CN106608717A - Thick knife-coated sand-textured building paint and preparation method thereof - Google Patents

Thick knife-coated sand-textured building paint and preparation method thereof Download PDF

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Publication number
CN106608717A
CN106608717A CN201510702972.XA CN201510702972A CN106608717A CN 106608717 A CN106608717 A CN 106608717A CN 201510702972 A CN201510702972 A CN 201510702972A CN 106608717 A CN106608717 A CN 106608717A
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China
Prior art keywords
sand
agent
textured building
building coating
thick matter
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CN201510702972.XA
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Chinese (zh)
Inventor
马安荣
梁乃文
李唤
池钟慷
何小敏
俞成钢
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Shanghai Sanyin Coating Technology Co Ltd
SHANGHAI SAN-YIN PAINTS Co Ltd
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Shanghai Sanyin Coating Technology Co Ltd
SHANGHAI SAN-YIN PAINTS Co Ltd
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Priority to CN201510702972.XA priority Critical patent/CN106608717A/en
Publication of CN106608717A publication Critical patent/CN106608717A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a thick knife-coated sand-textured building paint. The thick knife-coated sand-textured building paint comprises a sand-textured building paint emulsion, hydroxyethyl cellulose, an organic amine neutralizer, an antifoaming agent, an anti-whitening conditioning agent, an antifreezing agent, a film-forming aid, a bactericide, a waterborne anti-cracking agent, a bulking agent, a thickening agent, natural colored sand and water. The thick knife-coated sand-textured building paint has a decorative function and a protective function, is adaptive to knife-coating in batches, does not produce paint mist during construction and is free of the phenomenon of splash of the paint; a paint film formed by the paint has excellent performance like alkali resistance and artificial weathering aging resistance; the preparation method is simple in process, poses no adverse influence to operators during production and is suitable for industrial production. After construction, the thick knife-coated sand-textured building paint can produce identical decorative effect as natural stone while cost is reduced; the thickness of the paint is obviously higher than common sand-textured building paint; and the paint looks thick and heavy just as natural stone.

Description

Thick matter blade coating sand textured building coating and preparation method thereof
Technical field
The present invention relates to paint field, more particularly to building coating field, specifically refer to a kind of thick matter and scratch sand textured building coating And preparation method thereof.
Background technology
National standard is mainly using spray-finishing construction method and wet-film thickness is less than 3mm, with the extensive application of such product, Personalized demand is more and more.Existing product construction method is confined to spray-finishing construction method, and coating cloud is produced in work progress, right Workmen's personal protection is required higher and is also easy to produce atmosphere pollution.The paint vehicle amount of having a rebound is big in work progress, causes product wave Take more, produce solid waste.Wet-film thickness does not allow more than 3mm when existing product is constructed, and wet-film thickness is once excessively thin, easily Cause floating.Paint film is blocked up when existing product is constructed and can cause product cracking and surface drying time more than 4h, so as to cause paint Film initial dry cracking resistance is unable to reach requirement.To sum up, either construction method or film thickness existing product far from satisfaction Market demands.
How developing one kind and can meet the market demand can meet sand textured building coating professional standard (JG/T 24-2000) again Thick matter blade coating sand textured building coating is the problem that those skilled in the art urgently need to solve.
The content of the invention
The purpose of the present invention is the shortcoming for overcoming above-mentioned prior art, there is provided one kind can not produce solid waste, paint film Thick matter blade coating sand textured building coating of surface flawless and preparation method thereof.
To achieve these goals, the present invention has following composition:
The thick matter scratches sand textured building coating, and it is mainly characterized by, and described thick matter blade coating sand textured building coating includes following The component of mass percent:
Sand textured building coating emulsion 11.96~14.04%;
Hydroxyethyl cellulose 0.1472~0.1728%;
Organic amine neuutralizer 0.046~0.054%;
Defoamer 0.046~0.054%;
The anti-conditioning agent 0.276~0.324% that turns white;
Antifreezing agent 0.276~0.324%;
Coalescents 0.368~0.432%;
Bactericide 0.184~0.216%;
Aqueous crack resistence agent 0.3~0.5%;
Leavening agent 0.05~0.2%;
Thickener 0.0184~0.0216%;
20-40 mesh natural colour sand 34.2~50.9%;
40-80 mesh natural colour sand 12.2~32.2%;
80-120 mesh natural colour sand 0.47~4.0%;And
Water 9.0784~10.8116%.
Preferably, the VOC of described sand textured building coating emulsion is in below 20g/L, metope adhesive force≤1 Level, solids content 48 ± 2%, pH value 6.0~8.0,800~3000mPa.s of viscosity at 25 DEG C, MFT≤23 DEG C.
It is highly preferred that the 1% solution viscosity >=3000mPas of 20 DEG C described of hydroxyethyl cellulose, 98% particle size < 500 μm, 0.5% solution ph 5~7.
It is further preferred that described defoamer is polysiloxane-polyether copoly type defoamer, active ingredient >=18%.
It is further preferred that described bactericide be broad-spectrum antibacterial agent, effective ingredient >=2.5%, at 20 DEG C density 1.00~ 1.10g/ml。
Still further preferably, mass content >=99% of described coalescents, at 20 DEG C, proportion is that 0.95, refractive power refers to Number for 1.4423, it is water insoluble;It is 0.002 that butyl acetate is 1 evaporation rate, and boiling point is 255 DEG C, freezing point is -50 DEG C.
Preferably, described crack resistence agent is white powder crystal, into monoclinic system, and with six sides flake and flakey shape State is present, 1000 DEG C of dry combustion method weightlessness 4.3~6.3%, 2.78~2.82g/cm of proportion3, refractive index 1.55 ± 0.05, particle diameter 32~ 50μm。
It is highly preferred that described leavening agent is nonionic fatty alcohol esters leavening agent, pH value is 6.0~8.0.
It is further preferred that described 20-40 mesh natural colour sands, 40-80 mesh natural colour sands, 80-120 mesh natural colour sands are passed through Stainless steel classifying screen mesh screen is selected, and mass ratio is sieved thereon and is not higher than 5%, and lower sieve mass ratio is not higher than 20%;1h is boiled in boiling water not Fade, not efflorescence, nondiscolouring after 500h artificial weathering ageing resistances.
Most preferably, described antifreezing agent is propane diols and/or ethylene glycol.
A kind of thick matter scratches the preparation method of sand textured building coating, and it is mainly characterized by, and described preparation method includes following step Suddenly:
(1) by described hydroxyethyl cellulose and 50.0~80.0% deionized water, 30.0~50.0% organic amine Nertralizer and 30.0~50.0% defoamer are stirred to obtain mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by step (1) plus the remaining defoamer, described kill Microbial inoculum, the building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, The thickener and the remaining deionized water, stir to obtain mixture B;
(3) under stirring, sequentially add in the mixture B obtained by step (2) 40~80 mesh natural colour sands, 20~ 40 mesh natural colour sands and 80~120 mesh natural colour sands, the thick matter blade coating sand textured building coating for stirring described;
Wherein, percentage is the mass percent relative to each respective components quality.
Preferably, described step (1) is specially:
By described hydroxyethyl cellulose and 50.0~80.0% deionized water, the neutralization of 30.0~50.0% organic amine Agent and 30.0~50.0% defoamer, 1200~1500 revs/min of high-speed stirreds for carrying out 15~20 minutes obtain mixed dissolution Liquid A.
It is highly preferred that described step (2) is specially:
Under stirring, in the mixed dissolution thing A obtained by step (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, the increasing Thick dose and the remaining deionized water, 800~1100 revs/min of moderate-speed mixers for carrying out 5~15 minutes obtain mixture B.
It is further preferred that described step (3) is specially:
Under stirring, in the mixture B obtained by step (2) 40~80 mesh natural colour sands, 20~40 mesh are sequentially added Natural colour sand and 80~120 mesh natural colour sands, 500~700 revs/min of stirring at low speed for carrying out 5~15 minutes obtain described thick matter Blade coating sand textured building coating.
Most preferably, described stirring is carried out under 5~40 DEG C of room temperature.
Decoration functions and defencive function that the sand textured building coating in the invention has sand textured building coating are employed, product can Criticize to scrape and do not produce in construction, work progress coating cloud, do not produce paint vehicle splashing, thus atmosphere pollution and solid waste will not be produced; Product can thickness be applied to more than 6mm, surface drying time≤4h, initial dry cracking resistance pass through, diameter (50 ± 2) mm, weight The spherical counterweight of 1000g ± 10g freely falls from height 500mm, at a distance of three positions of 50mm, detects by an unaided eye, Coating surface flawless, peeling and substantially deformation;The coating paint film has the excellent property such as alkali resistance, artificial weathering ageing resistance Can, and the thick matter blade coating sand textured building coating is non-dangerous article, to production, transport, is stored in a warehouse without strict fire protection requirement; Operating personnel are had no adverse effects by the product preparation method process is simple of the present invention during production, are suitable to industrialization production;The present invention Be obtained and the equal decorative effect of lithotome after product construction, but cost can decline 35~80%, and product thickness apparently higher than Common sand textured building coating, shows the thick and heavy effect same with lithotome;Simultaneously product adhesive force is strong, and toolability is strong.
Specific embodiment
In order to more clearly describe the technology contents of the present invention, conduct further description with reference to specific embodiment.
The experimental technique of unreceipted actual conditions in the following example, conventionally and condition, or selects according to catalogue Select.
Raw materials used source in following embodiments:
Sand textured building coating emulsion GHT-1D:Jiangsu Guolian Technology Co., Ltd. produces;
Sand textured building coating emulsion SD-818:Nantong Shengda Chemical Co., Ltd. produces;
Sand textured building coating latex A rchsol 8039:Wanhua Chemical Group Co., Ltd. produces;
Described sand textured building coating emulsion, its VOC preferably in below 20g/L, metope adhesive force compared with Goodly≤1 grade, solids content 48 ± 2%, pH value 6.0~8.0,800~3000mPa.s of viscosity (25 DEG C), MFT ≤ 23 DEG C, Calcium ion stability passes through, and with excellent alkali resistance, immersion is not whitened.
Hydroxyethyl cellulose YT30000:Feicheng Yu Tian Chemical Co., Ltd.s produce;
Described hydroxyethyl cellulose is 20 DEG C of viscosity (1% solution) >=3000mPas, 500 μm of particle size < (98%), 0.5% solution ph 5-7.
Organic amine neuutralizer LCD-695:Hangzhou Luo Chuan Chemical Co., Ltd.s produce;
Described organic amine neuutralizer is low smell, ammoniacal liquor and 2- -2 methyl isophthalic acids of amino-propyl alcohol can be effectively substituted, for adjusting The pH value of emulsion paint, increases the organic amine neuutralizer for helping moisture dispersibility agent of pigment and filler.
Defoamer LT-201:Shanghai Li Qi auxiliary chemicals Co., Ltd produces;
Polyether Modified Polysiloxanes Defoaming Agent DT-650:Foshan City South Sea land for growing field crops Chemical Co., Ltd. produces;
Modified organic silicon defoamer XPS-200:Water defoamer Co., Ltd of Nanjing Huaxing produces;
Described defoamer is polysiloxane-polyether copoly type defoamer, its active ingredient analysis >=18%, being capable of quickly de-bubble and effect Persistently can not affected by extreme temperature and pressure and pH value.
The anti-conditioning agent that turns white:The butyl glycol ether solvent of the red industry development Co., Ltd sale of upper current chart;
The described anti-conditioning agent that turns white can be such that muddy speed inside and outside coating products is consistent and solvent miscible with water.
Thickener SD-15-P:Guangzhou three obtains Chemical Co., Ltd.'s production;
Described thickener is polyurethane thickener, with unique pseudoplastic rheological characteristic, cuts in and also has excellent when height cuts Performance, it can make system obtain viscosity in higher tank.
Anticorrosion and bactericidal agent YN-188:Baoding sunlight auxiliary agent Co., Ltd produces;
Described bactericide can be efficient, wide spectrum commonly used in the art, environmental friendly, anti-corrosive bactericide, with quick, efficient Sterilization and anticorrosion effect, wider pH value (<9.5) it is in the range of effectively, non-stimulated to human body in concentration scope, do not contain Heavy metal and other poisonous and harmful compositions, to the microorganisms such as bacterium, actinomyces, fungi (saccharomycete, mould) tool wide spectrum, height Effect is killed in the suppression of effect, its outward appearance be faint yellow or yellow green transparency liquid, effective ingredient >=2.5%, density (20 DEG C) 1.00~ 1.10g/ml。
HD3001 crack resistence auxiliary agents:Huzhou Han Du industrial chemicals Co., Ltd produces;
ME8158 crack resistence agent:Dongguan City camphorwood Tou Yi trades Co., Ltd produces;
Bang Le Australia AB crack resistence agent:The sharp Xin Qiyejia Building Materials Factories production in Guilin;
Described crack resistence agent is crack resistence auxiliary agent commonly used in the art, is a kind of white powder crystal, main into monoclinic system To exist with six sides flake and flakey form, its thermal coefficient of expansion is very little, with excellent toughness and elastic and corrosion-resistant Property, the mechanical strength of coating can be significantly improved, strengthen toughness and adhesive force.1000 DEG C of dry combustion method weightlessness 4.3~6.3%, proportion 2.78~ 2.82g/cm3, refractive index 1.55 ± 0.05,32~50 μm of particle diameter.
Leavening agent CF200:Dongguan City Han Feng Chemical Industry Science Co., Ltd produces;
Leavening agent V-1080:The logical technology application Co., Ltd production of Wuhuization;
Leavening agent F-339:Dongguan City Ke Feng textile auxiliaries Industrial Co., Ltd. produces;
Described leavening agent selects have fatty alcohol esters leavening agent, with fluffy handle effect, with high osmosis compatibility, with Crack resistence auxiliary agent, antifreezing agent compatibility are splendid, non yellowing, without APEO, NPEO, reach coating fluffy, plentiful.Its Outward appearance be light white thick liquid, nonionic, pH value 6.0~8.0.
20-40 mesh natural colour sands:Shijiazhuang Yin Long mineral products Co., Ltd, Hebei province Lingshou County science-star's mineral products processing factory, Shijiazhuang are prosperous Any one production of good natural colour sand factory;
40-80 mesh natural colour sands:Shijiazhuang Yin Long mineral products Co., Ltd, Hebei province Lingshou County science-star's mineral products processing factory, Shijiazhuang are prosperous Any one production of good natural colour sand factory;
80-120 mesh natural colour sands:Shijiazhuang Yin Long mineral products Co., Ltd, Hebei province Lingshou County science-star's mineral products processing factory, Shijiazhuang Any one production of Xin Liang natural colour sands factory;
20-40 mesh natural colour sands, 40-80 mesh natural colour sands, 80-120 mesh natural colour sand are through the stainless steel classification of correspondence mesh number Screen cloth carries out screening of sieving, the natural colour sand of the screening that makes to sieve, and mass ratio is sieved thereon and is not higher than 5%, and lower sieve mass ratio is not higher than 20%.The mechanical stability of natural colour sand passes through, and product packaging is intact, mark is clear, without drenching with rain.Product is boiled in boiling water 1h does not fade, not efflorescence, nondiscolouring after 500h artificial weathering ageing resistances.
Coalescents Lauryl Alcohol ester:Shanghai sky Gui auxiliary agents Co., Ltd produces;
Described coalescents for the low taste liquid of water white transparency coalescents, coalescents mass content >=99%, the proportion Solubility (20 DEG C) insoluble, evaporation rate (acetic acid fourth in (20 DEG C) 0.95, refraction index (20 DEG C) 1.4423, water Ester=1) 0.002,255 DEG C of boiling point (760mmHg), -50 DEG C of freezing point, it can be ensured that the density of paint film, make emulsion paint Good paint film property is reached when being dried under unfavorable temperature and humidity.
Sand textured building coating B5001-2:Shenzhen Guang Bao Chemical Co., Ltd.s;
Sand textured building coating L601:Upper marine rainbow evil spirit coating Co., Ltd.
Embodiment 1
Thick matter scratches composition of raw materials (wt%) such as table 1 below of sand textured building coating.
The thick matter of the embodiment of table 1 scratches the composition of raw materials (wt%) of sand textured building coating
Sand textured building coating emulsion GHT-1D 14.04%
Hydroxyethyl cellulose YT30000 0.1728%
Organic amine neuutralizer LCD-695 0.054%
Defoamer LT-201 0.054%
Coalescents Lauryl Alcohol ester 0.432%
Anticorrosion and bactericidal agent YN-188 0.216%
Antifreezing agent propane diols 0.324%
The anti-conditioning agent BCS that turns white 0.324%
Crack resistence auxiliary agent HD3001 0.5%
Leavening agent CF200 0.05%
Thickener SD-15-P 0.0216%
Deionized water 10.8116%
40-80 mesh white marbles 32.2%
20-40 mesh white marbles 27.39%
20-40 mesh phoenix is green 6.29%
20-40 mesh cream colour 4.04%
20-40 mesh is steel gray 2.61%
80-120 mesh gray jades 0.36%
80-120 mesh Chrysan Yellows 0.11%
The preparation method of thick matter blade coating sand textured building coating is as follows:
(1) by described hydroxyethyl cellulose and 50.0% deionized water, 30.0% organic amine neuutralizer and 30.0% defoamer carry out 1200 revs/min carry out high-speed stirred 20 minutes mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, the increasing Thick dose and the remaining deionized water, 800 revs/min carry out moderate-speed mixer and obtain mixture B in 15 minutes;
(3) under stirring, sequentially add in the mixture B obtained by (2) 40~80 mesh natural colour sands, 20~40 Mesh natural colour sand and 80~120 mesh natural colour sands.500 revs/min carry out stirring at low speed and obtain within 15 minutes product thickness matter blade coating of the present invention Sand textured building coating.
Wherein, percentage is the mass percent relative to each respective components quality.
Embodiment 2
Thick matter scratches composition of raw materials (wt%) such as table 2 below of sand textured building coating.
The thick matter of the embodiment of table 2 scratches the composition of raw materials (wt%) of sand textured building coating
Sand textured building coating emulsion SD-818 11.96%
Hydroxyethyl cellulose YT30000 0.1472%
Organic amine neuutralizer LCD-695 0.046%
Polyether Modified Polysiloxanes Defoaming Agent DT-650 0.046%
Anticorrosion and bactericidal agent YN-188 0.184%
Coalescents Lauryl Alcohol ester 0.368%
Antifreeze glycol 0.276%
The anti-conditioning agent BCS that turns white 0.276%
Crack resistence agent ME8158 0.4%
Leavening agent V-1080 0.2%
Thickener SD-15-P 0.0184%
Deionized water 9.0784%
40-80 mesh Snow Flower Whites 24.5%
20-40 mesh white marbles 20.8%
20-40 mesh is orange 13.2%
20-40 mesh floor is yellow 7.3%
20-40 mesh is steel gray 9.6%
80-120 mesh providence is red 1%
80-120 mesh diamond blacks 0.6%
The preparation method of thick matter blade coating sand textured building coating is as follows:
(1) by described hydroxyethyl cellulose and 60.0% deionized water, 40.0% organic amine neuutralizer and 40.0% defoamer carry out 1300 revs/min carry out high-speed stirred 18 minutes mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, the increasing Thick dose and the remaining deionized water, 1000 revs/min carry out moderate-speed mixer and obtain mixture B in 10 minutes;
(3) under stirring, sequentially add in the mixture B obtained by (2) 40~80 mesh natural colour sands, 20~40 Mesh natural colour sand and 80~120 mesh natural colour sands.600 revs/min carry out stirring at low speed and obtain within 10 minutes product thickness matter blade coating of the present invention Sand textured building coating.
Wherein, percentage is the mass percent relative to each respective components quality.
Embodiment 3
Thick matter scratches composition of raw materials (wt%) such as table 3 below of sand textured building coating.
The thick matter of the embodiment of table 3 scratches the composition of raw materials (wt%) of sand textured building coating
Sand textured building coating latex A rchsol 8039 13.0%
Hydroxyethyl cellulose YT30000 0.16%
Organic amine neuutralizer LCD-695 0.05%
Modified organic silicon defoamer XPS-200 0.05%
Anticorrosion and bactericidal agent YN-188 0.2%
Coalescents Lauryl Alcohol ester 0.4%
Antifreezing agent propane diols 0.3%
The anti-conditioning agent BCS that turns white 0.3%
Crack resistence Ji Bangle Australia AB 0.3%
Leavening agent F-339 0.18%
Thickener SD-15-P 0.02%
Deionized water 9.92%
40-80 mesh white marbles 12.2%
20-40 mesh white marbles 24.2%
20-40 mesh African Reds 11.9%
20-40 mesh is golden yellow 8.3%
20-40 mesh China Darks 1.4%
80-120 mesh is steel gray 2.0%
80-120 mesh floor is yellow 1.5%
The preparation method of thick matter blade coating sand textured building coating is as follows:
(1) by described hydroxyethyl cellulose and 80.0% deionized water, 50.0% organic amine neuutralizer and 50.0% defoamer carry out 1500 revs/min carry out high-speed stirred 15 minutes mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, the increasing Thick dose and the remaining deionized water, 1100 revs/min carry out moderate-speed mixer and obtain mixture B in 5 minutes;
(3) under stirring, sequentially add in the mixture B obtained by (2) 40~80 mesh natural colour sands, 20~40 Mesh natural colour sand and 80~120 mesh natural colour sands.700 revs/min carry out stirring at low speed and obtain within 5 minutes product thickness matter blade coating of the present invention Sand textured building coating.
Wherein, percentage is the mass percent relative to each respective components quality.
Embodiment 4:
Composition of raw materials (wt%) such as table 4 below of sand textured building coating.
The composition of raw materials (wt%) of the sand textured building coating of the embodiment 4 of table 4
Sand textured building coating latex A rchsol 8039 28.0%
Hydroxyethyl cellulose YT30000 1.0%
Organic amine neuutralizer LCD-695 0.4%
Modified organic silicon defoamer XPS-200 0.4%
Anticorrosion and bactericidal agent YN-188 0.3%
Thickener SD-15-P 1.2%
Coalescents Lauryl Alcohol ester 1.0%
Antifreeze glycol 0.8%
Deionized water 7.7%
40-80 mesh white marbles 4.8%
80-120 mesh white marbles 34.2%
80-120 mesh African Reds 11.9%
20-40 mesh is golden yellow 8.3%
The preparation method of sand textured building coating is as follows:
(1) by described hydroxyethyl cellulose and 90.0% deionized water, the neutralization of 60.0~50.0% organic amine Agent and 60.0% defoamer carry out 1500 revs/min carry out high-speed stirred 25 minutes mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, the thickener and the remaining deionized water, 700 Rev/min carry out moderate-speed mixer 25 minutes mixture B;
(3) under stirring, sequentially add in the mixture B obtained by (2) 40~80 mesh natural colour sands, 20~40 Mesh natural colour sand and 80~120 mesh natural colour sands.500 revs/min carry out stirring at low speed and obtain within 20 minutes product thickness matter blade coating of the present invention Sand textured building coating.
Wherein, percentage is the mass percent relative to each respective components quality.
Embodiment 5
The elastic building paint of embodiment 1~3, commercially available sub- scholar E9000 elastic coatings, the super exterior wall paint of magnificent Multifunctional elastic The coating of CHG-M900 and embodiment 4 carries out performance, environmental protection index contrast experiment, and concrete outcome is shown in Table 5 and table 6.
The each product performance index of table 5
The environmental protection index of table 6
As seen from Table 5, the sprayable construction of thick matter of the invention blade coating sand textured building coating, can knife-coat application, product can one It is secondary to construct to 6mm, hence it is evident that better than commercially available sand textured building coating B5001-2, L601 and comparative example of the present invention.Product Drying time, initial dry cracking resistance and artificial weathering ageing resistance are also significantly better than commercially available prod and the embodiment of the present invention 4.This Other performance indications of invention disclosure satisfy that and require better than current effectively product standard JG/T24-2000W type product technology.
As seen from Table 6, thick matter of the invention blade coating sand textured building coating VOC content is applied far below commercially available sand wall-like building Material B5001-2, L601 and the embodiment of the present invention 4, and do not detect free formaldehyde, benzene, toluene and heavy metal substance, Ke Yiman Limits of harmful substances in sufficient HJ2537-2014 environmental labelling products technical requirements and GB24408-2009 exterior coatings for building, It is a kind of environment-friendlywater-based water-based paint for meeting current generation demand.Commercially available sand textured building coating B5001-2, L601 and this Thick matter blade coating sand textured building coating of the content of volatile organic compound (VOC) of bright comparative example apparently higher than the present invention.
Decoration functions and defencive function that the sand textured building coating in the invention has sand textured building coating are employed, product can Criticize to scrape and do not produce in construction, work progress coating cloud, do not produce paint vehicle splashing, thus atmosphere pollution and solid waste will not be produced; Product can thickness be applied to more than 6mm, surface drying time≤4h, initial dry cracking resistance pass through, diameter (50 ± 2) mm, weight The spherical counterweight of 1000g ± 10g freely falls from height 500mm, at a distance of three positions of 50mm, detects by an unaided eye, Coating surface flawless, peeling and substantially deformation;The coating paint film has the excellent property such as alkali resistance, artificial weathering ageing resistance Can, and the thick matter blade coating sand textured building coating is non-dangerous article, to production, transport, is stored in a warehouse without strict fire protection requirement; Operating personnel are had no adverse effects by the product preparation method process is simple of the present invention during production, are suitable to industrialization production;The present invention Be obtained and the equal decorative effect of lithotome after product construction, but cost can decline 35~80%, and product thickness apparently higher than Common sand textured building coating, shows the thick and heavy effect same with lithotome;Simultaneously product adhesive force is strong, and toolability is strong.
In this description, the present invention is described with reference to its specific embodiment.But it is clear that still can make various Modification and conversion are without departing from the spirit and scope of the present invention.Therefore, specification is regarded in an illustrative, rather than a restrictive.

Claims (15)

1. a kind of thick matter scratches sand textured building coating, it is characterised in that under described thick matter blade coating sand textured building coating includes State the component of mass percent:
Sand textured building coating emulsion 11.96~14.04%;
Hydroxyethyl cellulose 0.1472~0.1728%;
Organic amine neuutralizer 0.046~0.054%;
Defoamer 0.046~0.054%;
The anti-conditioning agent 0.276~0.324% that turns white;
Antifreezing agent 0.276~0.324%;
Coalescents 0.368~0.432%;
Bactericide 0.184~0.216%;
Aqueous crack resistence agent 0.3~0.5%;
Leavening agent 0.05~0.2%;
Thickener 0.0184~0.0216%;
20-40 mesh natural colour sand 34.2~50.9%;
40-80 mesh natural colour sand 12.2~32.2%;
80-120 mesh natural colour sand 0.47~4.0%;And
Water 9.0784~10.8116%.
2. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described sand wall-like building is applied The VOC of material emulsion in below 20g/L, metope adhesive force≤1 grade, solids content 48 ± 2%, pH value 6.0~ 8.0,800~3000mPa.s of viscosity at 25 DEG C, MFT≤23 DEG C.
3. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described hydroxyethyl cellulose 20 DEG C of 1% solution viscosity >=3000mPas, 98% 500 μm of particle size <, 0.5% solution ph 5~7.
4. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described defoamer is poly- silicon Oxygen alkane-polyethers copoly type defoamer, active ingredient >=18%.
5. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described bactericide is wide spectrum Bacteriostatic agent, effective ingredient >=2.5%, 1.00~1.10g/ml of density at 20 DEG C.
6. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that the matter of described coalescents Amount content >=99%, at 20 DEG C proportion be 0.95, refraction index be 1.4423, it is water insoluble;Butyl acetate is 1 to wave It is 0.002 to send out speed, and boiling point is 255 DEG C, freezing point is -50 DEG C.
7. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described crack resistence agent is white Color powder crystal, into monoclinic system, and exists, 1000 DEG C of dry combustion method weightlessness 4.3~6.3% with six sides flake and flakey form, 2.78~2.82g/cm of proportion3, refractive index 1.55 ± 0.05,32~50 μm of particle diameter.
8. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described leavening agent for it is non-from Subtype fatty alcohol esters leavening agent, pH value is 6.0~8.0.
9. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described 20-40 mesh is natural Color sand, 40-80 mesh natural colour sands, 80-120 mesh natural colour sand are selected through stainless steel classifying screen mesh screen, sieve mass ratio not thereon Higher than 5%, lower sieve mass ratio is not higher than 20%;Boil 1h in boiling water not fade, not efflorescence after 500h artificial weathering ageing resistances, Nondiscolouring.
10. thick matter according to claim 1 scratches sand textured building coating, it is characterised in that described antifreezing agent is third Glycol and/or ethylene glycol.
Thick matter any one of a kind of 11. claims 1~10 scratches the preparation method of sand textured building coating, its feature It is that described preparation method comprises the steps:
(1) by described hydroxyethyl cellulose and 50.0~80.0% deionized water, 30.0~50.0% organic amine Nertralizer and 30.0~50.0% defoamer are stirred to obtain mixed dissolution liquid A;
(2) under stirring, in the mixed dissolution thing A obtained by step (1) plus the remaining defoamer, described kill Microbial inoculum, the building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, The thickener and the remaining deionized water, stir to obtain mixture B;
(3) under stirring, sequentially add in the mixture B obtained by step (2) 40~80 mesh natural colour sands, 20~ 40 mesh natural colour sands and 80~120 mesh natural colour sands, the thick matter blade coating sand textured building coating for stirring described;
Wherein, percentage is the mass percent relative to each respective components quality.
12. thick matter according to claim 11 scratch the preparation method of sand textured building coating, it is characterised in that described Step (1) is specially:
By described hydroxyethyl cellulose and 50.0~80.0% deionized water, the neutralization of 30.0~50.0% organic amine Agent and 30.0~50.0% defoamer, 1200~1500 revs/min of high-speed stirreds for carrying out 15~20 minutes obtain mixed dissolution Liquid A.
13. thick matter according to claim 11 scratch the preparation method of sand textured building coating, it is characterised in that described Step (2) is specially:
Under stirring, in the mixed dissolution thing A obtained by step (1) plus the remaining defoamer, the bactericide, The building elastic emulsion, the coalescents, the antifreezing agent, described crack resistence agent, described leavening agent, the increasing Thick dose and the remaining deionized water, 800~1100 revs/min of moderate-speed mixers for carrying out 5~15 minutes obtain mixture B.
14. thick matter according to claim 11 scratch the preparation method of sand textured building coating, it is characterised in that described Step (3) is specially:
Under stirring, in the mixture B obtained by step (2) 40~80 mesh natural colour sands, 20~40 mesh are sequentially added Natural colour sand and 80~120 mesh natural colour sands, 500~700 revs/min of stirring at low speed for carrying out 5~15 minutes obtain described thick matter Blade coating sand textured building coating.
15. thick matter according to claim 11 scratch the preparation method of sand textured building coating, it is characterised in that described Stirring is carried out under 5~40 DEG C of room temperature.
CN201510702972.XA 2015-10-26 2015-10-26 Thick knife-coated sand-textured building paint and preparation method thereof Pending CN106608717A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109455983A (en) * 2018-10-10 2019-03-12 舒城白桦林涂料有限公司 A kind of sand textured coating of preventing sand drop and preparation method thereof
CN112521859A (en) * 2019-09-17 2021-03-19 上海三银涂料科技股份有限公司 Sand textured coating for concrete building enclosure and preparation method thereof
CN113683346A (en) * 2020-05-18 2021-11-23 上海三银涂料科技股份有限公司 Water-based granite-like coating capable of preventing composite rock slices from warping and preparation method thereof
CN115521654A (en) * 2021-06-25 2022-12-27 上海三银涂料科技股份有限公司 Sand-wall-shaped building coating and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876143A (en) * 2012-08-31 2013-01-16 芜湖县双宝建材有限公司 Marble paint and preparation method thereof
CN104946033A (en) * 2015-07-24 2015-09-30 武汉德美涂料股份有限公司 Sand texture paint and production method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876143A (en) * 2012-08-31 2013-01-16 芜湖县双宝建材有限公司 Marble paint and preparation method thereof
CN104946033A (en) * 2015-07-24 2015-09-30 武汉德美涂料股份有限公司 Sand texture paint and production method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109455983A (en) * 2018-10-10 2019-03-12 舒城白桦林涂料有限公司 A kind of sand textured coating of preventing sand drop and preparation method thereof
CN112521859A (en) * 2019-09-17 2021-03-19 上海三银涂料科技股份有限公司 Sand textured coating for concrete building enclosure and preparation method thereof
CN113683346A (en) * 2020-05-18 2021-11-23 上海三银涂料科技股份有限公司 Water-based granite-like coating capable of preventing composite rock slices from warping and preparation method thereof
CN115521654A (en) * 2021-06-25 2022-12-27 上海三银涂料科技股份有限公司 Sand-wall-shaped building coating and application thereof

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Application publication date: 20170503