CN106752498A - A kind of multifunctional aqueous paint and preparation method thereof - Google Patents
A kind of multifunctional aqueous paint and preparation method thereof Download PDFInfo
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- CN106752498A CN106752498A CN201611062293.1A CN201611062293A CN106752498A CN 106752498 A CN106752498 A CN 106752498A CN 201611062293 A CN201611062293 A CN 201611062293A CN 106752498 A CN106752498 A CN 106752498A
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- multifunctional aqueous
- aqueous paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
- C09D7/44—Combinations of two or more thickening agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of multifunctional aqueous paint, the water paint is prepared from using the following components of mass percent meter：Aqueous acrylic emulsion 13 15%；Titanium dioxide 3 8%；Filler 35 45%；Wetting agent 0.1 0.5%；Dispersant 0.2 0.5%；Defoamer 0.1 0.3%；Thickener 1 2%；Coalescents 1.2 1.8%；Levelling agent 0.5 1%；Resistant auxiliary agent 0.5 1.5%；PH adjusting agent 0.1 0.5%；Deionized water 30 40%；The total percentage composition of above-mentioned each component is 100%.The invention also discloses a kind of preparation method of multifunctional aqueous paint.The present invention is by strict control wetting agent and the proportioning of dispersant, the composition of the wetting agent being best suitable for, dispersant is selected by lot of experiments testing sieve, pigment, filler can be made to be present in coating with disposable particle as far as possible, and coating can be made to keep the dispersion of uniform stabilization for a long time, the coating prepared using the water paint also has that abrasion resistance is strong, anti-pollution characteristic is good, cohesive force is strong, low cost, environmental protection, covering power high the characteristics of.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of multifunctional aqueous paint and preparation method thereof.
Background technology
Water paint is the class coating with macromolecule emulsion as film forming matter, with synthetic resin emulsion as base-material add pigment,
The class water paint that filler and various auxiliary agents are formulated.Water paint is one of indoor wall, ceiling primary decoration material, spy
Point is good decorating effect, and easy construction, environmental pollution is small, low cost, using extremely wide.
At present, on the market high PVC (PVC refer to pigment and filler in coating volume with formula in all non-volatile points
The ratio between cumulative volume) water paint is very different, water paint plays the part of indispensable as a branch of coating in decorating indoors
Role, its wash-resistant property and anti-pollution characteristic are the important indicators for evaluating emulsion paint performance, how to improve the washable of emulsion paint
Brush performance and anti-pollution characteristic are the problems that we need to solve.
The content of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of emulsion paint of abrasion resistance, pass through
Each component is reasonably compounded, there is provided a kind of abrasion resistance is strong, anti-pollution characteristic is good, cohesive force is strong, uvioresistant performance is strong
Be easy to construction emulsion paint, while the emulsion paint also have low cost, environmental protection, covering power high the characteristics of.
The purpose of the present invention is realized using following technical scheme：
A kind of multifunctional aqueous paint, it is characterized in that, the water paint is using the following components preparation of mass percent meter
Into：
Raw material used in the present invention is obtained from purchase on the market.
Preferably, the titanium dioxide is nano level rutile titanium white powder.Can be made using nano level rutile titanium white powder
Absorbability of the emulsion paint to ultraviolet light can be enhanced, the compactness of paint film is improve, the washability of coating is substantially improved
Performance, while the paint film also has certain anti-microbial property, when the consumption of titanium dioxide can influence the caking property of coating less than 3%
Can, when the consumption of titanium dioxide is higher than 8%, the abrasion resistance and mechanical strength of coating can be significantly reduced.
Preferably, described filler is nano silicon, talcum powder, wollastonite, the mixture of mica powder.
Preferably, the nano silicon accounts for the 13-15% of the emulsion paint gross weight, and talcum powder accounts for the emulsion paint
The 8-12% of gross weight, wollastonite account for the 4- that the 10-12% of the emulsion paint gross weight, mica powder account for the emulsion paint gross weight
6%.When nano silicon, talcum powder, wollastonite, mica powder are used cooperatively using the formula ratio, showed between each component
Go out significant synergistic function, and the covering power of coating is strong, and levelling effect is good.
Preferably, the thickener is hydroxyethyl cellulose, acrylic emulsion thickener TT-935, polyurethanes thickening
Agent, bentonitic any two or more mixture.Various thickeners are used cooperatively, and limit the consumption of titanium dioxide,
The use of heavy metallic pigment can be reduced.
Preferably, the hydroxyethyl cellulose accounts for 0.4-0.8%, the acrylic emulsion thickener of the emulsion paint gross weight
TT-935 0.2-0.4%, polyurethanes thickener 0.1-0.2%, bentonite 0.3-0.6%.Thickener is set according to this programme
Meter, can make pigment and filler keep preferably dispersiveness, and the coating for preparing has good storage stability and freeze thawing steady
It is qualitative.
Preferably, the pH adjusting agent is any one in ammoniacal liquor, AMP-95, ethoxy urea.
Preferably, the dispersant is potassium hydroxide, and the wetting agent is any in acrylate, polyurethane, polyester
It is a kind of.
Preferably, the coalescents are Lauryl Alcohol ester；The defoamer is silicone oil or ethanol, and the levelling agent is 1,
2- propane diols.
A kind of method for preparing described multifunctional aqueous paint, it is characterized in that, using following steps：
1) sequentially added in stirred tank the deionized water of formula ratio, dispersant, levelling agent, coalescents, resistant auxiliary agent,
The defoamer of wetting agent, 1/2nd formula ratios, stirs under 800-1000r/min；
2) by step 1) in the mixing speed of stirred tank be adjusted to 300-500r/min, add the titanium dioxide of formula ratio, stirring
The filler and remaining defoamer of formula ratio are added after uniform, is stirred；
3) by step 2) in the mixing speed of stirred tank be adjusted to 1200-1500r/min, add the thickener of formula ratio, stir
Mix uniform, tinning.
Compared to existing technology, the beneficial effects of the present invention are：
1st, the present invention is reasonably compounded by each component, balances the consumption of various materials, there is provided a kind of washable
Brush is strong, anti-pollution characteristic is good, cohesive force is strong, uvioresistant performance is strong and is easy to the emulsion paint of construction, while the emulsion paint also has
The characteristics of low cost, environmental protection, covering power high.
2nd, the present invention uses cooperatively different types of thickener, and the synergy between different thickeners ensure that coating
State in a reservoir, while also having good storage stability, the hydroxyethyl cellulose of addition can also strengthen the coating
Freeze-thaw stability.
3rd, the proportioning of wetting agent and dispersant is strictly controlled in the present invention, selects what is be best suitable for by lot of experiments testing sieve
The composition of wetting agent, dispersant, can be such that pigment, filler is present in coating with disposable particle as far as possible, and coating can be made long
The holding of time dispersion uniformly, stable.
Specific embodiment
Below, with reference to specific embodiment, the present invention is described further：
A kind of multifunctional aqueous paint, the water paint is prepared from using the following components of mass percent meter：
A kind of method for preparing described multifunctional aqueous paint, using following steps：
1) sequentially added in stirred tank the deionized water of formula ratio, dispersant, levelling agent, coalescents, resistant auxiliary agent,
The defoamer of wetting agent, 1/2nd formula ratios, stirs under 800-1000r/min；
2) by step 1) in the mixing speed of stirred tank be adjusted to 300-500r/min, add the titanium dioxide of formula ratio, stirring
The filler and remaining defoamer of formula ratio are added after uniform, is stirred；
3) by step 2) in the mixing speed of stirred tank be adjusted to 1200-1500r/min, add the thickener of formula ratio, stir
Mix uniform, tinning.
Embodiment 1
Water paint in the present embodiment is prepared from by the following components of mass percent meter：Aqueous acrylic emulsion
13%th, nm-class rutile titanium dioxide 5%, nano silicon 16%, talcum powder 10%, wollastonite 10%, mica powder 6%,
Acrylate 0.5%, the dispersant 0.2% of potassium hydroxide 0.2%, silicone oil 0.3%, hydroxyethyl cellulose 0.3%, acrylic emulsion
Thickener TT-935 0.2%, polyurethanes thickener 0.1%, bentonite 0.4%, Lauryl Alcohol ester 1.2%, 1,2- propane diols
0.5%th, resistant auxiliary agent 0.5%, AMP-95 0.5%, deionized water 35.3%.
End properties are detected with testing result is as follows according to GB/T9765-2001 and GB18582-2008：This implementation
Emulsion paint storage state in a reservoir in example is to be evenly distributed without lump, and after stirring, the drying time after smearing
Less than 2 hours, hiding rare reached 0.97, and abrasion resistance reaches 1200 times, while film coated surface is smooth.
Embodiment 2
Water paint in the present embodiment is prepared from by the following components of mass percent meter：Aqueous acrylic emulsion
15%th, nm-class rutile titanium dioxide 3%, nano silicon 13%, talcum powder 12%, wollastonite 10%, mica powder 3%,
Polyurethane 0.2%, potassium hydroxide 0.5%, silicone oil 0.2%, hydroxyethyl cellulose 0.8%, acrylic emulsion thickener TT-935
0.4%th, polyurethanes thickener 0.2%, bentonite 0.6%, Lauryl Alcohol ester 1.8%, 1,2- propane diols 1%, resistant auxiliary agent
1.5%th, ammoniacal liquor 0.5%, deionized water 36.3%.
End properties are detected with testing result is as follows according to GB/T9765-2001 and GB18582-2008：This implementation
Emulsion paint storage state in a reservoir in example is to be evenly distributed without lump, and after stirring, the drying time after smearing
Less than 2 hours, hiding rare reached 0.95, and abrasion resistance reaches 1100 times, while film coated surface is smooth.
Embodiment 3
Water paint in the present embodiment is prepared from by the following components of mass percent meter：Aqueous acrylic emulsion
14%th, nm-class rutile titanium dioxide 6%, nano silicon 13%, talcum powder 8%, wollastonite 10%, mica powder 4%, poly-
Urethane 0.1%, potassium hydroxide 0.5%, ethanol 0.1%, hydroxyethyl cellulose 0.6%, acrylic emulsion thickener TT-935
0.2%th, polyurethanes thickener 0.2%, bentonite 0.5%, Lauryl Alcohol ester 1.5%, 1,2- propane diols 0.8%, resistant are helped
Agent 1%, ammoniacal liquor 0.1%, deionized water 39.4%.
End properties are detected with testing result is as follows according to GB/T9765-2001 and GB18582-2008：This implementation
Emulsion paint storage state in a reservoir in example is to be evenly distributed without lump, and after stirring, the drying time after smearing
Less than 2 hours, hiding rare reached 0.94, and abrasion resistance reaches 1050 times, while film coated surface is smooth.
Embodiment 4
Water paint in the present embodiment is prepared from by the following components of mass percent meter：Aqueous acrylic emulsion
15%th, nm-class rutile titanium dioxide 5%, nano silicon 14%, talcum powder 8%, wollastonite 12%, mica powder 2%, poly-
Ester 0.3%, potassium hydroxide 0.4%, ethanol 0.1%, hydroxyethyl cellulose 0.6%, acrylic emulsion thickener TT-935
0.2%th, polyurethanes thickener 0.2%, bentonite 0.5%, Lauryl Alcohol ester 1.5%, 1,2- propane diols 0.8%, resistant are helped
Agent 1%, ammoniacal liquor 0.1%, deionized water 38.3%.
End properties are detected with testing result is as follows according to GB/T9765-2001 and GB18582-2008：This implementation
Emulsion paint storage state in a reservoir in example is to be evenly distributed without lump, and after stirring, the drying time after smearing
Less than 2 hours, hiding rare reached 0.95, and abrasion resistance reaches 1020 times, while film coated surface is smooth.
It will be apparent to those skilled in the art that technical scheme that can be as described above and design, make other various
It is corresponding to change and deformation, and all these change and deformation should all belong to the protection domain of the claims in the present invention
Within.
Claims (10)
1. a kind of multifunctional aqueous paint, it is characterized in that, the water paint is prepared from using the following components of mass percent meter：
The total percentage composition of above-mentioned each component is 100%.
2. multifunctional aqueous paint according to claim 1, it is characterized in that, the titanium dioxide is nano level rutile titanium white
Powder.
3. multifunctional aqueous paint according to claim 1, it is characterized in that, described filler be nano silicon, talcum powder,
The mixture of wollastonite, mica powder.
4. multifunctional aqueous paint according to claim 3, it is characterized in that, it is total that the nano silicon accounts for the emulsion paint
The 13-15% of weight, talcum powder accounts for the 10- that the 8-12% of the emulsion paint gross weight, wollastonite account for the emulsion paint gross weight
12%th, mica powder accounts for the 4-6% of the emulsion paint gross weight.
5. multifunctional aqueous paint according to claim 1, it is characterized in that, the thickener is hydroxyethyl cellulose, propylene
Sour emulsion thickener TT-935, polyurethanes thickener, bentonitic any two or more mixture.
6. multifunctional aqueous paint according to claim 5, it is characterized in that, it is total that the hydroxyethyl cellulose accounts for the emulsion paint
The 0.4-0.8% of weight, acrylic emulsion thickener TT-9350.2-0.4%, polyurethanes thickener 0.1-0.2%, swelling
Native 0.3-0.6%.
7. multifunctional aqueous paint according to claim 1, it is characterized in that, the pH adjusting agent is ammoniacal liquor, AMP-95, hydroxyl second
Any one in base urea.
8. multifunctional aqueous paint according to claim 1, it is characterized in that, the dispersant is potassium hydroxide, the wetting
Agent is any one in acrylate, polyurethane, polyester.
9. multifunctional aqueous paint according to claim 1, it is characterized in that, the coalescents are Lauryl Alcohol ester；It is described
Defoamer is silicone oil or ethanol, and the levelling agent is 1,2-PD.
10. a kind of method for preparing the multifunctional aqueous paint in claim 1-9 described in any one, it is characterized in that, use with
Lower step：
1) deionized water, dispersant, levelling agent, coalescents, resistant auxiliary agent, the wetting of formula ratio are sequentially added in stirred tank
Agent, the defoamer of 1/2nd formula ratios, stir under 800-1000r/min；
2) by step 1) in the mixing speed of stirred tank be adjusted to 300-500r/min, add the titanium dioxide of formula ratio, stirring is equal
The filler and remaining defoamer of formula ratio are added after even, is stirred；
3) by step 2) in the mixing speed of stirred tank be adjusted to 1200-1500r/min, add the thickener of formula ratio, stirring
Uniformly, tinning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611062293.1A CN106752498A (en) | 2016-11-28 | 2016-11-28 | A kind of multifunctional aqueous paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611062293.1A CN106752498A (en) | 2016-11-28 | 2016-11-28 | A kind of multifunctional aqueous paint and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019038909A (en) * | 2017-08-24 | 2019-03-14 | ベック株式会社 | Aqueous coating material |
| CN109749557A (en) * | 2019-02-14 | 2019-05-14 | 天津通用科技有限公司 | A kind of water paint and preparation method thereof that covering power effect is good |
| CN110272671A (en) * | 2019-06-17 | 2019-09-24 | 河北晨阳工贸集团有限公司 | A kind of resistant water paint and preparation method thereof |
| CN112080181A (en) * | 2020-09-11 | 2020-12-15 | 曾万祥 | Non-toxic environment-friendly water-based paint and preparation method thereof |
| CN112094548A (en) * | 2020-05-27 | 2020-12-18 | 慧瑞环保涂料(上海)有限公司 | Sanding-free hot-pressing type coating |
| CN116239916A (en) * | 2022-09-05 | 2023-06-09 | 龙牌涂料(北京)有限公司 | Ultraviolet-absorbing indoor coating and preparation method thereof |
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| EP2213697A4 (en) * | 2008-05-22 | 2013-01-02 | Dainippon Ink & Chemicals | Aqueous composite resin composition, coating agent containing the same, and multilayer body using the coating agent |
| US20150011675A1 (en) * | 2012-02-28 | 2015-01-08 | Kaneka Corporation | Coating composition and coating film obtained from coating composition |
| CN104530863A (en) * | 2014-12-26 | 2015-04-22 | 青岛佳尚创意文化有限公司 | High-performance anti-staining interior wall latex paint |
| CN105524528A (en) * | 2016-02-02 | 2016-04-27 | 贵州联和新型建材有限公司 | Ecological and environment-friendly coating and preparation method thereof |
| CN106009989A (en) * | 2016-06-03 | 2016-10-12 | 上海展辰涂料有限公司 | Waterborne wood paint adhesive force enhancement undercoat and topcoat |
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| EP2213697A4 (en) * | 2008-05-22 | 2013-01-02 | Dainippon Ink & Chemicals | Aqueous composite resin composition, coating agent containing the same, and multilayer body using the coating agent |
| US20150011675A1 (en) * | 2012-02-28 | 2015-01-08 | Kaneka Corporation | Coating composition and coating film obtained from coating composition |
| CN104530863A (en) * | 2014-12-26 | 2015-04-22 | 青岛佳尚创意文化有限公司 | High-performance anti-staining interior wall latex paint |
| CN105524528A (en) * | 2016-02-02 | 2016-04-27 | 贵州联和新型建材有限公司 | Ecological and environment-friendly coating and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019038909A (en) * | 2017-08-24 | 2019-03-14 | ベック株式会社 | Aqueous coating material |
| JP7023067B2 (en) | 2017-08-24 | 2022-02-21 | ベック株式会社 | Aqueous dressing |
| CN109749557A (en) * | 2019-02-14 | 2019-05-14 | 天津通用科技有限公司 | A kind of water paint and preparation method thereof that covering power effect is good |
| CN110272671A (en) * | 2019-06-17 | 2019-09-24 | 河北晨阳工贸集团有限公司 | A kind of resistant water paint and preparation method thereof |
| CN112094548A (en) * | 2020-05-27 | 2020-12-18 | 慧瑞环保涂料(上海)有限公司 | Sanding-free hot-pressing type coating |
| CN112080181A (en) * | 2020-09-11 | 2020-12-15 | 曾万祥 | Non-toxic environment-friendly water-based paint and preparation method thereof |
| CN116239916A (en) * | 2022-09-05 | 2023-06-09 | 龙牌涂料(北京)有限公司 | Ultraviolet-absorbing indoor coating and preparation method thereof |
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Correction item: Applicant|Address Correct: Guangdong Huazibuxin Mstar Technology Ltd|528437 No. 12 Deneng West Road, Torch Development Zone, Zhongshan City, Guangdong Province False: Zhongshan Motu New Material Technology Co., Ltd.|528437 First Floor of the Second Factory Building of Yixian Industrial Park (beside Weida Printing Co., Ltd.) in Zhongshan Torch Development Zone, Guangdong Province Number: 51-02 Volume: 34 |
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