CN104473820B - Environmental-friendly nail polish and preparation method thereof - Google Patents
Environmental-friendly nail polish and preparation method thereof Download PDFInfo
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- CN104473820B CN104473820B CN201410713248.2A CN201410713248A CN104473820B CN 104473820 B CN104473820 B CN 104473820B CN 201410713248 A CN201410713248 A CN 201410713248A CN 104473820 B CN104473820 B CN 104473820B
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Abstract
The invention discloses an environment-friendly nail polish and a preparation method thereof. The environment-friendly nail polish comprises the following components in parts by weight: 65-90 parts of a water-based self-crosslinking acrylate emulsion, 0.7-1 part of sodium stearate or zinc stearate, 0.6-1 part of a nonionic surface active agent, 3-5 parts of a polyurethanes thickening flatting agent, 0.1-0.2 part of an antifoaming agent, 0.05-0.15 part of sodium polyacrylate, 1.1-2.6 parts of an antifreezing agent, 6.5-9 parts of a pigment and a plant pigment and 3-15 parts of water, wherein the nonionic surface active agent is fatty acid polyoxyethylene ether. A water-based nail polish coating has a good adhesive force, hardness, water resistance and good glossness.
Description
Technical field
The present invention relates to environmentally friendly beauty treatment fields, more particularly to a kind of environmental protection nail polish and preparation method thereof.
Background technology
China's nail polish industry development speed in recent years, benefit from nail polish industry production technology improve constantly and
Downstream demand market constantly expands, and nail polish industry is all very good with development situation on international market at home, China's nail
Oily industry welcomes good opportunity to develop.Currently on the market nail oil quality is very different, and oiliness nail polish is with acetone, acetic acid second
Ester, formaldehyde, phthalic acid ester, benzene etc. are inflammable, explosive, have the finger that the organic solvent of high risks is raw material to human body, environment
Nail polish product, there is great corrosiveness to nail.The pole that oiliness nail polish quality problems and the impact to human body, environment cause
Big attention, the generation and development of its substitute water-based nail polish are to answer environmental protection and the requirement of women's health quickly to tie
Really.But because water-based nail polish coating there is also some problems in application, so currently without can completely replace oiliness to refer to
Nail polish.
The technology of water-based nail polish is as involved by number of patent application is CN2013105114165 and CN2013105135458
Water-based nail polish take out and use phthalide type leuco dye, and other aqueous promoters etc. are prepared from;Patent
A kind of environment-friendly resin involved by CN2009101126858 is the water-based nail polish of main component, does not injure nail.Existing skill
Not the problems such as water-based nail polish in art is not mentioned to adhesive force, hardness and the resistance to water that water-based nail polish needs are solved.
The content of the invention
For the above-mentioned problems in the prior art, the present invention from the performance weakness of existing water-based nail polish,
Targetedly utilize the various auxiliary agents of waterborne self-crosslinkable latex composite compounding, the water-based nail polish coating prepared that there is preferably attachment
Power, hardness, resistance to water and higher gloss.
The present invention provides a kind of environmental protection nail polish, and it is constituted by the component of following weight portion, waterborne self-crosslinkable propylene
Acid esters emulsion 65-90 part, odium stearate or zinc stearate 0.7-1 parts, nonionic surface active agent 0.6-1 parts, polyurethanes
Thickening leveling agent 3-5 parts, defoamer 0.1-0.2 parts, Sodium Polyacrylate 0.05-0.15 parts, antifreezing agent 1.1-2.6 parts, pigment with
Phytochrome 6.5-9 parts, water 3-15 parts;
Wherein, described nonionic surface active agent is aliphatic acid polyethenoxy ether;
Wherein, described pigment is selected from iron pigment or phthualocyanine pigment;
Wherein, described phytochrome is selected from essence, pigment or essential oil;
The present invention provides a kind of preparation method of environmental protection nail polish, and its step is included first odium stearate or tristearin
Sour zinc is added in water-borne Self-Crosslinked Acrylic ester emulsion in the case of stirring, after addition water and ground dispersible pigment color paste, plus
Enter nonionic surface active agent, then add the agent of polyurethanes thickening leveling and other remaining ingredients, last metering packing.
The present invention uses water-borne Self-Crosslinked Acrylic ester emulsion as base-material, reduces the consumption of coalescents, carries
The intensity of high coating so that product itself water-tolerant, good film-forming property, good endurance, while being aqueous, comparison is environmentally friendly;City
On field commonly use be nitrocellulose as base-material, be oiliness, not environmentally;Nonionic surface active agent improves aqueous nail
Adhesive force and its addition of the oil on nail causes to generate preferable cooperative effect between each component, and obtained nail polish exists
Drying time, adhesive force and the aspect performance of resistance to water three are excellent;Odium stearate or stearic acid, for improving the anti-of nail polish coatings
Aqueous, its contact angle can reach more than 90 degree, and surface is hydrophobic surface;It is equipped with that levelling is good, the polyurethanes thickening stream of not delustring
Flat agent, makes nail polish reach optimal using effect;Other Cheng Shuiru water, plant extracts, pigment.
The present invention has found that nonionic surface active agent is the introducing of aliphatic acid polyethenoxy ether to system by many experiments
The environmental protection nail polish performance for obtaining is significantly improved, and especially shows drying time, adhesive force and the aspect of resistance to water three, and
Nonionic surface active agent also has considerable influence for the addition of aliphatic acid polyethenoxy ether to final products performance.
Specific embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment, and the embodiment can be made further to the present invention
Supplement and explanation, but the present invention is not limited to these embodiments.
Embodiment 1
The environmental protection nail polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion
65 parts, 0.7 part of odium stearate, 0.6 part of aliphatic acid polyethenoxy ether, 3 parts of polyurethanes thickening leveling agent, 0.1 part of defoamer gathers
6.5 parts of 0.05 part of PAA, 1.1 parts of antifreezing agent, iron pigment and essence, 3 parts of water;
Preparation method includes odium stearate is added in water-borne Self-Crosslinked Acrylic ester emulsion in the case of stirring first,
After addition water and ground dispersible pigment color paste, corresponding aliphatic acid polyethenoxy ether is added, then add polyurethanes thickening stream
Flat agent and other remaining ingredients, last metering packing.
Embodiment 2
The environmental protection nail polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion
90 parts, 1 part of odium stearate, 1 part of aliphatic acid polyethenoxy ether, 5 parts of polyurethanes thickening leveling agent, 0.2 part of defoamer, polypropylene
9 parts of 0.15 part of sour sodium, 2.6 parts of antifreezing agent, phthualocyanine pigment and essential oil, 15 parts of water;
Preparation method includes odium stearate is added in water-borne Self-Crosslinked Acrylic ester emulsion in the case of stirring first,
After addition water and ground dispersible pigment color paste, corresponding aliphatic acid polyethenoxy ether is added, then add polyurethanes thickening stream
Flat agent and other remaining ingredients, last metering packing.
Embodiment 3
The environmental protection nail polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion
75 parts, 1 part of zinc stearate, 0.8 part of aliphatic acid polyethenoxy ether, 4 parts of polyurethanes thickening leveling agent, 0.2 part of defoamer, poly- third
9 parts of 0.10 part of olefin(e) acid sodium, 2 parts of antifreezing agent, phthualocyanine pigment and essential oil, 15 parts of water;
Preparation method includes odium stearate is added in water-borne Self-Crosslinked Acrylic ester emulsion in the case of stirring first,
After addition water and ground dispersible pigment color paste, corresponding aliphatic acid polyethenoxy ether is added, then add polyurethanes thickening stream
Flat agent and other remaining ingredients, last metering packing.
Comparative example 1
Nonionic surface active agent is APES, remaining component, content and preparation condition and embodiment 1
It is identical.
Comparative example 2
Nonionic surface active agent is aliphatic acid polyethenoxy ether, and its content is 0.5 part, remaining component, content and system
Standby condition is same as Example 1.
Comparative example 3
Nonionic surface active agent is aliphatic acid polyethenoxy ether, and its content is 1.2 parts, remaining component, content and system
Standby condition is same as Example 1.
The traditional performance of the water-based nail polish of preparation presses the skill of II types in Chinese light industry standard (QB/T2287-2011)
Art requires detection drying time, and hardness, adhesive force and resistance to water are determined respectively according to GB/T 6739-1996 hardness of film pencil
In method, the cross cut test of GB/T 9286-1998 paint and varnish paint films and GB/T1733-1993 paint film resistance to water determination methods
Method is detected, as a result as shown in the table.
Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
Pencil hardness | H | H | HB | H | HB | H |
Adhesive force | It is excellent | It is excellent | It is excellent | Typically | Typically | Typically |
Resistance to water | 96h is without exception | 96h is without exception | 96h is without exception | 50h is without exception | 51h is without exception | 48h is without exception |
Drying time min | 2-3 | 2-3 | 2-3 | 10 | 10 | 10 |
Although the present invention is disclosed as above with embodiment, it is not limited to protection scope of the present invention, any ripe
The technical staff of the technology is known, in the change made without departing from the spirit and scope of the invention and retouching, this all should be belonged to
The protection domain of invention.
Claims (2)
1. a kind of environmental protection nail polish, it is characterised in that consisting of the component of following weight portion, water-borne Self-Crosslinked Acrylic
Ester emulsion 65-90 part, odium stearate or zinc stearate 0.7-1 parts, nonionic surface active agent 0.6-1 parts, polyurethanes increases
Thick levelling agent 3-5 parts, defoamer 0.1-0.2 parts, Sodium Polyacrylate 0.05-0.15 parts, antifreezing agent 1.1-2.6 parts, pigment and plant
Look for plain 6.5-9 parts, water 3-15 parts;Described nonionic surface active agent is aliphatic acid polyethenoxy ether;Described pigment
Selected from iron pigment or phthualocyanine pigment.
2. a kind of method for preparing environmental protection nail polish as claimed in claim 1, it is characterised in that its step is included first
Odium stearate or zinc stearate are added in water-borne Self-Crosslinked Acrylic ester emulsion in the case of stirring, addition water and ground
Dispersible pigment color paste after, add nonionic surface active agent, then add the agent of polyurethanes thickening leveling and other remaining sets
Point, last metering packing.
Priority Applications (1)
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CN201410713248.2A CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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CN201410713248.2A CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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CN104473820A CN104473820A (en) | 2015-04-01 |
CN104473820B true CN104473820B (en) | 2017-05-10 |
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CN201410713248.2A Active CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105997570B (en) * | 2016-06-12 | 2020-02-18 | 北京氢爽生物科技有限公司 | Water-based nail polish and preparation method thereof |
CN108714113B (en) * | 2018-06-02 | 2021-08-17 | 浙江莱凡化妆品有限公司 | Printing nail polish and preparation process and use method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
CN103565656A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Environmental-friendly water-based nail polish |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
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2014
- 2014-11-28 CN CN201410713248.2A patent/CN104473820B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
CN103565656A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Environmental-friendly water-based nail polish |
Non-Patent Citations (1)
Title |
---|
水性指甲化妆品开发的可行性研究;陈晓锋 等;《日用化学工业》;20021231;第32卷(第06期);34-35,48 * |
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