CN104327655A - Water-based air topcoat and preparation method thereof - Google Patents

Water-based air topcoat and preparation method thereof Download PDF

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Publication number
CN104327655A
CN104327655A CN201410558362.2A CN201410558362A CN104327655A CN 104327655 A CN104327655 A CN 104327655A CN 201410558362 A CN201410558362 A CN 201410558362A CN 104327655 A CN104327655 A CN 104327655A
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China
Prior art keywords
water
agent
dow chemical
finishing paint
feature
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CN201410558362.2A
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Chinese (zh)
Inventor
陈炳耀
黄德
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Guangdong Sanhe Chemical Industry Technology Co Ltd
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Guangdong Sanhe Chemical Industry Technology Co Ltd
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Priority to CN201410558362.2A priority Critical patent/CN104327655A/en
Publication of CN104327655A publication Critical patent/CN104327655A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Abstract

The invention discloses water-based air topcoat and a preparation method thereof. The water-based air topcoat comprises a wetting agent, a defoaming agent, an anti-freezing agent, a pH regulating agent, a thickening agent, an emulsion, a stain-resistant agent, a film formation additive, an anticorrosive agent, a mildew-proof anti-algae agent, a rheological additive and water. The water-based air topcoat has the advantages that the surface energy and water absorption rate of a paint film are reduced by preferable formula; the water-based air topcoat is high in strain-resistant performance; the water-white resistance, the adhesive force and the weather resistance endurance performance of the coating film are improved; the problems that the gloss is uneven, and the stability and the transparency of the system are reduced caused by powder extinction can be solved; the water-based air topcoat is safe, non-toxic and environment-friendly, and is high in construction property, high in surface drying speed and convenient to use.

Description

A kind of water-based finishing paint and preparation method thereof
Technical field
The present invention relates to a kind of water-based finishing paint, particularly a kind of method dumb light emulsion, epoxy silane crosslinker and low surface energy auxiliary agent being applied to water-based dumb light finishing paint.
Background technology
Since entering 21 century, economy develops rapidly, and particularly real estate is in full flourish in the whole nation in recent years, and a large amount of buildings is rised sheer from level ground, and advances the fast development of building coating.In building coating especially exterior coating plate, the development of emulsion paint tends towards stability, and increasing people starts to select the texture coating having more decorative effect to carry out the application of exterior wall, and texture coating is increasing in the accounting of Coating Market.Texture coating can carry out the construction effects such as parian, Bark mark, imitative brick, but due to the coarse unfairness of its coatingsurface, stain resistant ability is relatively poor.Therefore, all can carry out the construction of finishing paint after general texture coating construction, except improving coating stain resistant ability, also have very large effect to weathering resistance.
In the construction of texture coating, due to the advantage of the aspect such as material cost and the feature of environmental protection, most people select water-miscible paint cover but not oil-base paint.In water-based finishing paint product instantly, the gloss of coating is between 20 to 40 degree mostly.Use and there is the finishing paint of certain gloss, easily cause gloss uneven after construction and produce metope and grow dim, gloss is too high cause constructing after male and female face color differ, or color and aim colour produce difference; When carrying out the imitative brick of texture paint, imitative stone effect, there is the finishing paint of light also can affect its emulation property; The glossiness finishing paint of part is anti-simultaneously after-tacks difference, and stain resistant is undesirable.Number of patent application: 201310505087.3, super-hydrophobic composite water soluble finishing varnish and preparation method thereof, it adopts and hydrophobic silica aerogel material is coated to the hydrophobic cover film of water-based finishing paint surface formation, although its water tolerance is better, construction is complicated and coating gloss is higher.Number of patent application: 200710103370.8, a kind of finish coat paint of high water proof construction coatings, production is simple, cost is low, coating gloss also declines to some extent, but water-fast, stain resistant ability is poor, and its softening agent used and emulsifying agent etc. have not met the requirement of nowadays national environmental protection regulation, the feature of environmental protection of product is too poor.Due to the defect having light shield finish paint to use, dumb light finishing paint is prepared by adding flatting silica in common finishing paint by current minority manufacturer, but the interpolation of flatting silica can cause the transparency of finishing paint and contaminated resistance to decline, system is unstable simultaneously, very easily there is the flocculation of finishing paint storage layered, there is lustre lacking uniformity during use, affect painting effect.The gloss of common finishing paint can the true effect imitative to texture coating application impact, and water-based dumb light finishing paint product exists larger defect at present, therefore develops a kind of transparency good, excellent performance and the water-based dumb light finishing paint of shelf-stable is imperative.
Pure-acrylic emulsion is formed by acrylic monomer copolymerization, and particle diameter is thin, weathering resistance is very excellent, and water tolerance is also very outstanding with anti-performance of after-tacking, excellent combination property, but can produce higher gloss when being used alone in finishing paint.Pure-acrylic emulsion breast, spy clean scholar SL-200 that gloss is lower and liquid matting agent to be arranged in pairs or groups by a certain percentage use, gloss can be obtained lower than the dull finishing coat of 5 degree, and the matting agent of liquid state is beneficial to dispersion than solid, powdery matting agent, by the stability of favourable guarantee system and transparency.
Suitable low surface energy auxiliary agent is used in coating, effectively can reduce the surface energy of paint film, increase the contact angle of rainwater and lacquer painting, thus reduce lacquer painting water-intake rate and attaching dust in air, prevent dust from entering coat inside with rainwater, improve the contaminated resistance of lacquer painting.Add epoxysilicone linking agent, the condensation reaction that is hydrolyzed of alkoxyl group and water forms siloxane bond, can increase substantially the sticking power of finishing paint, water tolerance and weather-proof endurance quality simultaneously.
Summary of the invention
A kind of water-based finishing paint of the present invention, adopts pure-acrylic emulsion, liquid matting agent, SL-200 is composite reaches extinction effect; Add the stain resistant auxiliary agent of epoxysilicone linking agent and low surface energy, improve the weathering resistance of finishing paint, chemical resistant properties, water-whitening resistance and stain resistant ability; Its formula is for as follows by weight ratio:
Water 58 ~ 70
Wetting agent 0.1 ~ 0.3
Defoamer 0.1 ~ 0.3
Frostproofer 0.7 ~ 1.3
PH adjusting agent 0.2 ~ 0.5
Thickening material 0.5 ~ 2.0
Emulsion 25 ~ 35
Stain resistant agent 2.0 ~ 4.5
Film coalescence aid 0.8 ~ 1.3
Sanitas 0.2 ~ 0.4
Mildew-resistant algae-resistant agent 0.3 ~ 0.6
Auxiliary rheological agents 0.1 ~ 0.3;
Described wetting agent is at least one in DOW Chemical BD-109, Clariant LCN 407, the modest FX365 of moral;
Described defoamer is at least one in the peaceful Foamstar 223 of section, Blackburn CF1369, Sheng Nuopuke SN-DEFOAMER 328;
Described antifreezing agent is at least one in ethylene glycol, propylene glycol;
Described pH adjusting agent is at least one in Sears chemical industry Ammonia, DOW Chemical AMP-95, watt gram BS168;
Described thickening material is at least one in DOW Chemical DR-72, the modest RHEOLATE 420 of moral, DOW Chemical TT-615;
Described emulsion be the mixture of at least one in DOW Chemical TX-100, BASF Acronal 7015, the rich RS-9765 of Ahmedabad and DOW Chemical SL-200, Sheng Nuopuke 1001W; By weight ratio: the TX-100 of family name's chemistry and or BASF Acronal 7015 and or rich RS-9765: DOW Chemical SL-200: Sheng Nuopuke 1001W=1 ~ 5 of Ahmedabad: 8 ~ 15: 1 ~ 2;
Described stain resistant agent is that at least one in watt gram Silres BS 1306, a Bi Ke BYK-Silclean 3700, Du Pont Zonyl 8952 moisten the mixture of chemical industry XR-500 with west, by weight ratio: watt gram Silres BS 1306 He or Bi Ke BYK-Silclean 3700 He or Du Pont Zonyl 8952: chemical industry XR-500=3 ~ 6 are moistened in west: 1 ~ 3;
Described film coalescence aid is Yi Shiman Texanol, Yi Shiman OE300, at least one of moistening in safe chemical C-12;
Described sanitas is at least one in Sol Acticde RS, enlightening beautiful KSG103, DOW Chemical LXE;
Described mildew-resistant algae-resistant agent is at least one in Sol ACTICIDE EPW, the beautiful BDM film preservative of enlightening, Sol EW PASTE;
Described auxiliary rheological agents is at least one in sub-Silan chemistry NLS 210, DOW Chemical RM-2020 NPR, Sheng Nuopuke SN-THICKENER 612.
The preparation method of described a kind of water-based finishing paint is as follows:
By formulation weight part proportioning, water is dropped into Scattered Kettle, under agitation drop into wetting agent, defoamer, antifreezing agent, pH adjusting agent successively again, slowly thickening material is dropped into after stirring, then emulsion, matting agent, stain resistant agent is dropped into, drop into film coalescence aid, sanitas, mildew-resistant algae-resistant agent, auxiliary rheological agents after being uniformly dispersed, stir and namely obtain finished product.
Products characteristics:
A kind of water-based finishing paint of the present invention has the following advantages:
1. use low surface energy auxiliary agent and epoxy silane crosslinker composite, reduce the surface energy of paint film and water-intake rate, make it possess excellent contaminated resistance, improve the water-whitening resistance of film, sticking power and weather-proof endurance quality;
2. use the composite use by a certain percentage of pure-acrylic emulsion, low light emulsion and liquid matting agent, solve the problem of gloss uneven, system stability and the transparency decline using powder delustring to cause;
3. product application property is good, and surface drying speed is fast, easy to use;
4. this product take water as medium, safety non-toxic, environmental friendliness.
Specific embodiments:
Embodiment 1
By weight ratio, 58 parts of water are dropped into Scattered Kettle, DOW Chemical BD-109 0.1 part, Sheng Nuopuke SN-DEFOAMER 328 0.1 parts, propylene glycol 0.7 part, watt gram BS168 0.5 part is dropped into successively under 500 revs/min of rotating speeds, be uniformly dispersed, the modest RHEOLATE of moral 420 1.8 parts, promotes rotating speed to 700 revs/min of dispersions 3 minutes; Drop into DOW Chemical TX-100 2.0 parts, SL-200 30 parts, Sheng Nuopuke 1001W 2.0 parts, west profit chemical industry XR-500 1.5 part, watt gram Silres BS 1,306 0.5 parts more successively, disperse after 5 minutes, to drop into Yi Shiman OE300 1.3 parts, the beautiful KSG103 0.2 part of enlightening, the beautiful BDM film preservative 0.6 part of enlightening, sub-Silan chemistry NLS 210 0.1 parts, stir and namely obtain finished product.
Embodiment 2
By weight ratio, 70 parts of water are dropped into Scattered Kettle, Clariant LCN 407 0.2 parts, Blackburn CF1369 0.2 part, ethylene glycol 1.0 parts, DOW Chemical AMP-95 0.3 part is dropped into successively under 900 revs/min of rotating speeds, be uniformly dispersed, slow input DOW Chemical DR-72 1.1 parts, disperses 3 minutes; Drop into BASF Acronal 7,015 5.0 parts, SL-200 16.0 parts, Sheng Nuopuke 1001W 4.0 parts, west profit chemical industry XR-500 2.4 parts, Du Pont Zonyl 8,952 1.1 parts more successively, disperse after 7 minutes, to drop into profit safe chemical C-12 0.8 part, DOW Chemical LXE 0.4 part, Sol ACTICIDE EPW 0.3 part, DOW Chemical RM-2020 NPR 0.2 part, stir and namely obtain finished product.
Embodiment 3
By weight ratio, 60 parts of water are dropped into Scattered Kettle, the modest FX365 of moral 0.3 part, the peaceful Foamstar of section 223 0.3 parts, propylene glycol 1.3 parts, Sears chemical industry Ammonia 0.2 part is dropped into successively under 600 revs/min of rotating speeds, be uniformly dispersed, slow input DOW Chemical TT-615 0.5 part, promotes rotating speed to 800 revs/min of dispersions 5 minutes; Drop into Ahmedabad rich RS-9765 10.0 parts, SL-200 22.0 parts, Sheng Nuopuke 1001W 3.0 parts, west profit chemical industry XR-500 3.0 parts, Bi Ke BYK-Silclean 3,700 1.5 parts more successively, disperse the SN-THICKENER 612 0.3 parts dropping into Yi Shiman Texanol 1.0 parts, Sol Acticde RS 0.3 part, Sol EW PASTE 0.4 part, Sheng Nuopuke after 8 minutes, stir and namely obtain finished product.
Comparative example 4
By weight ratio, 64 parts of water are dropped into Scattered Kettle, under 600 revs/min of rotating speeds, drop into DOW Chemical easy 0.5 part soon, Clariant LCN 407 0.2 parts, the peaceful Foamstar of section 223 0.3 parts, ethylene glycol 1.2 parts, DOW Chemical AMP-95 0.3 part, flatting silica HK-460 6.0 parts successively, promote rotating speed to 800 revs/min of dispersions 15 minutes; Slow input DOW Chemical TT-615 0.5 part, drop into the rich RS-9765 25 parts of Ahmedabad more successively, disperse after 5 minutes, to drop into the safe chemical C-12 1.1 parts of profit, enlightening beautiful KSG103 0.2 part, Sol EW PASTE 0.4 part, DOW Chemical RM-2020 NPR 0.3 part, stir and namely obtain finished product.
Following methods is adopted to measure to the correlated performance of the paint product product of showing up of embodiment 1 ~ 3, comparative example 4:
1. the mensuration of gloss: measure according to the mensuration of standard GB/T 9754-2007 paint and varnish not 20 °, 60 ° and 85 ° specular glosss of the colored paint paint film of containing metal pigment.
2. the mensuration of transparency: spray true mineral varnish on the cement increased pressure board of 20cm × 30cm, coating thickness is about 2mm, drying at room temperature 24h, then use (2.5 ± 0.1) g finishing paint evenly to brush 1/2 area in this true mineral varnish surface, contrast range estimation transparency after drying at room temperature 6h.
3. the mensuration of water-whitening resistance: finishing paint 100 μm of spreaders are coated on 10cm × 15cm sheet glass, after drying at room temperature 6h, sheet glass 1/2 is soaked in water, takes out after 24h, evaluation water-whitening resistance.
4. the mensuration of time of drying: measure by surface drying second law regulation in GB/T1728-1979 paint film putty membrane assay method time of drying.
5. the mensuration of contamination resistance: brushing white latex paint on the asbestos cement plate of 15cm × 7cm, with its surface of about 1.0g finishing paint even spread after drying at room temperature 24h, Air drying 7 days, then test according to GB/T9780-2005 Test method for dirt resistance of film of architectural coatings and paint.
6. the mensuration of artificial ageing resistance: the xenon arc radiation that the artificial weathering of GB/T1865-2009 paint and varnish and man-made radiation expose filtration to the open air is tested, evaluates by the ranking method of GB/T 1766-2008 paint and varnish coating aging.
7. the mensuration of low-temperature stability: in the mensuration of GB/T 9268-2008 emulsion paint freeze-thaw resistance, " B method " measures.
8. package stability measures: loaded by about 800mL finishing paint sample in 1L plastics pot, sealing, puts into (50 ± 2) DEG C baking oven, store and take out after 30 days, and room temperature places 3h, opens plastics pot and observes sample property to evaluate.
The correlated performance test result of a kind of water-based finishing paint of embodiment 1 ~ 3, comparative example 4 gained is as shown in table 1 below:
Table 1
As can be seen from the above table, a kind of water-based finishing paint of the present invention, compared with prior art (comparative example 4), significantly reduces the gloss of finishing paint, improves the package stability of product, and transparency, resistance to water-white, contamination resistance and weathering resistance are all more excellent.

Claims (10)

1. a kind of water-based finishing paint of the present invention, feature part is, formula ratio comprises:
Water 58 ~ 70
Wetting agent 0.1 ~ 0.3
Defoamer 0.1 ~ 0.3
Antifreezing agent 0.7 ~ 1.3
PH adjusting agent 0.2 ~ 0.5
Thickening material 0.5 ~ 2.0
Emulsion 20 ~ 35
Stain resistant agent 2.0 ~ 4.5
Film coalescence aid 0.8 ~ 1.3
Sanitas 0.2 ~ 0.4
Mildew-resistant algae-resistant agent 0.3 ~ 0.6
Auxiliary rheological agents 0.1 ~ 0.3.
2. a kind of water-based finishing paint as claimed in claim 1, feature part is, described wetting agent is at least one in DOW Chemical BD-109, Clariant LCN 407, the modest FX365 of moral.
3. a kind of water-based finishing paint as claimed in claim 1, feature part is, described defoamer is at least one in the peaceful Foamstar 223 of section, Blackburn CF1369, Sheng Nuopuke SN-DEFOAMER 328.
4. a kind of water-based finishing paint as claimed in claim 1, feature part is, described antifreezing agent is at least one in ethylene glycol, propylene glycol; Described pH adjusting agent is at least one in Sears chemical industry Ammonia, DOW Chemical AMP-95, watt gram BS168.
5. a kind of water-based finishing paint as claimed in claim 1, feature part is, described thickening material is at least one in DOW Chemical DR-72, the modest RHEOLATE 420 of moral, DOW Chemical TT-615.
6. a kind of water-based finishing paint as claimed in claim 1, feature part is, described emulsion be the mixture of at least one in DOW Chemical TX-100, BASF Acronal 7015, the rich RS-9765 of Ahmedabad and DOW Chemical SL-200, Sheng Nuopuke 1001W; By weight ratio: the TX-100 of DOW Chemical and or BASF Acronal 7015 and or rich RS-9765: DOW Chemical SL-200: Sheng Nuopuke 1001W=1 ~ 5 of Ahmedabad: 8 ~ 15: 1 ~ 2.
7. a kind of water-based finishing paint as claimed in claim 1, feature part is, described stain resistant agent is that at least one in watt gram Silres BS 1306, a Bi Ke BYK-Silclean 3700, Du Pont Zonyl 8952 moisten the mixture of chemical industry XR-500 with west, by weight ratio: watt gram Silres BS 1306 He or Bi Ke BYK-Silclean 3700 He or Du Pont Zonyl 8952: chemical industry XR-500=3 ~ 6 are moistened in west: 1 ~ 3.
8. a kind of water-based finishing paint as claimed in claim 1, feature part is, described film coalescence aid is Yi Shiman Texanol, Yi Shiman OE300, at least one of moistening in safe chemical C-12; Described sanitas is at least one in Sol Acticde RS, enlightening beautiful KSG103, DOW Chemical LXE.
9. a kind of water-based finishing paint as claimed in claim 1, feature part is, described mildew-resistant algae-resistant agent is at least one in Sol ACTICIDE EPW, the beautiful BDM film preservative of enlightening, Sol EW PASTE; Described auxiliary rheological agents is at least one in the SN-THICKENER 612 of sub-Silan chemistry NLS 210, DOW Chemical RM-2020 NPR, Sheng Nuopuke.
10. the preparation method of a kind of water-based finishing paint as described in claim 1, feature part is, by formulation weight part proportioning, water is dropped into Scattered Kettle, under agitation drop into wetting agent, defoamer, antifreezing agent, pH adjusting agent successively again, after stirring, slowly drop into thickening material, then drop into emulsion, matting agent, stain resistant agent, drop into film coalescence aid, sanitas, mildew-resistant algae-resistant agent, auxiliary rheological agents after being uniformly dispersed, stir and namely obtain finished product.
CN201410558362.2A 2014-10-17 2014-10-17 Water-based air topcoat and preparation method thereof Pending CN104327655A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111870A (en) * 2015-10-19 2015-12-02 展辰新材料集团股份有限公司 Organic and inorganic compound finish for outer walls
CN106032449A (en) * 2015-03-17 2016-10-19 山西亮龙涂料有限公司 Matt finishing varnish and preparation process thereof
CN106380976A (en) * 2016-08-31 2017-02-08 铃鹿复合建材(上海)有限公司 Matte transparent finishing coat and preparation method thereof
CN109181454A (en) * 2018-08-13 2019-01-11 广州昊特建材有限公司 A kind of finishing varnish, preparation method and application
CN110423503A (en) * 2019-07-22 2019-11-08 东莞市建工集团有限公司 A kind of wall water-repellent paint and its coating method
CN110819164A (en) * 2019-11-15 2020-02-21 杭州海维特化工科技有限公司 PVC furniture film aqueous jet printing ink and preparation method thereof
CN111876038A (en) * 2020-06-24 2020-11-03 雷帝(中国)建筑材料有限公司 Finish paint for decorative mortar and preparation method thereof
CN113831797A (en) * 2021-09-16 2021-12-24 三棵树涂料股份有限公司 Hydrophobic high-stain-resistance matte finish varnish and preparation method thereof

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JP4038392B2 (en) * 2002-06-04 2008-01-23 ダイセル化学工業株式会社 Water-resistant cationic fine particle resin composition and method for producing the same
CN103450765A (en) * 2013-08-14 2013-12-18 青岛益群漆业集团有限公司 Preparation of elastic finish paint
CN103468081A (en) * 2013-08-14 2013-12-25 青岛益群漆业集团有限公司 Nanometer glaring self-cleaning paint
CN103725138A (en) * 2013-12-14 2014-04-16 青岛益群漆业集团有限公司 Silica sol high-permeability multifunctional transparent finish-coat paint

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JP4038392B2 (en) * 2002-06-04 2008-01-23 ダイセル化学工業株式会社 Water-resistant cationic fine particle resin composition and method for producing the same
CN103450765A (en) * 2013-08-14 2013-12-18 青岛益群漆业集团有限公司 Preparation of elastic finish paint
CN103468081A (en) * 2013-08-14 2013-12-25 青岛益群漆业集团有限公司 Nanometer glaring self-cleaning paint
CN103725138A (en) * 2013-12-14 2014-04-16 青岛益群漆业集团有限公司 Silica sol high-permeability multifunctional transparent finish-coat paint

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106032449A (en) * 2015-03-17 2016-10-19 山西亮龙涂料有限公司 Matt finishing varnish and preparation process thereof
CN106032449B (en) * 2015-03-17 2019-02-01 山西亮龙涂料有限公司 A kind of dumb light finishing varnish and its preparation process
CN105111870A (en) * 2015-10-19 2015-12-02 展辰新材料集团股份有限公司 Organic and inorganic compound finish for outer walls
CN105111870B (en) * 2015-10-19 2018-05-22 展辰新材料集团股份有限公司 A kind of organic-inorganic compounds exterior wall finish
CN106380976A (en) * 2016-08-31 2017-02-08 铃鹿复合建材(上海)有限公司 Matte transparent finishing coat and preparation method thereof
CN109181454A (en) * 2018-08-13 2019-01-11 广州昊特建材有限公司 A kind of finishing varnish, preparation method and application
CN110423503A (en) * 2019-07-22 2019-11-08 东莞市建工集团有限公司 A kind of wall water-repellent paint and its coating method
CN110423503B (en) * 2019-07-22 2021-10-15 东莞市建工集团有限公司 Wall waterproof coating and coating method thereof
CN110819164A (en) * 2019-11-15 2020-02-21 杭州海维特化工科技有限公司 PVC furniture film aqueous jet printing ink and preparation method thereof
CN111876038A (en) * 2020-06-24 2020-11-03 雷帝(中国)建筑材料有限公司 Finish paint for decorative mortar and preparation method thereof
CN113831797A (en) * 2021-09-16 2021-12-24 三棵树涂料股份有限公司 Hydrophobic high-stain-resistance matte finish varnish and preparation method thereof

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Application publication date: 20150204