CN105462412A - Water-based encapsulation glaze for woodware - Google Patents
Water-based encapsulation glaze for woodware Download PDFInfo
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- CN105462412A CN105462412A CN201510997880.9A CN201510997880A CN105462412A CN 105462412 A CN105462412 A CN 105462412A CN 201510997880 A CN201510997880 A CN 201510997880A CN 105462412 A CN105462412 A CN 105462412A
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- China
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- parts
- lisi
- woodenware
- encapsulation
- use encapsulation
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a water-based encapsulation glaze for woodware. The technical scheme is as follows: the water-based encapsulation glaze for woodware is composed of the following components in parts by weight: 60-80 parts of acrylic emulsion, 10-20 parts of propanediol, 0.1-0.3 part of defoaming agent, 0.1-0.3 part of wetting agent, 4-9 parts of film forming assistant, 5-8 parts of calcium sulfate powder filler, 7-10 parts of sanding assistant, 0.2-0.5 part of thickening agent, 0.1-0.3 part of bactericide, 40-50 parts of 800-1250-mesh talcum powder, 5-10 parts of colored filler and 30-40 parts of water. The film forming assistant comprises 2-6 parts of dipropylene glycol monobutyl ether and 2-3 parts of diethylene glycol butyl ether. The film forming assistant diethylene glycol butyl ether introduced into the formula has favorable solubility for grease in wood, thereby enhancing the transparency of the water-based paint. The added calcium sulfate powder filler is matched with the permeation system of diethylene glycol butyl ether for wood, so that the calcium sulfate powder filler can well permeate into the wood surface, thereby enhancing the transparency, glossiness and structural strength.
Description
Technical field
The present invention relates to a kind of coating lacquer, more particularly, it relates to a kind of woodenware use encapsulation Ge Lisi.
Background technology
Woodenware is exactly a kind of everyday devices that people often use from ancient times, and in order to avoid the wood thorn of woodenware in use brings inconvenience, and be also to make woodenware more attractive in appearance, ancestor is from bringing into use paint at brushing woodenware very early.
The wood lacquer brought into use most is natural wood lacquer, is commonly called as " lacquer ", taps the juice got off and is called Chinese lacquer or former bucket paint, be called raw lacquer with calico elimination impurity from lacquer tree.Natural wood lacquer not only strong adhesion, hardness is large, glossiness is high, and has outstanding durable, wear-resisting, water-fast, oil resistant, solvent resistant, high temperature resistant, resistance to soil and pharmaceutical chemicals corrodes and the excellent properties such as insulation.But natural wood lacquer needs directly to squeeze from the lacquer tree of self-sow, and need the growth cycle yielding to lacquer tree, therefore production efficiency is lower, is not suitable for the scale operation of modern automation industry.
Enter eighties of last century, significant achievement and the succeeding in developing of various macromolecular compound of polymer science theory are put into production, for the New Times has been started in paint development.Succeeded in developing the special Synolac being used as the filmogen of coating the twenties in last century, from then on various synthetic resins newly developed is applied very soon in coating, makes coating enter to synthesize filmogen for the main epoch.From now, just engendered miscellaneous oiliness wood lacquer, the most frequently used oiliness wood lacquer is exactly Polyester Paint and polyurethane paint, and it is tough that oiliness wood lacquer has paint film, gloss is plentiful, strong adhesion, the advantage such as water proof and wearable, erosion resistance, therefore be once widely used in high-class woodenware furniture.But oiliness wood lacquer needs to add organic solvent, such as we " lacquer thinner " often heard, make oiliness wood lacquer in use can release a large amount of volatile organic compoundss (i.e. VOC), comprise benzene, dimethylbenzene and formaldehyde etc., these volatile organic compoundss can cause very large pollution to environment, also can cause great harm to the healthy of the personnel touched simultaneously.In addition, all belong to highly flammable article containing benzene, dimethylbenzene, acetone, industrial naptha, thinner in oiliness wood lacquer, make oiliness wood lacquer product have combustibility, make oiliness wood lacquer in the process produced, transport and use, all have the danger of presence of fire.Above-mentioned reason make nowadays oiliness wood lacquer eliminate by increasing user.
For the many disadvantages that oiliness wood lacquer shows, more energy has been moved on in the exploitation to aqueous woodware paint by present wood lacquer industry, and compared to oiliness wood lacquer, aqueous woodware paint has following several large advantage:
(1) toxicity: because water-miscible paint adopts advanced vinylformic acid and the synthetics of urethane, ultralow
VOC content (compulsory standard lower than national 200mg/L) is really nonpoisonous and tasteless high-tech environmentfriendly products.And pyroxylin(e)finish and Polyester Paint with the addition of organic solvent, containing benzene,toluene,xylene and derivative thereof in its product, so the toxicity of Polyester Paint is the highest, the toxicity of pyroxylin(e)finish is then taken second place.
(2) flammable: aqueous woodware paint have employed water to replace organic solvent, its product has the non-flammable feature of safety.Greatly reduce production, the Hazard Factor of intermediate links and trouble.And be all belong to highly flammable article containing benzene, dimethylbenzene, acetone, industrial naptha, thinner in pyroxylin(e)finish and Polyester Paint.
(3) pungent odour: aqueous woodware paint have employed water to replace organic solvent, its product, when brushing, can not produce any pungent odour.And pyroxylin(e)finish and Polyester Paint are containing organic solvent, all can evaporate in air in brushing and dry process and go, directly stimulate the sensory organ of human body.
(4) time is moved in after paint: it is few that aqueous woodware paint has brushing pass, and quick-drying is easily coated with, and do not join the time limitation after paint, is painted with and namely can moves in.And pyroxylin(e)finish and Polyester Paint all can volatilize harmful gas due to its organic solvent in the process of drying, so, use the house of pyroxylin(e)finish and Polyester Paint finishing, generally all cannot be painted with and directly to move in afterwards, need wait one section of isolation time.
But aqueous woodware paint still exists some problems, such as it is not good to the wetting property on woodenware surface, and therefore compared to oiliness wood lacquer, the transparency of aqueous woodware paint is poor.
Ge Lisi is a kind of to be translucently made up of in oil solvent to transparent pigment colorant resin dissolves, dry slow, can by wiping, grooming and do level light and shade, makes that integral color is soft, nature, gradation sense strong, and the overwhelming majority is use in NC paints.Ge Lisi: red, yellow, black, reddish brown, black brown NC Ge Lisi is a kind of obliterating tinting material, can color be inserted in the pore of timber, and the light and shade depth of color can be adjusted by wiping, increase the gradation sense of film color and the sharpness of wood grain, tradition Ge Lisi seepage force is not strong, easily fade, priming paint need be carried out in upper strata, the application of finish paint just can reach the provide protection to timber, and construction easily causes finishing coat to come off accidentally, the phenomenons such as cracking, in order to improve the working strength of Ge Lisi, also in order to save Ge Lisi construction time loaded down with trivial details, can say that Ge Lisi carries out mixed with aqueous woodware paint, therefore need to design a kind of woodenware use Ge Lisi.
Summary of the invention
For the deficiency that prior art exists, the object of the present invention is to provide a kind of woodenware use encapsulation Ge Lisi timber being had to better wettability.
For achieving the above object, the invention provides following technical scheme: a kind of woodenware use encapsulation Ge Lisi, the recipe ingredient of this woodenware use encapsulation Ge Lisi is counted by weight:
Wherein film coalescence aid comprises:
Dipropylene 2 ~ 6 parts
Butyl 2 ~ 3 parts.
Preferably, described thickening material comprises:,
Urethane thickening flow agent 0.1 ~ 0.3 part
Polyurethane thickener 0.1 ~ 0.2 part.
Preferably, described wetting agent is low bubble organosilicon wetting agent.
Select low bubble organosilicon wetting agent to be: because low bubble organosilicon wetting agent effectively can suppress the generation of bubble playing wetting effect while, thus contribute to the planeness improving paint vehicle.
Preferably, described defoamer is waterborne organic silicon defoamer.
The reason of waterborne organic silicon defoamer is selected to be: defoamer a kind ofly adds in foaming system the material destroying or suppress foam with lower concentration, oily, emulsion form, solid, paste etc. can be divided into by its state, be widely used in the fields such as chemical industry, weaving, printing and dyeing, papermaking, medicine, fermentation; The advantage of silicone antifoam agent is: (1) has good unreactiveness, generally not with by the medium generation chemical reaction of froth breaking; (2) there is positive spreading coefficient, can the rapid drawout in gas one liquid interface in foamed system; (3) have lower surface tension, silicon oil surface tension is (1.5 ~ 20) × 10-5N/cm; (4) not easily by the tensio-active agent institute solubilising existed in foaming system.
Preferably, described thickening material is cellulose ethers thickening material.
The reason of cellulose ethers thickening material is selected to be: cellulose ethers thickening material is the macromolecular chain with hydroxyl, with water, strong hydration can occur, can produce intermolecular winding again, thus effectively increase aqueous viscosity.
Preferably, described cellulose ethers thickening material is the one in Xylo-Mucine, Vltra tears and Natvosol.
Preferably, described grinding auxiliary agent is Zinic stearas slurry.
Zinic stearas slurry is selected as the reason of grinding auxiliary agent to be: in Zinic stearas slurry, the fineness of Zinic stearas is evenly distributed, in bruting process, Zinic stearas can float up to coating surface to a certain extent, can either play very good polishing effect when floating level and fineness are worked good.
Preferably, described sterilant is azoles quinoline series bactericidal agent.
The reason of azoles quinoline series bactericidal agent is selected to be: being killed livestock by the key and plaing that disconnects bacterium and algae protein matter is acted on.After isothiazolinone contacts with microorganism, can promptly irreversibly suppress it to grow, thus cause the death of microorganism cells, therefore to common bacteria, fungi, algae etc., there is very strong suppression and killing action.Efficiency of killing livestock is high, and degradation property is good, have do not produce residual, operational safety, compatibleness are good, stability is strong, use cost is low.
Preferably, described azoles quinoline series bactericidal agent is the one in isothiazolinone and BIT.
Preferably, the order number of described calcium sulfate powder stuffing is 1400 ~ 1800 orders.
The reason of calcium sulfate powder stuffing is selected to be: calcium carbonate powder filler can either be applied in powder coating as pigment extender, can be used in again exterior coating and improve its tint retention, when being used for indoor ornamentation, above-mentioned performance then shows more obvious, and cost is lower.
Compared with prior art the present invention has following advantage: introduce film coalescence aid butyl in formula, because butyl has good solubility to the grease in timber, substantially increase the wettability to timber, thus improve the transparency of water-miscible paint, also in this woodenware use encapsulation Ge Lisi, with the addition of calcium sulfate powder stuffing simultaneously, coordinate butyl to the osmotic system of timber with calcium sulfate powder stuffing, calcium sulfate powder stuffing can be made to infiltrate through well in wood surface along with butyl, further increase the transparency of this woodenware use encapsulation Ge Lisi, glossiness and structural strength, butyl is coordinated to be familiar with coated timber further with propylene glycol, color filters is made to infiltrate through in timber well, and by adding talcum powder as filler, effectively strengthen the intensity of this woodenware use encapsulation Ge Lisi, also improve the glossiness of woodenware use encapsulation Ge Lisi color.
Embodiment
Embodiment 1
Wherein film coalescence aid comprises
Dipropylene 6 parts
Butyl 3 parts
Wherein thickening material comprises
Urethane thickening flow agent 0.3 part
Polyurethane thickener 0.2 part
Embodiment 2
Wherein film coalescence aid comprises
Dipropylene 2 parts
Butyl 2 parts
Wherein thickening material comprises
Urethane thickening flow agent 0.1 part
Polyurethane thickener 0.1 part
Embodiment 3
Wherein film coalescence aid comprises
Dipropylene 3 parts
Butyl 3 parts
Wherein thickening material comprises
Urethane thickening flow agent 0.2 part
Polyurethane thickener 0.13 part
Embodiment 4
Wherein film coalescence aid comprises
Dipropylene 5 parts
Butyl 2.7 parts
Wherein thickening material comprises
Urethane thickening flow agent 0.25 part
Polyurethane thickener 0.2 part
The above is only the preferred embodiment of the present invention, protection scope of the present invention be not only confined to above-described embodiment, and all technical schemes belonged under thinking of the present invention all belong to protection scope of the present invention.It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications also should be considered as protection scope of the present invention.
Product performance detect
(1) volatile organic compounds (VOC) content measuring result
| GB | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| VOC content | 20 parts | 16.32 parts | 13.73 parts | 14.66 parts | 15.53 parts |
Visible according to upper table data, the per-cent of VOC content is directly proportional to the content of film coalescence aid, and the VOC content of all products is all well below GB, the environmental requirement of compound required for us.
(2) characterization test of the transparency of product
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Transparence | 82.98 parts | 75.43 parts | 76.02 parts | 78.67 parts |
(3) characterization test of product firmness
4 embodiment products are brushed respectively getting 20 grams in same wooden plate, with the grinding abrasive disk of 600rpm, wearing treatment is carried out to it, compare and all timber be colored all is worn and torn the required time.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Wearing-in period | 18.7 seconds | 23.5 seconds | 21.4 seconds | 19.2 seconds |
Visible according to upper table data, the transparence of product is directly proportional to the content of film coalescence aid, therefore introduces film coalescence aid butyl in visible formula, has good solubility to the grease in timber, substantially increase the wettability to timber, thus improve the transparency of water-miscible paint.
Claims (10)
1. a woodenware use encapsulation Ge Lisi, is characterized in that: the recipe ingredient precentagewise of this woodenware use encapsulation Ge Lisi is counted:
Wherein film coalescence aid comprises:
Dipropylene 2 ~ 6 parts
Butyl 2 ~ 3 parts.
2. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described thickening material comprises:
Urethane thickening flow agent 0.1 ~ 0.3 part
Polyurethane thickener 0.1 ~ 0.2 part.
3. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described wetting agent is low bubble organosilicon wetting agent.
4. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described defoamer is waterborne organic silicon defoamer.
5. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described thickening material is cellulose ethers thickening material.
6. woodenware use encapsulation Ge Lisi according to claim 5, is characterized in that: described cellulose ethers thickening material is the one in Xylo-Mucine, Vltra tears and Natvosol.
7. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described grinding auxiliary agent is Zinic stearas slurry.
8. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: described sterilant is azoles quinoline series bactericidal agent.
9. woodenware use according to claim 8 encapsulation Ge Lisi, is characterized in that: described azoles quinoline series bactericidal agent is the one in isothiazolinone and BIT.
10. woodenware use encapsulation Ge Lisi according to claim 1, is characterized in that: the order number of described calcium sulfate powder stuffing is 1400 ~ 1800 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510997880.9A CN105462412A (en) | 2015-12-26 | 2015-12-26 | Water-based encapsulation glaze for woodware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510997880.9A CN105462412A (en) | 2015-12-26 | 2015-12-26 | Water-based encapsulation glaze for woodware |
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| CN105462412A true CN105462412A (en) | 2016-04-06 |
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| CN201510997880.9A Pending CN105462412A (en) | 2015-12-26 | 2015-12-26 | Water-based encapsulation glaze for woodware |
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Cited By (5)
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|---|---|---|---|---|
| CN106752433A (en) * | 2016-12-29 | 2017-05-31 | 澳达树熊涂料(惠州)有限公司 | A kind of woodenware aqueous filling glaze high and preparation method thereof and construction technology |
| CN108250883A (en) * | 2018-01-24 | 2018-07-06 | 河北晨阳工贸集团有限公司 | A kind of aqueous transparent glaze host agent and preparation method thereof |
| CN109486331A (en) * | 2018-10-26 | 2019-03-19 | 江门市新会区明洋化工实业有限公司 | A kind of coating composition and preparation method thereof |
| CN110128900A (en) * | 2019-05-21 | 2019-08-16 | 东莞市涂芭新材料有限公司 | A kind of aqueous height is saturating to wipe well glaze modelled after an antique and preparation method thereof |
| WO2022133678A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Method for preparing glaze wiping agent |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752433A (en) * | 2016-12-29 | 2017-05-31 | 澳达树熊涂料(惠州)有限公司 | A kind of woodenware aqueous filling glaze high and preparation method thereof and construction technology |
| CN108250883A (en) * | 2018-01-24 | 2018-07-06 | 河北晨阳工贸集团有限公司 | A kind of aqueous transparent glaze host agent and preparation method thereof |
| CN109486331A (en) * | 2018-10-26 | 2019-03-19 | 江门市新会区明洋化工实业有限公司 | A kind of coating composition and preparation method thereof |
| CN110128900A (en) * | 2019-05-21 | 2019-08-16 | 东莞市涂芭新材料有限公司 | A kind of aqueous height is saturating to wipe well glaze modelled after an antique and preparation method thereof |
| WO2022133678A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Method for preparing glaze wiping agent |
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Application publication date: 20160406 |