CN106007634B - A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction - Google Patents
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction Download PDFInfo
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- CN106007634B CN106007634B CN201610349654.4A CN201610349654A CN106007634B CN 106007634 B CN106007634 B CN 106007634B CN 201610349654 A CN201610349654 A CN 201610349654A CN 106007634 B CN106007634 B CN 106007634B
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- low temperature
- relative humidity
- thickener
- high relative
- humidity environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is characterized in that it is mainly made up of color sand, Si modification styrene-acrylic emulsion, coalescents, Ludox, thickener and conven-tional adjuvants, the mass fraction of its sand of prizing is 70 80%, the mass fraction of Si modification styrene-acrylic emulsion 8666 is 12 15%, the mass fraction of coalescents is 0.6 0.8%, and the mass fraction of Ludox is 2.0 3.0%, and the mass fraction of thickener is 0.1 0.15%, surplus is conven-tional adjuvants, and each component sum is 100%；Described coalescents are mainly formed by Texanol ester alcohols, ethylene glycol monobutyl ether and phenmethylol compounding, and described thickener is formed by polyurethane thickener and alkali thickening agent compounding.The true mineral varnish of the present invention, constructs up to the workability under normal temperature environment under low temperature and high relative humidity environment.
Description
Technical field
The present invention relates to a kind of exterior coating, especially a kind of exterior wall true stone paint, specifically a kind of suitable low temperature height
The exterior wall true stone paint of wet environment construction.
Background technology
Exterior wall true stone paint be using the natural rubbles such as natural granite, powder as main raw material(s), using synthetic resin emulsion as
Adhesive, and it is aided with the coating that a variety of auxiliary agents are formulated.Exterior wall true stone paint, possess abundant texture, the third dimension of lithotome,
And with the serious, aesthetic feeling of harmony；Moreover, compared with facing tile, dry hanging granite, its more good and cheap economy is suitable
The property used.The decorative effect of exterior wall true stone paint is more suitable for moulding various designs comparable to stone material, and than stone material, durability and impervious
Property is more longlasting, therefore is quite welcome by construction market.
However, during at the beginning of last month of spring in winter, national most area（Such as East China）Environment temperature can as little as 0~5 DEG C,
Highest humidity is up to 85%RH, and when carrying out true mineral varnish construction in such circumstances, water evaporation rate is slow, causes drying varniss speed
Slowly, filming performance is by extreme influence, paint film cracking, poor water resistance easily occurs, meets water and easily turn white the problems such as growing dim.According to inventor
It is known, it there is no a kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction available at present.
The content of the invention
The purpose of the present invention is also easy to produce paint film cracking, water-fast when being and being constructed for existing true mineral varnish under low temperature and high relative humidity environment
Property poor, paint film meet water and easily turn white the problems such as growing dim, a kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction of invention.
The technical scheme is that：
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is characterized in that it is mainly by color sand, Si modification phenylpropyl alcohol
Emulsion, coalescents, Ludox, thickener and conven-tional adjuvants composition, the mass fraction of its sand of prizing are 70-80%, Si modification benzene
The mass fraction of acrylic emulsion 8666 is 12-15%, and the mass fraction of coalescents is 0.6-0.8%, and the mass fraction of Ludox is
2.0-3.0%, the mass fraction of thickener is 0.1-0.15%, and surplus is conven-tional adjuvants, and each component sum is 100%；It is described into
Film auxiliary agent is mainly formed by Texanol ester alcohols, ethylene glycol monobutyl ether and phenmethylol compounding, and described thickener is thickened by polyurethane
Agent and alkali thickening agent compounding form.
The color sand is made up of two kinds of 40-80 mesh coarse sand and 80-120 mesh fine sand, and the proportion relation of coarse sand and fine sand is 3-
5：2.5-4.5, optimum proportioning 4:3.5.
The particle diameter of the Si modification styrene-acrylic emulsion 8666 is at 0.1-0.6 μm, and the milky white slightly blue phase of outward appearance.
The ratio for the coalescents three that the Texanol ester alcohols, ethylene glycol monobutyl ether, phenmethylol compound is 2-4：1-3：
1-3, optimum proportioning 3:2:2.
The thickener of the polyurethane thickener and alkali thickening agent compounding, wherein both polyurethane thickener and alkali thickening agent
Proportion relation is 4-6：5-7, optimum proportioning 5:6.
During the true mineral varnish construction, basic unit's moisture content is less than 10%, pH value and is less than 10, and preferably with hanging basket spraying method
Construction.
Part that the present invention does not relate to is same as the prior art or can be realized using prior art.
Beneficial effects of the present invention：
（1）True mineral varnish of the present invention uses Si modification styrene-acrylic emulsion 8666, plays Si modification styrene-acrylic emulsion 8666 and synthesizes
When the response type silane monomer that is added, make in-Si-O- implantation emulsion polymers ,-Si-O the keys introduced after its film forming make paint film
Water-whitening resistance, water resistance and adhesive force and adhesion strength be significantly improved；Constructed under low temperature and high relative humidity environment, it has very
Good water-whitening resistance.
（2）The present invention is reducing film-forming temperature etc. based on coalescents from the compatibility of emulsion and different coalescents
Characteristic, creatively using Texanol ester alcohols, ethylene glycol monobutyl ether, phenmethylol compounding coalescents, simultaneously；Determine
The triangular ratio of Texanol ester alcohols, ethylene glycol monobutyl ether, phenmethylol, ensure that it constructs under low temperature and high relative humidity environment into
Film properties.
（3）True mineral varnish of the present invention with the addition of a certain proportion of Ludox, and it has extremely strong permeability to basic unit, and
And calcium silicates can be generated with the calcium hydroxide reaction in basic unit, network structure is easily formed after drying, film is not only hard, adhesive force
By force, water-fast good weatherability, and electrostatic is not produced, the difficult stain resistance for adhering to, improving true mineral varnish of various dust in air.
Brief description of the drawings
The true mineral varnish model water-whitening resistance test real object photo of Fig. 1 present invention.
The true mineral varnish model of Fig. 2 present invention construction contrast photo in kind under low temperature and high relative humidity environment and under normal temperature.
The common true mineral varnish model water-whitening resistance test real object photos of Fig. 3.
Embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples.
As Figure 1-3.
Embodiment one.
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is mainly by 75kg coloured silks sand, 13kg Si modification phenylpropyl alcohols
Emulsion 8666,0.7kg coalescents, 2.5kg Ludox, 0.11kg thickeners and 8.69kg conven-tional adjuvants（Containing diluent）Group
Into.Its sand of prizing is made up of 40kg 40-80 mesh coarse sand and 35kg two kinds of 80-120 mesh fine sand；Si modification styrene-acrylic emulsion
8666 particle diameter is at 0.1-0.6 μm, and the milky white slightly blue phase of outward appearance；Coalescents are by 0.3kg Texanol ester alcohols, 0.2kg
Ethylene glycol monobutyl ether and 0.2kg phenmethylol compounding form；Thickener is by 0.05kg polyurethane thickener and 0.06kg alkali
Thickener（Such as hydrophobically modified acrylic copolymer, carboxylic acid acrylic copolymer, similarly hereinafter）Compounding forms.During true mineral varnish construction,
Control basic unit's moisture content to be less than 10%, pH value and be less than 10, constructed using hanging basket spraying method.Prepare under the conditions of of the same race and surveyed for performance
Small size model on probation, by model after 0-5 DEG C, 85% time maintenance of humidity 7 days, paint film during observation hygrometric state after immersion 48 hours
State of blush, show good water-whitening resistance（Fig. 1）；By model after 0-5 DEG C, the maintenance 7 days of humidity 85% time, performance is carried out
Test meets standard JG/T24-2000；Further with 23 ± 2 DEG C maintenance 2 days after model carry out aberration contrast, both film forming colors
Pool nothing is clearly distinguished（Fig. 2）, show the true mineral varnish of the present invention under the construction of low temperature and high relative humidity environment up to workability under normal temperature environment.
Embodiment two.
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is mainly by 80kg coloured silks sand, 12kg Si modification phenylpropyl alcohols
Emulsion 8666,0.6kg coalescents, 2kg Ludox, 0.1kg thickeners and 5.3kg conven-tional adjuvants（Containing diluent）Composition.
Its sand of prizing is made up of 42.7kg 40-80 mesh coarse sand and 37.3kg 80-120 mesh fine sands；Si modification styrene-acrylic emulsion 8666
Particle diameter is at 0.1-0.6 μm, and the milky white slightly blue phase of outward appearance；Texanol ester alcohol, 0.1714kg second of the coalescents by 0.257kg
Glycol monobutyl ether and 0.1714kg phenmethylols compounding form；Thickener by 0.045kg polyurethane thickeners and 0.055kg compounding and
Into.During true mineral varnish construction, control basic unit moisture content is less than 10%, pH value and is less than 10, is constructed using hanging basket spraying method.It is described true
Mineral varnish performance is identical with embodiment one.
Embodiment three.
A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is mainly by 70kg coloured silks sand, 15kg Si modification phenylpropyl alcohols
Emulsion 8666,0.8kg coalescents, 3kg Ludox, 0.15kg thickeners and 11.05kg conven-tional adjuvants（Containing diluent）Group
Into.Its sand of prizing is made up of 37.33kg 40-80 mesh coarse sand and 32.67kg 80-120 mesh fine sands；Si modification styrene-acrylic emulsion
8666 particle diameter is at 0.1-0.6 μm, and the milky white slightly blue phase of outward appearance；Coalescents by 0.343kg Texanol ester alcohols,
0.228kg ethylene glycol monobutyl ethers and 0.228kg phenmethylols compounding form；Thickener by 0.0682kg polyurethane thickeners and
0.0818kg compoundings form.During true mineral varnish construction, control basic unit moisture content is less than 10%, pH value and is less than 10, using hanging basket spraying side
Formula is constructed.The true mineral varnish performance is identical with embodiment one.
Example IV.
The difference of the present embodiment and embodiment one is that the ratio of color sand medium coarse sand and fine sand is 3：2.5 in coalescents
Texanol ester alcohols, ethylene glycol monobutyl ether, the ratio of phenmethylol three are 2：1：1, polyurethane thickener and alkali thickening in thickener
The proportion relation of both agent is 4：5, remaining is identical with embodiment one.
Embodiment five.
The difference of the present embodiment and embodiment two is that the ratio of color sand medium coarse sand and fine sand is 5：4.5, in coalescents
Texanol ester alcohols, ethylene glycol monobutyl ether, the ratio of phenmethylol three are 4：3：3, polyurethane thickener and alkali thickening in thickener
The proportion relation of both agent is 6：7, remaining is identical with embodiment two.
Embodiment six.
The difference of the present embodiment and embodiment three is that the ratio of color sand medium coarse sand and fine sand is 4：4, in coalescents
Texanol ester alcohols, ethylene glycol monobutyl ether, the ratio of phenmethylol three are 4：2.5：2.5, polyurethane thickener and alkali in thickener
The proportion relation of both thickeners is 5：7, remaining is identical with embodiment three.
Comparative example one.
A kind of common exterior wall true stone paint, it is characterized in that the true mineral varnish is prized the mass fraction of sand be 75%, its prize sand by
The proportion relation of coarse sand and fine sand is 4 to two kinds of compositions of 40-80 mesh coarse sand and 80-120 mesh fine sand simultaneously:3.5；Emulsion is common benzene
Acrylic emulsion, its mass fraction are 13%；Coalescents ethylene glycol monobutyl ether, its mass fraction are 0.3%；The quality of alkali thickening agent point
Number is 0.07%.During true mineral varnish construction, control basic unit moisture content is less than 10%, pH value and is less than 10, is constructed using hanging basket spraying method.
Prepared under the conditions of of the same race and supply performance test small size model, by model after 0-5 DEG C, humidity 85% time conserve 7 days, soak 48
The state of blush of paint film, its water-whitening resistance when hygrometric state is observed after hour（Fig. 3）Relative to the true mineral varnish of the present invention（Fig. 1）Want difference very
It is more.
Foregoing description and explanation simply express the technical concept and feature and its representative implementation case of the present invention
Example, it is not intended to limit the scope of the present invention, all equivalence changes substantially done according to present inventive concept or modification,
It should all cover within the scope of the present invention.
The part that the present invention does not relate to such as composition of conven-tional adjuvants, diluent, dosage is same as the prior art or can use
Prior art is realized.
Claims (8)
- A kind of 1. exterior wall true stone paint of suitable low temperature and high relative humidity environment construction, it is characterized in that it is mainly by color sand, Si modification phenylpropyl alcohol breast Liquid 8666, coalescents, Ludox, thickener and conven-tional adjuvants composition, the mass fraction of its sand of prizing are 70-80%, Si modification The mass fraction of styrene-acrylic emulsion 8666 is 12-15%, and the mass fractions of coalescents is 0.6-0.8%, the mass fraction of Ludox For 2.0-3.0%, the mass fraction of thickener is 0.1-0.15%, and surplus is conven-tional adjuvants, and each component sum is 100%；Described Coalescents are mainly formed by Texanol ester alcohols, ethylene glycol monobutyl ether and phenmethylol compounding, and described thickener is by polyurethane Thick dose forms with alkali thickening agent compounding；Described low temperature is 0~5 DEG C, and described high humidity refers to that humidity is 85%；The film forming helps Texanol ester alcohols, ethylene glycol monobutyl ether, the compound proportion of phenmethylol three are 2-4 in agent:1-3:1-3.
- 2. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the color sand is by 40- The proportion relation of two kinds of compositions of 80 mesh coarse sands and 80-120 mesh fine sand, its medium coarse sand and fine sand is 3-5:2.5-4.5.
- 3. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 2, it is characterized in that thick in the color sand The proportion relation of sand and fine sand is 4：3.5.
- 4. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the Si modification benzene The particle diameter of acrylic emulsion 8666 is at 0.1-0.6 μm, and the milky white slightly blue phase of outward appearance.
- 5. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the coalescents Middle Texanol ester alcohols, ethylene glycol monobutyl ether, the compound proportion of phenmethylol three are 3:2:2.
- 6. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the polyurethane Thick dose and the thickener of alkali thickening agent compounding, wherein both polyurethane thickener and alkali thickening agent proportion relation is 4-6:5-7.
- 7. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the polyurethane Thick dose and the thickener of alkali thickening agent compounding, wherein both polyurethane thickener and alkali thickening agent proportion relation are 5:6.
- 8. it is adapted to the exterior wall true stone paint of low temperature and high relative humidity environment construction according to claim 1, it is characterized in that the true mineral varnish is applied Man-hour, basic unit's moisture content are less than 10%, pH value and are less than 10, are constructed using hanging basket spraying method.
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| CN201610349654.4A CN106007634B (en) | 2016-05-23 | 2016-05-23 | A kind of exterior wall true stone paint of suitable low temperature and high relative humidity environment construction |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066138A (en) * | 2019-03-23 | 2019-07-30 | 上海雷鸟涂料有限公司 | A kind of heat-resistance type lacquer and its preparation process |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106645658A (en) * | 2016-12-31 | 2017-05-10 | 佛山市顺德区巴德富实业有限公司 | Stone-like coating detection method |
| CN114806235A (en) * | 2022-04-15 | 2022-07-29 | 青岛黄海学院 | Whitening-resistant exterior wall stone-like paint and preparation method thereof |
| CN114752271A (en) * | 2022-05-05 | 2022-07-15 | 天津德普威涂料有限公司 | Low-temperature-resistant crystal color stone imitation paint and preparation process thereof |
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| CN106007634A (en) | 2016-10-12 |
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Effective date of registration: 20200909 Address after: 424415 second floor, comprehensive building, Xinye sunshine new town, extension section of Ouyanghai Avenue, Longtan street, Guiyang County, Chenzhou City, Hunan Province Patentee after: Hunan detai Construction Engineering Co., Ltd Address before: 225127 No. 199, Yang Hua Xi Road, Yangzhou, Jiangsu Patentee before: YANGZHOU POLYTECHNIC INSTITUTE |