CN109535878A - One kind is containing colorful stone-like coating of sand and preparation method thereof - Google Patents

One kind is containing colorful stone-like coating of sand and preparation method thereof Download PDF

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Publication number
CN109535878A
CN109535878A CN201811521783.2A CN201811521783A CN109535878A CN 109535878 A CN109535878 A CN 109535878A CN 201811521783 A CN201811521783 A CN 201811521783A CN 109535878 A CN109535878 A CN 109535878A
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coating
sand
base paint
color
mixed
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Inventor
李贻甫
杜超
王平顺
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Xiamen Anbixin New Mstar Technology Ltd
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Xiamen Anbixin New Mstar Technology Ltd
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Priority to CN201811521783.2A priority Critical patent/CN109535878A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

Abstract

The invention discloses one kind containing colorful stone-like coating of sand and preparation method thereof, is related to building coating technical field.The raw material of stone-like coating includes granulation liquid and continuous phase, and the mass ratio of granulation liquid and continuous phase is (60-80): (40-20), and the granulation liquid includes color-mixed base paint and sand, and the mass ratio of the color-mixed base paint and sand is 100:(50-80);The color-mixed base paint includes following components in percentage by weight: hydrophobically modified celluloses 0.8-1.2%;Defoaming agent 0.2-0.4%;Wetting agent 0.2-0.4%;Coalescing agent 0.5-0.7%;Filler 10-15%;Multifunction amine auxiliary agent 0.1-0.2%;Preservative 0.3-0.5%;Acrylic emulsion 20-30%;Mill base 1-5%;Pregel 8-12%;Surplus is water.After cured later of the present invention film forming, color spot is clear, true to nature, has the verisimilitude of the lithotomes such as cladding marble coated on exterior wall, embody building it is muddy as day at decorative effect;The present invention is by choosing component and controlling the proportion of each component so that stone-like coating storage stability is good, storage 6 months it is not stratified, do not precipitate.

Description

One kind is containing colorful stone-like coating of sand and preparation method thereof
Technical field
The present invention relates to building coating technical field, more specifically, it relates to it is a kind of containing the colorful stone-like coating of sand and its Preparation method.
Background technique
Imitation stone lacquer is that a kind of decorative effect exactly likes marble, granitic thick matter exterior wall decorating coating.Mainly using various The particle of color is formulated.Building after imitation stone lacquer finishing, has natural true natural colour, give it is graceful and Humorous, serious aesthetic feeling.It is suitable for the indoor and outdoor decoration of all kinds of buildings, especially decorates on curved-surface building object, Ke Yishou To vivid, the effect of back to nature.Imitation stone lacquer has fire prevention, waterproof, acid and alkali-resistance, anti-pollution, nontoxic, tasteless, bonding force By force, the features such as will never fade, can effectively stop extraneous adverse circumstances and corrode building, extends the service life of building.
A kind of rock colored stone sheet stone-like coating is disclosed in the Chinese invention patent of Publication No. CN106433359A, by The each component of following weight percent is made: silicone acrylic emulsion 26-38%, venamul 1-3%, polyaminoester emulsion 2- 5%, decylene glycol ester 1.7-2.2%, 2,2,4- trimethylpentanediol -1,3 mono isobutyrate 0.8-1.5%, propylene glycol 1-2%, The carboxymethyl chitosan acetum 0.5-2% of deionized water 20-30%, 1.5wt%, trichlorocarbanilide 0.1-0.2%, sulphur Sour polysaccharide 0.05-0.1%, defoaming agent 0.1-0.15%, PH regulator 0.1-0.2%, thickener 1-3%, sliver 25- 30%.
Above-mentioned patent is using sliver as color spot, and sliver is easy emersion coating in spraying, and the color spot formed is easy drift It floats on exterior coating, the flexible vividness of color spot is poor, causes its fidelity poor.
Summary of the invention
In view of the deficienciess of the prior art, the purpose of the present invention one is to provide a kind of colorful stone-like coating containing sand, Have the advantages that color spot is clear, true to nature.
The purpose of the present invention two is to provide a kind of preparation method of colorful stone-like coating containing sand, clear with color spot, Advantage true to nature.
To achieve the above object one, the present invention provides the following technical scheme that
A kind of colorful stone-like coating containing sand, raw material include granulation liquid and continuous phase, and the mass ratio of granulation liquid and continuous phase is (60-80): (40-20), the granulation liquid include color-mixed base paint and sand, and the mass ratio of the color-mixed base paint and sand is 100:(50-80);The base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8-1.2%;
Defoaming agent 0.2-0.4%;
Wetting agent 0.2-0.4%;
Coalescing agent 0.5-0.7%;
Filler 10-15%;
Multifunction amine auxiliary agent 0.1-0.2%;
Preservative 0.3-0.5%;
Acrylic emulsion 20-30%;
Mill base 1-5%;
Pregel 8-12%;
Surplus is water.
By using above-mentioned technical proposal, the present invention mixes colours to base paint using mill base, hydrophobically modified celluloses, profit After humectant and pregel are used in compounding, sand and color-mixed base paint can be made to form thick fluid, advantageously formed independent Color spot avoids mill base dispersion and colour mixture;Coalescing agent and acrylic emulsion are conducive to color spot cured later film forming, color spot is clear, It is true to nature;And color-mixed base paint storage stability is good, storage 6 months it is not stratified, do not precipitate.
Further preferably, the pregel includes following components in percentage by weight:
Preservative 0.1-0.3%;
Aluminium-magnesium silicate 6-10%;
Surplus is water.
By using above-mentioned technical proposal, aluminium-magnesium silicate has unique three-dimensional space chain structure and special needle, stick Shape crystal structure, thus have unusual colloid and absorption property.Its thickening property, suspension, colloid shake to melt and have excellent performance, The association networks that " card palace " formula is formed in aqueous medium, improve the stability of coating.
Further preferably, the continuous phase includes following components in percentage by weight:
Preservative 0.4-0.6%;
Mould inhibitor 0.5-1%;
Ethylene glycol 2-3%;
12 2-4% of alcohol ester;
Acrylic emulsion 45-55%;
Multifunction amine auxiliary agent 0.4-0.6%;
Thickener 1-2%;
Surplus is water.
By using above-mentioned technical proposal, the main component of continuous phase is similar to granulation liquid, and compatibility is good, enables granulation liquid It is enough evenly dispersed.
Further preferably, the viscosity number of the continuous phase is 115-120KU.
By using above-mentioned technical proposal, the viscosity number of continuous phase is too big, is unfavorable for the dispersion of granulation liquid, and continuous phase is glued Angle value is too small, is unfavorable for spraying film forming.
Further preferably, the granulation liquid further includes following components in percentage by weight:
Alkaline thickener 0.2-0.3%;
Multifunction amine auxiliary agent 0.1-0.2%;
Pregel 20-25%;
Color-mixed base paint 65-70%;
Surplus is water.
By using above-mentioned technical proposal, alkaline thickener, multifunction amine auxiliary agent, pregel and water are mixing uniformly to form Liquid is wrapped up, after color-mixed base paint is added in package liquid, stirring is broken up, and color-mixed base paint is sufficiently wrapped up by package liquid, is conducive to shape At independent color spot, mill base dispersion and colour mixture are avoided.
To achieve the above object two, the present invention provides the following technical scheme that
A kind of preparation method of the colorful stone-like coating containing sand, which comprises the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed and is uniformly dispersed, obtains pregel;
Step 2 prepares base paint, divides after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed It dissipates uniformly, adds multifunction amine auxiliary agent, preservative, acrylic emulsion and be uniformly dispersed, be slow added into pregel and be uniformly dispersed, Obtain base paint;
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into It is uniformly dispersed in corresponding base paint, obtains color-mixed base paint;
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, added Color-mixed base paint stirs evenly, and is distributed color-mixed base paint in pelletized form, obtains granulation liquid;
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol are sequentially added under stirring and is uniformly mixed, is obtained It is added in mixed liquor, stirs evenly after mixing to mixed liquor, then by alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent, Obtain continuous phase;
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, is mixed evenly, and obtains finished product coating.
By using above-mentioned technical proposal, after hydrophobically modified celluloses, wetting agent and pregel are used in compounding, sand can be made Son and color-mixed base paint form thick fluid, advantageously form independent color spot, avoid mill base dispersion and colour mixture;Coalescing agent Be conducive to color spot cured later film forming with acrylic emulsion, color spot is clear, true to nature;And color-mixed base paint storage stability is good, Storage 6 months it is not stratified, do not precipitate.
Further preferably, the step 2 specifically includes: base paint is prepared, by hydrophobically modified celluloses, defoaming agent, profit It is uniformly dispersed after humectant, coalescing agent, filler, water mixing, rate of dispersion is 1700-1900 revs/min, jitter time 15- 25 minutes, multifunction amine auxiliary agent, preservative, acrylic emulsion dispersion are added when rate of dispersion is dropped to 400-500 revs/min Uniformly, jitter time is 4-6 minutes, is slow added into pregel and is uniformly dispersed, and rate of dispersion is 850-950 revs/min, dispersion Time is 8-12 minutes, obtains base paint.
By using above-mentioned technical proposal, on the one hand each component is stirred evenly, it is suitable on the other hand can to obtain viscosity In base paint.
Further preferably, the pH of the finished product coating is 8-9, viscosity number 95-100KU.
By using above-mentioned technical proposal, stone-like coating of the invention is alkalescent system, by controlling pH and viscosity number, Raising storage stability is not only improved, spraying film forming is also beneficial to, viscosity number is tested using stormer viscosity meter STM-IV (B).
In conclusion compared with prior art, the invention has the following advantages:
(1) present invention mixes colours to base paint using mill base, and hydrophobically modified celluloses, wetting agent and pregel are used in compounding Afterwards, sand and color-mixed base paint can be made to form thick fluid, advantageously forms independent color spot, mill base is avoided to disperse and mix Color;Coalescing agent and acrylic emulsion are conducive to color spot cured later film forming, and color spot is clear, true to nature, are coated on exterior wall with dry Hang the verisimilitude of the lithotomes such as marble, embody building it is muddy as day at decorative effect;
(2) present invention passes through the proportion chosen component and control each component, so that stone-like coating storage stability is good, stores 6 The moon is not stratified, does not precipitate;
(3) stone-like coating provided by the invention belongs to Water-borne modification product, and VOC content is less than 15g/L, is far below China's exterior coating 120g/L limit value as defined in standard, it is environmentally protective.
Specific embodiment
Below with reference to embodiment, the present invention will be described in detail.
A kind of embodiment 1: preparation method of the colorful stone-like coating containing sand, comprising the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed, 60 points are dispersed under 1500 revs/min of speed Clock obtains pregel, and pregel includes following components in percentage by weight: preservative 0.1%;Aluminium-magnesium silicate 6%;Surplus is Water, the main component of preservative are Kathon CGs.
Step 2 prepares base paint, and hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed After be uniformly dispersed, rate of dispersion be 1700 revs/min, jitter time be 25 minutes, when rate of dispersion is dropped to 400 revs/min It adds multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 6 minutes, is slow added into pregel It is uniformly dispersed, rate of dispersion is 850 revs/min, and jitter time is 12 minutes, obtains base paint;
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into It is uniformly dispersed in corresponding base paint, adds sand, obtain color-mixed base paint, the mass ratio of color-mixed base paint and sand is 100:50;
Color-mixed base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8%;
Defoaming agent 0.2%;
Wetting agent 0.2%;
Coalescing agent 0.5%;
Filler 10%;
Multifunction amine auxiliary agent 0.1%;
Preservative 0.3%;
Acrylic emulsion 20%;
Mill base 1%;
Pregel 8%;
Surplus is water.
Wherein, hydrophobically modified celluloses is hydrophobically modified hydroxyethyl cellulose, and defoaming agent is defoaming agent NXZ, defoaming agent NXZ It is the hydrophobic gas-phase silica of mineral oil and metal soap defoaming agent;Wetting agent is high-performance Cationic thickeners, trade mark FT- 417;Coalescing agent is alcohol ester 12;Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, the weight hundred of three Ratio is divided to be followed successively by 0.5%, 4.5%, 5%;Multifunction amine auxiliary agent is AMP-95, and chemical name is 2- amino-2-methyl -1- third Alcohol;Preservative is Kathon CG;Mill base is available from the aqueous color paste of Guangdong Ke Di new material Science and Technology Ltd..
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, then Color-mixed base paint is added, stirs evenly, is distributed color-mixed base paint in pelletized form, obtain granulation liquid;
Granulation liquid includes following components in percentage by weight: alkaline thickener 0.2%;Multifunction amine auxiliary agent 0.1%;Pregel 20%;Color-mixed base paint 65%;Surplus is water;Alkaline thickener is the happy suitable hydrophobically modified alkali-soluble emulsion type in ROHM AND HAAS Asia Thickener, trade mark TT935, the multifunction amine auxiliary agent trade mark are AMP-95, and chemical name is 2-amino-2-methyl-1-propanol.
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol mixing are sequentially added under stirring It is even, mixed liquor is obtained, then alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent are added in mixed liquor after mixing, stirred 5 minutes, continuous phase is obtained, the viscosity number of continuous phase is 115KU;
Continuous phase includes following components in percentage by weight: preservative 0.6%;Mould inhibitor 1%;Ethylene glycol 3%;Alcohol ester 12 4%;Acrylic emulsion 55%;Multifunction amine auxiliary agent 0.6%;Thickener 2%;Surplus is water;Multifunction amine auxiliary agent A MP-95, Chemical name is 2-amino-2-methyl-1-propanol, and thickener is the mixture that TT-935 is mixed with water with weight ratio for 1:1.
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, and the mass ratio of granulation liquid and continuous phase is 60:20 is mixed evenly, and revolving speed is 200 revs/min, obtains finished product coating, the pH of finished product coating is 8, and viscosity number is 95KU。
Embodiment 2: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, pregel Including following components in percentage by weight: preservative 0.2%;Aluminium-magnesium silicate 8%;Surplus is water.
Embodiment 3: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, pregel Including following components in percentage by weight: preservative 0.3%;Aluminium-magnesium silicate 10%;Surplus is water.
Embodiment 4: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 3 The mass ratio of middle color-mixed base paint and sand is 100:65.
Embodiment 5: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 3 The mass ratio of middle color-mixed base paint and sand is 100:80.
Embodiment 6: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 1.0%;
Defoaming agent 0.3%;
Wetting agent 0.3%;
Coalescing agent 0.6%;
Filler 12%;
Multifunction amine auxiliary agent 0.15%;
Preservative 0.4;
Acrylic emulsion 25%;
Mill base 3%;
Pregel 10%;
Surplus is water;Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, and the weight percent of three is followed successively by 0.4%, 5.6%, 6%.The pH of finished product coating is 8.5, viscosity number 98KU.
Embodiment 7: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 1.2%;
Defoaming agent 0.4%;
Wetting agent 0.4%;
Coalescing agent 0.7%;
Filler 15%;
Multifunction amine auxiliary agent 0.2%;
Preservative 0.5;
Acrylic emulsion 30%;
Mill base 5%;
Pregel 12%;
Surplus is water;Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, and the weight percent of three is followed successively by 0.4%, 7.6%, 7%.The pH of finished product coating is 9, viscosity number 100KU.
Embodiment 8: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, granulation liquid Mass ratio with continuous phase is 70:30.
Embodiment 9: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, granulation liquid Mass ratio with continuous phase is 80:40.
Embodiment 10: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuously The viscosity number of phase is 118KU, and continuous phase includes following components in percentage by weight:
Preservative 0.4%;
Mould inhibitor 0.5%;
Ethylene glycol 2%;
Alcohol ester ten two 2%;
Acrylic emulsion 45%;
Multifunction amine auxiliary agent 0.4%;
Thickener 1%;
Surplus is water.
Embodiment 11: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuously The viscosity number of phase is 120KU, and continuous phase includes following components in percentage by weight:
Preservative 0.5%;
Mould inhibitor 0.8%;
Ethylene glycol 2.5%;
Alcohol ester ten two 3%;
Acrylic emulsion 50%;
Multifunction amine auxiliary agent 0.5%;
Thickener 1.5%;
Surplus is water.
Embodiment 12: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it is granulated Liquid includes following components in percentage by weight: alkaline thickener 0.25%;Multifunction amine auxiliary agent 0.15%;Pregel 22%;It adjusts Color base paint 68%;Surplus is water.
Embodiment 13: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it is granulated Liquid includes following components in percentage by weight: alkaline thickener 0.3%;Multifunction amine auxiliary agent 0.2%;Pregel 25%;Toning Base paint 70%;Surplus is water.
Embodiment 14: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step Two specifically include: preparing base paint, divide after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed It dissipates uniformly, rate of dispersion is 1800 revs/min, and jitter time is 20 minutes, and rate of dispersion is dropped to 450 revs/min of Shi Zaijia Enter multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 5 minutes, is slow added into pregel dispersion Uniformly, rate of dispersion is 900 revs/min, and jitter time is 10 minutes, obtains base paint.
Embodiment 15: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step Two specifically include: preparing base paint, divide after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed It dissipates uniformly, rate of dispersion is 1900 revs/min, and jitter time is 15 minutes, and rate of dispersion is dropped to 500 revs/min of Shi Zaijia Enter multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 4 minutes, is slow added into pregel dispersion Uniformly, rate of dispersion is 950 revs/min, and jitter time is 8 minutes, obtains base paint.
Comparative example 1: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, by silicic acid Magnalium replaces with the organic siliconresin of equal weight percent.
Comparative example 2: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it will be hydrophobic Modified cellulose replaces with the ethyl cellulose of equal weight percent.
Comparative example 3: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours Wetting agent is not added in plinth paint.
Comparative example 4: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 0.5%;
Defoaming agent 0.2%;
Wetting agent 0.1%;
Coalescing agent 0.5%;
Filler 10%;
Multifunction amine auxiliary agent 0.1%;
Preservative 0.3%;
Acrylic emulsion 20%;
Mill base 1%;
Pregel 6%;
Surplus is water.
Comparative example 5: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuous phase Including following components in percentage by weight: preservative 0.6%;Mould inhibitor 1%;Ethylene glycol 1%;Alcohol ester ten two 1%;Propylene yogurt Liquid 40%;Multifunction amine auxiliary agent 0.6%;Thickener 0.5%;Surplus is water.
Comparative example 6: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 2 It specifically includes: preparing base paint, by hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water, multifunction amine Auxiliary agent, preservative, acrylic emulsion, pregel are uniformly dispersed, and rate of dispersion is 2000 revs/min, and jitter time is 10 minutes, Obtain base paint.
Comparative example 7: imitative stone is prepared using the embodiment 1 in the Chinese invention patent of Publication No. CN106433359A and is applied Material.
Test an ocular estimate
Test specimen: the stone-like coating obtained in embodiment 1-15 is sprayed on substrate, and test specimen 1-15 is used as after parching, The stone-like coating obtained in comparative example 1-7 is sprayed on substrate, as control sample 1-7 after parching.
Test method: test specimen 1-15 and control sample 1-7 are compared with true stone material template respectively, and to emulation Degree and color spot clarity score respectively, and minimum 0 point, highest 100 is divided.
Test result: the appraisal result of test specimen 1-15 and control sample 1-7 are as shown in table 1.As shown in Table 1, implement The fidelity and color spot clarity of example 1-15 scores at 90 points or more, and the scoring of control sample 1-7 is at 41 points hereinafter, right The fidelity of product 1-3 and color spot clarity scoring summation are below test specimen 1 in the same old way, illustrate the present invention using mill base to basis Qi Jinhang toning, after hydrophobically modified celluloses, wetting agent and pregel are used in compounding, can be such that sand and color-mixed base paint is formed Thick fluid advantageously forms independent color spot, avoids mill base dispersion and colour mixture;Coalescing agent and acrylic emulsion are conducive to Color spot cured later film forming, color spot is clear, true to nature, has the verisimilitude of the lithotomes such as cladding marble, body coated on exterior wall Existing building it is muddy as day at decorative effect.
The appraisal result of table 1 test specimen 1-15 and control sample 1-7
Test two performance tests
Test specimen: using the stone-like coating obtained in embodiment 1-15 as test specimen 1-15, by what is obtained in comparative example 1-7 Stone-like coating is used as control sample 1-7.
Test method: test sample is detected according to the method in JG/T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS The drying time of product 1-15 and control sample 1-7, water resistance, alkali resistance, adhesion strength and thermal storage stability.
Test result: the test result of test specimen 1-15 and control sample 1-7 are as shown in table 2.As shown in Table 2, it tests Drying time, water resistance, alkali resistance, adhesion strength and the thermal storage stability of sample 1-15 meets the requirements of the standard, and right Product 1-7 occurs being layered after 30 days, has precipitating in the same old way, and thermal storage stability does not meet standard requirements, illustrates that the present invention passes through It chooses component and controls the proportion of each component, it is not stratified after long-time storage, do not sink so that stone-like coating storage stability is good It forms sediment.
The test result of table 2 test specimen 1-15 and control sample 1-7
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment, All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (8)

1. a kind of colorful stone-like coating containing sand, which is characterized in that its raw material includes granulation liquid and continuous phase, granulation liquid and continuous phase Mass ratio be (60-80): (40-20), the granulation liquid includes color-mixed base paint and sand, the color-mixed base paint and sand Mass ratio be 100:(50-80);The color-mixed base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8-1.2%;
Defoaming agent 0.2-0.4%;
Wetting agent 0.2-0.4%;
Coalescing agent 0.5-0.7%;
Filler 10-15%;
Multifunction amine auxiliary agent 0.1-0.2%;
Preservative 0.3-0.5%;
Acrylic emulsion 20-30%;
Mill base 1-5%;
Pregel 8-12%;
Surplus is water.
2. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the pregel includes following heavy Measure the component of percentage:
Preservative 0.1-0.3%;
Aluminium-magnesium silicate 6-10%;
Surplus is water.
3. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the continuous phase includes following heavy Measure the component of percentage:
Preservative 0.4-0.6%;
Mould inhibitor 0.5-1%;
Ethylene glycol 2-3%;
12 2-4% of alcohol ester;
Acrylic emulsion 45-55%;
Multifunction amine auxiliary agent 0.4-0.6%;
Thickener 1-2%;
Surplus is water.
4. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the viscosity number of the continuous phase is 115-120KU。
5. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the granulation liquid further includes following The component of weight percent:
Alkaline thickener 0.2-0.3%;
Multifunction amine auxiliary agent 0.1-0.2%;
Pregel 20-25%;
Color-mixed base paint 65-70%;
Surplus is water.
6. a kind of preparation method of the colorful stone-like coating containing sand, which comprises the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed and is uniformly dispersed, obtains pregel;
Step 2 prepares base paint, divides after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed It dissipates uniformly, adds multifunction amine auxiliary agent, preservative, acrylic emulsion and be uniformly dispersed, be slow added into pregel and be uniformly dispersed, Obtain base paint;
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into It is uniformly dispersed in corresponding base paint, obtains color-mixed base paint;
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, added Color-mixed base paint stirs evenly, and is distributed color-mixed base paint in pelletized form, obtains granulation liquid;
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol are sequentially added under stirring and is uniformly mixed, is obtained It is added in mixed liquor, stirs evenly after mixing to mixed liquor, then by alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent, Obtain continuous phase;
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, is mixed evenly, and obtains finished product coating.
7. a kind of preparation method of colorful stone-like coating containing sand according to claim 6, which is characterized in that the step 2 It specifically includes: preparing base paint, disperse after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed Uniformly, rate of dispersion is 1700-1900 revs/min, and jitter time is 15-25 minute, rate of dispersion drop to 400-500 turn/ It adds multifunction amine auxiliary agent, preservative, acrylic emulsion when minute to be uniformly dispersed, jitter time is 4-6 minutes, then slowly adds Enter pregel to be uniformly dispersed, rate of dispersion is 850-950 revs/min, and jitter time is 8-12 minutes, obtains base paint.
8. a kind of preparation method of colorful stone-like coating containing sand according to claim 6, which is characterized in that the finished product applies The pH of material is 8-9, viscosity number 95-100KU.
CN201811521783.2A 2018-12-12 2018-12-12 One kind is containing colorful stone-like coating of sand and preparation method thereof Pending CN109535878A (en)

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CN111363436A (en) * 2020-04-29 2020-07-03 广东法兰迪涂料有限公司 Water-based multicolor paint and preparation method thereof
CN111925700A (en) * 2020-07-29 2020-11-13 广西瑞顺建材有限公司 Base paint of water-based stone-like coating and preparation method thereof
CN112574627A (en) * 2020-11-30 2021-03-30 三棵树(上海)新材料研究有限公司 Marble-like water-based reflective heat-insulation exterior wall sand-containing multicolor paint and preparation method thereof
CN113621292A (en) * 2021-08-24 2021-11-09 广东美涂士建材股份有限公司 Mirror-surface colorful stone-like paint for exterior wall

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111363436A (en) * 2020-04-29 2020-07-03 广东法兰迪涂料有限公司 Water-based multicolor paint and preparation method thereof
CN111925700A (en) * 2020-07-29 2020-11-13 广西瑞顺建材有限公司 Base paint of water-based stone-like coating and preparation method thereof
CN112574627A (en) * 2020-11-30 2021-03-30 三棵树(上海)新材料研究有限公司 Marble-like water-based reflective heat-insulation exterior wall sand-containing multicolor paint and preparation method thereof
CN113621292A (en) * 2021-08-24 2021-11-09 广东美涂士建材股份有限公司 Mirror-surface colorful stone-like paint for exterior wall

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