bridgewater), SP3000, SP4000 (type is Vac/E) of MP2050 (type is Vac/E) and Kuraray company.
Preventol D7F (mixture of multiple isothiazolinone and formaldehyde), the Preventol BIT 20N (aqueous mixture of BIT) etc. of described in-can preservation sterilant such as German Lanxess Corporation (LANXESS).
The Sokalan PA30CL (modified polycarboxylic acid salt) that the TEGO Dispers750W (modified polypropene acid solution class) that Hydropalat640A (sodium polyacrylate salt), German Ying Chuandigao chemical company (EVONIK) that described wetting dispersing agent is produced as Hai Chuan Chemical Co., Ltd. of Shenzhen produce, German BASF Chemical Co., Ltd. (BASF SE) produce.
The DALPADTM D (dipropylene) of described film coalescence aid such as Dow Chemical or the butyl (DB) of U.S. Yi Siman chemistry (Eastman).
The Foamster309A (mineral oil base class) that BYK024 (polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class), Hai Chuan Chemical Co., Ltd. of Shenzhen that described defoamer is produced as A10 (nano polysilicon oxygen alkane-copolyether emulsion class), the SN-154 (polypropylene glycols) of Ninghua work (China) company limited of section (Cognis), German Bi Ke chemistry (Asia-Pacific) private limited partnership (BYK-Chemie GmbH) produce.
Described filler is that preferred oil number is little and have the water-ground limestone of certain opacifying power, such as CC1500, CC2500 of Pingxiang City calcium carbonate Industrial Co., Ltd..
Described thickening material is as the Thixol 53L (acrylic acid copolymer soln) of French brother Supreme Being scholar (COATEX) and Coapur830w (non-ion aqueous polyurethane), the PUR62 (polyurethanes) of the bright icepro of Germany (M ü nzing), the QP15000 (hydroxyethyl ether cellulose) etc. of Clariant (Clariant).
Described wollastonite is coating level wollastonite powder, such as the SC1250 of wide Fujian material.Wollastonite consists of CaSiO
3or CaOSiO
2, it is containing SiO
251.75%, CaO 48.25%, Chang Hantie, manganese, magnesium.
Embodiment 6
Preparation process is with embodiment 2, and each component unlike the waterborne edge sealing paint of the present embodiment is as follows:
Composition |
Weight (kg) |
UC84 (solids content 35 ± 1%) |
160 |
SP3000 |
100 |
DB |
20 |
Preventol D7F |
2 |
Preventol BIT 20N |
1 |
BYK024 |
6 |
Hydropalat 640A |
5 |
TEGO Dispers750W |
4 |
SC1250 wollastonite powder |
150 |
CC1500 calcium carbonate |
300 |
CC2500 calcium carbonate |
160 |
Coapur830w |
3 |
Deionized water |
89 |
Adjustment stormer viscosity is to 93KU/25 DEG C.
Comparative example 1
Its preparation process is with embodiment 2, other compositions are identical with embodiment 2, unlike each component of the waterborne edge sealing paint of this comparative example as following table, essential difference is that common pure acrylic resin only selected by resin, be specially the AlberdingkAC 2514 of German A Erbai Dinke company (ALBERDINGK BOLEY GmbH), this water-base resin is ACRYLIC EMULSION, and solids content is 43%, powder, without wollastonite, uses CC1500 equivalent replacement.And do not add redispersable latex powder.
Composition |
Weight (kg) |
Alberdingk AC 2514 |
250 |
DALPADTM D |
20 |
DB |
15 |
Preventol D7F |
3 |
BYK024 |
2 |
SN-154 |
4 |
Hydropalat 640A |
9 |
CC1500 calcium carbonate |
405 |
CC2500 calcium carbonate |
210 |
PUR62 |
2 |
Thixol 53L |
1 |
Deionized water |
79 |
Comparative example 2
The each component of embodiment 1 of patent application CN 201110175391.7 is as shown in the table:
Production method is as follows:
1, waterborne polyurethane resin is added in a reservoir;
2, then add dispersion agent and defoamer, disperse 5 minutes;
3, water-ground limestone and Rutile type Titanium Dioxide is added again, rapid stirring dispersion 20-30 minute;
4, finally add thickening material and water adjustment stormer viscosity, stir 5 minutes, can use.
Experimental example: the detection of embodiment and comparative example
Test respectively embodiment 1 ~ 6 and comparative example 1 ~ 2 according to GB/T 23999-2009 " indoor decorating use woodwork coating " standard, test result is as shown in following table (standard testing result):
Standard testing result
As can be seen from the above table, waterborne edge sealing paint of the present invention is compared with selecting the paint of common water borne pure acrylic resin, under the prerequisite meeting national standard, also there is non-volatile part content promote to some extent, rate of drying is obviously accelerated, and hardness rises fast, and paint film is smooth not to subside, sticking power is excellent, the advantages such as grinability is fine.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, all belong to the scope of protection of present invention.