CN104473820A - Environmental-friendly nail polish and preparation method thereof - Google Patents
Environmental-friendly nail polish and preparation method thereof Download PDFInfo
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- CN104473820A CN104473820A CN201410713248.2A CN201410713248A CN104473820A CN 104473820 A CN104473820 A CN 104473820A CN 201410713248 A CN201410713248 A CN 201410713248A CN 104473820 A CN104473820 A CN 104473820A
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Abstract
The invention discloses an environment-friendly nail polish and a preparation method thereof. The environment-friendly nail polish comprises the following components in parts by weight: 65-90 parts of a water-based self-crosslinking acrylate emulsion, 0.7-1 part of sodium stearate or zinc stearate, 0.6-1 part of a nonionic surface active agent, 3-5 parts of a polyurethanes thickening flatting agent, 0.1-0.2 part of an antifoaming agent, 0.05-0.15 part of sodium polyacrylate, 1.1-2.6 parts of an antifreezing agent, 6.5-9 parts of a pigment and a plant pigment and 3-15 parts of water, wherein the nonionic surface active agent is fatty acid polyoxyethylene ether. A water-based nail polish coating has a good adhesive force, hardness, water resistance and good glossness.
Description
Technical field
The present invention relates to environmental protection beauty treatment fields, particularly relate to a kind of environmental protection nial polish and preparation method thereof.
Background technology
China's nial polish industry development speed in recent years, benefit from nial polish industry production technology to improve constantly and downstream demand market constantly expands, nial polish industry is all very good with development situation on international market at home, and China's nial polish industry welcomes good opportunity to develop.Now commercially nial polish quality is very different, oiliness nial polish is inflammable, explosive with acetone, ethyl acetate, formaldehyde, phthalic acid ester, benzene etc., human body, environment are had to the nail polish products of organic solvent for raw material of high risks, has great corrosiveness to fingernail.Oiliness nial polish quality problems and the great attention caused the impact of human body, environment, the emergence and development of its succedaneum water-based nail polish is the requirement result fast of answering environmental conservation and women's health.But because water-based nail polish coating also exists some problems, so do not have replace oiliness nial polish completely current in application.
The technology of water-based nail polish is Phthalide type leuco dye as the water-based nail polish extraction of number of patent application involved by CN2013105114165 and CN2013105135458, and other aqueous promoters etc. are prepared from; A kind of environment-friendly resin involved by patent CN2009101126858 is the water-based nail polish of main component, does not injure fingernail.Water-based nail polish of the prior art is not mentioned to the problem such as adhesive force, hardness and resistance to water that water-based nail polish needs to solve.
Summary of the invention
For the above-mentioned problems in the prior art, the present invention is from the performance weakness of existing water-based nail polish, utilize the various auxiliary agent of waterborne self-crosslinkable latex composite compounding targetedly, the water-based nail polish coating prepared has good adhesive force, hardness, resistance to water and higher gloss.
The invention provides a kind of environmental protection nial polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion 65-90 part, sodium stearate or zinc stearate 0.7-1 part, nonionic surfactant 0.6-1 part, polyurethanes thickening leveling agent 3-5 part, defoamer 0.1-0.2 part, sodium polyacrylate 0.05-0.15 part, antifreezing agent 1.1-2.6 part, pigment and plant pigment 6.5-9 part, water 3-15 part;
Wherein, described nonionic surfactant is aliphatic acid polyethenoxy ether;
Wherein, described pigment chosen from Fe series pigments or phthualocyanine pigment;
Wherein, described plant pigment is selected from essence, pigment or quintessence oil;
The invention provides a kind of preparation method of environmental protection nial polish, its step comprises and first sodium stearate or zinc stearate is added in water-borne Self-Crosslinked Acrylic ester emulsion when stirring, after adding water and ground dispersible pigment color paste, add corresponding surfactant, then polyurethanes thickening agent and other components is used, last metering packing.
Water-borne Self-Crosslinked Acrylic ester emulsion that what the present invention adopted is, as base material, decreases the consumption of coalescents, improves the intensity of coating, make product self water-tolerant, good film-forming property, good endurance, be aqueous simultaneously, compare environmental protection; On market conventional be nitrocellulose as base material, be oiliness, not environmentally; Nonionic surfactant improves the adhesive force of water-based nail polish on fingernail and it adds and makes to create good cooperative effect between each component, and obtained nial polish shows excellence in drying time, adhesive force and resistance to water three; Sodium stearate or stearic acid, for improving the water-resistance of nail polish coatings, its contact angle can reach more than 90 degree, and surface is hydrophobic surface; Be equipped with levelling good, the polyurethanes thickening leveling agent of not delustring, make the result of use that nial polish reaches best; Other Cheng Shuiru water, plant extract, pigment.
The present invention is found by many experiments, nonionic surfactant is that the introducing of aliphatic acid polyethenoxy ether is significantly improved to obtained environmental protection nial polish performance, especially show drying time, adhesive force and resistance to water three aspect, and the addition that nonionic surfactant is aliphatic acid polyethenoxy ether also there is considerable influence to final products performance.
Detailed description of the invention
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment, and described embodiment can be done further to supplement and illustrate to the present invention, but the present invention is not limited to these embodiments.
Embodiment 1
This environmental protection nial polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion 65 parts, sodium stearate 0.7 part, aliphatic acid polyethenoxy ether 0.6 part, polyurethanes thickening leveling agent 3 parts, defoamer 0.1 part, sodium polyacrylate 0.05 part, antifreezing agent 1.1 parts, iron pigment and 6.5 parts, essence, 3 parts, water;
Preparation method comprise first sodium stearate when stir add in water-borne Self-Crosslinked Acrylic ester emulsion, after adding water and ground dispersible pigment color paste, add corresponding aliphatic acid polyethenoxy ether, then use polyurethanes thickening agent and other components, last metering packing.
Embodiment 2
This environmental protection nial polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion 90 parts, sodium stearate 1 part, aliphatic acid polyethenoxy ether 1 part, polyurethanes thickening leveling agent 5 parts, defoamer 0.2 part, sodium polyacrylate 0.15 part, antifreezing agent 2.6 parts, phthualocyanine pigment and quintessence oil 9 parts, 15 parts, water;
Preparation method comprise first sodium stearate when stir add in water-borne Self-Crosslinked Acrylic ester emulsion, after adding water and ground dispersible pigment color paste, add corresponding aliphatic acid polyethenoxy ether, then use polyurethanes thickening agent and other components, last metering packing.
Embodiment 3
This environmental protection nial polish, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion 75 parts, zinc stearate 1 part, aliphatic acid polyethenoxy ether 0.8 part, polyurethanes thickening leveling agent 4 parts, defoamer 0.2 part, sodium polyacrylate 0.10 part, antifreezing agent 2 parts, phthualocyanine pigment and quintessence oil 9 parts, 15 parts, water;
Preparation method comprise first sodium stearate when stir add in water-borne Self-Crosslinked Acrylic ester emulsion, after adding water and ground dispersible pigment color paste, add corresponding aliphatic acid polyethenoxy ether, then use polyurethanes thickening agent and other components, last metering packing.
Comparative example 1
Nonionic surfactant is alkylphenol polyoxyethylene, and all the other components, content are identical with embodiment 1 with preparation condition.
Comparative example 2
Nonionic surfactant is aliphatic acid polyethenoxy ether, and its content is 0.5 part, and all the other components, content are identical with embodiment 1 with preparation condition.
Comparative example 3
Nonionic surfactant is aliphatic acid polyethenoxy ether, and its content is 1.2 parts, and all the other components, content are identical with embodiment 1 with preparation condition.
The traditional performance of the water-based nail polish of preparation detects drying time by the technical requirement of II type in Chinese light industry standard (QB/T2287-2011), hardness, adhesive force and resistance to water detect according to the method in the cross cut test of GB/T 6739-1996 hardness of film pencil algoscopy, GB/T 9286-1998 paint and varnish paint film and GB/T1733-1993 paint film resistance to water algoscopy respectively, and result is as shown in the table.
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Pencil hardness | H | H | HB | H | HB | H |
| Adhesive force | Excellent | Excellent | Excellent | Generally | Generally | Generally |
| Resistance to water | 96h is without exception | 96h is without exception | 96h is without exception | 50h is without exception | 51h is without exception | 48h is without exception |
| Drying time min | 2-3 | 2-3 | 2-3 | 10 | 10 | 10 |
Although the present invention with embodiment openly as above; but it is also not used to limit protection scope of the present invention; any technical staff being familiar with this technology, not departing from the change and retouching done in the spirit and scope of the present invention, all should belong to protection scope of the present invention.
Claims (5)
1. an environmental protection nial polish, it is characterized in that, its composition is made up of the component of following weight portion, water-borne Self-Crosslinked Acrylic ester emulsion 65-90 part, sodium stearate or zinc stearate 0.7-1 part, nonionic surfactant 0.6-1 part, polyurethanes thickening leveling agent 3-5 part, defoamer 0.1-0.2 part, sodium polyacrylate 0.05-0.15 part, antifreezing agent 1.1-2.6 part, pigment and plant pigment 6.5-9 part, water 3-15 part.
2. environmental protection nial polish according to claim 1, is characterized in that, described nonionic surfactant is aliphatic acid polyethenoxy ether.
3. environmental protection nial polish according to claim 1, is characterized in that, described pigment chosen from Fe series pigments or phthualocyanine pigment.
4. environmental protection nial polish according to claim 1, is characterized in that, described plant pigment is selected from essence, pigment or quintessence oil.
5. prepare the method for the environmental protection nial polish of claim 1-4 described in one of them for one kind, it is characterized in that, its step comprises and first sodium stearate or zinc stearate is added in water-borne Self-Crosslinked Acrylic ester emulsion when stirring, after adding water and ground dispersible pigment color paste, add corresponding surfactant, then polyurethanes thickening agent and other components is used, last metering packing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410713248.2A CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410713248.2A CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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| CN104473820A true CN104473820A (en) | 2015-04-01 |
| CN104473820B CN104473820B (en) | 2017-05-10 |
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| CN201410713248.2A Active CN104473820B (en) | 2014-11-28 | 2014-11-28 | Environmental-friendly nail polish and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105997570A (en) * | 2016-06-12 | 2016-10-12 | 茌平县红粉天使化妆品科技有限公司 | Waterborne nail polish and preparation method thereof |
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN103565656A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Environmental-friendly water-based nail polish |
-
2014
- 2014-11-28 CN CN201410713248.2A patent/CN104473820B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050220731A1 (en) * | 2004-03-23 | 2005-10-06 | Philippe Ilekti | Nail varnish composition comprising at least one polymer and at least one plasticizer |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN103565656A (en) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | Environmental-friendly water-based nail polish |
Non-Patent Citations (1)
| Title |
|---|
| 陈晓锋 等: "水性指甲化妆品开发的可行性研究", 《日用化学工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105997570A (en) * | 2016-06-12 | 2016-10-12 | 茌平县红粉天使化妆品科技有限公司 | Waterborne nail polish and preparation method thereof |
| CN105997570B (en) * | 2016-06-12 | 2020-02-18 | 北京氢爽生物科技有限公司 | Water-based nail polish and preparation method thereof |
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104473820B (en) | 2017-05-10 |
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