CN108727922A - One kind exempting from cover and imitates lime mineral varnish and preparation method thereof - Google Patents
One kind exempting from cover and imitates lime mineral varnish and preparation method thereof Download PDFInfo
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- CN108727922A CN108727922A CN201810419670.5A CN201810419670A CN108727922A CN 108727922 A CN108727922 A CN 108727922A CN 201810419670 A CN201810419670 A CN 201810419670A CN 108727922 A CN108727922 A CN 108727922A
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- parts
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to one kind exempting from imitative lime mineral varnish of cover and preparation method thereof, belongs to technical field of coatings.In terms of parts by weight, including 45-60 parts of water, 0.1-1 parts of fungicide, 0.1-1 parts of dispersant, 0.1-0.5 parts of wetting agent, 0.5-1.5 parts of cellulose, 0.05-0.15 parts of pH adjusting agent, 0.1-2 parts of antifoaming agent, 20-30 parts of filler, 5-15 parts of lotion, 0.1-1 parts of coalescents, 0.5-1.5 parts of antifreezing agent, 0.1-0.2 parts of antifoaming agent, 0.1-0.5 parts of thickener.Exempt from cover and imitate lime mineral varnish and preparation method thereof and have to can reach the excellent performances such as water-fast, weather-proof without cover using of the present invention, not only simplifies the advantages of construction technology saves cost again.
Description
Technical field
The present invention relates to one kind exempting from imitative lime mineral varnish of cover and preparation method thereof, belongs to rapid shaping technique field.
Background technology
For lime stone as a kind of lithotome, the application in modern high-grade decoration of exterior wall is more and more extensive.However, due to
For lime stone as a kind of lithotome, cladding load is overweight, after using for a longer period, is easily caused due to own wt
It falls off and hurts sb.'s feelings.In addition, lime stone as lithotome, needs to be exploited from the Nature, and resource can be led to by largely exploiting
A series of problems, such as waste and awful weather.
In the prior art, it is a kind of NEW PAINT SYSTEMS FOR BUILDINGS to imitate lime stone effect coating, and film has natural limestone
Texture, decorative strong, fidelity can be used for the covering with paint of the external walls such as high-grade office building, villa building, before up to 80% or more
Scape is wide.However, existing imitative lime fluorspar coating is since water resistance and weatherability are poor, after being used in building surface, usually
It needs to coat one layer of cover in top layer to improve the water-fast and weatherability of imitative lime fluorspar coating, which not only adds construction works
The complexity of skill, and also increase cost；The present invention invents one kind for this problem and exempts from the imitative lime mineral varnish of cover.
Invention content
In view of the above technical problems, the present invention, which provides one kind and exempting from cover, imitates lime mineral varnish and preparation method thereof.
In order to solve the above technical problems, the technical solution used in the present invention is：One kind exempting from cover and imitates lime mineral varnish, with weight
Measure number meter, including 45-60 parts of water, 0.1-1 parts of fungicide, 0.1-1 parts of dispersant, 0.1-0.5 parts of wetting agent, cellulose 0.5-
1.5 parts, 0.05-0.15 parts of pH adjusting agent, 0.1-2 parts of antifoaming agent, 20-30 parts of filler, 5-15 parts of lotion, coalescents 0.1-1
Part, 0.5-1.5 parts of antifreezing agent, 0.1-0.2 parts of antifoaming agent, 0.1-0.5 parts of thickener.
Further, the fungicide is MERGAL K9N；The dispersant is ROHM AND HAAS dispersant 731A；Institute
State the X-405 that wetting agent is Tao Shi Chemical Manufactures.
Further, the cellulose is one in hydroxyethyl cellulose 30000YP2 or hydroxyethyl cellulose HS10W
Kind or two kinds of mixtures by a certain percentage.
Further, the PH conditioning agents are the 2-amino-2-methyl-1-propanol AMP-95 and Ai Wangde of DOW Chemical
Any one in butylethanolamine or two kinds of mixtures by a certain percentage.
Further, it is 20 that the lotion, which is acrylic emulsion with triethylene glycol dimethacrylate with mass ratio,:0.8 hands over
Connection cation acrylic lotion obtained.
Further, the filler is coarse whiting;The coalescents are alcohol ester-12；The antifreezing agent foreignizes work to be emerging
The propylene glycol of production；The antifoaming agent is the FoamStar A10 of Kening Co., Ltd；The thickener is ACRYSOL TT-935.
The present invention also provides a kind of preparation methods exempted from cover and imitate lime mineral varnish, include the following steps：
A. formula ratio is pressed, deionized water is added in suitable container；
B.600-700r/min under, accurate fungicide, wetting agent, the dispersant of being added is claimed to stir 2min successively；
C. it is slowly added to cellulose, then sequentially adds PH conditioning agents, antifoaming agent, filler, big turn gradually is opened as viscosity increases
Speed stirs 25min to 1500r/min；
D.800-1000r/min it is slowly added to lotion, coalescents down, stirs 10min, antifreezing agent, antifoaming agent, thickener is added
It is filling to stir 10min.
Due to using the technology described above, the technique effect reached is the present invention：
（1）Cover of the present invention of exempting from imitates lime mineral varnish and preparation method thereof, obtained to exempt from cover to imitate lime mineral varnish comparison existing
Imitative lime mineral varnish, it is that can reach the excellent performances such as water-fast, weather-proof to have without cover, not only simplifies construction technology and saves again
Cost；Exempt from cover in particular by prepared by acrylic acid ester emulsion and triethylene glycol dimethacrylate crosslinking lotion obtained
The water resistance of imitative lime mineral varnish is significantly improved, and has excellent physical property.
Specific implementation mode
The present invention is described in detail with reference to embodiment.
Raw material employed in following embodiments is as follows：
The fungicide is MERGAL K9N, is fungicide in a kind of wide spectrum tank, is free of solvent and formaldehyde；
The dispersant is ROHM AND HAAS dispersant 731A, is a kind of universal sodium polycarboxylate dipersant, the dispersant
Hydrophobically modified structure make Orotan 731A that there is the incomparable water resistance of similar sodium salt dispersant and its to be free of formaldehyde, with
Water is carrier, is widely used in the bloom prepared by pure third, phenylpropyl alcohol and acrylate and vinyl acetate emulsion, has in light to low luster coating, has to each
The high dispersion efficiency of class color stuffing gives full play to the covering potentiality of color stuffing.
The wetting agent is the X-405 of Tao Shi Chemical Manufactures；
The cellulose is one or both of hydroxyethyl cellulose 30000YP2 or hydroxyethyl cellulose HS10W by certain
Ratio coordinates, and the preferred hydroxyethyl cellulose 30000YP2 and hydroxyethyl cellulose HS10W is by as follows in following implementations
Mass ratio 2:1 mixes.
The PH conditioning agents are that one kind of the butylethanolamine of the AMP-95 and Ai Wangde of DOW Chemical or two kinds of arbitrary proportion mix
Close object；The butylethanolamine in following embodiments being preferably the AMP-95 and Ai Wangde of DOW Chemical is 2 in mass ratio:1 mixes；
It is with good lime stone is raw material that the filler, which is coarse whiting, and white powder is machined to through lime milling, it main
Ingredient is CaCO3；
It is 20 that the lotion, which is acrylic emulsion with triethylene glycol dimethacrylate with mass ratio,:0.8 crosslinking sun obtained from
Sub- acrylic emulsion；
The coalescents be alcohol ester-12, molecular formula 2,2,4- trimethyl -1,3 the eleventh of the twelve Earthly Branches monoisobutyrates, also known as 12
Carbon ester, alcohol ester-12 is adaptable, and dosage is few to have good stability, film forming closely knit under different PH environment；
The antifreezing agent is the propylene glycol of emerging foreign Chemical Manufacture；
The antifoaming agent is the FoamStar A10 of Kening Co., Ltd, and the wetting that there is this antifoaming agent traditional antifoaming agent not have is made
With additive amount is lower than traditional antifoaming agent, cost-effective；
The thickener is that ACRYSOL TT-935 are a kind of alkali-soluble emulsion type thickeners of hydrophobically modified.
Embodiment 1
Exempt from the imitative lime mineral varnish of cover described in the present embodiment to be grouped as by following group by weight：
49 parts of water
0.1 part of fungicide
1 part of dispersant
0.1 part of wetting agent
1.5 parts of cellulose
0.1 part of PH conditioning agents
1 part of antifoaming agent
20 parts of filler
25 parts of lotion
1.5 parts of coalescents
0.5 part of antifreezing agent
0.1 part of antifoaming agent
0.1 part of thickener
Embodiment 2
Exempt from the imitative lime mineral varnish of cover described in the present embodiment to be grouped as by following group by weight：
Main 45-60 parts of water, 0.1-1 parts of fungicide, 0.1-1 parts of dispersant, 0.1-0.5 parts of wetting agent, cellulose 0.5-1.5
Part, 0.1-0.5 parts of PH conditioning agents, 0.1-2 parts of antifoaming agent, 10-20 parts of filler, 10-25 parts of lotion, 0.1-1 parts of coalescents are prevented
Freeze 0.5-1.5 parts of agent, 0.1-0.2 parts of antifoaming agent, 0.1-0.5 parts of thickener；
55 parts of water
0.1 part of fungicide
0.5 part of dispersant
0.1 part of wetting agent
1.5 parts of cellulose
0.1 part of PH conditioning agents
1 part of antifoaming agent
20 parts of filler
20 parts of lotion
0.5 part of coalescents
0.5 part of antifreezing agent
0.1 part of antifoaming agent
0.1 part of thickener
Embodiment 3
Exempt from the imitative lime mineral varnish of cover described in the present embodiment to be grouped as by following group by weight：
60 parts of water
0.1 part of fungicide
0.5 part of dispersant
0.1 part of wetting agent
1.5 parts of cellulose
0.1 part of PH conditioning agents
1 part of antifoaming agent
11 parts of filler
25 parts of lotion
1 part of coalescents
0.5 part of antifreezing agent
0.1 part of antifoaming agent
0.1 part of thickener
Further, the present invention also provides the preparation methods for exempting from the imitative lime mineral varnish of cover described in above-described embodiment, including such as
Lower step：
A. deionized water is added in suitable container；
B.600-700r/min under, accurate fungicide, wetting agent, the dispersant of being added is claimed to stir 2min successively；
C. it is slowly added to cellulose, then sequentially adds PH conditioning agents, antifoaming agent, filler, big turn gradually is opened as viscosity increases
Speed stirs 25min to 1500r/min；
D.800-1000r/min it is slowly added to lotion, coalescents down, stirs 10min, antifreezing agent, antifoaming agent, thickener is added
It is filling to stir 10min.
Further, the present invention also provides the performance surveys exempted from cover and imitate lime mineral varnish being prepared in embodiment 1 ~ 3
Method for testing and the performance test results, test method reference supplement test method, test result is as follows：
Water resistance testing method：By the water-fast test method detection of exterior wall paint in GB/T 9755-2014
Test result：Exempt from the imitative lime mineral varnish of cover made from above-described embodiment 1 ~ 3 and meets finishing coat in GB/T 9755-2014
Water-fast index.
It can be that professional and technical personnel in the field realize or use that above-described embodiment, which is intended to illustrate the present invention, to above-mentioned reality
The mode of applying, which is modified, will be apparent to those skilled in the art, thus the present invention include but not limited on
Embodiment is stated, it is any to meet the claims or specification description, meet and principles disclosed herein and novelty, wound
The method of the property made feature, technique, product, each fall within protection scope of the present invention.
Claims (7)
1. one kind, which exempting from cover, imitates lime mineral varnish, it is characterised in that：In terms of parts by weight, including 45-60 parts of water, fungicide 0.1-1
Part, 0.1-1 parts of dispersant, 0.1-0.5 parts of wetting agent, 0.5-1.5 parts of cellulose, 0.05-0.15 parts of pH adjusting agent, antifoaming agent
0.1-2 parts, 20-30 parts of filler, 5-15 parts of lotion, 0.1-1 parts of coalescents, 0.5-1.5 parts of antifreezing agent, antifoaming agent 0.1-0.2
Part, 0.1-0.5 parts of thickener.
2. cover as described in claim 1 of exempting from imitates lime mineral varnish, it is characterised in that：The fungicide is MERGAL K9N；
The dispersant is ROHM AND HAAS dispersant 731A；The wetting agent is the X-405 of Tao Shi Chemical Manufactures.
3. cover as described in claim 1 of exempting from imitates lime mineral varnish, it is characterised in that：The cellulose is hydroxyethyl cellulose
30000YP2 or one kind in hydroxyethyl cellulose HS10W or two kinds of mixtures by a certain percentage.
4. cover as described in claim 1 of exempting from imitates lime mineral varnish, it is characterised in that：The PH conditioning agents are the 2- of DOW Chemical
Any one or by a certain percentage two kinds in the butylethanolamine of amino-2-methyl -1- propyl alcohol AMP-95 and Ai Wangde are mixed
Close object.
5. cover as described in claim 1 of exempting from imitates lime mineral varnish, it is characterised in that：The lotion is that acrylic emulsion and three are sweet
Alcohol dimethylacrylate is with mass ratio for 20:0.8 crosslinking cation acrylic lotion obtained.
6. cover as described in claim 1 of exempting from imitates lime mineral varnish, it is characterised in that：The filler is coarse whiting;The film forming
Auxiliary agent is alcohol ester-12；The antifreezing agent is the propylene glycol of emerging foreign Chemical Manufacture；The antifoaming agent is Kening Co., Ltd
FoamStar A10；The thickener is ACRYSOL TT-935.
7. any preparation method exempted from cover and imitate lime mineral varnish of claim 1 ~ 6, which is characterized in that include the following steps：
By formula ratio, deionized water is added in suitable container；
Under 600-700r/min, accurate fungicide, wetting agent, the dispersant of being added is claimed to stir 2min successively；
It is slowly added to cellulose, then sequentially adds PH conditioning agents, antifoaming agent, filler, as big rotating speed is gradually opened in viscosity increase
To 1500r/min, 25min is stirred；
It is slowly added to lotion, coalescents under 800-1000r/min, stirs 10min, antifreezing agent, antifoaming agent, thickener is added and stirs
It is filling to mix 10min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419670.5A CN108727922A (en) | 2018-05-04 | 2018-05-04 | One kind exempting from cover and imitates lime mineral varnish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419670.5A CN108727922A (en) | 2018-05-04 | 2018-05-04 | One kind exempting from cover and imitates lime mineral varnish and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108727922A true CN108727922A (en) | 2018-11-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810419670.5A Pending CN108727922A (en) | 2018-05-04 | 2018-05-04 | One kind exempting from cover and imitates lime mineral varnish and preparation method thereof |
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| CN (1) | CN108727922A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988473A (en) * | 2019-03-28 | 2019-07-09 | 河北晨阳工贸集团有限公司 | A kind of high tolerance texture paint and preparation method thereof |
| CN111116103A (en) * | 2019-12-02 | 2020-05-08 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN111704833A (en) * | 2020-07-09 | 2020-09-25 | 湖州金强涂料厂 | Preparation method of limestone coating and material increasing structure thereof |
| CN113444414A (en) * | 2019-06-11 | 2021-09-28 | 河北晨阳工贸集团有限公司 | High-weather-resistance antibacterial coating imitating limestone and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988473A (en) * | 2019-03-28 | 2019-07-09 | 河北晨阳工贸集团有限公司 | A kind of high tolerance texture paint and preparation method thereof |
| CN113444414A (en) * | 2019-06-11 | 2021-09-28 | 河北晨阳工贸集团有限公司 | High-weather-resistance antibacterial coating imitating limestone and preparation method thereof |
| CN111116103A (en) * | 2019-12-02 | 2020-05-08 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN111116103B (en) * | 2019-12-02 | 2021-12-07 | 河北嘉宝莉涂料有限公司 | Aqueous limestone-like coating paint and preparation method thereof |
| CN111704833A (en) * | 2020-07-09 | 2020-09-25 | 湖州金强涂料厂 | Preparation method of limestone coating and material increasing structure thereof |
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