CN105348958A - Two-component organic/inorganic hybrid aqueous matted coating varnish, preparation method and construction method thereof - Google Patents
Two-component organic/inorganic hybrid aqueous matted coating varnish, preparation method and construction method thereof Download PDFInfo
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- CN105348958A CN105348958A CN201510698240.8A CN201510698240A CN105348958A CN 105348958 A CN105348958 A CN 105348958A CN 201510698240 A CN201510698240 A CN 201510698240A CN 105348958 A CN105348958 A CN 105348958A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a two-component organic/inorganic hybrid aqueous matted coating varnish, a preparation method and a construction method thereof. The varnish is composed of a component A and a component B according to a volume ratio being 2:1-1:1, the component A comprises the following ingredients by mass percentage: 30.0-60.0% of an acrylic acid emulsion, 40.0-60.0% of inorganic sol, 0.1-2.0% of an antifoaming agent, 2.0-5.0% of a film forming auxiliary agent, 0.5-5.0% of an antifreezing agent and 0.1-30.0% of water; and the component B is organosiloxane. The two-component organic/inorganic hybrid aqueous matted coating varnish containing no matting powder is composed of the component A and the component B, before construction, the component A and the component B are premixed and aged, the component B organosiloxane is hydrolyzed and is subjected to a crosslinking reaction with the component A inorganic sol, an inorganic macro-molecule structure capable of reducing surface flatness of a paint film during a drying process is formed, luster is reduced, matte effect is generated without usage of the matting powder, unfavorable influence due to addition of the matting powder is avoided, and simultaneously, the addition of the inorganic sol greatly enhances the wear-resistant performance of the paint film.
Description
Technical field
The present invention relates to coating varnish preparation field used for building exterior wall, particularly relate to a kind of two component organic inorganic hybridization water-based dumb light coating varnish and preparation method thereof and constructional method.
Background technology
In order to protect outer wall coating further, outer wall building coating needs to brush water-based finishing varnish, to improve weathering resistance, the contamination resistance of coating and to meet special decorative effect after construction usually.The conventional organic coating varnish main component of water-based is polymer emulsion, and be characterized in that paint film is smooth, glossiness is high, easily produces the equation of light, occur grow diming phenomenon in large-area construction process.Water-based dumb light coating varnish can address this problem easily.
At present, the preparation method of water-based dumb light coating varnish mainly obtains by adding flatting silica in polymer emulsion.By adding flatting silica, coating is after film forming, and the flatting silica particle be distributed in paint film forms a kind of slightly rough surface, makes surface irregularity, increases scattering of light and reduces reflection, thus producing the matte effect of low gloss.But due to the restriction of flatting silica material self character, flatting silica is difficulties in dispersion in polymer emulsion, and prolonged storage very easily produces sedimentation.In addition due to flatting silica poor transparency, easily cause laccase prodution, the phenomenon that permeability reduces.
Therefore, existing water-based dumb light coating varnish technology great majority obtain by adding flatting silica, and flatting silica is difficulties in dispersion in polymer emulsion, and prolonged storage very easily produces sedimentation.Flatting silica poor transparency, easily causes laccase prodution, the phenomenon that permeability reduces.Flatting silica has stronger thickening property simultaneously, and add-on is limited, is difficult to the obtained product compared with low-luster.
Summary of the invention
Based on the problem existing for above-mentioned prior art, the invention provides a kind of two component organic inorganic hybridization water-based dumb light coating varnish and preparation method thereof and constructional method, can make coating surface roughness descent, gloss reduces, while producing matte effect, greatly promote the wear resisting property of paint film.
For solving the problems of the technologies described above, the invention provides a kind of two component organic inorganic hybridization water-based dumb light coating varnish, this varnish is made up of by the volume ratio of 2:1 ~ 1:1 A, B component, and wherein, described component A is made up of following component by mass percentage:
Described B component is organo-siloxane.
In above-mentioned varnish, ACRYLIC EMULSION adopts Henkel 2800 emulsion.
In above-mentioned varnish, inorganic sol adopts any one or two kinds of in silicon sol and Alumina gel.
In above-mentioned varnish, silicon sol adopts the alkaline silica sol of 25wt%;
Described Alumina gel adopts the alkaline Alumina gel of 25wt%.
In above-mentioned varnish, defoamer adopts silicone based defoamer.
In above-mentioned varnish, film coalescence aid adopts alcohol ester 12.
In above-mentioned varnish, frostproofer adopts propylene glycol.
In above-mentioned varnish, the organo-siloxane of B component adopts methyltrimethoxy silane or adopts the methyltrimethoxy silane of 70% by mass percentage and the phenyltrimethoxysila,e of 30%.
The embodiment of the present invention also provides the preparation method of a kind of pair of component organic inorganic hybridization water-based dumb light coating varnish, for the preparation of varnish of the present invention, comprising:
Prepare A, B component respectively, wherein,
Preparation component A is: get each component by component A formula of the present invention, water is added in container, add inorganic sol, ACRYLIC EMULSION, film coalescence aid, frostproofer and defoamer while stirring, being namely stirred under 300-500rmp rotating speed is uniformly dispersed obtains component A;
Preparation B component is: one or both the mixture directly adopting commercially available organo-siloxane finished product.
The embodiment of the present invention provides the constructional method of a kind of pair of component organic inorganic hybridization water-based dumb light coating varnish further, it is characterized in that, for constructing with varnish of the present invention, comprising:
Before construction, the A of varnish, B component are mixed slaking 6-12h, carry out after slaking spraying or roller coating construction.
Beneficial effect of the present invention is: owing to containing inorganic sol and ACRYLIC EMULSION in component A, B component adopts organo-siloxane, thus both can form not containing the water-based dumb light coating varnish of two component organic inorganic hybridizations of flatting silica, this varnish can before construction, by being pre-mixed A, B component also carries out slaking, make B component organo-siloxane occur hydrolysis and and component A inorganic sol generation crosslinking reaction, be formed in drying process the inorganic macromolecular structure that can cause coating surface roughness descent, reduce gloss, matte effect is produced without flatting silica, avoid the disadvantageous effect adding flatting silica and cause.Meanwhile, inorganic sol add the wear resisting property also greatly improving paint film.
Embodiment
Be clearly and completely described the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on embodiments of the invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to protection scope of the present invention.
Below in conjunction with specific embodiment, the invention will be further described
Embodiment one
The present embodiment provides a kind of two component organic inorganic hybridization water-based dumb light coating varnish, and this varnish is made up of A, B two kinds of components, and wherein, A, B component are made up of following component by mass percentage respectively:
In above-mentioned component A, ACRYLIC EMULSION adopts Henkel 2800 emulsion; Silicon sol as organosol adopts commercially available 25wt% alkaline silica sol; Defoamer adopts silicone based defoamer BYK024; Film coalescence aid adopts alcohol ester 12; Frostproofer adopts propylene glycol; Hydromining tap water.
The preparation method of above-mentioned water-based dumb light coating varnish is: preparation component A, step is specially: take each component according to upper table part by weight, first water is added in container, add silicon sol, ACRYLIC EMULSION, film coalescence aid, frostproofer and defoamer while stirring, under the rotating speed of 300-500rmp, stir 5min to the i.e. obtained component A that is uniformly dispersed;
The commercially available methyltrimethoxy silane of direct use is as B component.
Constructional method when varnish prepared by the present embodiment uses is: by component A and B component 2:1 mixing by volume, and slaking 6-12h (preferred slaking 6 hours) carries out after slaking spraying or roller coating construction.
Embodiment two
The present embodiment provides a kind of two component organic inorganic hybridization water-based dumb light coating varnish, and this varnish is made up of A, B two kinds of components, and wherein, A, B component are made up of following component by mass percentage respectively:
In above-mentioned component A, ACRYLIC EMULSION adopts Henkel 2800 emulsion; Be commercially available 25wt% alkalescence Alumina gel as the Alumina gel of organosol and Alumina gel; PH adjusting agent is acetic acid; Defoamer adopts silicone based defoamer BYK024; Film coalescence aid adopts alcohol ester 12; Frostproofer adopts propylene glycol; Hydromining tap water.
The preparation method of above-mentioned water-based dumb light coating varnish is: the concrete steps of preparation component A are: each component taking component A according to the part by weight of upper table, first water is added in container, add Alumina gel, ACRYLIC EMULSION, film coalescence aid, frostproofer and defoamer while stirring, under 300-500rmp rotating speed, stir 5min to the i.e. obtained component A that is uniformly dispersed;
Concrete steps prepared by B component are: both are mixed and namely obtain B component by the commercially available methyltrimethoxy silane and the phenyltrimethoxysila,e that take composition B component according to upper table weight ratio.
Constructional method when varnish prepared by the present embodiment uses is: by component A and B component 1:1 mixing by volume, and slaking 6-12h (preferred slaking 9 hours) carries out after slaking spraying or roller coating construction.
Embodiment three
The present embodiment provides a kind of two component organic inorganic hybridization water-based dumb light coating varnish, and this varnish is made up of A, B two kinds of components, and wherein, A, B component are made up of following component by mass percentage respectively:
In above-mentioned component A, ACRYLIC EMULSION adopts Henkel 2800 emulsion; Silicon sol and Alumina gel composition organosol, wherein, silicon sol is commercially available 25wt% alkaline silica sol, and above-mentioned Alumina gel is commercially available 25wt% alkalescence Alumina gel; Defoamer adopts silicone based defoamer BYK024; Film coalescence aid adopts alcohol ester 12; Frostproofer adopts propylene glycol; Hydromining tap water.
The preparation method of above-mentioned water-based dumb light coating varnish is: the concrete steps of preparation component A are: each component taking component A according to upper table part by weight, first water is added in container, add silicon sol, Alumina gel, ACRYLIC EMULSION, film coalescence aid, frostproofer and defoamer while stirring, under 300-500rmp rotating speed, stir 5min to the i.e. obtained component A that is uniformly dispersed;
The commercially available methyltrimethoxy silane of direct use is as B component.
Constructional method when varnish prepared by the present embodiment uses is: by component A and B component 2:1 mixing by volume, and slaking 6-12h (preferred slaking 12 hours) carries out after slaking spraying or roller coating construction.
The above; be only the present invention's preferably embodiment, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.
Claims (10)
1. a two component organic inorganic hybridization water-based dumb light coating varnish, it is characterized in that, this varnish is made up of by the volume ratio of 2:1 ~ 1:1 A, B component, and wherein, described component A is made up of following component by mass percentage:
ACRYLIC EMULSION 30.0 ~ 60.0%
Inorganic sol 30.0 ~ 60.0%
Defoamer 0.1 ~ 2.0%
Film coalescence aid 2.0 ~ 5.0%
Frostproofer 0.5 ~ 5.0%
Water 0.1 ~ 30.0%;
Described B component is organo-siloxane.
2. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, described ACRYLIC EMULSION adopts Henkel 2800 emulsion.
3. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, described inorganic sol adopts any one or two kinds of in silicon sol and Alumina gel.
4. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 3, it is characterized in that, described silicon sol adopts the alkaline silica sol of 25wt%;
Described Alumina gel adopts the alkaline Alumina gel of 25wt%.
5. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, described defoamer adopts silicone based defoamer.
6. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, described film coalescence aid adopts alcohol ester 12.
7. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, described frostproofer adopts propylene glycol.
8. the two component organic inorganic hybridization water-based dumb light coating varnish of one according to claim 1, it is characterized in that, the organo-siloxane of described B component adopts methyltrimethoxy silane or adopts the methyltrimethoxy silane of 70% by mass percentage and the phenyltrimethoxysila,e of 30%.
9. a preparation method for two component organic inorganic hybridization water-based dumb light coating varnish, is characterized in that, for the preparation of the varnish described in any one of claim 1 to 8, comprising:
Prepare A, B component respectively, wherein,
Preparation component A for: get each component by component A formula described in any one of claim 1 to 8, water is added in container, add inorganic sol, ACRYLIC EMULSION, film coalescence aid, frostproofer and defoamer while stirring, being namely stirred under 300-500rmp rotating speed is uniformly dispersed obtains component A;
Preparation B component is: one or both the mixture directly adopting commercially available organo-siloxane finished product.
10. a constructional method for two component organic inorganic hybridization water-based dumb light coating varnish, is characterized in that, for constructing with the varnish described in any one of claim 1 to 8, comprising:
Before construction, the A of varnish, B component are mixed slaking 6-12h, carry out after slaking spraying or roller coating construction.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510698240.8A CN105348958B (en) | 2015-10-23 | 2015-10-23 | A kind of water-based dumb light coating varnish of two-component organic inorganic hybridization and preparation method thereof and construction method |
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| CN201510698240.8A CN105348958B (en) | 2015-10-23 | 2015-10-23 | A kind of water-based dumb light coating varnish of two-component organic inorganic hybridization and preparation method thereof and construction method |
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| CN105348958B CN105348958B (en) | 2017-12-05 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929441A (en) * | 2018-03-05 | 2018-12-04 | 富思特新材料科技发展股份有限公司 | A kind of preparation method from delustring dumb light lotion with Shuangzi structure |
| CN109354944A (en) * | 2018-09-27 | 2019-02-19 | 广州亮豹涂料科技有限公司 | A kind of inorganic modified Flat varnish for waterborne wood and preparation method thereof |
| CN113502105A (en) * | 2021-09-01 | 2021-10-15 | 广东美涂士建材股份有限公司 | High-strength surface varnish |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020905A (en) * | 2010-12-14 | 2011-04-20 | 惠州市长润发涂料有限公司 | One-component water-based semi-gloss varnish and preparation method thereof |
| CN102911581A (en) * | 2012-11-14 | 2013-02-06 | 中国海洋石油总公司 | Organic-inorganic composite hydrophilic coating |
| CN103333570A (en) * | 2013-07-26 | 2013-10-02 | 江苏足迹涂料有限公司 | Water-based coating varnish and preparation technology thereof |
| CN104592832A (en) * | 2015-01-30 | 2015-05-06 | 富思特新材料科技发展股份有限公司 | Double-component water-based matte coating varnish and preparation method thereof |
-
2015
- 2015-10-23 CN CN201510698240.8A patent/CN105348958B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020905A (en) * | 2010-12-14 | 2011-04-20 | 惠州市长润发涂料有限公司 | One-component water-based semi-gloss varnish and preparation method thereof |
| CN102911581A (en) * | 2012-11-14 | 2013-02-06 | 中国海洋石油总公司 | Organic-inorganic composite hydrophilic coating |
| CN103333570A (en) * | 2013-07-26 | 2013-10-02 | 江苏足迹涂料有限公司 | Water-based coating varnish and preparation technology thereof |
| CN104592832A (en) * | 2015-01-30 | 2015-05-06 | 富思特新材料科技发展股份有限公司 | Double-component water-based matte coating varnish and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108929441A (en) * | 2018-03-05 | 2018-12-04 | 富思特新材料科技发展股份有限公司 | A kind of preparation method from delustring dumb light lotion with Shuangzi structure |
| CN109354944A (en) * | 2018-09-27 | 2019-02-19 | 广州亮豹涂料科技有限公司 | A kind of inorganic modified Flat varnish for waterborne wood and preparation method thereof |
| CN109354944B (en) * | 2018-09-27 | 2021-01-12 | 丁贤勇 | Inorganic modified water-based woodware matte varnish and preparation method thereof |
| CN113502105A (en) * | 2021-09-01 | 2021-10-15 | 广东美涂士建材股份有限公司 | High-strength surface varnish |
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