CN104046183B - Water-water multi-color lacquer - Google Patents
Water-water multi-color lacquer Download PDFInfo
- Publication number
- CN104046183B CN104046183B CN201410226171.6A CN201410226171A CN104046183B CN 104046183 B CN104046183 B CN 104046183B CN 201410226171 A CN201410226171 A CN 201410226171A CN 104046183 B CN104046183 B CN 104046183B
- Authority
- CN
- China
- Prior art keywords
- water
- powder
- color lacquer
- defoamer
- model
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of water-water multi-color lacquer, comprise the raw material of following weight part: base just paints: Vltra tears 0.6-1, propylene glycol 1.5-2.5, film coalescence aid 1.3-2, wetting dispersing agent 0.3-0.5, defoamer 0.2-0.3, pH value conditioning agent 0.1-0.2, sanitas 0.2-0.3, nano titanium diboride 1.5-2.5,4000 order kaolin 15-20, organosilicon crylic acid latex 25-35, high viscosity defoamer 0.2-0.3, stablizer 0.2-0.3, Tourmaline powder 8-12, bamboo charcoal powder 3-6, composite nano powder 5-10; Protection glue: water 25-38, trisodium phosphate 0.2-0.3, calcium lignin sulphonate 0.15-0.25, protection rubber powder 1.5-2; Outsourcing water: organosilicon crylic acid latex 18-23, Nitrocellulose 0.4-0.8, film coalescence aid 1-2, propylene glycol 1-2, sanitas 0.1-0.2, pH value conditioning agent 0.1-0.2, thickening material 0.3-0.8, stablizer 0.2-0.3.Can not be there is floating layer in water-water multi-color lacquer of the present invention, bleeding phenomenon has good application property in storage process.
Description
Technical field
The present invention relates to a kind of water-water multi-color lacquer, belong to building coating technical field.
Background technology
Water-water multi-color lacquer is the decorative effect of a kind of energy reduction marble true to nature, grouan, and because quality is light, being specially adapted to the interior/exterior decoration of all kinds of buildings, is the economical alternative of high-grade stone.But, easily there is floating layer, the problem of bleeding in current most water-water multi-color lacquer less stable, impact construction and decorative effect.
Summary of the invention
Object of the present invention, in order to solve the defect existed in prior art, provides one to solve floating layer, the water-water multi-color lacquer of bleeding problem.
In order to achieve the above object, the present invention adopts following technical scheme:
A kind of water-water multi-color lacquer, comprises the raw material of following weight part:
Base just paints: Vltra tears 0.6-1, propylene glycol 1.5-2.5, film coalescence aid 1.3-2, wetting dispersing agent 0.3-0.5, defoamer 0.2-0.3, pH value conditioning agent 0.1-0.2, sanitas 0.2-0.3, nano titanium diboride 1.5-2.5,4000 order kaolin 15-20, organosilicon crylic acid latex 25-35, high viscosity defoamer 0.2-0.3, stablizer 0.2-0.3, Tourmaline powder 8-12, bamboo charcoal powder 3-6, composite nano powder 5-10;
Protection glue: water 25-38, trisodium phosphate 0.2-0.3, calcium lignin sulphonate 0.15-0.25, protection rubber powder 1.5-2;
Outsourcing water: organosilicon crylic acid latex 18-23, Nitrocellulose 0.4-0.8, film coalescence aid 1-2, propylene glycol 1-2, sanitas 0.1-0.2, pH value conditioning agent 0.1-0.2, thickening material 0.3-0.8, stablizer 0.2-0.3.
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 5-10:4-8:3-6, mixes, and 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieve; (2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add the diallyl dimethyl ammoniumchloride of sodium polystyrene sulfonate, the trolamine of 3-5%, the citric acid of 1.5-2.5%, the tripoly phosphate sodium STPP of 2-3% and the 3-6% being equivalent to suspension weight 4-8% again, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries; (3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2-3 times amount, add the nano zinc powder of tetraethoxy, the vinyltriethoxysilane of 5-10%, the polyvinylpyrrolidone of 3-6%, the tannic acid of 2-4% and the 1-3% being equivalent to mixed solution weight 15-20%, ultrasonic disperse 20-30min, then by acetic acid or ammoniacal liquor adjust ph to 4-5, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries; (4) by step (3) dry after powder dispersion in 2-3 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 80-90 DEG C is warming up under nitrogen protection; add the methyl methacrylate, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1% that are equivalent to mixed solution weight 10-15%; stir 1-2h; filter; washing, dries.
Described wetting dispersing agent is that Changfeng Chemical Plant, Shanghai produces, and model is CF5564.
Described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028.
Described sanitas is that Nantong Han Tai Chemical Co., Ltd. produces, and model is TF-1.
Described high viscosity defoamer is that Nantong Han Tai Chemical Co., Ltd. produces, and model is T-607.
Described stablizer is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is ST-3.
Described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-2038.
Described protection rubber powder is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is T110.
Described pH value conditioning agent is selected from the one in 2-amino-2-methyl-1-propanol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
Described film coalescence aid is selected from the one of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester kind.
The present invention has following advantage than prior art: this formula is on original formula basis; at base paint; appropriate stablizer is added respectively in the link of protection glue and outsourcing water; effectively overcome the floating layer of water-water multi-color lacquer; bleeding problem; substantially increase its stability in storage, and do not affect decorative effect and the application property of water-water multi-color lacquer.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Water-water multi-color lacquer is configured by the raw material of following weight part and forms:
Base just paints: Vltra tears 0.6, propylene glycol 1.5, film coalescence aid 1.3, wetting dispersing agent 0.3, defoamer 0.2, pH value conditioning agent 0.1, sanitas 0.2, nano titanium diboride 1.5,4000 order kaolin 15, organosilicon crylic acid latex 25, high viscosity defoamer 0.2, stablizer 0.2, Tourmaline powder 8, bamboo charcoal powder 3, composite nano powder 5;
Protection glue: water 25, trisodium phosphate 0.2, calcium lignin sulphonate 0.15, protection rubber powder 1.5;
Outsourcing water: organosilicon crylic acid latex 18, Nitrocellulose 0.4, film coalescence aid 1, propylene glycol 1, sanitas 0.1, pH value conditioning agent 0.1, thickening material 0.3, stablizer 0.2.
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 7:5:3, mixes, and 850 DEG C of calcining 1.5h, are cooled to room temperature, are ground into nano-powder, sieve; (2) powder after sieving adds water and makes the suspension that concentration is 50%, add again be equivalent to suspension weight 6% sodium polystyrene sulfonate, 4% trolamine, the citric acid of 2%, the tripoly phosphate sodium STPP of 2.5% and 4% diallyl dimethyl ammoniumchloride, 3500rpm speed lapping 0.5h, filter, washing, dries; (3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2.5 times amount, add be equivalent to mixed solution weight 18% tetraethoxy, 7% vinyltriethoxysilane, the polyvinylpyrrolidone of 5%, the tannic acid of 3% and 2% nano zinc powder, ultrasonic disperse 20-30min, then by acetic acid or ammoniacal liquor adjust ph to 4.5, be heated to 75 DEG C, stir 1h, filter, washing, dries; (4) by step (3) dry after powder dispersion in 2 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 90 DEG C are warming up under nitrogen protection; add be equivalent to mixed solution weight 10% methyl methacrylate, 10% vinylformic acid, the vinylbenzene of 8%, maleic anhydride, the Vinylstyrene of 3%, the benzoyl peroxide of 0.6% of 7%; stir 1h; filter; washing, dries.
Embodiment 2
Water-water multi-color lacquer is configured by the raw material of following weight part and forms:
Base just paints: Vltra tears 0.8, propylene glycol 2, film coalescence aid 1.6, wetting dispersing agent 0.4, defoamer 0.25, pH value conditioning agent 0.15, sanitas 0.25, nano titanium diboride 2,4000 order kaolin 18, organosilicon crylic acid latex 30, high viscosity defoamer 0.25, stablizer 0.25, Tourmaline powder 10, bamboo charcoal powder 4, composite nano powder 8;
Protection glue: water 32, trisodium phosphate 0.25, calcium lignin sulphonate 0.2, protection rubber powder 1.8;
Outsourcing water: organosilicon crylic acid latex 20, Nitrocellulose 0.6, film coalescence aid 1.5, propylene glycol 1.5, sanitas 0.15, pH value conditioning agent 0.15, thickening material 0.6, stablizer 0.25.
The preparation method of composite nano powder is with embodiment 1.
Embodiment 3
Water-water multi-color lacquer is configured by the raw material of following weight part and forms:
Base just paints: Vltra tears 1, propylene glycol 2.5, film coalescence aid 2, wetting dispersing agent 0.5, defoamer 0.3, pH value conditioning agent 0.2, sanitas 0.3, nano titanium diboride 2.5,4000 order kaolin 20, organosilicon crylic acid latex 35, high viscosity defoamer 0.3, stablizer 0.3, Tourmaline powder 12, bamboo charcoal powder 6, composite nano powder 10;
Protection glue: water 38, trisodium phosphate 0.3, calcium lignin sulphonate 0.25, protection rubber powder 2;
Outsourcing water: organosilicon crylic acid latex 23, Nitrocellulose 0.8, film coalescence aid 2, propylene glycol 2, sanitas 0.2, pH value conditioning agent 0.2, thickening material 0.8, stablizer 0.3.
The preparation method of composite nano powder is with embodiment 1.
The water-water multi-color lacquer that above-described embodiment obtains meets industry service requirements, and in storage process, floating layer can not occur, and bleeding phenomenon has good application property.The performance test results is as shown in the table:
Claims (7)
1. a water-water multi-color lacquer, is characterized in that, comprises the raw material of following weight part:
Base just paints: Vltra tears 0.6-1, propylene glycol 1.5-2.5, film coalescence aid 1.3-2, wetting dispersing agent 0.3-0.5, defoamer 0.2-0.3, pH value regulator 0.1-0.2, sanitas 0.2-0.3, nano titanium diboride 1.5-2.5,4000 order kaolin 15-20, organosilicon crylic acid latex 25-35, high viscosity defoamer 0.2-0.3, stablizer 0.2-0.3,2-5, Tourmaline powder 8-12, bamboo charcoal powder 3-6, composite nano powder 5-10; Described high viscosity defoamer is that Nantong Han Tai Chemical Co., Ltd. produces, and model is T-607; Described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028;
Protection glue: water 25-38, trisodium phosphate 0.2-0.3, calcium lignin sulphonate 0.15-0.25, protection rubber powder 1.5-2;
Outsourcing water: organosilicon crylic acid latex 18-23, Nitrocellulose 0.4-0.8, film coalescence aid 1-2, propylene glycol 1-2, sanitas 0.1-0.2, pH value regulator 0.1-0.2, thickening material 0.3-0.8, stablizer 0.2-0.3;
Described stablizer is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is ST-3;
The preparation method of described composite nano powder is as follows:
(1) take illite, six ring stone and sericites by weight 5-10:4-8:3-6, mix, 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieve;
(2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add the diallyl dimethyl ammoniumchloride of sodium polystyrene sulfonate, the trolamine of 3-5%, the citric acid of 1.5-2.5%, the tripoly phosphate sodium STPP of 2-3% and the 3-6% being equivalent to suspension weight 4-8% again, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries;
(3) powder dispersion after step (2) being dried is in 85% ethanolic soln of 2-3 times amount, add the nano zinc powder of tetraethoxy, the vinyltriethoxysilane of 5-10%, the polyvinylpyrrolidone of 3-6%, the tannic acid of 2-4% and the 1-3% being equivalent to mixed solution weight 15-20%, ultrasonic disperse 20-30min, then use acetic acid adjust ph to 4-5, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries;
(4) by step (3) dry after powder dispersion in 2-3 times amount butylacetate and dimethylbenzene equal-volume mixing solutions in; 80-90 DEG C is warming up under nitrogen protection; add the methyl methacrylate, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1% that are equivalent to mixed solution weight 10-15%; stir 1-2h; filter; washing, dries.
2. water-water multi-color lacquer according to claim 1, is characterized in that, described wetting dispersing agent is that Changfeng Chemical Plant, Shanghai produces, and model is CF5564.
3. water-water multi-color lacquer according to claim 1, is characterized in that, described sanitas is that Nantong Han Tai Chemical Co., Ltd. produces, and model is TF-1.
4. water-water multi-color lacquer according to claim 1, is characterized in that, described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-2038.
5. water-water multi-color lacquer according to claim 1, is characterized in that, described protection rubber powder is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is T110.
6. water-water multi-color lacquer according to claim 1, is characterized in that, described pH value regulator is selected from the one in 2-amino-2-methyl-1-propanol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
7. water-water multi-color lacquer according to claim 1, it is characterized in that, described film coalescence aid is selected from the one in ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410226171.6A CN104046183B (en) | 2014-05-23 | 2014-05-23 | Water-water multi-color lacquer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410226171.6A CN104046183B (en) | 2014-05-23 | 2014-05-23 | Water-water multi-color lacquer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104046183A CN104046183A (en) | 2014-09-17 |
| CN104046183B true CN104046183B (en) | 2016-03-30 |
Family
ID=51499597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410226171.6A Active CN104046183B (en) | 2014-05-23 | 2014-05-23 | Water-water multi-color lacquer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104046183B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086676A (en) * | 2015-09-01 | 2015-11-25 | 天长市开林化工有限公司 | Uniform-texture bamboo-fiber-added antibacterial latex paint and preparation method therefor |
| BR102015032910B1 (en) | 2015-12-29 | 2021-03-09 | Companhia Nitro Química Brasileira | process of obtaining a colloidal dispersion, colloidal dispersion and its use |
| CN106189820A (en) * | 2016-08-11 | 2016-12-07 | 北京佑琳生科技有限公司 | A kind of radioprotective water-water multi-color |
| CN107540277B (en) * | 2017-08-17 | 2020-06-05 | 无棣隆翔宇涂料有限公司 | Environment-friendly stone-like paint coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3038869A (en) * | 1959-08-28 | 1962-06-12 | Goodyear Tire & Rubber | Multi-color coating composition |
| CN102391751A (en) * | 2011-10-13 | 2012-03-28 | 沈阳顺风新城建筑材料有限公司 | Water-in-water multicolor paint and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53108127A (en) * | 1977-03-04 | 1978-09-20 | Kansai Paint Co Ltd | Water-based coating with multi-color effect |
| JPS555965A (en) * | 1978-06-29 | 1980-01-17 | Kowa Kagaku Kogyo Kk | Preparation of multi-color paint |
| JPH07247450A (en) * | 1994-03-11 | 1995-09-26 | Internatl Paint Kk | Aqueous multi-color coating composition |
| KR100901141B1 (en) * | 2009-02-12 | 2009-06-04 | 삼한건업(주) | A functional multi-color paint composition of water in water-paint type and manufacturing method thereof |
| KR101037333B1 (en) * | 2011-03-15 | 2011-05-26 | 삼한건업(주) | Manufacturing method of multi-color paint composition having improved antibiosis, contamination resistance, scratch resistance and uv resistnace, multi-color paint composition manufactured by the same and coating method using the same |
-
2014
- 2014-05-23 CN CN201410226171.6A patent/CN104046183B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3038869A (en) * | 1959-08-28 | 1962-06-12 | Goodyear Tire & Rubber | Multi-color coating composition |
| CN102391751A (en) * | 2011-10-13 | 2012-03-28 | 沈阳顺风新城建筑材料有限公司 | Water-in-water multicolor paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 内外墙多彩涂料的概况及研究进展;蔡青青等;《涂料工业》;20101001;第40卷(第10期);第76-79页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104046183A (en) | 2014-09-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101157812B (en) | Aqueous texture wallpaper paint and method for making same | |
| CN102815888B (en) | Coating with characteristics of ceramic color and quartz sand texture, preparation method and application thereof | |
| CN104046183B (en) | Water-water multi-color lacquer | |
| CN104692707A (en) | Functional real stone paint building exterior wall coating material and preparation method thereof | |
| CN101492577A (en) | Process for producing watersoluble stone design imitating color slice and use scheme | |
| CN104946033A (en) | Sand texture paint and production method thereof | |
| CN103627272B (en) | Liquid rock particles of artificial granite sand textured coating | |
| CN110903721A (en) | Colorful sand-in-water coating and preparation method thereof | |
| CN101638544A (en) | Coating for forming flexible imitation marble facing and preparation method thereof | |
| CN104250499A (en) | Rough granite-simulative water-in-water colorful textural paint and preparation method thereof | |
| CN108841274B (en) | Preparation method and construction process of multi-dimensional stone-like paint | |
| CN102617071A (en) | High-gloss real stone lacquer and marble simulation lacquer | |
| CN105199525A (en) | Organic-inorganic hybridization multicolor coating material and preparation method thereof | |
| CN104046182B (en) | The true mineral varnish of quick-dry type | |
| CN106243880A (en) | A kind of environment-friendly type high life true mineral varnish of anti-soil | |
| CN111057407B (en) | Construction process of real stone paint | |
| CN104449167A (en) | Alkaline-resistant anti-cracking paint for exterior wall | |
| CN104046184B (en) | Water-based sliver multi-color lacquer | |
| CN104559591A (en) | Environment-friendly water-based paint for aluminum profile production and preparation method thereof | |
| CN106752595A (en) | A kind of stone imitation material | |
| CN103289497A (en) | High-efficient spraying maishi paint and preparation method thereof | |
| CN106336749B (en) | A kind of resistant lacquer | |
| CN111117331A (en) | Colorful water-based paint with fluorescent effect | |
| CN104046185B (en) | Texture paint | |
| CN104073070A (en) | Ecological fiber emulsion paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180720 Address after: No. 5, Sha Ming Road, Hong District, Liaoning Province, Shenyang, Liaoning Patentee after: Shenyang Jin Haiyun paint Co. Address before: 241100 Sunshine Avenue, Wuhu County Economic Development Zone, Wuhu, Anhui Patentee before: Wuhu Lang Run novel material company limited |