CN108384356A - Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof - Google Patents

Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof Download PDF

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Publication number
CN108384356A
CN108384356A CN201810036113.5A CN201810036113A CN108384356A CN 108384356 A CN108384356 A CN 108384356A CN 201810036113 A CN201810036113 A CN 201810036113A CN 108384356 A CN108384356 A CN 108384356A
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China
Prior art keywords
sand
color
added
novel evacuated
multicolor finish
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CN201810036113.5A
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Chinese (zh)
Inventor
薛小倩
刘洪亮
胡中源
董立志
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201810036113.5A priority Critical patent/CN108384356A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of novel evacuated sieving water burnt-in sand multicolor finishes and preparation method thereof.The novel evacuated sieving water burnt-in sand multicolor finish of one kind of the present invention, the novel evacuated sieving water burnt-in sand multicolor finish include that by mass percentage following group is grouped as:Dispersed phase color-mixed base paint 40 50%, continuous phase varnish 30% protect sol solution 20 30%.Concave-convex sense is strong and rich in color after the paint film drying of the present invention, and fidelity is high, and colour retention is high.

Description

Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof
Technical field
The present invention relates to paint fields, and in particular to the novel evacuated sieving water burnt-in sand multicolor finish of one kind and its preparation side Method.
Background technology
Water-in-water multicolor coating can be divided into oil packet oil, Water-In-Oil, oil-in-water, 4 class of water-water, with the research of water paint Constantly bring forth new ideas, the raising that China's Efforts To Develop requires Water-borne modification the research of water-soluble colorful coating and people, preceding three classes base This is eliminated, and water-in-water multicolor coating becomes the hot spot of research.Water-in-water multicolor coating is also known as liquid granite, therefore water-water is more Color coating material is the fidelity for reaching part stone material, it is necessary to assure coating has concave-convex sense after construction, therefore in water-in-water multicolor coating Addition quartz sand has become following development trend, but based on water burnt-in sand is mixed colours with aqueous color paste mostly currently on the market, and matches Square stability is poor, is primarily present following technical bottleneck:
First, based on existing water burnt-in sand system needs to mix colours with aqueous color paste, concave-convex sense is poor after paint film drying, to part stone Material fidelity is poor, and colour retention is low.Secondly, color is single in color grain after existing water burnt-in sand system paint film drying, and color is not abundant enough. Again, based on existing water burnt-in sand system is sliced with dispersion machine mostly, color grain is easily influenced by shearing force, and limitation is larger, repeatability It is bad, it is difficult to control.
Invention content
Strong the purpose of the present invention is to provide concave-convex sense after a kind of drying of paint film and coloury novel evacuated sieving water Burnt-in sand multicolor finish and preparation method thereof.
In order to achieve the above objectives, present invention employs following technical proposals:The novel evacuated sieving water packet of one kind of the present invention Sand multicolor finish, the novel evacuated sieving water burnt-in sand multicolor finish include that by mass percentage following group is grouped as:
Dispersed phase color-mixed base paint 50%,
Continuous phase varnish 30%,
Protect sol solution 20%.
Further, the dispersed phase color-mixed base paint is made of white basis paint and colorful quartz sands,
The dispersed phase color-mixed base paint includes that by mass percentage following group is grouped as:
Further, the continuous phase varnish by mass percentage following group is grouped as:
Further, the protection sol solution is by mass percentage:
Protection glue powder 6-7%,
Deionized water 93-94%.
Further, the cellulose is hydroxyethyl cellulose;The wetting agent dispersant is ammonium polyacrylate salt Dispersant;The color stuffing is the combination of one or both of rutile type titanium white, calcined kaolin;The film forming Auxiliary agent is 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates;The white basis paint acrylic emulsion is organic nothing Machine complex emulsions, admittedly containing 50%, the high-performance hydrophobic elastomeric lotion with splendid water resistance, the synthetic emulsion of continuous phase varnish is The silicone acrylic emulsion of silicone cross-linked type, grain size is in 80nm, solid content 43%;The antifoaming agent is in mineral oil defoaming agent One or two kinds of combinations;The pH adjusting agent is 2-amino-2-methyl-1-propanol;The color sand is that sintering is color One or more combinations in sand or high-performance dyeing color sand, and naturally adopt sand ratio, rich in color with bright in luster, resistance to Hou Xingqiang, wear-resisting acid and alkali-resistance, impurity content≤0.5%, porosity≤10%, acid-fast alkali-proof 8h are unchanged.
By selecting high-performance color sand to mix colours, high-performance hydrophobic elastomeric lotion of arranging in pairs or groups and extra-weather-proof silicone acrylic emulsion make The advantages such as water burnt-in sand has concave-convex sense strong, and weather resistance is good, flexibility is good.
Further, the Protection glue powder is lithium magnesium silicate;The thickener is the swollen class thickening of association type alkali soluble Agent.
The preparation method of novel evacuated sieving water burnt-in sand multicolor finish of the present invention, includes the following steps:
(1) it is spare to prepare dispersed phase color-mixed base paint:The accurate each component weighed described in claim 2, it is suitable to select Color sand is added in white basis paint and mixes colours, and stirs evenly, and dispersed phase color-mixed base paint is made;
(2) Protection glue solution for standby is prepared;
(3) it is spare to prepare continuous phase varnish;
(4) the dispersed phase color-mixed base paint mixed colours in step (1) is added in protection sol solution, is sieved with colorful particle Filter selects suitable sieve to be granulated;It is added in continuous phase varnish, is uniformly mixed by the particle is made in step (2); Novel evacuated sieving water burnt-in sand multicolor finish is made.
Further, in step (1), the preparation of dispersed phase color-mixed base paint:
Step1 accurately weighs each component of claim 2, is first added to the container deionized water, is slowly added to cellulose, 4-5min is stirred with the speed of 450-500r/min;
PH adjusting agent is added in step2, and pH value is transferred to 8-8.5, is slowly added to wetting agent and dispersant successively, will be calcined Kaolin is added to the container, and 30-40min is stirred with the speed of 1000-1200r/min;
Step3 sequentially adds coalescents, propylene glycol and aqueous acrylic emulsion in the mixture obtained by step2, stirs It is smooth to surface to mix 5-10min, then sequentially adds antifoaming agent, fungicide and protection sol solution, dispersed phase color-mixed base is made Paint.
Further, in step (2), the preparation of sol solution is protected:
Deionized water, is first added to the container by the accurate each component for weighing claim 4, starts dispersion 200-300r/ Protection glue powder is added to the container, then high speed dispersion by min, and 30-40min, system are stirred with the speed of 1000-1200r/min Sol solution must be protected.
Further, in step (3), the preparation of continuous phase varnish:
Step1 accurately weighs each component of claim 3, is first added to the container deionized water, and synthesis breast is then added Liquid starts dispersion 200-300r/min;
Step2 is slowly added to coalescents, propylene glycol, pH adjusting agent, antifoaming agent and fungicide, 400-500r/ successively Min stirs 10-15min, spare;
Thickener and deionized water are 1 according to mass ratio by step3:1 open it is dilute after, be slowly added to, 400-500r/min is stirred 15-20min is mixed, continuous phase varnish is made;The thickening efficiency of pure thickener is high, is on the one hand not easily controlled dosage, on the other hand It is not easy to scatter.After dilution, dosage can be controlled, is also easy to be uniformly dispersed, the coating of viscous consistency is made, is thickened after avoiding Problem.
In step (4), the colorful particle straining machine is the full of power and grandeur colorful particle straining machine of DC types in Jiangsu.
Advantageous effect:Concave-convex sense is strong and rich in color after paint film drying of the present invention, and fidelity is high, and colour retention is high.
Compared with prior art, the invention has the advantages that:
(1) it is not necessarily to aqueous color paste toning and is directly added into that colorful quartz sands toning, dry film concave-convex sense is strong, colour retention bright in luster Well, there is high emulation to stone material and production is stablized.
(2) natural colour sand or calcining color sand are selected, rich in color, concave-convex sense is strong after paint film drying, and fidelity is better than existing The colorful system of water burnt-in sand.Aqueous color paste toning is abandoned, water burnt-in sand system, which is not easy surfactant in by aqueous color paste, to be influenced to lead Cause system is unstable;Vacuum straining machine is selected to be granulated, production paint stability improves.
(3) in dispersed phase color-mixed base paint the surfactant in aqueous color paste is avoided without adding aqueous color paste toning The stability of the colorful system of water burnt-in sand is influenced, colour retention is high.Add color sand in dispersed phase, concave-convex sense is strong after paint film drying and color Abundant, fidelity is high.It selects vacuum straining machine to be granulated, coloured silk grain when Workshop Production is avoided to be influenced to cause broken point is more to ask by shearing force Topic occurs.
Specific implementation mode
By following embodiment, present invention be described in more detail, but should be noted that the scope of the present invention is not implemented by these Any restrictions of example.
Embodiment 1
The novel evacuated sieving water burnt-in sand multicolor finish of one kind of the present invention, the novel evacuated colorful painting of sieving water burnt-in sand Material is grouped as including following group by mass percentage:
Dispersed phase color-mixed base paint 50%,
Continuous phase varnish 30%,
Protect sol solution 20%.
The dispersed phase color-mixed base paint is made of white basis paint and colorful quartz sands,
The dispersed phase color-mixed base paint includes that by mass percentage following group is grouped as:
The white basis paint:
The continuous phase varnish by mass percentage following group is grouped as:
The protection sol solution is by mass percentage:
Protection glue powder 6.5%,
Deionized water 93.5%.
The cellulose is hydroxyethyl cellulose;The wetting agent dispersant is ammonium polyacrylate dipersant;Institute The color stuffing stated is rutile type titanium white;The coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates; The white basis paint is organo-mineral complexing lotion with acrylic emulsion, admittedly contain 50%, the high property with splendid water resistance Energy hydrophobic elastomeric lotion, the synthetic emulsion of continuous phase varnish are the silicone acrylic emulsion of silicone cross-linked type, and grain size is in 80nm, solid content It is 43%;The antifoaming agent is the combination of one or both of mineral oil defoaming agent;The pH adjusting agent is 2- Amino-2-methyl -1- propyl alcohol;The color sand is that high-performance dyes color sand, impurity content≤0.5% of the color sand, hole Porosity≤10%, acid-fast alkali-proof 8h are unchanged.
The Protection glue powder is lithium magnesium silicate;The thickener is the swollen class thickener of association type alkali soluble.
The preparation method of novel evacuated sieving water burnt-in sand multicolor finish of the present invention, includes the following steps:(1) it prepares Dispersed phase color-mixed base paint is spare:It is accurate to weigh each component, it selects suitable color sand to be added in white basis paint and carries out Toning, stirs evenly, and dispersed phase color-mixed base paint is made;
The preparation of dispersed phase color-mixed base paint:
Deionized water, is first added to the container by each component that step1 is accurately weighed, and is slowly added to cellulose, with 500r/ The speed of min stirs 5min;
PH adjusting agent is added in step2, and pH value is transferred to 8, is slowly added to wetting agent and dispersant successively, will calcine kaolinite Soil is added to the container, and 30min is stirred with the speed of 1000r/min;
Step3 sequentially adds coalescents, propylene glycol and aqueous acrylic emulsion in the mixture obtained by step2, stirs It is smooth to surface to mix 10min, then sequentially adds antifoaming agent, fungicide and protection sol solution, dispersed phase color-mixed base paint is made.
(2) Protection glue solution for standby is prepared;
Protect the preparation of sol solution:
Each component accurately is weighed, is first added to the container deionized water, dispersion 300r/min is started, Protection glue powder is added Enter in container, then high speed dispersion, 30min is stirred with the speed of 1200r/min, protection sol solution is made.
(3) it is spare to prepare continuous phase varnish;
The preparation of continuous phase varnish:
Step1 accurately weighs each component, is first added to the container deionized water, and synthetic emulsion is then added, and starts dispersion 300r/min;
Step2 is slowly added to coalescents, propylene glycol, pH adjusting agent, antifoaming agent and fungicide successively, and 500r/min is stirred 10min is mixed, it is spare;
Thickener and deionized water are 1 according to mass ratio by step3:1 open it is dilute after, be slowly added to, 500r/min stirring Continuous phase varnish is made in 15min;
(4) the dispersed phase color-mixed base paint mixed colours in step (1) is added in protection sol solution, is sieved with colorful particle Filter selects suitable sieve to be granulated;It is added in continuous phase varnish, is uniformly mixed by the particle is made in step (2); Novel evacuated sieving water burnt-in sand multicolor finish is made.The colorful particle straining machine is the colorful particle sieve of the full of power and grandeur DC types in Jiangsu Filter.
Embodiment 2
Embodiment 2 and embodiment 1 difference lies in:
The novel evacuated sieving water burnt-in sand multicolor finish of one kind of the present invention, the novel evacuated colorful painting of sieving water burnt-in sand Material is grouped as including following group by mass percentage:
Dispersed phase color-mixed base paint 40%,
Continuous phase varnish 30%,
Protect sol solution 30%.
The dispersed phase color-mixed base paint is made of white basis paint and colorful quartz sands,
The dispersed phase color-mixed base paint includes that by mass percentage following group is grouped as:
The white basis paint:
The continuous phase varnish by mass percentage following group is grouped as:
The protection sol solution is by mass percentage:
Protection glue powder 6%,
Deionized water 94%.
The combination that the color stuffing is two kinds in rutile type titanium white and calcined kaolin;The color sand is sintering One or more combinations in color sand or high-performance dyeing color sand.
The Protection glue powder is lithium magnesium silicate;The thickener is the swollen class thickener of association type alkali soluble.
The preparation method of novel evacuated sieving water burnt-in sand multicolor finish of the present invention, includes the following steps:In step (1) in, it is spare to prepare dispersed phase color-mixed base paint:It is accurate to weigh each component, select suitable color sand that white base is added It mixes colours, stirs evenly in plinth paint, dispersed phase color-mixed base paint is made;
The preparation of dispersed phase color-mixed base paint:
Step1 accurately weighs each component, is first added to the container deionized water, is slowly added to cellulose, with 450r/min Speed stir 4min;
PH adjusting agent is added in step2, and pH value is transferred to 8.2, is slowly added to wetting agent and dispersant successively, and calcining is high Ridge soil is added to the container, and 40min is stirred with the speed of 1200r/min;
Step3 sequentially adds coalescents, propylene glycol and aqueous acrylic emulsion in the mixture obtained by step2, stirs It is smooth to surface to mix 7min, then sequentially adds antifoaming agent, fungicide and protection sol solution, dispersed phase color-mixed base paint is made.
In step (2), Protection glue solution for standby is prepared;
Protect the preparation of sol solution:
Each component accurately is weighed, is first added to the container deionized water, dispersion 200r/min is started, Protection glue powder is added Enter in container, then high speed dispersion, 32min is stirred with the speed of 1000r/min, protection sol solution is made.
In step (3), it is spare to prepare continuous phase varnish;
The preparation of continuous phase varnish:
Step1 accurately weighs each component, is first added to the container deionized water, and synthetic emulsion is then added, and starts dispersion 250r/min;
Step2 is slowly added to coalescents, propylene glycol, pH adjusting agent, antifoaming agent and fungicide successively, and 400r/min is stirred 15min is mixed, it is spare;
Thickener and deionized water are 1 according to mass ratio by step3:1 open it is dilute after, be slowly added to, 450r/min stirring Continuous phase varnish is made in 20min.
Embodiment 3
Embodiment 3 and embodiment 1 difference lies in:
The novel evacuated sieving water burnt-in sand multicolor finish of one kind of the present invention, the novel evacuated colorful painting of sieving water burnt-in sand Material is grouped as including following group by mass percentage:
Dispersed phase color-mixed base paint 45%,
Continuous phase varnish 35%,
Protect sol solution 20%.
The dispersed phase color-mixed base paint is made of white basis paint and colorful quartz sands, dispersed phase toning base Plinth enamel-cover include by mass percentage following group is grouped as:
The white basis paint:
The continuous phase varnish by mass percentage following group is grouped as:
The protection sol solution is by mass percentage:
Protection glue powder 7%,
Deionized water 93%.
The cellulose is hydroxyethyl cellulose;The wetting agent dispersant is ammonium polyacrylate dipersant;Institute The color stuffing stated is calcined kaolin;The coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates;It is described Acrylic emulsion be aqueous organically-modified emulsion acrylic resin;The antifoaming agent is one kind in mineral oil defoaming agent Or several combination;The pH adjusting agent is 2-amino-2-methyl-1-propanol;The color sand is burning colorful sand.
The Protection glue powder is lithium magnesium silicate;The thickener is the swollen class thickener of association type alkali soluble.
The preparation method of novel evacuated sieving water burnt-in sand multicolor finish of the present invention, includes the following steps:In step (1) in, it is spare to prepare dispersed phase color-mixed base paint:It is accurate to weigh each component, select suitable color sand that white base is added It mixes colours, stirs evenly in plinth paint, dispersed phase color-mixed base paint is made;
The preparation of dispersed phase color-mixed base paint:
Deionized water, is first added to the container by each component that step1 is accurately weighed, and is slowly added to cellulose, with 480r/ The speed of min stirs 4.5min;
PH adjusting agent is added in step2, and pH value is transferred to 8.5, is slowly added to wetting agent and dispersant successively, and calcining is high Ridge soil is added to the container, and 35min is stirred with the speed of 1100r/min;
Step3 sequentially adds coalescents, propylene glycol and aqueous acrylic emulsion in the mixture obtained by step2, stirs It is smooth to surface to mix 5min, then sequentially adds antifoaming agent, fungicide and protection sol solution, dispersed phase color-mixed base paint is made.
In step (2), Protection glue solution for standby is prepared;
Protect the preparation of sol solution:
Each component accurately is weighed, is first added to the container deionized water, dispersion 200r/min is started, Protection glue powder is added Enter in container, then high speed dispersion, 40min is stirred with the speed of 1100r/min, protection sol solution is made.
In step (3), it is spare to prepare continuous phase varnish;
The preparation of continuous phase varnish:
Step1 accurately weighs each component, is first added to the container deionized water, and synthetic emulsion is then added, and starts dispersion 250r/min;
Step2 is slowly added to coalescents, propylene glycol, pH adjusting agent, antifoaming agent and fungicide successively, and 450r/min is stirred 12min is mixed, it is spare;
Thickener and deionized water are 1 according to mass ratio by step3:1 open it is dilute after, be slowly added to, 400r/min stirring Continuous phase varnish is made in 18min.
Embodiment 4
Embodiment 4 and embodiment 1 difference lies in:
The novel evacuated sieving water burnt-in sand multicolor finish of one kind of the present invention, the novel evacuated colorful painting of sieving water burnt-in sand Material is grouped as including following group by mass percentage:
Dispersed phase color-mixed base paint 50%,
Continuous phase varnish 25%,
Protect sol solution 25%.
The continuous phase varnish by mass percentage following group is grouped as:
Experiment 1
The test result of implementation 1 to the embodiment 3 of the present invention meets HG/T 4343-2012《Aqueous colorful building applies Material》Flexible standard in standard, table 1 are other detection projects:
Table 1
As shown in table 1, it can be seen that by using organo-mineral complexing lotion and silicone acrylic emulsion according to the above experimental data Dye the collocation of color sand and burning colorful sand with high-performance, film performance is substantially better than national Testing index, film concave-convex sense it is strong and It is rich in color, there is excellent weatherability, resistance to acid and alkali, and cover the ability of blind crack.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, the present invention Claimed range is delineated by the appended claims, the specification and equivalents thereof from the appended claims.

Claims (10)

1. a kind of novel evacuated sieving water burnt-in sand multicolor finish, it is characterised in that:The novel evacuated sieving water burnt-in sand is colorful Coating includes that by mass percentage following group is grouped as:
Dispersed phase color-mixed base paint 40-50%,
Continuous phase varnish 25-35%,
Protect sol solution 20-30%.
2. novel evacuated sieving water burnt-in sand multicolor finish according to claim 1, it is characterised in that:The dispersed phase tune Color base paint is made of white basis paint and colorful quartz sands, and the dispersed phase color-mixed base paint includes by mass percentage Following group is grouped as:
3. novel evacuated sieving water burnt-in sand multicolor finish according to claim 1, it is characterised in that:The continuous phase is clear Following group painted by mass percentage is grouped as:
4. novel evacuated sieving water burnt-in sand multicolor finish according to claim 1, it is characterised in that:The protection peptization Liquid is by mass percentage:
Protection glue powder 6-7%,
Deionized water 93-94%.
5. novel evacuated sieving water burnt-in sand multicolor finish according to claim 1, it is characterised in that:The cellulose is Hydroxyethyl cellulose;The wetting agent dispersant is ammonium polyacrylate dipersant;The color stuffing is rutile type titanium The combination of one or both of white powder, calcined kaolin;The coalescents are 2,2,4- trimethyl -1,3- pentanediol lists Isobutyrate;The white basis paint is organo-mineral complexing lotion with acrylic emulsion, admittedly contain 50%, continuous phase varnish Synthetic emulsion is the silicone acrylic emulsion of silicone cross-linked type, and grain size is in 80nm, solid content 43%;The antifoaming agent is mineral oil The combination of one or both of class antifoaming agent;The pH adjusting agent is 2-amino-2-methyl-1-propanol;The coloured silk Sand is that burning colorful sand or high-performance dye one or more combinations in color sand, impurity content≤0.5% of the color sand, Porosity≤10%.
6. novel evacuated sieving water burnt-in sand multicolor finish according to claim 1, it is characterised in that:The protection rubber powder Body is lithium magnesium silicate;The thickener is the swollen class thickener of association type alkali soluble.
7. the preparation method of novel evacuated sieving water burnt-in sand multicolor finish described in claim 1, it is characterised in that including as follows Step:
(1) it is spare to prepare dispersed phase color-mixed base paint:The accurate each component weighed described in claim 2, selects suitable color sand It is added in white basis paint and mixes colours, stir evenly, dispersed phase color-mixed base paint is made;
(2) Protection glue solution for standby is prepared;
(3) it is spare to prepare continuous phase varnish;
(4) the dispersed phase color-mixed base paint mixed colours in step (1) is added in protection sol solution, with colorful particle straining machine Suitable sieve is selected to be granulated;It is added in continuous phase varnish, is uniformly mixed by the particle is made in step (2);It is made Novel evacuated sieving water burnt-in sand multicolor finish.
8. the preparation method of novel evacuated sieving water burnt-in sand multicolor finish according to claim 7, it is characterised in that:
In step (1), the preparation of dispersed phase color-mixed base paint:
Step1 accurately weighs each component of claim 2, is first added to the container deionized water, is slowly added to cellulose, with The speed of 450-500r/min stirs 4-5min;
PH adjusting agent is added in step2, and pH value is transferred to 8-8.5, is slowly added to wetting agent and dispersant successively, will calcine kaolinite Soil is added to the container, and 30-40min is stirred with the speed of 1000-1200r/min;
Step3 sequentially adds coalescents, propylene glycol and aqueous acrylic emulsion in the mixture obtained by step2, stir 5- 10min is smooth to surface, then sequentially adds antifoaming agent, fungicide and protection sol solution, dispersed phase color-mixed base paint is made.
9. the preparation method of novel evacuated sieving water burnt-in sand multicolor finish according to claim 7, it is characterised in that:
In step (2), the preparation of sol solution is protected:
Deionized water, is first added to the container by the accurate each component for weighing claim 4, starts dispersion 200-300r/min, will Protection glue powder is added to the container, then high speed dispersion, stirs 30-40min with the speed of 1000-1200r/min, protection is made Sol solution.
10. the preparation method of novel evacuated sieving water burnt-in sand multicolor finish according to claim 7, it is characterised in that:
In step (3), the preparation of continuous phase varnish:
Step1 accurately weighs each component of claim 3, is first added to the container deionized water, and synthetic emulsion is then added, and opens Dynamic dispersion 200-300r/min;
Step2 is slowly added to coalescents, propylene glycol, pH adjusting agent, antifoaming agent and fungicide successively, and 400-500r/min is stirred 10-15min is mixed, it is spare;
Thickener and deionized water are 1 according to mass ratio by step3:1 open it is dilute after, be slowly added to, 400-500r/min stir 15- Continuous phase varnish is made in 20min;
In step (4), the colorful particle straining machine is the full of power and grandeur colorful particle straining machine of DC types in Jiangsu.
CN201810036113.5A 2018-01-15 2018-01-15 Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof Withdrawn CN108384356A (en)

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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108485437A (en) * 2018-04-25 2018-09-04 廊坊旭博涂立德新型材料科技有限公司 A kind of colorful paint formula
CN108997875A (en) * 2018-09-07 2018-12-14 上海贝塔建筑科技有限公司 A kind of stone-like coating and preparation method thereof
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CN111484778A (en) * 2019-01-28 2020-08-04 嘉兴市威纳建材有限公司 Cross-linking reaction type sand-in-water colorful granite stone-like coating and preparation method thereof
CN111500133A (en) * 2020-04-24 2020-08-07 容七英 Sand-in-water multicolor paint and preparation method thereof
CN111607294A (en) * 2019-02-23 2020-09-01 湖南梨树园涂料有限公司 Sand-in-water multi-color paint toning bag and preparation method thereof
CN111748250A (en) * 2019-03-28 2020-10-09 河北晨阳工贸集团有限公司 Anion sand-in-water multicolor paint and preparation method thereof
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CN115678372A (en) * 2022-10-14 2023-02-03 江西易必居新型建材有限公司 Novel colorful stone-like paint and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104109440A (en) * 2014-07-01 2014-10-22 芜湖县双宝建材有限公司 Waterproof weather-resistant acrylate exterior wall coating
CN104194457A (en) * 2014-08-29 2014-12-10 亚士漆(上海)有限公司 Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof
CN106366814A (en) * 2016-08-25 2017-02-01 上海磐彩环保科技股份有限公司 Sand-containing colorful environment-friendly coating and preparation method of same
CN107227111A (en) * 2017-07-20 2017-10-03 中山市粤马建筑涂料有限公司 A kind of new type water burnt-in sand coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104109440A (en) * 2014-07-01 2014-10-22 芜湖县双宝建材有限公司 Waterproof weather-resistant acrylate exterior wall coating
CN104194457A (en) * 2014-08-29 2014-12-10 亚士漆(上海)有限公司 Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof
CN106366814A (en) * 2016-08-25 2017-02-01 上海磐彩环保科技股份有限公司 Sand-containing colorful environment-friendly coating and preparation method of same
CN107227111A (en) * 2017-07-20 2017-10-03 中山市粤马建筑涂料有限公司 A kind of new type water burnt-in sand coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
苏国徽等: "水性含砂多彩涂料的制备与性能研究", 《涂料工业》 *

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