CN104046183A - Water-in-water multi-color paint - Google Patents
Water-in-water multi-color paint Download PDFInfo
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- CN104046183A CN104046183A CN201410226171.6A CN201410226171A CN104046183A CN 104046183 A CN104046183 A CN 104046183A CN 201410226171 A CN201410226171 A CN 201410226171A CN 104046183 A CN104046183 A CN 104046183A
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Abstract
The invention discloses a water-in-water multi-color paint, which comprises the following raw materials by weight: a base paint containing 0.6-1 part of hydroxypropyl methyl cellulose, 1.5-2.5 parts of propylene glycol, 1.3-2 parts of a coalescent, 0.3-0.5 part of a wetting and dispersing agent, 0.2-0.3 part of a defoaming agent, 0.1-0.2 part of a pH regulator, 0.2-0.3 part of a preservative, 1.5-2.5 of nano titanium diboride, 15-20 parts of kaolin of 4000 mesh, 25-35 parts of silicone acrylate emulsion, 0.2-0.3 part of a high-viscosity defoaming agent, 0.2-0.3 part of a stabilizer, 8-12 parts of tourmaline powder, 3-6 parts of charcoal powder and 5-10 parts of nanocomposite powder; a protection glue water containing 25-38 parts of water, 0.2-0.3 part of sodium pyrophosphate, 0.15-0.25 part of lignin sulfonic acid calcium and 1.5-2 parts of a protective rubber powder; and coating water containing 18-23 parts of silicone acrylic emulsion, 0.4-0.8 part of nitro cellulose, 1-2 parts of a coalescent, 1-2 parts of propylene glycol, 0.1-0.2 part of a preservative, 0.1-0.2 part of a pH regulator, 0.3-0.8 part of a thickener and 0.2-0.3 part of a stabilizer. The water-in-water multi-color paint provided by the invention does not generate the phenomena of floating layer and color bleeding during storage, and has good application property.
Description
Technical field
The present invention relates to a kind of water bag water multi-color lacquer, belong to building coating technical field.
Background technology
Water bag water multi-color lacquer is the decorative effect of a kind of energy reduction marble true to nature, grouan, and because quality is light, the indoor and outdoor that is specially adapted to all kinds of buildingss is decorated, and is the economical alternative of high-grade stone material.But current most water bag water multi-color lacquer less stable, is prone to floating layer, the problem of bleeding, impact construction and decorative effect.
Summary of the invention
Object of the present invention, in order to solve the defect existing in prior art, provides one to solve floating layer, the water bag water multi-color lacquer of bleeding problem.
In order to achieve the above object, the present invention adopts following technical scheme:
A kind of water bag water multi-color lacquer, comprises the raw material of following weight part:
Base just paints: Vltra tears 0.6-1, propylene glycol 1.5-2.5, film coalescence aid 1.3-2, wetting dispersing agent 0.3-0.5, defoamer 0.2-0.3, pH value conditioning agent 0.1-0.2, sanitas 0.2-0.3, nano titanium diboride 1.5-2.5,4000 order kaolin 15-20, organosilicon crylic acid latex 25-35, high viscosity defoamer 0.2-0.3, stablizer 0.2-0.3, Tourmaline powder 8-12, bamboo charcoal powder 3-6, composite nano powder 5-10;
Protection glue: water 25-38, trisodium phosphate 0.2-0.3, calcium lignin sulphonate 0.15-0.25, protection rubber powder 1.5-2;
Outsourcing water: organosilicon crylic acid latex 18-23, Nitrocellulose 0.4-0.8, film coalescence aid 1-2, propylene glycol 1-2, sanitas 0.1-0.2, pH value conditioning agent 0.1-0.2, thickening material 0.3-0.8, stablizer 0.2-0.3.
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 5-10:4-8:3-6, mixes, and 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieves; (2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add again and be equivalent to the sodium polystyrene sulfonate of suspension weight 4-8%, the trolamine of 3-5%, citric acid, the tripoly phosphate sodium STPP of 2-3% and the diallyl dimethyl ammoniumchloride of 3-6% of 1.5-2.5%, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries; (3) powder after step (2) is dried is scattered in 85% ethanolic soln that 2-3 doubly measures, add and be equivalent to the tetraethoxy of mixed solution weight 15-20%, the vinyltriethoxysilane of 5-10%, polyvinylpyrrolidone, the tannic acid of 2-4% and the nano zinc powder of 1-3% of 3-6%, ultrasonic dispersion 20-30min, then regulate pH value to 4-5 with acetic acid or ammoniacal liquor, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries; (4) powder after step (3) is dried be scattered in that 2-3 doubly measures butylacetate and dimethylbenzene equal-volume mixing solutions in; under nitrogen protection, be warming up to 80-90 DEG C; add and be equivalent to the methyl methacrylate of mixed solution weight 10-15%, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1%; stir 1-2h; filter; washing, dries.
Described wetting dispersing agent is that Changfeng Chemical Plant, Shanghai produces, and model is CF5564.
Described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028.
Described sanitas is that Nantong Han Tai Chemical Co., Ltd. produces, and model is TF-1.
Described high viscosity defoamer is that Nantong Han Tai Chemical Co., Ltd. produces, and model is T-607.
Described stablizer is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is ST-3.
Described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-2038.
Described protection rubber powder is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is T110.
Described pH value conditioning agent is selected from the one in 2-amino-2-methyl-1-propanol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
Described film coalescence aid is selected from the one of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester kind.
The present invention has following advantage than prior art: this formula is on original formula basis; at base paint; in the link of protection glue and outsourcing water, add respectively appropriate stablizer; effectively overcome the floating layer of water bag water multi-color lacquer; bleeding problem; greatly improve its stability in storage, and do not affected decorative effect and the application property of water bag water multi-color lacquer.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
Water bag water multi-color lacquer is formed by the raw material configuration of following weight part:
Base just paints: Vltra tears 0.6, propylene glycol 1.5, film coalescence aid 1.3, wetting dispersing agent 0.3, defoamer 0.2, pH value conditioning agent 0.1, sanitas 0.2, nano titanium diboride 1.5,4000 order kaolin 15, organosilicon crylic acid latex 25, high viscosity defoamer 0.2, stablizer 0.2, Tourmaline powder 8, bamboo charcoal powder 3, composite nano powder 5;
Protection glue: water 25, trisodium phosphate 0.2, calcium lignin sulphonate 0.15, protection rubber powder 1.5;
Outsourcing water: organosilicon crylic acid latex 18, Nitrocellulose 0.4, film coalescence aid 1, propylene glycol 1, sanitas 0.1, pH value conditioning agent 0.1, thickening material 0.3, stablizer 0.2.
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 7:5:3, mixes, and 850 DEG C of calcining 1.5h, are cooled to room temperature, are ground into nano-powder, sieve; (2) to add water and make concentration be 50% suspension to the powder after sieving, add again sodium polystyrene sulfonate, 4% trolamine, 2% the citric acid, 2.5% tripoly phosphate sodium STPP and 4% the diallyl dimethyl ammoniumchloride that are equivalent to suspension weight 6%, 3500rpm speed lapping 0.5h, filter, washing, dries; (3) powder after step (2) oven dry is scattered in 85% ethanolic soln of 2.5 times of amounts, add tetraethoxy, 7% vinyltriethoxysilane, 5% the polyvinylpyrrolidone, 3% tannic acid and 2% the nano zinc powder that are equivalent to mixed solution weight 18%, ultrasonic dispersion 20-30min, then regulate pH value to 4.5 with acetic acid or ammoniacal liquor, be heated to 75 DEG C, stir 1h, filter, washing, dries; (4) by step (3) dry after powder be scattered in 2 times of amounts butylacetate and dimethylbenzene equal-volume mixing solutions in; under nitrogen protection, be warming up to 90 DEG C; add and be equivalent to the methyl methacrylate of mixed solution weight 10%, 10% vinylformic acid, 8% vinylbenzene, 7% maleic anhydride, 3% Vinylstyrene, 0.6% benzoyl peroxide; stir 1h; filter; washing, dries.
Embodiment 2
Water bag water multi-color lacquer is formed by the raw material configuration of following weight part:
Base just paints: Vltra tears 0.8, propylene glycol 2, film coalescence aid 1.6, wetting dispersing agent 0.4, defoamer 0.25, pH value conditioning agent 0.15, sanitas 0.25, nano titanium diboride 2,4000 order kaolin 18, organosilicon crylic acid latex 30, high viscosity defoamer 0.25, stablizer 0.25, Tourmaline powder 10, bamboo charcoal powder 4, composite nano powder 8;
Protection glue: water 32, trisodium phosphate 0.25, calcium lignin sulphonate 0.2, protection rubber powder 1.8;
Outsourcing water: organosilicon crylic acid latex 20, Nitrocellulose 0.6, film coalescence aid 1.5, propylene glycol 1.5, sanitas 0.15, pH value conditioning agent 0.15, thickening material 0.6, stablizer 0.25.
The preparation method of composite nano powder is with embodiment 1.
Embodiment 3
Water bag water multi-color lacquer is formed by the raw material configuration of following weight part:
Base just paints: Vltra tears 1, propylene glycol 2.5, film coalescence aid 2, wetting dispersing agent 0.5, defoamer 0.3, pH value conditioning agent 0.2, sanitas 0.3, nano titanium diboride 2.5,4000 order kaolin 20, organosilicon crylic acid latex 35, high viscosity defoamer 0.3, stablizer 0.3, Tourmaline powder 12, bamboo charcoal powder 6, composite nano powder 10;
Protection glue: water 38, trisodium phosphate 0.3, calcium lignin sulphonate 0.25, protection rubber powder 2;
Outsourcing water: organosilicon crylic acid latex 23, Nitrocellulose 0.8, film coalescence aid 2, propylene glycol 2, sanitas 0.2, pH value conditioning agent 0.2, thickening material 0.8, stablizer 0.3.
The preparation method of composite nano powder is with embodiment 1.
The water bag water multi-color lacquer that above-described embodiment obtains meets industry service requirements, and floating layer can not occur in storage process, and bleeding phenomenon, has good application property.The performance test results is as shown in the table:
Claims (10)
1. a water bag water multi-color lacquer, is characterized in that, comprises the raw material of following weight part:
Base just paints: Vltra tears 0.6-1, propylene glycol 1.5-2.5, film coalescence aid 1.3-2, wetting dispersing agent 0.3-0.5, defoamer 0.2-0.3, pH value conditioning agent 0.1-0.2, sanitas 0.2-0.3, nano titanium diboride 1.5-2.5,4000 order kaolin 15-20, organosilicon crylic acid latex 25-35, high viscosity defoamer 0.2-0.3, stablizer 0.2-0.3,2-5, Tourmaline powder 8-12, bamboo charcoal powder 3-6, composite nano powder 5-10;
Protection glue: water 25-38, trisodium phosphate 0.2-0.3, calcium lignin sulphonate 0.15-0.25, protection rubber powder 1.5-2;
Outsourcing water: organosilicon crylic acid latex 18-23, Nitrocellulose 0.4-0.8, film coalescence aid 1-2, propylene glycol 1-2, sanitas 0.1-0.2, pH value conditioning agent 0.1-0.2, thickening material 0.3-0.8, stablizer 0.2-0.3;
The preparation method of described composite nano powder is as follows: (1) takes illite, six ring stone and sericites by weight 5-10:4-8:3-6, mixes, and 820-880 DEG C of calcining 1-2h, is cooled to room temperature, is ground into nano-powder, sieves; (2) powder after sieving adds water and makes the suspension that concentration is 40-50%, add again and be equivalent to the sodium polystyrene sulfonate of suspension weight 4-8%, the trolamine of 3-5%, citric acid, the tripoly phosphate sodium STPP of 2-3% and the diallyl dimethyl ammoniumchloride of 3-6% of 1.5-2.5%, 3000-4000rpm speed lapping 0.5-1h, filter, washing, dries; (3) powder after step (2) is dried is scattered in 85% ethanolic soln that 2-3 doubly measures, add and be equivalent to the tetraethoxy of mixed solution weight 15-20%, the vinyltriethoxysilane of 5-10%, polyvinylpyrrolidone, the tannic acid of 2-4% and the nano zinc powder of 1-3% of 3-6%, ultrasonic dispersion 20-30min, then regulate pH value to 4-5 with acetic acid or ammoniacal liquor, be heated to 70-80 DEG C, stir 1-2h, filter, washing, dries; (4) powder after step (3) is dried be scattered in that 2-3 doubly measures butylacetate and dimethylbenzene equal-volume mixing solutions in; under nitrogen protection, be warming up to 80-90 DEG C; add and be equivalent to the methyl methacrylate of mixed solution weight 10-15%, the vinylformic acid of 8-12%, the vinylbenzene of 5-10%, the maleic anhydride of 4-8%, the Vinylstyrene of 3-6%, the benzoyl peroxide of 0.5-1%; stir 1-2h; filter; washing, dries.
2. water bag water multi-color lacquer according to claim 1, is characterized in that, described wetting dispersing agent is that Changfeng Chemical Plant, Shanghai produces, and model is CF5564.
3. water bag water multi-color lacquer according to claim 1, is characterized in that, described defoamer is that Changfeng Chemical Plant, Shanghai produces, and model is CF1028.
4. water bag water multi-color lacquer according to claim 1, is characterized in that, described sanitas is that Nantong Han Tai Chemical Co., Ltd. produces, and model is TF-1.
5. water bag water multi-color lacquer according to claim 1, is characterized in that, described high viscosity defoamer is that Nantong Han Tai Chemical Co., Ltd. produces, and model is T-607.
6. water bag water multi-color lacquer according to claim 1, is characterized in that, described stablizer is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is ST-3.
7. water bag water multi-color lacquer according to claim 1, is characterized in that, described thickening material is that Changfeng Chemical Plant, Shanghai produces, and model is T-2038.
8. water bag water multi-color lacquer according to claim 1, is characterized in that, described protection rubber powder is that Shanghai Ju Wei coatings additive(s) company limited produces, and model is T110.
9. water bag water multi-color lacquer according to claim 1, is characterized in that, described pH value conditioning agent is selected from the one in 2-amino-2-methyl isophthalic acid-propyl alcohol, ammoniacal liquor, trolamine, diethanolamine, sodium hydroxide, sodium bicarbonate.
10. water bag water multi-color lacquer according to claim 1, it is characterized in that, described film coalescence aid is selected from the one of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, Diethylene glycol monopropyl ether, Triethylene glycol ethyl ether, propylene glycol monomethyl ether, propylene glycol phenylate, ethylene glycol phenyl ether, Lauryl Alcohol ester kind.
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| CN201410226171.6A CN104046183B (en) | 2014-05-23 | 2014-05-23 | Water-water multi-color lacquer |
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| CN201410226171.6A CN104046183B (en) | 2014-05-23 | 2014-05-23 | Water-water multi-color lacquer |
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| CN104046183B CN104046183B (en) | 2016-03-30 |
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Cited By (4)
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| CN105086676A (en) * | 2015-09-01 | 2015-11-25 | 天长市开林化工有限公司 | Uniform-texture bamboo-fiber-added antibacterial latex paint and preparation method therefor |
| CN106189820A (en) * | 2016-08-11 | 2016-12-07 | 北京佑琳生科技有限公司 | A kind of radioprotective water-water multi-color |
| WO2017113000A1 (en) * | 2015-12-29 | 2017-07-06 | Companhia Nitro Química Brasileira | Method for obtaining a colloidal dispersion, colloidal dispersion and use thereof |
| CN107540277A (en) * | 2017-08-17 | 2018-01-05 | 储旭 | The true mineral varnish coating of environmental protection |
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| CN107540277A (en) * | 2017-08-17 | 2018-01-05 | 储旭 | The true mineral varnish coating of environmental protection |
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| CN104046183B (en) | 2016-03-30 |
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Effective date of registration: 20180720 Address after: No. 5, Sha Ming Road, Hong District, Liaoning Province, Shenyang, Liaoning Patentee after: Shenyang Jin Haiyun paint Co. Address before: 241100 Sunshine Avenue, Wuhu County Economic Development Zone, Wuhu, Anhui Patentee before: Wuhu Lang Run novel material company limited |
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