CN111500133A - Sand-in-water multicolor paint and preparation method thereof - Google Patents

Sand-in-water multicolor paint and preparation method thereof Download PDF

Info

Publication number
CN111500133A
CN111500133A CN202010335327.XA CN202010335327A CN111500133A CN 111500133 A CN111500133 A CN 111500133A CN 202010335327 A CN202010335327 A CN 202010335327A CN 111500133 A CN111500133 A CN 111500133A
Authority
CN
China
Prior art keywords
parts
weight
paint
sand
deionized water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010335327.XA
Other languages
Chinese (zh)
Inventor
容七英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN202010335327.XA priority Critical patent/CN111500133A/en
Publication of CN111500133A publication Critical patent/CN111500133A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to a sand-in-water multicolor paint and a preparation method thereof, wherein the sand-in-water multicolor paint comprises the following components in parts by weight: 60-80 parts of multicolor particles, 30-50 parts of continuous phase emulsion and 1-5 parts of thickening agent, wherein the continuous phase emulsion comprises the following components in parts by weight: 10-40 parts of deionized water, 60-90 parts of body emulsion, 0.1-0.5 part of organic amine auxiliary agent, 1-5 parts of film-forming auxiliary agent, 0.2-0.6 part of defoaming agent and 1-3 parts of thickening agent; the multicolor particles are prepared by granulating raw materials containing composite protective glue and basic color mixing paint through a granulator, wherein the composite protective glue is the composite protective glue containing magnesium lithium silicate. The sand-in-water multicolor paint has excellent bleeding resistance, water-white resistance and storage stability, has strong concave-convex feeling and rich colors after a paint film is dried, has high simulation degree and simple preparation process, and is suitable for large-scale industrial production.

Description

Sand-in-water multicolor paint and preparation method thereof
Technical Field
The invention belongs to the technical field of building coatings, and relates to a sand-in-water multicolor coating and a preparation method thereof.
Background
Nowadays, with the continuous improvement of the living standard of substances, people can not meet the original single-color paint any more, and compared with the real stone paint and texture paint, the colorful paint is favored by more and more users due to the advantages of high simulation degree, light weight, high construction speed, low manufacturing cost and the like. In the aspect of raw material sources of colors, the raw materials of various colors of the sand-in-water coating can be realized by industrial production, and the color of the real stone paint completely depends on the color of natural colored sand, but at present, along with the fact that the natural colored sand resources are less and less, the raw material sources of the colors are uncontrollably increased, and the popularization and development of the real stone paint are greatly influenced. In addition, the traditional multicolor paint has a plane effect, does not have the texture of real stone paint, and in order to enable the multicolor paint to have the texture effect, the current common method is to use the real stone paint as a modeling layer and then spray the multicolor paint, so that one procedure is increased, and the material cost is increased. Therefore, the sand-in-water multicolor paint is produced as a new generation product, is simpler and more convenient than the traditional real stone paint in construction, has the simulation degree of the multicolor paint and the texture effect of the real stone paint through one-time spraying, and effectively saves the construction and material cost.
However, the development of sand-in-water multicolor paint technology has also encountered troublesome technical problems, such as poor stability due to the presence of sand with a high density in the dispersed phase of the sand-in-water multicolor paint; the particle size of the sand is larger, so that the flexible continuous film formed by the gelation of the protective adhesive on the surface of the color point has defects, the color point is easy to be broken, color paste in the color point is separated out, serious bleeding is caused to influence the hue, the color points in the finished product are easy to sink, the color points are adhered together and are difficult to be dispersed again, and the phenomenon that construction cannot be carried out occurs; this also adversely affects the water-white resistance of the sand-in-water multicolor paint due to the addition of sand. The sand-in-water multicolor paint has the defects, so that the use of the sand-in-water multicolor paint in the building outer wall is restricted.
Disclosure of Invention
The invention aims to solve the technical problems and provide a sand-in-water multicolor paint which has good bleeding resistance, water-white resistance, excellent storage stability and environmental protection.
The invention also aims to provide a preparation method of the sand-in-water multicolor paint.
The sand-in-water multicolor paint comprises the following components in parts by weight: 60-80 parts of multicolor particles, 30-50 parts of continuous phase emulsion and 1-5 parts of thickening agent, wherein the continuous phase emulsion comprises the following components in parts by weight: 10-40 parts of deionized water, 60-90 parts of body emulsion, 0.1-0.5 part of organic amine auxiliary agent, 1-5 parts of film-forming auxiliary agent, 0.2-0.6 part of defoaming agent and 1-3 parts of thickening agent.
As a preferred embodiment, the multicolor particles are prepared by granulating raw materials containing composite protective glue and basic toning paint by a granulator, and the composite protective glue is the composite protective glue containing magnesium lithium silicate.
As a preferred embodiment, the raw materials comprising the composite protective adhesive and the basic toning color paint comprise the following components in parts by weight: 10-20 parts of deionized water, 20-40 parts of composite protective adhesive and 50-75 parts of basic toning colored paint.
As a preferred embodiment, the basic toning color paint comprises the following components in parts by weight: 20-40 parts of deionized water, 10-30 parts of base paint emulsion, 1-3 parts of cellulose ether, 0.1-0.3 part of organic amine auxiliary agent, 0.5-1.5 parts of dispersing agent, 2-10 parts of surface modified pigment and filler, 1-5 parts of film forming auxiliary agent, 1-3 parts of propylene glycol, 0.1-0.5 part of defoaming agent, 0.5-1.5 parts of composite protective adhesive and 30-50 parts of colored quartz sand.
As a preferred embodiment, the composite protective adhesive comprises the following components in parts by weight: 5-20 parts of lithium magnesium silicate, 2-10 parts of hydroxypropyl guar gum, 1-5 parts of polyanionic cellulose and 80-95 parts of deionized water.
As a preferred embodiment, the base paint emulsion is selected from acrylic emulsion, the organic amine auxiliary agent is selected from one of TCP-95 or AMP-95, the dispersing agent is selected from at least one of polyacrylic acid ammonium salt, polyacrylamide or fatty acid polyglycol ester, the grain size of the colored quartz sand is 80-200 meshes, and the porosity is less than or equal to 10%.
As a preferred embodiment, the cellulose ether may be selected from commercially available hydroxyethyl cellulose ethers having a relative molecular mass of 5 to 10 ten thousand.
As a preferred embodiment, the surface modified pigment filler is a pigment filler whose surface is coated with a hydrophilic polymer coating.
As a preferred embodiment, the pigment and filler is selected from at least one of titanium dioxide, organic modified bentonite or calcined kaolin, and the hydrophilic polymer is selected from any one of polyacrylic acid or polyvinyl alcohol.
The hydrophilic polymer coating of the surface-modified pigment and filler can be applied on the surface of the pigment and filler particles by the conventional coating technology (e.g., pre-coating or spraying), and the amount of the hydrophilic polymer coating can be controlled to be 0.2-1% of the total mass of the surface-modified pigment and filler. In the practical application process, the hydrophilic polymer coating can play a role of serving as a temporary protective layer to effectively prevent the pigment and filler particles from being seriously agglomerated, can effectively improve the compatibility between the pigment and filler particles and the base paint emulsion, can obviously improve the dispersibility of the pigment and filler particles, and effectively avoids the phenomenon of agglomeration, sedimentation or precipitation in a base color-mixing paint system.
As a preferred embodiment, the bulk emulsion is selected from any one of a pure acrylic emulsion, a silicone acrylic emulsion or a vinyl acetate acrylic emulsion, the film forming aid is selected from at least one of an alcohol ester film forming aid, an alcohol ether film forming aid or an alcohol ether ester film forming aid, the defoaming agent is selected from at least one of a mineral oil defoaming agent or a silicone defoaming agent, and the thickener is selected from at least one of an alkali swelling thickener or an associated thickener.
As a further preferred embodiment, the alcohol ester-based coalescent may be selected from commercially available lauryl alcohol esters, the alcohol ether-based coalescent may be selected from commercially available one of ethylene glycol butyl ether, propylene glycol butyl ether, or dipropylene glycol monomethyl ether, and the alcohol ether ester-based coalescent may be selected from commercially available hexylene glycol butyl ether acetate or ethyl 3-ethoxypropionate.
A preparation method of sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 5-20 parts of lithium magnesium silicate, 2-10 parts of hydroxypropyl guar gum, 1-5 parts of polyanionic cellulose and 80-95 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 20-40 parts of deionized water, 10-30 parts of base paint emulsion, 1-3 parts of cellulose ether, 0.1-0.3 part of organic amine auxiliary agent, 0.5-1.5 parts of dispersing agent, 2-10 parts of surface modified pigment filler, 1-5 parts of film forming auxiliary agent, 1-3 parts of propylene glycol, 0.1-0.5 part of defoaming agent, 0.5-1.5 parts of composite protective adhesive and 30-50 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, cellulose ether, a dispersing agent, a defoaming agent, an organic amine additive and a surface modified pigment filler according to parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding a base paint emulsion, a film-forming additive and propylene glycol according to parts by weight, adding a composite protective adhesive according to parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand according to parts by weight for color mixing, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 10-20 parts of deionized water, 20-40 parts of composite protective adhesive and 50-75 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 10-40 parts of deionized water, 60-90 parts of body emulsion, 0.1-0.5 part of organic amine auxiliary agent, 1-5 parts of film-forming auxiliary agent, 0.2-0.6 part of defoaming agent and 1-3 parts of thickening agent;
(4-2) under low-speed stirring, sequentially adding deionized water, an organic amine assistant, a film-forming assistant and a defoaming agent according to parts by weight, stirring and mixing uniformly, adding the body emulsion according to parts by weight, properly increasing the rotating speed, adding a thickening agent, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the parts by weight, stirring and mixing uniformly at a low speed, adding the thickening agent according to the parts by weight to adjust the viscosity of the system to a proper viscosity, and continuously stirring at a low speed for a proper time until the materials are fully and uniformly mixed to obtain the sand-in-water colorful coating.
According to the invention, when preparing colorful particles, a composite protective adhesive and a basic color-mixing paint are used as raw materials, wherein magnesium lithium silicate adopted in the composite protective adhesive is a trioctahedral layered silicate mineral, the surface of a sheet of the composite protective adhesive is negatively charged, the end surface of the sheet is positively charged, and the end surface of the separated sheet is attracted to the surface of another sheet, so that a three-dimensional colloid structure, namely a card palace structure, can be quickly formed; the compound polyanionic cellulose has good compatibility with the magnesium silicate lithium, can be effectively filled in a colloid structure of a three-dimensional space formed by the magnesium silicate lithium, plays a role of enhancing compactness to the colloid structure, is supplemented with the hydroxypropyl guar gum, can quickly and effectively form a continuous and compact gel film to wrap color particles under the mutual synergistic action of the three components, further effectively inhibits substances and color paste in the base paint from overflowing to a continuous phase, has good protection effect on the colorful particles, and can greatly improve the color impermeability of the sand-in-water colorful coating. In addition, polyanionic cellulose adopted in the composite protective adhesive has excellent acid-base salt resistance and bacterial mildew resistance, is beneficial to enhancing the stability and antibacterial property of the sand-in-water multicolor paint, and can be matched with cellulose ether in a system to promote the stable expansion of a colloid structure formed by magnesium lithium silicate in a three-dimensional space, so that the balance of the wrapping property of color particles and the crosslinking property of the protective adhesive is maintained, the color point is not easy to break, the stability of the sand-in-water multicolor paint is further improved, and the polyanionic cellulose and the magnesium lithium silicate have good compatibility, can play a role of a wetting agent in the system, and can effectively improve the water-white resistance of the sand-in-water multicolor paint.
The sand-in-water multicolor paint has the advantages of wide raw material sources, simple preparation process conditions, good controllability, suitability for large-scale industrial production, excellent bleeding resistance, water-white resistance and storage stability, strong concave-convex feeling and rich colors after a paint film is dried, high simulation degree, simple construction conditions, good economic and practical properties and capability of meeting the requirement of low emission on environmental protection.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without making any creative effort, shall fall within the protection scope of the present invention.
The low-speed stirring and the high-speed stirring mentioned in the preparation method of the invention are conventional choices in the field, and the invention has no special requirements for the low-speed stirring and the high-speed stirring. In addition, the starting materials used in the present invention are commercially available unless otherwise specified.
The coating and the preparation method of the present invention will be further described with reference to the following specific examples.
Example 1:
the water-coated sand multicolor paint comprises the following components in parts by weight: 65 parts of multicolor particles, 40 parts of continuous phase emulsion and 2 parts of alkali swelling thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 20 parts of deionized water, 65 parts of acrylic emulsion, 950.2 parts of AMP, 2 parts of dodecyl alcohol ester, 0.3 part of mineral oil defoaming agent and 1 part of alkali swelling thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 15 parts of deionized water, 30 parts of composite protective adhesive and 60 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 35 parts of deionized water, 20 parts of acrylic emulsion, 1.5 parts of hydroxyethyl cellulose ether, AMP-950.1 parts of polyacrylic acid ammonium salt, 4 parts of surface modified pigment and filler, 2 parts of dodecyl alcohol ester, 1.2 parts of propylene glycol, 0.2 part of mineral oil defoaming agent, 0.8 part of composite protective adhesive and 35 parts of colored quartz sand; wherein the grain size of the color quartz sand is 100 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 10 ten thousand, the surface modified pigment filler is titanium dioxide of which the surface is coated with a polyacrylic acid coating (by the conventional pre-coating method), and the dosage of the polyacrylic acid coating is controlled to be 0.3 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 10 parts of lithium magnesium silicate, 5 parts of hydroxypropyl guar gum, 2 parts of polyanionic cellulose and 80 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 10 parts of lithium magnesium silicate, 5 parts of hydroxypropyl guar gum, 2 parts of polyanionic cellulose and 80 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 35 parts of deionized water, 20 parts of acrylic emulsion, 1.5 parts of hydroxyethyl cellulose ether, AMP-950.1 parts of polyacrylic acid ammonium salt, 4 parts of surface modified pigment and filler, 2 parts of dodecyl alcohol ester, 1.2 parts of propylene glycol, 0.2 part of mineral oil defoaming agent, 0.8 part of composite protective adhesive and 35 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, mineral oil defoaming agent, AMP-95 and surface modified pigment and filler in parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 micrometers, sequentially adding acrylic emulsion, lauryl alcohol ester and propylene glycol in parts by weight, adding composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 15 parts of deionized water, 30 parts of composite protective adhesive and 60 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 20 parts of deionized water, 65 parts of acrylic emulsion, 950.2 parts of AMP, 2 parts of dodecyl alcohol ester, 0.3 part of mineral oil defoaming agent and 1 part of alkali swelling thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, dodecyl alcohol ester and mineral oil defoaming agent in parts by weight, stirring and mixing uniformly, adding the pure acrylic emulsion in parts by weight, properly increasing the rotating speed, adding the alkali swelling thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the weight portion, stirring and mixing uniformly at a low speed, adding the alkali swelling thickener according to the weight portion to adjust the viscosity of the system to be proper, and continuously stirring at a low speed for proper time until the colorful particles are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 2:
the water-coated sand multicolor paint comprises the following components in parts by weight: 72 parts of multicolor particles, 38 parts of continuous phase emulsion and 4 parts of alkali swelling thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 35 parts of deionized water, 70 parts of acrylic emulsion, AMP-950.3 parts, 3 parts of dodecyl alcohol ester, 0.2 part of mineral oil defoaming agent and 2 parts of alkali swelling thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 12 parts of deionized water, 23 parts of composite protective adhesive and 70 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 30 parts of deionized water, 15 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, AMP-950.2 parts of polyacrylic acid ammonium salt, 6 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2 parts of propylene glycol, 0.2 part of mineral oil defoaming agent, 1 part of composite protective adhesive and 40 parts of colored quartz sand; wherein the grain size of the color quartz sand is 150 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 10 ten thousand, the surface modified pigment filler is organic modified bentonite of which the surface is coated with a polyacrylic acid coating (by the conventional pre-coating method), and the dosage of the polyacrylic acid coating is controlled to be 0.5 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 16 parts of lithium magnesium silicate, 4 parts of hydroxypropyl guar gum, 5 parts of polyanionic cellulose and 85 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 16 parts of lithium magnesium silicate, 4 parts of hydroxypropyl guar gum, 5 parts of polyanionic cellulose and 85 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 30 parts of deionized water, 15 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, AMP-950.2 parts of polyacrylic acid ammonium salt, 6 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2 parts of propylene glycol, 0.2 part of mineral oil defoaming agent, 1 part of composite protective adhesive and 40 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, mineral oil defoaming agent, AMP-95 and surface modified pigment and filler in parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 micrometers, sequentially adding acrylic emulsion, lauryl alcohol ester and propylene glycol in parts by weight, adding composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 12 parts of deionized water, 23 parts of composite protective adhesive and 70 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 35 parts of deionized water, 70 parts of acrylic emulsion, 70 parts of AMP-950.3 parts, 3 parts of dodecyl alcohol ester, 0.2 part of mineral oil defoaming agent and 2 parts of alkali swelling thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, dodecyl alcohol ester and mineral oil defoaming agent in parts by weight, stirring and mixing uniformly, adding the pure acrylic emulsion in parts by weight, properly increasing the rotating speed, adding the alkali swelling thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the weight portion, stirring and mixing uniformly at a low speed, adding the alkali swelling thickener according to the weight portion to adjust the viscosity of the system to be proper, and continuously stirring at a low speed for proper time until the colorful particles are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 3:
the water-coated sand multicolor paint comprises the following components in parts by weight: 60 parts of multicolor particles, 40 parts of continuous phase emulsion and 2 parts of alkali swelling thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 10 parts of deionized water, 60 parts of silicone-acrylate emulsion, 950.1 parts of AMP, 1 part of propylene glycol butyl ether, 0.2 part of organic silicon defoamer and 1 part of alkali swelling thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 10 parts of deionized water, 20 parts of composite protective adhesive and 50 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 20 parts of deionized water, 10 parts of acrylic emulsion, 1 part of hydroxyethyl cellulose ether, AMP-950.1 parts, 0.5 part of polyacrylic acid ammonium salt, 3 parts of surface modified pigment and filler, 1 part of propylene glycol butyl ether, 1 part of propylene glycol, 0.2 part of organic silicon defoamer, 0.8 part of composite protective glue and 30 parts of colored quartz sand; wherein the grain size of the color quartz sand is 80 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 8 ten thousand, the surface modified pigment filler is calcined kaolin coated with a polyvinyl alcohol coating (by the conventional spraying method), and the dosage of the polyvinyl alcohol coating is controlled to be 0.2 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 5 parts of lithium magnesium silicate, 2 parts of hydroxypropyl guar gum, 2 parts of polyanionic cellulose and 80 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 5 parts of lithium magnesium silicate, 2 parts of hydroxypropyl guar gum, 2 parts of polyanionic cellulose and 80 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 20 parts of deionized water, 10 parts of acrylic emulsion, 1 part of hydroxyethyl cellulose ether, AMP-950.1 parts, 0.5 part of polyacrylic acid ammonium salt, 3 parts of surface modified pigment and filler, 1 part of propylene glycol butyl ether, 1 part of propylene glycol, 0.2 part of organic silicon defoamer, 0.8 part of composite protective glue and 30 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, an organic silicon defoamer, AMP-95 and a surface modified pigment filler in parts by weight, properly increasing the rotating speed with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding acrylic emulsion, propylene glycol butyl ether and propylene glycol in parts by weight, adding a composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color adjustment, and uniformly stirring and mixing;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 10 parts of deionized water, 20 parts of composite protective adhesive and 50 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 10 parts of deionized water, 60 parts of silicone-acrylate emulsion, 950.1 parts of AMP, 1 part of propylene glycol butyl ether, 0.2 part of organic silicon defoamer and 1 part of alkali swelling thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, propylene glycol monobutyl ether and an organic silicon defoamer according to parts by weight, stirring and mixing uniformly, adding a silicone-acrylic emulsion according to parts by weight, properly increasing the rotating speed, adding an alkali swelling thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the weight portion, stirring and mixing uniformly at a low speed, adding the alkali swelling thickener according to the weight portion to adjust the viscosity of the system to be proper, and continuously stirring at a low speed for proper time until the colorful particles are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 4:
the water-coated sand multicolor paint comprises the following components in parts by weight: 80 parts of multicolor particles, 50 parts of continuous phase emulsion and 5 parts of associative thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 40 parts of deionized water, 90 parts of vinyl acetate-acrylic emulsion, 5 parts of TCP-950.5 parts of butyl cellosolve acetate, 0.6 part of organic silicon defoamer and 3 parts of associative thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 20 parts of deionized water, 40 parts of composite protective adhesive and 75 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 40 parts of deionized water, 30 parts of acrylic emulsion, 3 parts of hydroxyethyl cellulose ether, 3 parts of TCP-950.3 parts, 1.5 parts of polyacrylic acid ammonium salt, 10 parts of surface modified pigment and filler, 5 parts of butyl cellosolve acetate, 3 parts of propylene glycol, 0.5 part of organic silicon defoamer, 1.5 parts of composite protective adhesive and 50 parts of colored quartz sand; wherein the grain size of the color quartz sand is 100 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 5 ten thousand, the surface modified pigment filler is calcined kaolin coated with a polyvinyl alcohol coating (by the conventional spraying method), and the dosage of the polyvinyl alcohol coating is controlled to be 1 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 20 parts of lithium magnesium silicate, 10 parts of hydroxypropyl guar gum, 5 parts of polyanionic cellulose and 95 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 20 parts of lithium magnesium silicate, 10 parts of hydroxypropyl guar gum, 5 parts of polyanionic cellulose and 95 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 40 parts of deionized water, 30 parts of acrylic emulsion, 3 parts of hydroxyethyl cellulose ether, 3 parts of TCP-950.3 parts, 1.5 parts of polyacrylic acid ammonium salt, 10 parts of surface modified pigment and filler, 5 parts of butyl cellosolve acetate, 3 parts of propylene glycol, 0.5 part of organic silicon defoamer, 1.5 parts of composite protective adhesive and 50 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, an organic silicon defoamer, TCP-95 and a surface modified pigment filler in parts by weight, properly increasing the rotating speed with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding acrylic emulsion, hexanediol butyl ether acetate and propylene glycol in parts by weight, adding a composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 20 parts of deionized water, 40 parts of composite protective adhesive and 75 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 40 parts of deionized water, 90 parts of vinyl acetate-acrylic emulsion, 5 parts of TCP-950.5 parts of butyl cellosolve acetate, 0.6 part of organic silicon defoamer and 3 parts of associative thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, TCP-95, hexanediol butyl ether acetate and an organic silicon defoamer according to parts by weight, stirring and mixing uniformly, adding a vinyl acetate-acrylic emulsion according to parts by weight, properly increasing the rotating speed, adding an associative thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the parts by weight, stirring and mixing uniformly at a low speed, adding the associative thickener according to the parts by weight to adjust the viscosity of the system to a proper viscosity, and continuously stirring at a low speed for a proper time until the materials are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 5:
the water-coated sand multicolor paint comprises the following components in parts by weight: 76 parts of multicolor particles, 42 parts of continuous phase emulsion and 2 parts of associative thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 28 parts of deionized water, 72 parts of silicone-acrylate emulsion, AMP-950.3 parts, 2.5 parts of dodecyl alcohol ester, 0.2 part of organic silicon defoamer and 2 parts of associative thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 18 parts of deionized water, 32 parts of composite protective adhesive and 65 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 36 parts of deionized water, 20 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, 2 parts of AMP-950.3 parts, 1.1 parts of polyacrylic acid ammonium salt, 7 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2.4 parts of propylene glycol, 0.2 part of organic silicon defoamer, 1 part of composite protective glue and 45 parts of colored quartz sand; wherein the grain size of the color quartz sand is 200 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 10 ten thousand, the surface modified pigment filler is calcined kaolin coated with a polyacrylic acid coating (by the conventional spraying method), and the dosage of the polyacrylic acid coating is controlled to be 0.6 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 8 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 83 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 8 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 83 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 36 parts of deionized water, 20 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, 2 parts of AMP-950.3 parts, 1.1 parts of polyacrylic acid ammonium salt, 7 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2.4 parts of propylene glycol, 0.2 part of organic silicon defoamer, 1 part of composite protective glue and 45 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, an organic silicon defoamer, AMP-95 and a surface modified pigment filler in parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding acrylic emulsion, lauryl alcohol ester and propylene glycol in parts by weight, adding a composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 18 parts of deionized water, 32 parts of composite protective adhesive and 65 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 28 parts of deionized water, 72 parts of silicone-acrylate emulsion, AMP-950.3 parts, 2.5 parts of dodecyl alcohol ester, 0.2 part of organic silicon defoamer and 2 parts of associative thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, dodecyl alcohol ester and an organic silicon defoamer according to parts by weight, stirring and mixing uniformly, adding a silicone-acrylic emulsion according to parts by weight, increasing the rotating speed properly, adding an associative thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the parts by weight, stirring and mixing uniformly at a low speed, adding the associative thickener according to the parts by weight to adjust the viscosity of the system to a proper viscosity, and continuously stirring at a low speed for a proper time until the materials are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 6:
the water-coated sand multicolor paint comprises the following components in parts by weight: 76 parts of multicolor particles, 42 parts of continuous phase emulsion and 2 parts of alkali swelling thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 28 parts of deionized water, 72 parts of silicone-acrylate emulsion, AMP-950.3 parts, 2.5 parts of dodecyl alcohol ester, 0.2 part of organic silicon defoamer and 2 parts of alkali swelling thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 18 parts of deionized water, 32 parts of composite protective adhesive and 65 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 36 parts of deionized water, 20 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, 2 parts of AMP-950.3 parts, 1.1 parts of polyacrylic acid ammonium salt, 7 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2.4 parts of propylene glycol, 0.2 part of organic silicon defoamer, 1 part of composite protective glue and 45 parts of colored quartz sand; wherein the grain size of the color quartz sand is 200 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 10 ten thousand, the surface modified pigment filler is calcined kaolin coated with a polyacrylic acid coating (by the conventional spraying method), and the dosage of the polyacrylic acid coating is controlled to be 0.6 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 8 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 83 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 8 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 83 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 36 parts of deionized water, 20 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, 2 parts of AMP-950.3 parts, 1.1 parts of polyacrylic acid ammonium salt, 7 parts of surface modified pigment and filler, 3 parts of dodecyl alcohol ester, 2.4 parts of propylene glycol, 0.2 part of organic silicon defoamer, 1 part of composite protective glue and 45 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, an organic silicon defoamer, AMP-95 and a surface modified pigment filler in parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding acrylic emulsion, lauryl alcohol ester and propylene glycol in parts by weight, adding a composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 18 parts of deionized water, 32 parts of composite protective adhesive and 65 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 28 parts of deionized water, 72 parts of silicone-acrylate emulsion, AMP-950.3 parts, 2.5 parts of dodecyl alcohol ester, 0.2 part of organic silicon defoamer and 2 parts of alkali swelling thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, dodecyl alcohol ester and an organic silicon defoaming agent according to parts by weight, stirring and mixing uniformly, adding a silicone-acrylic emulsion according to parts by weight, properly increasing the rotating speed, adding an alkali swelling thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the weight portion, stirring and mixing uniformly at a low speed, adding the alkali swelling thickener according to the weight portion to adjust the viscosity of the system to be proper, and continuously stirring at a low speed for proper time until the colorful particles are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Example 7:
the water-coated sand multicolor paint comprises the following components in parts by weight: 64 parts of multicolor particles, 36 parts of continuous phase emulsion and 5 parts of alkali swelling thickener, wherein the continuous phase emulsion comprises the following components in parts by weight: 30 parts of deionized water, 70 parts of silicone-acrylate emulsion, AMP-950.5 parts, 3 parts of dodecyl alcohol ester, 0.5 part of organic silicon defoaming agent and 3 parts of alkali swelling thickener.
In the embodiment, the multicolor particles are prepared by granulating the following raw materials in parts by weight through a granulator: 16 parts of deionized water, 28 parts of composite protective adhesive and 56 parts of basic toning colored paint.
The basic toning colored paint comprises the following components in parts by weight: 38 parts of deionized water, 16 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, AMP-950.2 parts of polyacrylic acid ammonium salt, 5 parts of surface modified pigment and filler, 2 parts of dodecyl alcohol ester, 2 parts of propylene glycol, 0.5 part of organic silicon defoamer, 0.9 part of composite protective glue and 40 parts of colored quartz sand; wherein the grain size of the color quartz sand is 200 meshes, and the porosity is less than or equal to 10 percent; the relative molecular mass of the hydroxyethyl cellulose ether is 10 ten thousand, the surface modified pigment filler is calcined kaolin coated with a polyacrylic acid coating (by the conventional spraying method), and the dosage of the polyacrylic acid coating is controlled to be 0.3 percent of the total mass of the surface modified pigment filler.
The composite protective adhesive comprises the following components in parts by weight: 16 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 90 parts of deionized water.
The preparation method of the sand-in-water multicolor paint comprises the following steps:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 16 parts of lithium magnesium silicate, 6 parts of hydroxypropyl guar gum, 3 parts of polyanionic cellulose and 90 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 38 parts of deionized water, 16 parts of acrylic emulsion, 2 parts of hydroxyethyl cellulose ether, AMP-950.2 parts of polyacrylic acid ammonium salt, 5 parts of surface modified pigment and filler, 2 parts of dodecyl alcohol ester, 2 parts of propylene glycol, 0.5 part of organic silicon defoamer, 0.9 part of composite protective glue and 40 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, hydroxyethyl cellulose ether, ammonium polyacrylate, an organic silicon defoamer, AMP-95 and a surface modified pigment filler in parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding acrylic emulsion, lauryl alcohol ester and propylene glycol in parts by weight, adding a composite protective adhesive in parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand in parts by weight for color matching, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 16 parts of deionized water, 28 parts of composite protective adhesive and 56 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 30 parts of deionized water, 70 parts of silicone-acrylate emulsion, 70 parts of AMP-950.5 parts, 3 parts of dodecyl alcohol ester, 0.5 part of organic silicon defoamer and 3 parts of alkali swelling thickener;
(4-2) under low-speed stirring, sequentially adding deionized water, AMP-95, dodecyl alcohol ester and an organic silicon defoaming agent according to parts by weight, stirring and mixing uniformly, adding a silicone-acrylic emulsion according to parts by weight, properly increasing the rotating speed, adding an alkali swelling thickener, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the weight portion, stirring and mixing uniformly at a low speed, adding the alkali swelling thickener according to the weight portion to adjust the viscosity of the system to be proper, and continuously stirring at a low speed for proper time until the colorful particles are fully and uniformly mixed to obtain the sand-in-water colorful coating.
Comparative example 1:
the formulation of the sand-in-water multicolor paint of the comparative example is substantially the same as that of example 7, except that the protective adhesive used in the comparative example is prepared by mixing 16 parts by weight of lithium magnesium silicate and 90 parts by weight of deionized water, and the rest is the same as that of example 7.
Comparative example 2:
the formula composition of the sand-in-water multicolor paint of the comparative example is basically the same as that of the example 7, except that the pigment and filler adopted in the formula of the basic toning paint of the comparative example is the common commercially available titanium dioxide, and the rest is the same as that of the example 7.
Comparative example 3:
the sand-in-water multicolor paint of the comparative example is a certain commercially available water-based multicolor architectural paint (which only adopts lithium magnesium silicate as the main component of the protective adhesive).
The sand-in-water multicolor paints of examples 1 to 7 and comparative examples 1 to 3 were subjected to a heat storage stability test (test method: HG/T4343-2012.5.4.3), a low temperature stability test (test method: HG/T4343-2012.5.4.4), a water resistance test (test water-resistant time) and a stain resistance test (test method: GB/T9280-2005) according to the present invention, and the test results are shown in Table 1 below.
Table 1 results of performance testing
Figure 1
As can be seen from Table 1, the sand-in-water multicolor paint of the invention has good heat storage stability, no bleeding phenomenon, outstanding bleeding resistance, low temperature stability, water resistance and stain resistance which all meet the industrial standards, and has very wide market prospect.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the foregoing description only for the purpose of illustrating the principles of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims, specification, and equivalents thereof.

Claims (10)

1. The sand-in-water multicolor paint is characterized by comprising the following components in parts by weight: 60-80 parts of multicolor particles, 30-50 parts of continuous phase emulsion and 1-5 parts of thickening agent, wherein the continuous phase emulsion comprises the following components in parts by weight: 10-40 parts of deionized water, 60-90 parts of body emulsion, 0.1-0.5 part of organic amine auxiliary agent, 1-5 parts of film-forming auxiliary agent, 0.2-0.6 part of defoaming agent and 1-3 parts of thickening agent.
2. The sand-in-water multicolor paint of claim 1, wherein the multicolor particles are prepared by granulating raw materials comprising a composite protective adhesive and a basic toning color paint through a granulator, and the composite protective adhesive is a composite protective adhesive comprising magnesium lithium silicate.
3. The sand-in-water multicolor paint as claimed in claim 2, wherein the raw materials comprising the composite protective glue and the basic toning paint comprise the following components in parts by weight: 10-20 parts of deionized water, 20-40 parts of composite protective adhesive and 50-75 parts of basic toning colored paint.
4. The sand-in-water multicolor paint of claim 3, wherein the basic toning color paint comprises the following components in parts by weight: 20-40 parts of deionized water, 10-30 parts of base paint emulsion, 1-3 parts of cellulose ether, 0.1-0.3 part of organic amine auxiliary agent, 0.5-1.5 parts of dispersing agent, 2-10 parts of surface modified pigment and filler, 1-5 parts of film forming auxiliary agent, 1-3 parts of propylene glycol, 0.1-0.5 part of defoaming agent, 0.5-1.5 parts of composite protective adhesive and 30-50 parts of colored quartz sand.
5. The sand-in-water multicolor paint according to any one of claims 2 to 4, wherein the composite protective glue comprises the following components in parts by weight: 5-20 parts of lithium magnesium silicate, 2-10 parts of hydroxypropyl guar gum, 1-5 parts of polyanionic cellulose and 80-95 parts of deionized water.
6. The sand-in-water multicolor paint as claimed in claim 4, wherein the base paint emulsion is selected from acrylic emulsion, the organic amine auxiliary agent is selected from one of TCP-95 or AMP-95, the dispersant is selected from at least one of polyacrylic acid ammonium salt, polyacrylamide or fatty acid polyglycol ester, the particle size of the colored quartz sand is 80-200 meshes, and the porosity is less than or equal to 10%.
7. The sand-in-water multicolor paint of claim 4, wherein the surface-modified color filler is a color filler whose surface is coated with a hydrophilic polymer coating.
8. The sand-in-water multicolor paint of claim 7, wherein the pigment and filler is at least one selected from titanium dioxide, organically modified bentonite or calcined kaolin, and the hydrophilic polymer is any one selected from polyacrylic acid or polyvinyl alcohol.
9. The sand-in-water multicolor paint of claim 1 or 4, wherein the bulk emulsion is selected from any one of pure acrylic emulsion, silicone acrylic emulsion or vinyl acetate acrylic emulsion, the film forming aid is selected from at least one of alcohol ester film forming aid, alcohol ether film forming aid or alcohol ether ester film forming aid, the defoamer is selected from at least one of mineral oil defoamer or silicone defoamer, and the thickener is selected from at least one of alkali swelling thickener or associative thickener.
10. The method of claim 1, comprising the steps of:
(1) preparing a composite protective adhesive:
(1-1) preparing the following components in parts by weight: 5-20 parts of lithium magnesium silicate, 2-10 parts of hydroxypropyl guar gum, 1-5 parts of polyanionic cellulose and 80-95 parts of deionized water;
(1-2) weighing deionized water according to parts by weight, adding hydroxypropyl guar gum and polyanionic cellulose while stirring, adding magnesium lithium silicate after uniformly mixing, and fully stirring and uniformly mixing;
(2) preparing basic toning paint:
(2-1) preparing the following components in parts by weight: 20-40 parts of deionized water, 10-30 parts of base paint emulsion, 1-3 parts of cellulose ether, 0.1-0.3 part of organic amine auxiliary agent, 0.5-1.5 parts of dispersing agent, 2-10 parts of surface modified pigment filler, 1-5 parts of film forming auxiliary agent, 1-3 parts of propylene glycol, 0.1-0.5 part of defoaming agent, 0.5-1.5 parts of composite protective adhesive and 30-50 parts of colored quartz sand;
(2-2) under low-speed stirring, sequentially adding deionized water, cellulose ether, a dispersing agent, a defoaming agent, an organic amine additive and a surface modified pigment filler according to parts by weight, properly increasing the rotating speed along with the increase of the viscosity of the system, dispersing at a high speed, reducing the rotating speed after measuring the fineness of less than or equal to 30 microns, sequentially adding a base paint emulsion, a film-forming additive and propylene glycol according to parts by weight, adding a composite protective adhesive according to parts by weight to adjust the viscosity of the system to be proper, finally adding colored quartz sand according to parts by weight for color mixing, and stirring and mixing uniformly;
(3) preparing multicolor particles:
(3-1) preparing the following components in parts by weight: 10-20 parts of deionized water, 20-40 parts of composite protective adhesive and 50-75 parts of basic toning colored paint;
(3-2) under low-speed stirring, sequentially adding deionized water and a composite protective adhesive in parts by weight, adding basic toning paint in parts by weight according to the color point proportion of the multicolor sample plate, uniformly mixing, and granulating by a multicolor paint granulator to obtain multicolor particles with proper sizes;
(4) preparing a continuous phase emulsion:
(4-1) preparing the following components in parts by weight: 10-40 parts of deionized water, 60-90 parts of body emulsion, 0.1-0.5 part of organic amine auxiliary agent, 1-5 parts of film-forming auxiliary agent, 0.2-0.6 part of defoaming agent and 1-3 parts of thickening agent;
(4-2) under low-speed stirring, sequentially adding deionized water, an organic amine assistant, a film-forming assistant and a defoaming agent according to parts by weight, stirring and mixing uniformly, adding the body emulsion according to parts by weight, properly increasing the rotating speed, adding a thickening agent, and stirring and mixing uniformly;
(5) preparing a finished sand-in-water multicolor paint product:
slowly adding the colorful particles into the continuous phase emulsion according to the parts by weight, stirring and mixing uniformly at a low speed, adding the thickening agent according to the parts by weight to adjust the viscosity of the system to a proper viscosity, and continuously stirring at a low speed for a proper time until the materials are fully and uniformly mixed to obtain the sand-in-water colorful coating.
CN202010335327.XA 2020-04-24 2020-04-24 Sand-in-water multicolor paint and preparation method thereof Pending CN111500133A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010335327.XA CN111500133A (en) 2020-04-24 2020-04-24 Sand-in-water multicolor paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010335327.XA CN111500133A (en) 2020-04-24 2020-04-24 Sand-in-water multicolor paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111500133A true CN111500133A (en) 2020-08-07

Family

ID=71866291

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010335327.XA Pending CN111500133A (en) 2020-04-24 2020-04-24 Sand-in-water multicolor paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN111500133A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462247A (en) * 2021-08-10 2021-10-01 卡本科技集团股份有限公司 Water-based sand-containing multicolor paint and preparation method thereof
CN114015340A (en) * 2021-12-01 2022-02-08 厦门富思特新材料科技有限公司 Sand-in-water multicolor paint and preparation method and application thereof
CN114479589A (en) * 2022-01-25 2022-05-13 福州居家逸涂料科技有限公司 Hemp color stone paint and preparation method thereof
CN115491069A (en) * 2022-06-15 2022-12-20 浙江虹达特种橡胶制品有限公司杭州分公司 Coated article
CN115637080A (en) * 2022-09-09 2023-01-24 上海保立佳化学技术有限公司 Light-weight high-toughness sand-in-water multicolor paint and preparation method thereof
CN115926554B (en) * 2022-12-12 2024-02-06 成都迪泰化工有限公司 Multi-color elegant crystal stone coating and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103952051A (en) * 2014-05-22 2014-07-30 富思特新材料科技发展股份有限公司 Internally-crosslinked multicolor paint and preparation method thereof
US20150183265A1 (en) * 2012-09-28 2015-07-02 Valspar Sourcing, Inc. Multilayered Laminate and Process For Preparing The Same
CN106366814A (en) * 2016-08-25 2017-02-01 上海磐彩环保科技股份有限公司 Sand-containing colorful environment-friendly coating and preparation method of same
CN106752482A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料（上海）股份有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN108384356A (en) * 2018-01-15 2018-08-10 河北晨阳工贸集团有限公司 Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof
CN109233519A (en) * 2018-09-06 2019-01-18 江门市工匠环保新材料有限公司 Imitation marble paint and its preparation method and application
CN110358384A (en) * 2019-06-14 2019-10-22 河北晨阳工贸集团有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN110372265A (en) * 2019-06-21 2019-10-25 河北晨阳工贸集团有限公司 A kind of water burnt-in sand coating and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150183265A1 (en) * 2012-09-28 2015-07-02 Valspar Sourcing, Inc. Multilayered Laminate and Process For Preparing The Same
CN103952051A (en) * 2014-05-22 2014-07-30 富思特新材料科技发展股份有限公司 Internally-crosslinked multicolor paint and preparation method thereof
CN106752482A (en) * 2015-11-25 2017-05-31 铂恩塞尔新材料（上海）股份有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN106366814A (en) * 2016-08-25 2017-02-01 上海磐彩环保科技股份有限公司 Sand-containing colorful environment-friendly coating and preparation method of same
CN108384356A (en) * 2018-01-15 2018-08-10 河北晨阳工贸集团有限公司 Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof
CN109233519A (en) * 2018-09-06 2019-01-18 江门市工匠环保新材料有限公司 Imitation marble paint and its preparation method and application
CN110358384A (en) * 2019-06-14 2019-10-22 河北晨阳工贸集团有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
CN110372265A (en) * 2019-06-21 2019-10-25 河北晨阳工贸集团有限公司 A kind of water burnt-in sand coating and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113462247A (en) * 2021-08-10 2021-10-01 卡本科技集团股份有限公司 Water-based sand-containing multicolor paint and preparation method thereof
CN114015340A (en) * 2021-12-01 2022-02-08 厦门富思特新材料科技有限公司 Sand-in-water multicolor paint and preparation method and application thereof
CN114479589A (en) * 2022-01-25 2022-05-13 福州居家逸涂料科技有限公司 Hemp color stone paint and preparation method thereof
CN115491069A (en) * 2022-06-15 2022-12-20 浙江虹达特种橡胶制品有限公司杭州分公司 Coated article
CN115491069B (en) * 2022-06-15 2023-05-30 浙江虹达特种橡胶制品有限公司杭州分公司 Coated article
CN115637080A (en) * 2022-09-09 2023-01-24 上海保立佳化学技术有限公司 Light-weight high-toughness sand-in-water multicolor paint and preparation method thereof
CN115926554B (en) * 2022-12-12 2024-02-06 成都迪泰化工有限公司 Multi-color elegant crystal stone coating and preparation method thereof

Similar Documents

Publication Publication Date Title
CN111500133A (en) Sand-in-water multicolor paint and preparation method thereof
CN113462247B (en) Water-based sand-containing multicolor paint and preparation method thereof
CN106590268A (en) Real-stone paint and preparation method thereof
CN107129735A (en) A kind of artificial granite speckle multicolor finish of waterproof and heat-insulating and preparation method thereof
CN109777223A (en) Colorful stone-like coating and preparation method thereof
CN109535878A (en) One kind is containing colorful stone-like coating of sand and preparation method thereof
CN113698804A (en) Crack-resistant and water-resistant all-inorganic coating and preparation method thereof
CN107118645A (en) A kind of waterproof artificial granite speckle multicolor finish and preparation method thereof
CN115124898A (en) Granite coating and preparation method thereof
CN104497728B (en) Net taste aqueous colorful coating compositions and preparation method thereof
CN103937355B (en) Base paint of waterborne stone-like coating and preparation method thereof
CN111621206A (en) Color-adjustable water-based self-thickening building coating and preparation method thereof
CN113088111A (en) Real stone texture coating with potassium silicate as main film forming substance and preparation method thereof
CN111117331A (en) Colorful water-based paint with fluorescent effect
CN115109483B (en) Rolling-coating stone-like paint, preparation method and application thereof
CN109988474A (en) A kind of early stage excellent water resistance water burnt-in sand multicolor finish
CN105860718A (en) Self-cleaning heat-insulating stone imitating water-based paint and preparing method
CN113956734B (en) Light easy-to-clean sand-in-water multicolor paint and preparation method and application thereof
CN115286945A (en) Compound inorganic resin, preparation method and single-component micro-cement artistic coating
CN111849272A (en) Sand coating and preparation method thereof
CN115960507A (en) Batch-scraping multifunctional colorful putty and preparation method thereof
CN110218497B (en) Corrosion-resistant water-based paint and preparation process thereof
CN113604124A (en) Water-based finishing paint and preparation method and application thereof
CN114133768A (en) Base paint, water-based inorganic sandstone-containing colored paint for exterior wall and preparation method thereof
CN109336455B (en) Colored coated hollow ceramic microsphere material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination