CN107540277A - The true mineral varnish coating of environmental protection - Google Patents
The true mineral varnish coating of environmental protection Download PDFInfo
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- CN107540277A CN107540277A CN201710705773.3A CN201710705773A CN107540277A CN 107540277 A CN107540277 A CN 107540277A CN 201710705773 A CN201710705773 A CN 201710705773A CN 107540277 A CN107540277 A CN 107540277A
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Abstract
The invention discloses a kind of true mineral varnish coating of environmental protection, it is prepared by following raw materials：0.05 0.15 parts by weight hydroxyethyl celluloses；The pentanediol mono isobutyrate of 0.4 1.2 parts by weight, 2,2,4 trimethyl 1,3；0.2 0.8 parts by weight ethylene glycol；The propyl alcohol of 0.05 0.15 parts by weight, 2 amino, 2 methyl 1；15 30 parts by weight silicone acrylic emulsions；50 100 parts by weight natural colour sands；24 parts by weight slivers；0.3 1.2 parts by weight glycol monoethyl ethers；0.3 1.2 parts by weight ethylene glycol monobutyl ethers；5 10 parts by weight water.True mineral varnish appearance colour of the present invention is gorgeous, water-fast, alkali resistance is good, and cohesive force is strong, and ageing resistance is strong, suitable for a variety of basal planes, and effectively building can be protected not corroded by adverse circumstances, extend its service life.
Description
Technical field
The present invention relates to a kind of coating, more particularly to a kind of true mineral varnish coating of environmental protection.
Background technology
True mineral varnish is the coating that a kind of decorative effect exactly likes marble, granite.The main natural stone for using a variety of colors
Powder is formulated, applied to the imitative stone effect of external wall, therefore also known as liquid stone.
Building after true mineral varnish finishing, has natural real natural colour, gives graceful, harmonious, serious U.S.
Sense, it is suitable for the indoor and outdoor decoration of all kinds of buildings.Particularly decorated on curved-surface building thing, it is vivid, there is a kind of recurrence
Natural effect.True mineral varnish has fire prevention, waterproof, acid and alkali-resistance, anti-pollution.It is nontoxic, tasteless, bonding force is strong, it is will never fade wait spy
Point, can effectively prevent extraneous adverse circumstances from corroding building, extend life-span of building, due to true mineral varnish possess it is good
Adhesive force and freeze-thaw resistance property, therefore be adapted to use in cold district.
The advantages of true mineral varnish:
It is ornamental strong.Natural colour, there is the texture of lithotome, various line lattice designs, various three-dimensional shapes can be provided
Pattern structure, can visually show the elegance of whole building and serious U.S., be dry-fasten stone on external wall best substitute.
It is widely applicable.Available for a variety of basal planes such as cement brick wall, foam, gypsum, aluminium sheet, glass, and can be with building
Any application of moulding.
Aqueous, environmental protective.Asepsis environment-protecting, meet requirement of the people to environmental protection.
Resistance to soiling is good.90% dirt is difficult to adhere to, as bright as new after rain drop erosion, and artificial cleaning is easier.
Service life is grown.The true mineral varnish service life of high-quality is 15 years.
Without potential safety hazard.Exterior wall will load upper kiloton added burden, serious threat to life property using stone material dry suspending.True stone
Paint materials 4-5 ㎏/㎡, only account for the 1/30 of stone material weight, adhesive force is strong, will not image-stone material integrally come off, effective guarantee safety.
The content of the invention
Inventor is by prolonged further investigation, after creative work is paid, technical problem to be solved：It is to carry
For a kind of true mineral varnish coating of environmental protection.
Specifically, it is achieved through the following technical solutions：
The true mineral varnish coating of environmental protection, by being prepared including following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
5-10 parts by weight water.
The true mineral varnish coating of environmental protection, by being prepared including following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
0.3-1.2 parts by weight glycol monoethyl ethers；
0.3-1.2 parts by weight ethylene glycol monobutyl ethers；
5-10 parts by weight water.
The true mineral varnish coating of environmental protection, by being prepared including following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
0.3-1.2 parts by weight glycol monoethyl ethers；
0.3-1.2 parts by weight ethylene glycol monobutyl ethers；
0.1-0.3 parts by weight defoamers；
0.1-0.3 parts by weight hydrophober；
0.1-0.3 parts by weight bactericide；
5-10 parts by weight water.
In the present invention,
Hydroxyethyl cellulose, No. CAS：9004-62-0.
2,2,4- trimethyl -1,3- pentanediol mono isobutyrates, No. CAS：25265-77-4.
2-amino-2-methyl-1-propanol, No. CAS：124-68-5.Addition in coating, it is possible to increase resistance to wiping properties and
Water resistance, in-tank corrosion and wink rust are reduced, effectively lowers coating smell.
Glycol monoethyl ether, No. CAS：109-86-4.
Ethylene glycol monobutyl ether, No. CAS：111-76-2.
Glycol monoethyl ether and ethylene glycol monobutyl ether, it is used as varnish quick dry agent and coating diluent in coatings industry, adds
It can make it easy to flow in coating, brush and levelling.
The silicone acrylic emulsion, it is to add the organic silicon monomer containing unsaturated bond with acrylic monomer suitably to help
Agent, the emulsion being polymerized by nucleocapsid cladding polymerization technique.Organosilicon fire-resistant, weatherability, chemical-resistant are combined,
High colour retention, pliability, the tack of hydrophobic, the low not v ulnerability of surface energy and acrylic resin.
The natural colour sand particle diameter is 20-100 mesh.The natural colour sand is that granularity is 80-100 mesh natural colour sand, granularity
For the mixture that 40-80 mesh natural colour sand and granularity are 20-40 mesh natural colour sands.Preferably, granularity is 80-100 mesh natural colors
The mass ratio that sand, granularity are 40-80 mesh natural colour sand and granularity is 20-40 mesh natural colour sands is (1-3)：(1-3)：(1-3).
The present invention environmentally friendly true mineral varnish coating can be prepared using this area conventional method, such as can will it is above-mentioned respectively
Raw material is uniformly mixed.
True mineral varnish appearance colour of the present invention is gorgeous, water-fast, alkali resistance is good, and cohesive force is strong, and ageing resistance is strong, fits
For a variety of basal planes, and effectively building can be protected not corroded by adverse circumstances, extend its service life.
Embodiment
80-100 mesh natural colour sands, provided by Lingshou County Tian Mei mineral products processings factory, color is yellow.
40-80 mesh natural colour sands, provided by Lingshou County Tian Mei mineral products processings factory, color is yellow.
20-40 mesh natural colour sands, provided by Lingshou County Tian Mei mineral products processings factory, color is yellow.
In embodiment 1-5, natural colour sand be granularity be 80-100 mesh natural colour sand, granularity be 40-80 mesh natural colour sand and
Granularity is the mixture of 20-40 mesh natural colour sands.Granularity is 80-100 mesh natural colour sand, granularity be 40-80 mesh natural colour sand and
Granularity is that the mass ratio of 20-40 mesh natural colour sands is 1：1：1.
In embodiment 1-5, sliver uses the 80-100 mesh golden yellow natural rocks that Lingshou County Ao Tai mineral products processings factory provides
Piece.
In embodiment 1-5, the silicone acrylic emulsion uses the SD-528 silicone acrylic emulsions of Nantong Shengda Chemical Co., Ltd.'s production,
It is esters of acrylic acid and water-based emulsion that organic silicon monomer graft copolymerization forms, film forming have higher gloss, preferable salt tolerant
Mist, alkali resistance, anti-corrosive properties, extremely strong adhesive force, water-tolerant, it is weather-proof excellent the features such as.It can be directly used for metal material
Anti-corrosion material, metallic paint, zinc rich paint, water-repellent paint, the finish paint of woodcare paint and various coating, high-grade exterior wall paint.
Silicone acrylic emulsion technical parameter：
| Project | Index | Project | Index |
| Outward appearance | Milky band blue light liquid | Solid content (wt%) | 48±1 |
| Glass transition temperature (Tg) | 15-25℃ | Viscosity (mpa.a) | 500-1500 |
| PH value (acid-base value) | 7.5-9.0 | Residual monomer (bromine number %) | ≤1.0 |
| Dilution stability | 20% aqueous solution passes through | Chemical stability (5% calcium chloride emulsion) | 1：2 without flocculation iso-metamorphism phenomenon |
| Mechanical stability | 4000r/min half an hour passes through | Freeze-thaw stability | 5 cycle through |
In embodiment 1-5, defoamer is that the German Bi Ke trades mark are BYK-024 aqueous defoamers.
In embodiment 1-5, hydrophober for watt gramBS1306CN organosilicon moisture repellents.
In embodiment 1-5, bactericide is ROHM AND HAASLXE bactericide.
Embodiment 1
The true mineral varnish coating of environmental protection, specific raw material are：
0.1 parts by weight hydroxyethyl cellulose；
0.8 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.5 parts by weight ethylene glycol；
0.1 parts by weight 2-amino-2-methyl-1-propanol；
20 parts by weight silicone acrylic emulsions；
90 parts by weight natural colour sands；
3 parts by weight slivers；
0.2 parts by weight defoamer；
0.2 parts by weight hydrophober；
0.2 parts by weight bactericide；
8 parts by weight water.
Above-mentioned each raw material is mixed, at room temperature, stirred 20 minutes with 600 revs/min of rotating speed, it is well mixed to can be prepared by this
The environmentally friendly true mineral varnish coating of invention.
The environmentally friendly true mineral varnish coating of the present invention is sprayed on mortar block plate, spray pressure is in 0.8Pa/cm2, spray gun bore is
8mm, muzzle are 60cm with metope distance, are sprayed twice, each coating thickness is 1mm, and paint film gross thickness is 2mm.
23 DEG C of temperature, humidity 65% conserves 14 days, then by JG/T24-2000《Synthetic resin emulsion sand wall-like building applies
Material》Carry out stain resistance, temperature-change resistance, the test of tensile bond strength and the test of test specimen immersion post-tensioning bond strength.
Test result：Stain resistance：It is 2 grades after 7 cyclic tests；Temperature-change resistance：12 secondary coatings start efflorescence, cracking,
Peel off, play drum, compared with standard edition, color starts to change；Adhesion strength standard state 1.0MPa, 0.5MPa after immersion.
Embodiment 2
The true mineral varnish coating of environmental protection, specific raw material are：
0.1 parts by weight hydroxyethyl cellulose；
0.8 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.5 parts by weight ethylene glycol；
0.1 parts by weight 2-amino-2-methyl-1-propanol；
20 parts by weight silicone acrylic emulsions；
90 parts by weight natural colour sands；
3 parts by weight slivers；
1 parts by weight glycol monoethyl ether；
0.2 parts by weight defoamer；
0.2 parts by weight hydrophober；
0.2 parts by weight bactericide；
8 parts by weight water.
Above-mentioned each raw material is mixed, at room temperature, stirred 20 minutes with 600 revs/min of rotating speed, it is well mixed to can be prepared by this
The environmentally friendly true mineral varnish coating of invention.
Method of testing is consistent with embodiment 1.
Stain resistance：It is 2 grades after 10 cyclic tests；Temperature-change resistance：15 secondary coatings start efflorescence, cracking, peeling, rise
Drum, compared with standard edition, color starts to change；Adhesion strength standard state 1.0MPa, 0.6MPa after immersion.
Embodiment 3
The true mineral varnish coating of environmental protection, specific raw material are：
0.1 parts by weight hydroxyethyl cellulose；
0.8 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.5 parts by weight ethylene glycol；
0.1 parts by weight 2-amino-2-methyl-1-propanol；
20 parts by weight silicone acrylic emulsions；
90 parts by weight natural colour sands；
3 parts by weight slivers；
1 parts by weight ethylene glycol monobutyl ether；
0.2 parts by weight defoamer；
0.2 parts by weight hydrophober；
0.2 parts by weight bactericide；
8 parts by weight water.
Above-mentioned each raw material is mixed, at room temperature, stirred 20 minutes with 600 revs/min of rotating speed, it is well mixed to can be prepared by this
The environmentally friendly true mineral varnish coating of invention.
Method of testing is consistent with embodiment 1.
Stain resistance：It is 2 grades after 12 cyclic tests；Temperature-change resistance：17 secondary coatings start efflorescence, cracking, peeling, rise
Drum, compared with standard edition, color starts to change；Adhesion strength standard state 1.0MPa, 0.6MPa after immersion.
Embodiment 4
The true mineral varnish coating of environmental protection, specific raw material are：
0.1 parts by weight hydroxyethyl cellulose；
0.8 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.5 parts by weight ethylene glycol；
0.1 parts by weight 2-amino-2-methyl-1-propanol；
20 parts by weight silicone acrylic emulsions；
90 parts by weight natural colour sands；
3 parts by weight slivers；
0.5 parts by weight glycol monoethyl ether；
0.5 parts by weight ethylene glycol monobutyl ether；
0.2 parts by weight defoamer；
0.2 parts by weight hydrophober；
0.2 parts by weight bactericide；
8 parts by weight water.
Above-mentioned each raw material is mixed, at room temperature, stirred 20 minutes with 600 revs/min of rotating speed, it is well mixed to can be prepared by this
The environmentally friendly true mineral varnish coating of invention.
Method of testing is consistent with embodiment 1.
Stain resistance：It is 2 grades after 16 cyclic tests；Temperature-change resistance：27 secondary coatings start efflorescence, cracking, peeling, rise
Drum, compared with standard edition, color starts to change；Adhesion strength standard state 1.0MPa, 0.8MPa after immersion.
Embodiment 5
The true mineral varnish coating of environmental protection, specific raw material are：
0.1 parts by weight hydroxyethyl cellulose；
0.8 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.5 parts by weight ethylene glycol；
0.1 parts by weight 2-amino-2-methyl-1-propanol；
20 parts by weight silicone acrylic emulsions；
90 parts by weight natural colour sands；
3 parts by weight slivers；
0.5 parts by weight glycol monoethyl ether；
0.5 parts by weight ethylene glycol monobutyl ether；
8 parts by weight water.
Above-mentioned each raw material is mixed, at room temperature, stirred 20 minutes with 600 revs/min of rotating speed, it is well mixed to can be prepared by this
The environmentally friendly true mineral varnish coating of invention.
Method of testing is consistent with embodiment 1.
Stain resistance：It is 2 grades after 16 cyclic tests；Temperature-change resistance：16 secondary coatings start efflorescence, cracking, peeling, rise
Drum, compared with standard edition, color starts to change；Adhesion strength standard state 1.0MPa, 0.6MPa after immersion.
True mineral varnish appearance colour of the present invention is gorgeous, water-fast, alkali resistance is good, and cohesive force is strong, and ageing resistance is strong, fits
For a variety of basal planes, and effectively building can be protected not corroded by adverse circumstances, extend its service life.
Claims (4)
1. a kind of true mineral varnish coating of environmental protection, it is characterised in that be prepared including following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
5-10 parts by weight water.
2. the true mineral varnish coating of environmental protection as claimed in claim 1, it is characterised in that be prepared including following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
0.3-1.2 parts by weight glycol monoethyl ethers；
0.3-1.2 parts by weight ethylene glycol monobutyl ethers；
5-10 parts by weight water.
3. the true mineral varnish coating of environmental protection as claimed in claim 2, it is characterised in that be prepared by following raw materials：
0.05-0.15 parts by weight hydroxyethyl celluloses；
0.4-1.2 parts by weight 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates；
0.2-0.8 parts by weight ethylene glycol；
0.05-0.15 parts by weight 2-amino-2-methyl-1-propanols；
15-30 parts by weight silicone acrylic emulsions；
50-100 parts by weight natural colour sands；
2-4 parts by weight slivers；
0.3-1.2 parts by weight glycol monoethyl ethers；
0.3-1.2 parts by weight ethylene glycol monobutyl ethers；
0.1-0.3 parts by weight defoamers；
0.1-0.3 parts by weight hydrophober；
0.1-0.3 parts by weight bactericide；
5-10 parts by weight water.
4. the environmentally friendly true mineral varnish coating as described in claims 1 to 3, it is characterised in that：The natural colour sand particle diameter is 20-100
Mesh.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
| CN111847990A (en) * | 2020-07-17 | 2020-10-30 | 江苏晨光涂料有限公司 | High-performance waterproof antifouling real stone paint |
| CN111876040A (en) * | 2020-07-17 | 2020-11-03 | 中山市华图建筑材料有限公司 | Intelligent high-tech lotus leaf stone-like paint |
| CN111892852A (en) * | 2020-07-28 | 2020-11-06 | 浙江志强涂料有限公司 | Corrosion-resistant epoxy modified silicon-acrylic stone paint |
| CN115873431A (en) * | 2022-12-12 | 2023-03-31 | 广东美涂士建材股份有限公司 | Real stone paint artistic coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
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| CN111876040A (en) * | 2020-07-17 | 2020-11-03 | 中山市华图建筑材料有限公司 | Intelligent high-tech lotus leaf stone-like paint |
| CN111892852A (en) * | 2020-07-28 | 2020-11-06 | 浙江志强涂料有限公司 | Corrosion-resistant epoxy modified silicon-acrylic stone paint |
| CN115873431A (en) * | 2022-12-12 | 2023-03-31 | 广东美涂士建材股份有限公司 | Real stone paint artistic coating and preparation method thereof |
| CN115873431B (en) * | 2022-12-12 | 2023-09-29 | 广东美涂士建材股份有限公司 | Real stone paint artistic coating and preparation method thereof |
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Effective date of registration: 20230810 Address after: 256600 meters west of Fengjiapu Community, Haifeng Street, Wudi County, Binzhou City, Shandong Province Patentee after: Shandong Zhuowei New Materials Co.,Ltd. Address before: 251900 South side of Diqing Street, Wudi County, Binzhou City, Shandong Province Patentee before: Wudi longxiangyu paint Co.,Ltd. |