CN111073380A - Preparation method of protective adhesive for sand-in-water multicolor paint - Google Patents
Preparation method of protective adhesive for sand-in-water multicolor paint Download PDFInfo
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- CN111073380A CN111073380A CN201911391243.1A CN201911391243A CN111073380A CN 111073380 A CN111073380 A CN 111073380A CN 201911391243 A CN201911391243 A CN 201911391243A CN 111073380 A CN111073380 A CN 111073380A
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- protective adhesive
- protective
- sand
- hectorite
- layered double
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/26—Cellulose ethers
- C08L1/28—Alkyl ethers
- C08L1/284—Alkyl ethers with hydroxylated hydrocarbon radicals
Abstract
The invention relates to the technical field of preparation of sand-in-water multicolor paint, and discloses protective glue for sand-in-water multicolor paint, which comprises, by mass, 40-50% of dispersed phase toning base paint, 25-35% of continuous phase varnish and 20-30% of protective glue solution, wherein the protective glue solution comprises 6-7% of protective glue powder and 93-94% of deionized water. According to the preparation method of the protective adhesive for the sand-in-water multicolor paint, through the setting in the step 3, various additives with certain mass percentage are added during the preparation of the protective adhesive, so that the protective adhesive is mixed with the protective adhesive before becoming a colloid, the stability and reliability of the whole protective adhesive are higher, and through the setting in the step 1, the layered double metal hydroxide is added into the protective adhesive, the adsorbability and the wrapping property of the protective adhesive to colored quartz are effectively improved, and the color of the whole paint is kept gorgeous and cannot be subjected to color bleeding.
Description
Technical Field
The invention relates to the technical field of preparation of sand-in-water multicolor coatings, in particular to a preparation method of a protective adhesive for a sand-in-water multicolor coating.
Background
As a novel building coating, the sand-in-water multicolor coating is a popular product of the stone-like coating for the outer wall in recent years, and the emulsion content is higher, so that the simulation effect of patterns is richer and fuller, compared with the water-in-water multicolor coating, the sand-in-water multicolor coating has better strength and better weather resistance, and is mainly combined by a disperse phase (colored quartz) and a continuous phase (silicone-acrylic solution) which are not mutually soluble, and a certain amount of protective adhesive needs to be added into the multicolor coating in order to prevent color mixing among colored particles, so that the shape, the strength and the stability of the colored quartz can be directly influenced by selecting and preparing the protective adhesive.
At present, protective glue is used as an additive for preparing multicolor paint and is mixed with other substances, but the protective glue is gelatinous and has larger whole viscosity, so that the protective glue is difficult to be fully and uniformly mixed with other additives, the components of each part of the protective glue have larger difference, the stability of the whole structure is poorer, the strength is lower when the colored quartz is coated, and the outdoor harsh use condition is difficult to meet.
Disclosure of Invention
Technical problem to be solved
The invention provides a preparation method of a protective adhesive for a sand-in-water multicolor paint, which has the advantages of high stability and strength, capability of meeting harsh outdoor use conditions and long service life, and solves the problems that the protective adhesive is mixed with other substances as an additive for preparing the multicolor paint, but the protective adhesive is difficult to be fully and uniformly mixed with other additives due to the gelatinous protective adhesive and high whole viscosity, so that colored quartz has poor stability and low strength and is difficult to meet the harsh outdoor use conditions.
(II) technical scheme
The invention provides the following technical scheme: the protective adhesive for the sand-in-water multicolor paint comprises, by mass, 40% -50% of dispersed phase toning base paint, 25% -35% of continuous phase varnish and 20% -30% of protective adhesive solution, wherein the protective adhesive solution comprises 6% -7% of protective adhesive powder and 93% -94% of deionized water.
Preferably, the protective colloid powder is a mixture consisting of hectorite (lithium magnesium silicate) and layered double hydroxide in a mass ratio of 4: 6.
Preferably, the protective glue solution is added with 0.1-0.2% of associated cellulose, 0.4-0.8% of antifreezing agent, 0.04-0.08% of defoaming agent, 0.1-0.2% of preservative and 0.04-0.06% of pH regulator.
A preparation method of a protective adhesive for sand-in-water multicolor paint comprises the following preparation processes:
step 1, respectively weighing quantitative hectorite and layered double-metal oxide according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, respectively grinding the hectorite and the layered double-metal oxide to be below 250 meshes, baking the hectorite and the layered double-metal oxide at the temperature of 500 ℃ for 2-3 h, taking out the hectorite and the layered double-metal oxide, and cooling the hectorite and the layered double-metal oxide in a drying oven to room temperature to respectively prepare hectorite powder and layered double-metal;
step 2, weighing a certain amount of deionized water according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, pouring the deionized water into a stirring tank, stirring the deionized water at the speed of 1000-1500 r/min by using a high-speed dispersion machine, uniformly and slowly adding the prepared hectorite powder and layered double-metal hydroxide powder into the stirring tank, and dispersing and stirring the mixture for 30-60 min;
and 3, adding the additives except the PH regulator in the claim 3 into the protective colloid solution in a dropwise manner according to the proportion, simultaneously reducing the speed of the high-speed dispersion machine to 800-1200 r/min, stirring for 15-45 min, and standing for 24h to obtain the protective colloid solution.
(III) advantageous effects
The invention has the following beneficial effects:
1. according to the preparation method of the protective adhesive for the sand-in-water multicolor paint, through the arrangement of the step 3, various additives in certain mass percentage are added during the preparation of the protective adhesive, so that the protective adhesive is mixed with the protective adhesive before the protective adhesive becomes a colloid, the components of the various additives in the protective adhesive are mixed uniformly, and the stability and the reliability of the whole protective colloid are high.
2. According to the preparation method of the protective adhesive for the sand-in-water multicolor paint, through the arrangement of the step 1, other moisture in the protective adhesive powder can be effectively removed, so that the problem that the protective adhesive is polluted by the moisture remained in the protective adhesive powder is solved, and the adsorbability and the wrapping property of the protective adhesive to colored quartz are effectively improved by adding the layered double hydroxide, so that the color of the whole paint is kept gorgeous and the phenomenon of color bleeding cannot occur.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The protective adhesive for the sand-in-water multicolor paint comprises, by mass, 40% -50% of dispersed phase toning base paint, 25% -35% of continuous phase varnish and 20% -30% of protective adhesive solution, wherein the protective adhesive solution comprises 6% -7% of protective adhesive powder and 93% -94% of deionized water.
Wherein, the dispersed phase toning base paint is prepared by mixing 0.7-1.2% of hydroxyethyl cellulose, adding the mixture into 40-55% of deionized water, dripping 0.2-0.3% of AMP-95 (a multifunctional amine assistant agent which has stable pH value and has wetting and dispersing effects) into the mixture, stirring the mixture for 0.5h at the speed of 800-1000 r/min, simultaneously adding 0.2-0.4% of dispersing agent, 0.1-0.2% of wetting agent and 10-20% of colored quartz in sequence, increasing the rotating speed to 3000-4000 r/min, stirring the mixture at a high speed for 30-60 min, then reducing the rotating speed to 1000-1500 r/min, adding 20-30% of silicone-acrylic emulsion, 1-2% of film forming assistant agent, 0.8-1.5% of propylene glycol, 0.1-0.2% of preservative agent and 3-10% of the protective adhesive solution in sequence, and stirring the mixture for 10-15 min, finally, adding a proper amount of thickening agent to adjust the viscosity to a proper value, and obtaining the dispersed phase toning base paint.
Wherein, the impurity content in the added colored quartz is less than or equal to 0.5 percent, and the porosity is less than or equal to 10 percent.
The continuous phase varnish is prepared by adding 10-15% of deionized water and 75-85% of silicone-acrylate emulsion into a stirring tank, stirring at a speed of 200-300 r/min for 10-50 min, then sequentially adding 2-3% of a film-forming aid, 1-2% of propylene glycol, 0.2-0.3% of a defoaming agent and 0.1-0.15% of a preservative, stirring at a speed of 300-500 r/min for 10-50 min, then diluting 0.1-0.15% of a thickening agent and deionized water at a mass ratio of 1:1, adding the diluted thickening agent and deionized water, and stirring at a speed of 500-800 r/min for 15-30 min.
In the technical scheme, the protective colloid powder is a mixture consisting of hectorite (lithium magnesium silicate) and layered double hydroxide in a mass ratio of 4: 6.
Wherein the metal cation is selected from Ca2+、Mg2+、Mn2+、Fe2+、Cu2+Or Zn2+And the hydroxide anion can be selected from NO3-、Cl-F-or Br-Any one of them.
In the technical scheme, 0.1-0.2% of association type cellulose, 0.4-0.8% of antifreezing agent, 0.04-0.08% of defoaming agent, 0.1-0.2% of preservative and 0.04-0.06% of pH regulator are added into the protective glue solution.
Wherein the associative cellulose is a mixture of hydroxyethyl methyl cellulose and hydroxyethyl cellulose with the viscosity of 350-700 mPa.S and 3400-5000 mPa.S respectively in a mass ratio of 1:1.8, and the pH regulator adopts one or two mixed solutions of industrial sodium hydroxide or potassium hydroxide.
Detailed description of the preferred embodiment
A preparation method of a protective adhesive for sand-in-water multicolor paint comprises the following preparation processes:
step 1, respectively weighing quantitative hectorite and layered double-metal oxide according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, respectively grinding the hectorite and the layered double-metal oxide to be below 250 meshes, baking the hectorite and the layered double-metal oxide at the temperature of 500 ℃ for 2-3 h, taking out the hectorite and the layered double-metal oxide, and cooling the hectorite and the layered double-metal oxide in a drying oven to room temperature to respectively prepare hectorite powder and layered double-metal;
step 2, weighing a certain amount of deionized water according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, pouring the deionized water into a stirring tank, stirring the deionized water at the speed of 1000-1500 r/min by using a high-speed dispersion machine, slowly and uniformly adding the protective adhesive powder which is weighed and mixed according to the proportion into the stirring tank, and performing dispersion stirring for 30-60 min;
step 3, adding the additives except the PH regulator in the claim 3 into the protective colloid solution in a dropwise manner according to the proportion, simultaneously reducing the speed of a high-speed dispersion machine to 800-1200 r/min, stirring for 15-45 min, and standing for 24h to obtain the protective colloid solution;
and 4, continuously and uniformly adding the prepared dispersed phase toning base paint and the prepared continuous phase varnish into a stirring tank according to the mass percent of claim 1, adjusting and controlling the dropping amount of the pH regulator according to the pH value of the solution to ensure that the pH value is between 8 and 8.5, and continuously stirring the solution at the speed of 400 to 800r/min for 15 to 30min to obtain the sand-in-water multicolor paint.
The preparation process of the protective adhesive for the sand-in-water multicolor paint and the improvement of the additive enable the protective adhesive to have good wrapping property on the colored quartz in the dispersed phase toning base paint, compared with the existing preparation process of the sand-in-water multicolor paint, the color displayed by the colored paint is rich and gorgeous, the stability and the corrosion resistance are high, fine cracks generated after the colorful paint is dried can be covered, and the attractive appearance is good.
Detailed description of the invention
A preparation method of a protective adhesive for sand-in-water multicolor paint comprises the following preparation processes:
step 1, respectively weighing quantitative hectorite and layered double-metal oxide according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, respectively grinding the hectorite and the layered double-metal oxide to be below 250 meshes, baking the hectorite and the layered double-metal oxide at the temperature of 500 ℃ for 2-3 h, taking out the hectorite and the layered double-metal oxide, and cooling the hectorite and the layered double-metal oxide in a drying oven to room temperature to respectively prepare hectorite powder and layered double-metal;
step 2, weighing a certain amount of deionized water according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, pouring the deionized water into a stirring tank, stirring the deionized water at the speed of 1000-1500 r/min by using a high-speed dispersion machine, uniformly and slowly adding the prepared hectorite powder and layered double-metal hydroxide powder into the stirring tank, and dispersing and stirring the mixture for 30-60 min;
and 3, continuously and uniformly adding the prepared dispersed phase toning base paint, continuous phase varnish, various additives except the pH regulator in claim 3, the prepared hectorite powder and the prepared layered double hydroxide powder into a stirring tank according to the mass percent of claim 1, adjusting and controlling the dropping amount of the pH regulator according to the pH value of the solution to enable the pH value to be 8-8.5, and continuously stirring the solution at the speed of 400-800 r/min for 15-30 min to obtain the water-coated sand multicolor paint.
Wherein, the additives in claim 3 are added into the protective glue solution to be stirred and mixed, then the dispersed phase toning base paint and the continuous phase varnish are sequentially added to prepare the sand-in-water multicolor paint, so that the color paint has stronger concave-convex feeling and better color vividness after being dried, and the problem of poor toning stability of the water-based color paste can be well avoided by utilizing the color quartz toning mode, if the additives are not added into the protective glue solution, but are directly stirred and mixed with the dispersed phase toning base paint and the continuous phase varnish according to the mass percentage, the mixing of the additives in the whole sand-in-water multicolor paint is not uniform, the color of the sand-in-water multicolor paint after being dried and formed is more fuzzy, and the color is darker than that of the specific embodiment, and the stability of the colorful coating after spraying is poor due to poor mixing uniformity of the colorful coating, so that the colorful coating is easy to corrode and fall off.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (4)
1. The protective adhesive for the sand-in-water multicolor paint comprises, by mass, 40% -50% of dispersed phase toning base paint, 25% -35% of continuous phase varnish and 20% -30% of protective adhesive solution, and is characterized in that the protective adhesive solution comprises 6% -7% of protective adhesive powder and 93% -94% of deionized water.
2. The protective adhesive for sand-in-water multicolor paint according to claim 1, characterized in that: the protective colloid powder is a mixture consisting of hectorite and layered double hydroxide in a mass ratio of 4: 6.
3. The protective adhesive for sand-in-water multicolor paint according to claim 1, characterized in that: the protective glue solution is added with 0.1-0.2% of association cellulose, 0.4-0.8% of antifreeze, 0.04-0.08% of defoamer, 0.1-0.2% of preservative and 0.04-0.06% of PH regulator.
4. The preparation method of the protective adhesive for the sand-in-water multicolor paint is characterized by comprising the following preparation processes:
step 1, respectively weighing quantitative hectorite and layered double-metal oxide according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, respectively grinding the hectorite and the layered double-metal oxide to be below 250 meshes, baking the hectorite and the layered double-metal oxide at the temperature of 500 ℃ for 2-3 h, taking out the hectorite and the layered double-metal oxide, and cooling the hectorite and the layered double-metal oxide in a drying oven to room temperature to respectively prepare hectorite powder and layered double-metal;
step 2, weighing a certain amount of deionized water according to the mass percent according to the preparation amount of the sand-in-water multicolor paint protective adhesive, pouring the deionized water into a stirring tank, stirring the deionized water at the speed of 1000-1500 r/min by using a high-speed dispersion machine, uniformly and slowly adding the prepared hectorite powder and layered double hydroxide powder into the stirring tank, and dispersing and stirring the mixture for 30-60 min;
and 3, adding the additives except the PH regulator in the claim 3 into the protective colloid solution in a dropwise manner according to the proportion, simultaneously reducing the speed of a high-speed dispersion machine to 800-1200 r/min, stirring for 15-45 min, and standing for 24h to obtain the protective colloid solution.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201911391243.1A CN111073380A (en) | 2019-12-30 | 2019-12-30 | Preparation method of protective adhesive for sand-in-water multicolor paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201911391243.1A CN111073380A (en) | 2019-12-30 | 2019-12-30 | Preparation method of protective adhesive for sand-in-water multicolor paint |
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| CN111073380A true CN111073380A (en) | 2020-04-28 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111808467A (en) * | 2020-07-31 | 2020-10-23 | 广州博峰化工科技有限公司 | Protective adhesive, preparation and application thereof |
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| CN109503026A (en) * | 2017-11-13 | 2019-03-22 | 天津德普威涂料有限公司 | A kind of colorful water burnt-in sand coating of high durable and preparation method thereof |
| CN110372265A (en) * | 2019-06-21 | 2019-10-25 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand coating and preparation method thereof |
| CN110564188A (en) * | 2019-09-11 | 2019-12-13 | 亚士漆(上海)有限公司 | Sand-in-water coating and preparation method and application thereof |
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| CN109503026A (en) * | 2017-11-13 | 2019-03-22 | 天津德普威涂料有限公司 | A kind of colorful water burnt-in sand coating of high durable and preparation method thereof |
| CN108384356A (en) * | 2018-01-15 | 2018-08-10 | 河北晨阳工贸集团有限公司 | Novel evacuated sieving water burnt-in sand multicolor finish of one kind and preparation method thereof |
| CN110372265A (en) * | 2019-06-21 | 2019-10-25 | 河北晨阳工贸集团有限公司 | A kind of water burnt-in sand coating and preparation method thereof |
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| CN111808467A (en) * | 2020-07-31 | 2020-10-23 | 广州博峰化工科技有限公司 | Protective adhesive, preparation and application thereof |
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Application publication date: 20200428 |
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