CN109439168A - A kind of water high light pool two-component polyurethane aluminium paint and preparation method thereof - Google Patents
A kind of water high light pool two-component polyurethane aluminium paint and preparation method thereof Download PDFInfo
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- CN109439168A CN109439168A CN201811256834.3A CN201811256834A CN109439168A CN 109439168 A CN109439168 A CN 109439168A CN 201811256834 A CN201811256834 A CN 201811256834A CN 109439168 A CN109439168 A CN 109439168A
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- water
- polyurethane
- mixed solution
- aluminium paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The invention discloses a kind of water high light pool two-component polyurethane aluminium paints and preparation method thereof.Hardness, impact strength, adhesive force, the weather-proof and impression of resistance to stacking and the stability of aluminium paint of the invention are in preferably horizontal, simultaneously with excellent glossiness and metal-like, comprehensive performance is preferable, and, water based acrylic resin dosage of the invention is few, required curing agent is relatively fewer, can reduce use cost, but paint film still has the characteristics that high glaze.In addition, aqueous double-component polyurethane aluminium paint of the invention has the characteristics that high glaze, thus the technique of priming paint covering light can be kept to a painting in practical applications, save the cost.
Description
Technical field
The present invention relates to water paint field more particularly to a kind of water high light pool two-component polyurethane aluminium paints and its system
Preparation Method.
Background technique
Currently, in view of the raising of national awareness of environment protection, and the pressure of every environmental protection policy, the Water-borne modification of coating has been big
Gesture is become, and the coating of auto-parts is existing to be much converted to water paint from traditional solvent type coating, and common one-component is certainly
Dry type water paint is easy for construction, surface drying speed is fast, cheap, there is now much molten applied to the substitution of auto-parts market
The case of dosage form coating, but its that there are coating hardness is not high, the defects of resistance to stacking indentation difference.
CN106590379A discloses a kind of Aqueous acrylic urethane's aluminium paint of two-component, it discloses component A by
35~45% water-based hydroxyl acrylic emulsions, 0.3~1% defoaming agent, 20~30% deionized waters, 0.3~1% wetting and dispersing
Agent, 5~15% and glycol butyl ether, 6~8% water-based silver powders, 5~10% ethylene-vinyl acetate copolymer wax emulsions, 5~15% water
Dispersible cellulose ester solution, 0.3~1% substrate wetting agents, B component are isocyanate curing agent, and also disclose its tool
There is paint film rate of drying fast, gloss and clarity are high, and silver powder directionality is good, have metal-like, and spraying is not easy the beneficial of sagging
Effect, but its water-based hydroxyl acrylic emulsion used is the Setaqua of the VSM6229w or Niu Peisi of profound new resin
6516, the hydroxy radical content of both resins is higher, admittedly more curing agent are needed, higher cost, and, weather resistance is not yet
It is good, meanwhile, cellulose esters also can hardness to paint film and glossiness impact；In addition, CN107619628A then discloses one
Kind of aqueous double-component acrylic hammer paint and preparation method thereof, and also disclose its paint film have it is dry quickly, firmly without it is crisp,
The beneficial effect that richness is good, hardness is good, corrosion-resistant chemical property is good, weather resistance is excellent, however its production is hammer paint,
Aluminium powder arrangement simultaneously and metal-like are bad, Yi Fahua, and appearance property is bad.
Summary of the invention
It is an object of the invention to a kind of water high light pool two-component polyurethane aluminium paints and preparation method thereof.
The technical solution used in the present invention is:
One of the objects of the present invention is to provide a kind of aqueous high damp two-component polyurethane aluminium paints, which includes A
Component and B component, wherein according to the mass fraction, component A are as follows: 3~12 parts of water aluminum-silver slurries, 3~12 parts of cosolvents, 40~55
Part water-based hydroxyl acrylic emulsion, 15~35 parts of deionized waters, 0.1~0.8 part of wetting agent, 0.1~0.5 part of defoaming agent, 0.5~
5 parts of alkali swollen thickeners, 0.05~0.5 part of polyurethane thickener, 1~8 part of aluminium powder arrange auxiliary agent, 0.2~0.5 part of diethanol
Amine；B component is water-based isocyanate curing agent.
Preferably, according to the mass fraction, component A are as follows: 5~10 parts of water aluminum-silver slurries, 5~10 parts of cosolvents, 45~50 parts
Water-based hydroxyl acrylic emulsion, 20~35 parts of deionized waters, 0.2~0.5 part of wetting agent, 0.1~0.3 part of defoaming agent, 2~5 parts
Alkali swollen thickener, 0.1~0.3 part of polyurethane thickener, 1~5 part of aluminium powder arrange auxiliary agent, 0.2~0.5 part of diethanol amine, B group
It is divided into water-based isocyanate curing agent.
Preferably, the mass fraction of above-mentioned B component is the 5~12% of component A mass fraction.
It is highly preferred that the mass fraction of above-mentioned B component is the 8~10% of component A mass fraction.
It is highly preferred that the mass parts ratio of water aluminum-silver slurry and cosolvent is 1:1.
Preferably, above-mentioned water aluminum-silver slurry be selected from love card Hydrolan501,801,9165, Hydromic ZP10818,
At least one of ZP10816.
Preferably, the upper cosolvent is selected from dipropylene glycol methyl ether.
Preferably, above-mentioned water-based hydroxyl acrylic emulsion is selected from the XK110 of Royal DSM.
Preferably, above-mentioned wetting agent is selected from BYK340, BYK349 of Bi Ke, wins in DEGO4100, DEGO270 of wound extremely
Few one kind.
Preferably, BYK022, BYK028 of the upper defoaming agent selected from Bi Ke, win in DEGO810, DEGO815 of wound
It is at least one.
Preferably, above-mentioned alkali swollen thickener is selected from the VISCOLAM 330 (V330) of Ning Baidi.
Preferably, in the U605 of 0620, ten thousand China's chemistry of the above-mentioned polyurethane thickener selected from OMG borchers at least
It is a kind of.
Preferably, above-mentioned aluminium powder arrangement auxiliary agent is selected from the 8421 of Bi Ke.
Preferably, above-mentioned water-based isocyanate curing agent is selected from the XP2655 of Cohan wound.
Another object of the present invention is to provide the preparation methods of above-mentioned water high light pool two-component urethane aluminium paint, including
Following preparation step:
1) water aluminum-silver slurry is dissolved with cosolvent in proportion, obtains solution a；
2) water-based hydroxyl acrylic emulsion, deionized water, wetting agent, defoaming agent are mixed in proportion, obtains mixed solution b；
3) it is proportionally added into polyurethane thickener in mixed solution b, obtains mixed solution c；
4) it is proportionally added into alkali swollen thickener in mixed solution c, obtains mixed solution d；
5) it is proportionally added into aluminium powder arrangement auxiliary agent in mixed solution d, obtains mixed solution e；
6) solution a is added in mixed solution e, and is proportionally added into diethanol amine, obtain component A；
7) component A and B component are mixed, obtains polyurethane aluminium paint.
Preferably, in step 6) component A pH=7.5~9, more preferably pH=8~8.5.
Preferably, step 7) further includes the steps that deionized water, which is added, adjusts viscosity.
The beneficial effects of the present invention are:
1, the present invention is obtained by the cross-linking reaction between water-based hydroxyl acrylic emulsion and water-based isocyanate curing agent
Dry paint film, overcome the deficiency of aqueous one-component self-drying paint, there is hardness, weather-proof, resistance to stacking of paint film etc.
It significantly improves.
2, component A of the present invention passes through the selection of water-based hydroxyl acrylic acid and cosolvent, and cooperation polyurethane thickener, alkali soluble is swollen
The collocation of thickener, aluminium powder arrangement auxiliary agent uses, and arranges the aluminium powder of paint film and is obviously improved with metal-like.
3, water based acrylic resin hydroxy radical content of the invention is low, Gu required curing agent is relatively fewer, can reduce makes
With cost, but paint film still has the characteristics that high glaze；
4, aqueous double-component polyurethane aluminium paint of the invention has the characteristics that high glaze, thus in practical applications can be with
The technique of priming paint covering light is kept to a painting, save the cost.
Specific embodiment
Enumerate embodiment further below with the present invention will be described in detail.It will similarly be understood that following embodiment is served only for this
Invention is further described, and should not be understood as limiting the scope of the invention, those skilled in the art are according to the present invention
Some nonessential modifications and adaptations that the principle of elaboration is made all belong to the scope of protection of the present invention.Following specific works of example
Skill parameter etc. is also only an example in OK range, i.e. those skilled in the art can do suitable model by the explanation of this paper
Interior selection is enclosed, and does not really want to be defined in hereafter exemplary specific data.
Below with reference to embodiment and comparative example, the present invention is described in detail, the powdery paints of each embodiment and comparative example
Component see the table below 1 (according to the mass fraction):
Table 1
The aqueous double-component high glaze polyurethane aluminium paint of Examples 1 to 3 and comparative example 1~6 the preparation method is as follows:
1) water aluminum-silver slurry is dissolved with cosolvent in proportion, obtains solution a；
2) water-based hydroxyl acrylic emulsion is weighed in proportion, and deionized water is sequentially added in the case where stirring at low speed, wetting agent, is disappeared
Infusion mixing, obtains mixed solution b；
3) polyurethane thickener is added in mixed solution b under moderate-speed mixer, obtains mixed solution c (if not poly- ammonia
This step of ester thickener can be omitted)；
4) alkali swollen thickener is added in mixed solution c under moderate-speed mixer, obtains mixed solution d (if without alkali soluble
This step of swollen thickener can be omitted)；
5) aluminium powder arrangement auxiliary agent is added in mixed solution d under moderate-speed mixer, obtains mixed solution e；
6) stir at low speed it is lower solution a is added in mixed solution e, and be proportionally added into diethanol amine, obtain component A；
7) component A and B component are uniformly mixed, adjust viscosity with deionized water, obtains water high light pool polyurethane aluminium paint.
Performance test:
Carbon steel sheet is made into grinding process with 800 mesh sand paper, is cleaned with alcohol, sprays embodiment after the processing of high pressure draught drifting dust
1~3 and comparative example 1~6 aqueous double-component polyurethane aluminium paint, room temperature levelling 3min, 20~25 μm of film thickness, 70 DEG C baking
After roasting 30min, paint film appearance is checked, room temperature performed the following performance tests paint film after 7 days, it the results are shown in Table 2:
1, hardness is tested according to GB/T 6739-96；
2, impact strength is tested according to GB/T1732-93；
3, adhesive force is tested according to GB/T9286-88；
4, ageing-resistant to be tested according to GB/T16422；
5, salt spray resistance is tested according to GB/T1771；
6, the impression of resistance to stacking is tested according to GB/T9280；
7, glossiness is tested according to GB/T9754；
8, metal-like is evaluated according to range estimation；
9, a month progress normal temperature storage stability observing is stored at normal temperature.
Table 2
Note: metal-like refers to the aluminium powder arrangement effect of paint film dry film, excellent: uniformly, exquisiteness, to glitter；It is good: more uniform, relatively thin
It is greasy, slightly glitter；In: it is uneven, slight to send out slightly, without glittering；Difference: floating, nigrescence, dimness.
As shown in Table 2: the hardness of aqueous double-component polyurethane aluminium paint of the invention, impact strength, adhesive force, it is weather-proof and
The impression of resistance to stacking and stability are in preferably level, meanwhile, the present invention also has excellent glossiness and metal-like, this
Illustrate that aluminium powder arrangement effect of the invention is preferable；And the metal-like of comparative example is poor, and also occur layering, precipitating it is bad
Problem.
Claims (10)
1. a kind of water high light pool two-component polyurethane aluminium paint, it is characterised in that: including component A and B component, wherein press matter
Measure number meter, component A are as follows: 3~12 parts of water aluminum-silver slurries, 3~12 parts of cosolvents, 40~55 parts of water-based hydroxyl acrylic emulsions,
15~35 parts of deionized waters, 0.1~0.8 part of wetting agent, 0.1~0.5 part of defoaming agent, 0.5~5 part of alkali swollen thickener, 0.05
~0.5 part of polyurethane thickener, 1~8 part of aluminium powder arrange auxiliary agent, 0.2~0.5 part of diethanol amine；B component is water-based isocyanate
Curing agent.
2. polyurethane aluminium paint according to claim 1, it is characterised in that: the mass fraction of the B component is component A matter
Measure the 5~12% of number.
3. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the water aluminum-silver slurry is selected from love card
At least one of Hydrolan501,801,9165, Hydromic ZP10818, ZP10816；Preferably, the cosolvent choosing
From dipropylene glycol methyl ether.
4. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the water-based hydroxyl acrylic emulsion choosing
From the XK110 of Royal DSM.
5. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the wetting agent is selected from Bi Ke's
At least one of BYK340, BYK349, DEGO4100, DEGO270 for winning wound；Preferably, the defoaming agent is selected from Bi Ke's
At least one of BYK022, BYK028, DEGO810, DEGO815 for winning wound.
6. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the alkali swollen thickener is selected from peaceful cypress
The VISCOLAM 330 of enlightening.
7. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the polyurethane thickener is selected from OMG
At least one of the U605 of 0620, ten thousand China's chemistry of borchers.
8. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the aluminium powder arrangement auxiliary agent is selected from Bi Ke
8421.
9. polyurethane aluminium paint according to claim 1 or 2, it is characterised in that: the water-based isocyanate curing agent choosing
The XP2655 created from Cohan.
10. the preparation method of water high light pool described in any one of claim 1 to 9 two-component polyurethane aluminium paint, special
Sign is: including following preparation step:
1) water aluminum-silver slurry is dissolved with cosolvent in proportion, obtains solution a；
2) water-based hydroxyl acrylic emulsion, deionized water, wetting agent, defoaming agent are mixed in proportion, obtains mixed solution b；
3) it is proportionally added into polyurethane thickener in mixed solution b, obtains mixed solution c；
4) it is proportionally added into alkali swollen thickener in mixed solution c, obtains mixed solution d；
5) it is proportionally added into aluminium powder arrangement auxiliary agent in mixed solution d, obtains mixed solution e；
6) solution a is added in mixed solution e, and is proportionally added into diethanol amine, obtain component A；
7) component A and B component are mixed, obtains water high light pool two-component polyurethane aluminium paint.
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| CN201811256834.3A CN109439168A (en) | 2018-10-26 | 2018-10-26 | A kind of water high light pool two-component polyurethane aluminium paint and preparation method thereof |
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| CN201811256834.3A CN109439168A (en) | 2018-10-26 | 2018-10-26 | A kind of water high light pool two-component polyurethane aluminium paint and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922877A (en) * | 2019-12-13 | 2020-03-27 | 广东四方威凯新材料有限公司 | Waterborne polyurethane coating and preparation method thereof |
| CN111961401A (en) * | 2020-08-29 | 2020-11-20 | 广东多柏斯化工新材料有限公司 | Double-component water-based anti-expansion transparent primer and preparation method thereof |
| CN115093762A (en) * | 2022-08-05 | 2022-09-23 | 雅图高新材料股份有限公司 | Water-based plain base paint and preparation method and application thereof |
| CN115197638A (en) * | 2022-07-27 | 2022-10-18 | 万华化学集团股份有限公司 | Preparation method and application of high-metal-texture, high-weather-resistance and high-corrosion-resistance bi-component air-drying silver paint |
| CN116727205A (en) * | 2023-05-31 | 2023-09-12 | 麓丰新材料(广东)有限公司 | Corrosion prevention treatment method for metal bipolar plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102876167A (en) * | 2012-10-08 | 2013-01-16 | 浙江圣力邦漆业有限公司 | Aqueous silvery aluminum powder flashing paint |
| CN104962189A (en) * | 2015-07-22 | 2015-10-07 | 河北晨阳工贸集团有限公司 | Aluminum powder plastic water paint and preparation method thereof |
| CN107201110A (en) * | 2017-02-21 | 2017-09-26 | 河北晨阳工贸集团有限公司 | Bicycle use high-temperature baking type water-based metal metallic finishe and preparation method thereof |
-
2018
- 2018-10-26 CN CN201811256834.3A patent/CN109439168A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102876167A (en) * | 2012-10-08 | 2013-01-16 | 浙江圣力邦漆业有限公司 | Aqueous silvery aluminum powder flashing paint |
| CN104962189A (en) * | 2015-07-22 | 2015-10-07 | 河北晨阳工贸集团有限公司 | Aluminum powder plastic water paint and preparation method thereof |
| CN107201110A (en) * | 2017-02-21 | 2017-09-26 | 河北晨阳工贸集团有限公司 | Bicycle use high-temperature baking type water-based metal metallic finishe and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王锡娇: "《涂料与颜料标准应用手册 上册》", 30 April 2005, 军事谊文出版社 * |
| 马春福等: "水性丙烯酸铝粉浸漆的研制及浸涂工艺探讨", 《涂料技术与文摘》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922877A (en) * | 2019-12-13 | 2020-03-27 | 广东四方威凯新材料有限公司 | Waterborne polyurethane coating and preparation method thereof |
| CN111961401A (en) * | 2020-08-29 | 2020-11-20 | 广东多柏斯化工新材料有限公司 | Double-component water-based anti-expansion transparent primer and preparation method thereof |
| CN115197638A (en) * | 2022-07-27 | 2022-10-18 | 万华化学集团股份有限公司 | Preparation method and application of high-metal-texture, high-weather-resistance and high-corrosion-resistance bi-component air-drying silver paint |
| CN115093762A (en) * | 2022-08-05 | 2022-09-23 | 雅图高新材料股份有限公司 | Water-based plain base paint and preparation method and application thereof |
| CN115093762B (en) * | 2022-08-05 | 2023-03-24 | 雅图高新材料股份有限公司 | Water-based plain base paint and preparation method and application thereof |
| CN116727205A (en) * | 2023-05-31 | 2023-09-12 | 麓丰新材料(广东)有限公司 | Corrosion prevention treatment method for metal bipolar plate |
| CN116727205B (en) * | 2023-05-31 | 2024-04-02 | 麓丰新材料(广东)有限公司 | Corrosion prevention treatment method for metal bipolar plate |
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Address after: No.5 Lisha East Road, Shatian Town, Dongguan City, Guangdong Province 523000 Applicant after: Qingtian Material Technology Co., Ltd Address before: Shiling Town, Huadu District, Guangzhou City, Guangdong province 510860 Yufeng Road No. 16 Applicant before: GUANGZHOU KINTE INDUSTRIAL Co.,Ltd. |
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Application publication date: 20190308 |