CN112375444A - 5D stone-like paint - Google Patents

5D stone-like paint Download PDF

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Publication number
CN112375444A
CN112375444A CN202011291721.4A CN202011291721A CN112375444A CN 112375444 A CN112375444 A CN 112375444A CN 202011291721 A CN202011291721 A CN 202011291721A CN 112375444 A CN112375444 A CN 112375444A
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parts
stone
paint
preservative
agent
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陈中
翁金城
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Fuzhou Jujiayi Coating Technology Co ltd
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Fuzhou Jujiayi Coating Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a 5D stone-like paint, which belongs to the technical field of stone-like paints, and comprises 6% of protective glue, a disperse phase and a continuous phase; the dispersed phase comprises hydroxyethyl cellulose, glycol, anionic styrene-acrylic emulsion, nano hollow ceramic microspheres, AMP95, 6% protective glue, snowflake white and other components; the continuous phase comprises ethylene glycol, a film forming auxiliary agent, AMP95, a defoaming agent, pure acrylic emulsion with nanometer particle size, KZ125 thickened emulsion and the like. The spraying area of this 5D imitative mineral varnish unit volume is showing and is improving, compares in traditional 5D imitative mineral varnish, and spraying area can promote 20-30% under the same quantity, can reduce user's cost by a wide margin, and gained paint film performance is unchangeable, and this 5D imitative mineral varnish stability is high simultaneously, can stable storage 8-12 months not appear dividing the problem of water, layering.

Description

5D stone-like paint
Technical Field
The invention belongs to the technical field of stone-like paint, and particularly relates to 5D stone-like paint.
Background
The 5D stone-like paint is different from common stone-like paint, the simulation degree of the 5D stone-like paint is extremely high, the color of the 5D stone-like paint can be the same as that of stone, the rough particle touch feeling which is extremely close can be achieved, and the touch can not be completely distinguished even if the 5D stone-like paint is observed in a close range. For example, the invention patent of China with the application number of 201810810560.1 discloses a sand-in-water multicolor thermal-crosslinking 5D nest stone paint, which is prepared by preparing pure tap water, protective rubber powder, a dustproof agent, cellulose, titanium dioxide, kaolin, a preservative, ethylene glycol, a film-forming additive, an emulsion, a defoaming agent, a multifunctional additive, a thickening agent and quartz sand into a protective liquid aqueous solution, a base paint, a finished product base emulsion and a finished product base material, and then preparing a finished product; the artificial stone has the characteristics of higher artificial stone degree, simple construction, low cost and high grinding strength. The appearance of the 5D stone-like paint solves the problems that the common stone-like paint has a good appearance in terms of simulation degree and has a long difference in surface condition and texture. However, in order to ensure the coating effect, the coating using amount of the 5D stone-like paint in unit area is large, and the cost is high.
Disclosure of Invention
In order to overcome the defects of the prior art, the technical problems to be solved by the invention are as follows: how to improve the unit coating area of the 5D stone-like paint.
In order to solve the technical problems, the invention adopts the technical scheme that: the 5D stone-like paint comprises 6% of protective glue, a disperse phase and a continuous phase;
the dispersed phase comprises hydroxyethyl cellulose, an ammonium salt dispersant, a wetting agent, a defoaming agent, titanium dioxide, kaolin, a film-forming auxiliary agent, ethylene glycol, anionic styrene-acrylic emulsion, nano hollow ceramic microspheres, AMP95, 6% protective glue, snow white, a preservative and water;
the continuous phase comprises ethylene glycol, a film forming aid, AMP95, a defoaming agent, a pure acrylic emulsion with a nano particle size, a KZ125 thickening emulsion, a thickening agent, a preservative and water.
The invention has the beneficial effects that: the invention provides a 5D stone-like paint, which is prepared by adding nano hollow ceramic microspheres in a dispersed phase, adding KZ125 thickening emulsion in a continuous phase and mixing the emulsion with protective glue to obtain the 5D stone-like paint, wherein the spraying area per unit dosage is obviously increased, compared with the traditional 5D stone-like paint, the spraying area can be increased by 20-30% under the same dosage, the cost of a user can be greatly reduced, the performance of the obtained paint film is unchanged, meanwhile, the 5D stone-like paint can be stably stored for 8-12 months without the problems of water diversion and layering, and the stability is greatly improved compared with the existing 5D stone-like paint which can only be stably stored for 1-3 months.
Drawings
FIG. 1 is a diagram showing the effect of 5D stone-like paint according to an embodiment of the present invention after spraying;
FIG. 2 is a diagram showing the effect of 5D stone-like paint according to an embodiment of the present invention after spraying;
FIG. 3 is a graph showing a comparison between 5D stone-like paints of examples and comparative examples according to an embodiment of the present invention after storage;
FIG. 4 is a graph showing a comparison between 5D stone-like paints of examples and comparative examples according to an embodiment of the present invention after storage;
FIG. 5 is a graph showing a comparison between 5D stone-like paints of examples of an embodiment of the present invention and comparative examples after storage;
FIG. 6 is a graph showing a comparison between 5D stone-like paints of examples of an embodiment of the present invention and comparative examples after storage.
Detailed Description
In order to explain technical contents, achieved objects, and effects of the present invention in detail, the following description is made with reference to the accompanying drawings in combination with the embodiments.
The 5D stone-like paint comprises 6% of protective glue, a disperse phase and a continuous phase;
the dispersed phase comprises hydroxyethyl cellulose, an ammonium salt dispersant, a wetting agent, a defoaming agent, titanium dioxide, kaolin, a film-forming auxiliary agent, ethylene glycol, anionic styrene-acrylic emulsion, nano hollow ceramic microspheres, AMP95, 6% protective glue, snow white, a preservative and water;
the continuous phase comprises ethylene glycol, a film forming aid, AMP95, a defoaming agent, a pure acrylic emulsion with a nano particle size, a KZ125 thickening emulsion, a thickening agent, a preservative and water.
From the above description, the beneficial effects of the present invention are: the invention provides a 5D stone-like paint, which is characterized in that nano hollow ceramic microspheres are added into a dispersed phase, KZ125 thickening emulsion is added into a continuous phase, and is mixed with protective glue to form a net structure, so that the use viscosity can be achieved on the premise of low viscosity, meanwhile, the suspension property of particles is improved by adding the KZ125 thickening emulsion and the nano hollow ceramic microspheres, the spraying area of unit dosage can be obviously improved, compared with the traditional 5D stone-like paint, the spraying area can be improved by 20-30% under the same dosage, the cost of a user can be greatly reduced, and the performance of an obtained paint film is unchanged. Meanwhile, the 5D stone-like paint provided by the invention has higher storage stability than the existing 5D stone-like paint for 1-3 months, can be stably stored for 8-12 months without the problems of water diversion and layering, and can effectively reduce the dosage of the thickener hydroxyethyl cellulose.
In the experimental process, the common hollow ceramic microspheres can not replace the nano hollow ceramic microspheres, and the effect of improving the spraying area can not be improved by adding the common hollow ceramic microspheres.
Further, the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water in percentage by weight.
Further, the dispersed phase comprises, by weight, 3-5 parts of hydroxyethyl cellulose, 1-2 parts of an ammonium salt dispersant, 0.3-0.6 part of a wetting agent, 0.3-0.6 part of a defoaming agent, 12-18 parts of titanium dioxide, 45-55 parts of kaolin, 2-5 parts of a film forming aid, 5-8 parts of ethylene glycol, 220 parts of 180-ion styrene-acrylic emulsion, 40-60 parts of nano hollow ceramic microspheres, 1-2 parts of AMP95, 32-50 parts of 6% protective glue, 550 parts of 450-ion snow white, 1.5-2.5 parts of a preservative and 190 parts of 150-ion water.
Further, the continuous phase comprises, by weight, 12-18 parts of ethylene glycol, 38-45 parts of a film forming aid, 2-4 parts of AMP95, 0.5-1.5 parts of a defoaming agent, 550 parts of a pure acrylic emulsion with a nano particle size, 180 parts of KZ125 thickened emulsion with 130-.
Further, in the dispersed phase, the ammonium salt dispersant is AA4040 dispersant; the wetting agent is a CF-10 wetting agent; the defoaming agent is ST2410 defoaming agent; the film-forming additive is alcohol ester twelve; the preservative is an LXE preservative.
Further, the hydroxyethyl cellulose is HS100000 cellulose, the kaolin is 4000-mesh calcined kaolin, and the snowflake white is 90-mesh snowflake white.
Further, in the continuous phase, the film-forming aid is twelve alcohol esters; the defoaming agent is ST2410 defoaming agent; the thickener is TT935 thickener; the preservative is an LXE preservative.
The compositions of the dispersed and continuous phases are shown in tables 1-2.
TABLE 1
Raw materials Disperse phase A Disperse phase B Disperse phase C Disperse phase D Disperse phase E
HS100000(kg) 4.5 3 5 4.5 4.5
AA4040(kg) 1.5 1 2 1.5 1.5
CF-10(kg) 0.5 0.3 0.6 0.5 0.5
ST2410(kg) 0.5 0.3 0.6 0.5 0.5
Titanium white powder (kg) 15 12 18 15 15
4000 mesh calcined Kaolin (kg) 50 55 45 50 50
Alcohol ester twelve (kg) 3 2 5 3 3
Ethylene glycol (kg) 6 5 8 6 6
8017 emulsion (kg) 200 180 220 200 200
Nanometer hollow ceramic micro-bead (kg) 40 50 60 / 20
AMP95(kg) 1 1.5 2 1 1
6% protective adhesive (kg) 40 32 50 40 40
90 mesh snowflake white (kg) 500 450 550 500 500
LXE(kg) 2 1.5 2.5 2 2
Water (kg) 175.5 150 190 175.5 175.5
In Table 1 HS100000 was purchased from Craine, ST2410, AA4040 and AMP95 were purchased from Pasteur, Germany, LXE and CF-10 were purchased from Dow chemical, alcohol ester twelve was purchased from Iseman, America, 8017 emulsion was purchased from Wanhua chemical. When the components in table 1 are used to prepare the dispersed phase, the raw materials are mixed and dispersed uniformly.
TABLE 2
Figure BDA0002784045680000041
Figure BDA0002784045680000051
In Table 2 ST2410 and AMP95 were purchased from Pasteff, Germany, the 8087 emulsion was purchased from Wanhua chemistry, the KZ125 thickened emulsion was purchased from Grignard New materials, the alcohol ester twelve was purchased from Issman, USA, and LXE and TT935 were purchased from Dow, USA. When the components in table 2 are used to prepare the continuous phase, the raw materials are all mixed and then uniformly dispersed.
Example 1:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase A in Table 1; the continuous phase is continuous phase a in table 1.
Example 2:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase B in Table 1; the continuous phase is continuous phase B in table 1.
Example 3:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersion phase is dispersion phase C in table 1; the continuous phase is continuous phase C in table 1.
Comparative example 1:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase D in Table 1; the continuous phase is continuous phase a in table 1.
Comparative example 2:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase E in Table 1; the continuous phase is continuous phase a in table 1.
Comparative example 3:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase A in Table 1; the continuous phase is continuous phase D in table 1.
Comparative example 4:
the 5D stone-like paint consists of 6 percent of protective glue, a dispersed phase and a continuous phase in a mass ratio of 1:3: 1; the 6% protective glue consists of 6% of S482 protective glue powder, 0.1% of preservative and 93.9% of water; the dispersed phase is dispersed phase B in Table 1; the continuous phase is continuous phase E in table 1.
The 5D stone-like paints of examples 1-3 and comparative examples 1-4 were prepared by mixing 6% of the protective gum, the dispersed phase and the continuous phase, which were mixed and dispersed uniformly, in a mass ratio of 1:3:1, and after mixing, the 5D stone-like paint was granulated after half an hour, and packaged after the viscosity was stabilized.
Experimental example 1:
the mixed 5D stone-like paints of examples 1-3 and comparative examples 1-4 were sprayed on the silicic acid cover plates coated with putty and alkali-resistant primer in sequence, the weight of the paint consumed by spraying 1 square meter was calculated, the spraying standard was that the silicic acid cover plates were completely covered, three silicic acid cover plates were sprayed per group, and the results were averaged as shown in Table 3.
TABLE 3
Example 1 Example 2 Example 3 Comparative example 1 Comparative example 2 Comparative example 3 Comparison ofExample 4
Spraying dosage (kg) 0.83 0.80 0.77 1.90 1.57 1.1 0.97
The effects of example 1 and example 2 after spraying are shown in fig. 1 and fig. 2, respectively, and it can be seen that there is a distinct sense of particle roughness.
Experimental example 2:
a commercially available 5D stone-like paint was purchased, and the same amount was sprayed onto a calcium silicate board in an amount of 1 m square as comparative example 5 to obtain a paint film after complete curing, and the paint film was subjected to a performance test as in the paint film of examples 1 to 3 and comparative examples 1 to 4 of example 1. The results are shown in Table 4. Wherein, the water-whitening resistance test is to completely submerge a calcium silicate board sprayed with a paint film of 1 square meter in water under the condition of no illumination, take out the board after soaking for 1 month, and observe whether the board is whitened; the artificial aging resistance test is to put the calcium silicate board sprayed with 1 square meter of paint film into a test box, use a xenon arc lamp filtered by a filter as radiation, and simulate natural conditions to carry out artificial climate accelerated aging on the coating.
TABLE 4
Figure BDA0002784045680000071
It can be seen that the 5D paint film provided herein does not affect the performance of the paint film by reducing the amount sprayed per unit area.
Experimental example 3:
the 5D stone-like paints of examples 1 to 3 and comparative examples 1 to 5 were sealed, subjected to a stability test in an environment of 30 ℃, and a lid was opened every 30 days to detect whether or not delamination occurred. The results show that the 5D stone-like paints of examples 1-3 did not separate and delaminate when stored for 8 months, comparative examples 1-2 did separate and delaminate when stored for 6 months, comparative example 4 did separate and delaminate when stored for 5 months, and comparative examples 3 and 5 did separate and delaminate when stored for 3 months. FIGS. 3 to 4 are photographs of 5D stone-like paints of example 1 and comparative example 3 taken after opening a sealed vessel when the vessel is stored in the sealed vessel under normal temperature and pressure conditions (5-7 months in 2020, Fuzhou) for 3 months, wherein the left side of FIGS. 3 and 4 is the 5D stone-like paint of comparative example 3, and the right side is the 5D stone-like paint of example 1; FIGS. 5 to 6 are comparative photographs taken after opening a sealed vessel when 5 months are filled in a sealed vessel under normal temperature and pressure conditions (5 to 9 months in 2020 in Fuzhou) of the 5D stone-like paints of example 2 and comparative example 4, and in FIGS. 5 and 6, the 5D stone-like paint of comparative example 4 is on the left side and the 5D stone-like paint of example 2 is on the right side; it can be seen that the 5D stone-like paint provided by the invention has stable storage performance.
In summary, according to the 5D stone-like paint provided by the invention, the nano hollow ceramic microspheres are added in the dispersed phase, the KZ125 thickening emulsion is added in the continuous phase, and the 5D stone-like paint is obtained after mixing with the protective adhesive, so that the spraying area per unit dosage is significantly increased, compared with the traditional 5D stone-like paint, the spraying area can be increased by 20-30% under the same dosage, the cost of a user can be greatly reduced, the performance of the obtained paint film is unchanged, meanwhile, the 5D stone-like paint can be stably stored for 8-12 months without water diversion and delamination, and the stability is greatly improved compared with the existing 5D stone-like paint which can be stably stored for only 1-3 months.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent changes made by using the contents of the present specification and the drawings, or applied directly or indirectly to the related technical fields, are included in the scope of the present invention.

Claims (7)

1.5D stone-like paint, which is characterized by comprising 6 percent of protective glue, a disperse phase and a continuous phase;
the dispersed phase comprises hydroxyethyl cellulose, an ammonium salt dispersant, a wetting agent, a defoaming agent, titanium dioxide, kaolin, a film-forming auxiliary agent, ethylene glycol, anionic styrene-acrylic emulsion, nano hollow ceramic microspheres, AMP95, 6% protective glue, snow white, a preservative and water;
the continuous phase comprises ethylene glycol, a film forming aid, AMP95, a defoaming agent, a pure acrylic emulsion with a nano particle size, a KZ125 thickening emulsion, a thickening agent, a preservative and water.
2. The 5D stone-like paint as claimed in claim 1, wherein the 6% protective glue is composed of 6% S482 protective glue powder, 0.1% preservative and 93.9% water by weight percentage.
3. The 5D stone-like paint as claimed in claim 1, wherein the dispersed phase comprises, by weight, 3-5 parts of hydroxyethyl cellulose, 1-2 parts of ammonium salt dispersant, 0.3-0.6 part of wetting agent, 0.3-0.6 part of defoaming agent, 12-18 parts of titanium dioxide, 45-55 parts of kaolin, 2-5 parts of film forming aid, 5-8 parts of ethylene glycol, 220 parts of anionic styrene-acrylic emulsion, 40-60 parts of nano hollow ceramic microspheres, 1-2 parts of AMP95, 32-50 parts of 6% protective glue, 550 parts of snow white, 1.5-2.5 parts of preservative and 150 parts of 190 parts of water.
4. The 5D stone-like paint as claimed in claim 1, wherein the continuous phase comprises, by weight, 12-18 parts of ethylene glycol, 38-45 parts of a film forming aid, 2-4 parts of AMP95, 0.5-1.5 parts of a defoaming agent, 550 parts of a nano-particle size pure acrylic emulsion, 180 parts of a KZ125 thickened emulsion, 5-8 parts of a thickening agent, 1-3 parts of a preservative and 280 parts of water, based on the weight parts.
5. The 5D stone-like paint as claimed in claim 1, wherein in the dispersed phase, the ammonium salt dispersant is AA4040 dispersant; the wetting agent is a CF-10 wetting agent; the defoaming agent is ST2410 defoaming agent; the film-forming additive is alcohol ester twelve; the preservative is an LXE preservative.
6. The 5D stone-like paint as claimed in claim 1, wherein the hydroxyethyl cellulose is HS100000 cellulose, the kaolin is 4000 mesh calcined kaolin, and the snowflake white is 90 mesh snowflake white.
7. The 5D stone-like paint of claim 1, wherein the coalescing agent is twelve alcohol esters in the continuous phase; the defoaming agent is ST2410 defoaming agent; the thickener is TT935 thickener; the preservative is an LXE preservative.
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CN108610983A (en) * 2017-01-17 2018-10-02 上海多博化工有限公司 A kind of water burnt-in sand multicolor finish and preparation method thereof
TW201934678A (en) * 2018-02-06 2019-09-01 大陸商漳州三德利油漆塗料有限公司 Sunlight heat-reflection thermal insulation sand-in-water multi-color eco-friendly paint and preparation method thereof capable of providing a decorative surface with a three-dimensional effect
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