CN104419315A - Waterborne metal anticorrosive coating - Google Patents
Waterborne metal anticorrosive coating Download PDFInfo
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- CN104419315A CN104419315A CN201310376131.5A CN201310376131A CN104419315A CN 104419315 A CN104419315 A CN 104419315A CN 201310376131 A CN201310376131 A CN 201310376131A CN 104419315 A CN104419315 A CN 104419315A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses a waterborne metal anticorrosive coating which is characterized by comprising, by weight, 80% of a waterborne metal anticorrosive coating dedicated emulsion, 10% of deionized water, 2% of nanometer slurry, 20% of fillers, 8% of a film forming auxiliary agent, and a proper amount of a dispersant, a levelling agent, a wetting agent, an antifoaming agent, a rheology modifier, a wax emulsion, and a mildew inhibitor. The preparation method comprises: adding water into the waterborne metal anticorrosive coating dedicated emulsion, stirring uniformly, then adding the nanometer slurry, after 30 min, orderly adding the wetting agent, the antifoaming agent, the levelling agent, the wax emulsion, and finally the rheology modifier, and filtering to obtain the coating. According to the invention, the solvent resistant performance of the coating film is improved by adding a nanomaterial into an antirust coating, the manufacturing process and the application have no adverse effect on human body and the environment, and the waterborne metal anticorrosive coating is a green and environment-friendly product.
Description
Technical field
The present invention relates to water-based metal anticorrosive coating, particularly relate to a kind of preparation method of water-based metal anticorrosive coating.This kind of coating can use as the rust-proofing primer of steel construction metal simultaneously, there is rust forwarding function, required color can also be deployed into as required, avoid traditional rust proof paint to lack the shortcoming of colorful color by the restriction of rust-stabilising pigment, and this coating have excellent weather resistance.
Background technology
Compared with oily antirust varniss, aqueous rust-proof coatings is owing to having not containing harmful composition, as benzene, formaldehyde etc., and also can not because having these to the chemical substance of HUMAN HEALTH and bad environmental in process of manufacture, avoid serious environmental pollution and ecological damage, therefore in today that environmental issue becomes increasingly conspicuous, the development of waterborne anti-rust finish paint and maturation are a kind of inevitable trend.But at present aqueous rust-proof coatings is compared with oil-base paint, still has some deficits in rustless property, weather resistance, hardness of paint film, paint film shock resistance etc., and the glossiness of finish paint, scoring resistance all show shortcoming, and user is often not easy acceptance.
This invention exploits a kind of water-based metal anticorrosive coating that can double as rust-proofing primer and decorative finishes, it has rust forwarding function, can in the construction of steel structure surface band rust, greatly reduce difficulty and the labor strength of engineering construction, and it has excellent decorative effect, glossiness is high, hardness is high, shock-resistance is good, can be deployed into abundant color according to the hobby of user, not by the restriction of traditional rust-stabilising pigment dull coloring.
Summary of the invention
For the deficiency of the above technology, goal of the invention of the present invention is to provide a kind of water-based metal anticorrosive coating.
Goal of the invention of the present invention is realized by following technology:
A preparation method for water-based metal anticorrosive coating, it is formed by following material mixture, contains by weight percentage:
Described water-based metal anticorrosive coating special emulsion is the aqueous polyurethane of particle diameter at 5 ~ 100 nano-scales and the copolymer emulsion of acrylate, and using epoxide group and bound phosphate groups to carry out graft copolymerization, the second-order transition temperature of this emulsion is between 40 ~ 60 DEG C.
1, nano pulp is one or more in nano titanium oxide, nano zine oxide, nanometer sepiolite slurry, nanometer silicon dioxide material;
2, film coalescence aid is one or more in CS12, DBE, BDE, dipropylene glycol n-butyl ether, ethylene glycol monobutyl ether;
3, filler is one or more in Rutile type Titanium Dioxide, process white, mica powder, silicon powder;
4, the agent of anti-sudden strain of a muscle rust is Sodium Nitrite;
5, dispersion agent is one or more in SN5040, CY540, DP518;
6, wetting agent is one or more in PE100, DOW405, H436;
7, defoamer is one or more in A10, SPA202, D160;
8, flow agent is one or more in RM2020, A203;
9, mill base is one or more in using the mill base of inorganic oxide iron pigment allotment or pigment dyestuff to starch;
10, wax emulsion is polyethylene emulsifying wax emulsion;
11, rheology modifier is one or more in D105, R301, Ultra-fine Bentonite;
12, sterilant is DF35.
A kind of preparation method of water-based metal anticorrosive coating implements in accordance with the following steps:
Take the materials prepared needed for finish paint: water-based metal anticorrosive coating special emulsion 50 ~ 80%, deionized water 10 ~ 30%, nano pulp 2 ~ 5%, film coalescence aid 8 ~ 10%, filler 20 ~ 30%, anti-sudden strain of a muscle become rusty, and agent is appropriate, dispersion agent is appropriate, wetting agent is appropriate, defoamer is appropriate, flow agent is appropriate, mill base is appropriate, wax emulsion is appropriate, rheology modifier is appropriate, sterilant is appropriate, and above-mentioned each component concentration percentage ratio sum is 100%;
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Adopt the water-based metal anticorrosive coating that obtains of the inventive method to spray, brush or roller coating in the steel construction metallic surface of band rust, also can be coated on above rust-proofing primer as decorative finishes, its coating luminous, the coating formed has good dryness, the hardness, sticking power, snappiness, shock resistance, temperature-change resistance, humidity resistance, salt fog resistance, freeze-thaw resistance etc. of coating are all excellent, and have environmental-protecting performance.
Embodiment
Embodiment 1
Take the materials prepared needed for water-based metal anticorrosive coating: second-order transition temperature is the water-based metal anticorrosive coating special emulsion 800 kilograms of 20 DEG C, deionized water 100 kilograms, nano titania slurry 15 kilograms, film coalescence aid DBE80 kilogram, Rutile type Titanium Dioxide 50 kilograms, 1250 order process whites 25 kilograms, Sodium Nitrite is appropriate, dispersion agent SN5040 is appropriate, wetting agent PE100 is appropriate, defoamer DEG0822 is appropriate, flow agent RM2020 is appropriate, rheology modifier wilkinite is appropriate, wax emulsion is appropriate, DF35 is appropriate, above-mentioned each component concentration percentage ratio sum is 100%,
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Embodiment 2
Take the materials prepared needed for water-based metal anticorrosive coating: second-order transition temperature is the water-based metal anticorrosive coating special emulsion 750 kilograms of 25 DEG C, deionized water 150 kilograms, nano zinc oxide slurry 20 kilograms, film coalescence aid alcohol ester 12 kilograms, Rutile type Titanium Dioxide 70 kilograms, 1250 order process whites 20 kilograms, Sodium Nitrite is appropriate, dispersing agent C Y540 is appropriate, wetting agent DOW405 is appropriate, defoamer DEG0822 is appropriate, flow agent RM2020 is appropriate, rheology modifier wilkinite is appropriate, wax emulsion is appropriate, DF35 is appropriate, above-mentioned each component concentration percentage ratio sum is 100%,
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Embodiment 3
Take the materials prepared needed for water-based metal anticorrosive coating: the water-based metal anticorrosive coating special emulsion 850 kilograms of second-order transition temperature 0 DEG C, deionized water 50 kilograms, film coalescence aid BDE10 kilogram, Rutile type Titanium Dioxide 50 kilograms, 1250 order process white 25 kilograms, Sodium Nitrite are appropriate, dispersion agent SN5040 appropriate, wetting agent PE100 is appropriate, defoamer DEG0822 is appropriate, flow agent 8W is appropriate, rheology modifier wilkinite is appropriate, wax emulsion is appropriate, DF35 is appropriate, above-mentioned each component concentration percentage ratio sum is 100%;
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Embodiment 4
Take the materials prepared needed for water-based metal anticorrosive coating: two kinds of water-based metal anticorrosive coating special emulsions of second-order transition temperature-5 DEG C and second-order transition temperature 25 DEG C add up to 800 kilograms (both ratios are 8: 2), deionized water 50 kilograms, nano zinc oxide slurry 20 kilograms, film coalescence aid alcohol ester 12 kilograms, Rutile type Titanium Dioxide 50 kilograms, 1250 order process whites 20 kilograms, Sodium Nitrite is appropriate, dispersing agent C Y540 is appropriate, wetting agent DOW405 is appropriate, defoamer DEG0822 is appropriate, flow agent RM2020 is appropriate, rheology modifier wilkinite is appropriate, white carbon black 5 kilograms, wax emulsion is appropriate, DF35 is appropriate, above-mentioned each component concentration percentage ratio sum is 100%,
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Claims (2)
1. a water-based metal anticorrosive coating, it contains by weight percentage:
1), nano pulp is one or more in nano titanium oxide, nano zine oxide, nanometer sepiolite slurry, nanometer silicon dioxide material;
2), film coalescence aid is one or more in CS12, DBE, BDE, dipropylene glycol n-butyl ether, ethylene glycol monobutyl ether;
3), filler is one or more in Rutile type Titanium Dioxide, process white, mica powder, silicon powder;
4), the agent of anti-sudden strain of a muscle rust is Sodium Nitrite;
5), dispersion agent is one or more in SN5040, CY540, DP518;
6), wetting agent is one or more in PE100, DOW405, H436;
7), defoamer is one or more in A10, SPA202, D160;
8), flow agent is one or more in RM2020, A203;
9), mill base is one or more in using the mill base of inorganic oxide iron pigment allotment or pigment dyestuff to starch;
10), wax emulsion is polyethylene emulsifying wax emulsion;
11), rheology modifier is one or more in D105, R301, Ultra-fine Bentonite;
12), sterilant is DF35, it is characterized in that: described water-based metal anticorrosive coating special emulsion is the aqueous polyurethane of particle diameter at 5 ~ 100 nano-scales and the copolymer emulsion of acrylate, and using epoxide group and bound phosphate groups to carry out graft copolymerization, the second-order transition temperature of this emulsion is between 40 ~ 60 DEG C.
2. the preparation method of a kind of water-based metal anticorrosive coating according to claim 1, is characterized in that:
Described preparation method of the present invention is in accordance with the following steps:
Take the materials prepared needed for finish paint: water-based metal anticorrosive coating special emulsion 50 ~ 80%, deionized water 10 ~ 30%, nano pulp 2 ~ 5%, film coalescence aid 8 ~ 10%, filler 20 ~ 30%, anti-sudden strain of a muscle become rusty, and agent is appropriate, dispersion agent is appropriate, wetting agent is appropriate, defoamer is appropriate, flow agent is appropriate, mill base is appropriate, wax emulsion is appropriate, rheology modifier is appropriate, sterilant is appropriate, and above-mentioned each component concentration percentage ratio sum is 100%;
Step 1, add in stirrer by water-based metal anticorrosive coating special emulsion and film coalescence aid, low whipping speed is stir obtained the first mixing solutionss mixed after about 30 minutes under the condition of about 500 revs/min;
Step 2, add in stirrer by the defoamer of deionized water, nano pulp, filler, dispersion agent, half weight, low whipping speed is stir obtained second mixing solutions after 40 minutes under the condition of about 1000 revs/min;
Step 3, the second obtained for step 2 mixing solutions to be joined in the first obtained mixing solutions of step 1, add anti-sudden strains of a muscle and to become rusty agent; Then second half defoamer, wetting agent, flow agent and wax emulsion is added under the state that low whipping speed is 500 revs/min; Last low whipping speed is stir after 60 minutes under the condition of 500 revs/min, and add rheology modifier, 200 revs/min of stirring at low speed, after 10 minutes, add mould inhibitor, agitation as appropriate, filter and obtain water-based metal anticorrosive coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310376131.5A CN104419315A (en) | 2013-08-26 | 2013-08-26 | Waterborne metal anticorrosive coating |
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| CN201310376131.5A CN104419315A (en) | 2013-08-26 | 2013-08-26 | Waterborne metal anticorrosive coating |
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| CN104419315A true CN104419315A (en) | 2015-03-18 |
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Cited By (20)
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| CN105860747A (en) * | 2016-04-28 | 2016-08-17 | 宿州市众力保温节能材料有限公司 | Double-component water-soluble epoxy anticorrosive paint and preparation method thereof |
| CN105925093A (en) * | 2016-06-24 | 2016-09-07 | 镇平星邦油漆有限公司 | Super-hydrophobic waterbone antirust paint and preparation process thereof |
| CN106118436A (en) * | 2016-06-27 | 2016-11-16 | 纳梁（上海）新材料科技有限公司 | Aqueous, environmental protective multifunctional coating |
| CN106281046A (en) * | 2015-05-27 | 2017-01-04 | 温州市芬尼斯皮革化工有限公司 | A kind of water-borne wax breast shoe polish ornamenting agent based on the modified oxidized wax of anion polyurethane and preparation method thereof |
| CN106497286A (en) * | 2016-10-26 | 2017-03-15 | 中国人民解放军空军勤务学院 | A kind of metal anti-corrosive paint |
| WO2017049698A1 (en) * | 2015-09-23 | 2017-03-30 | 南通瑞普埃尔生物工程有限公司 | Low-temperature baking water-based environmentally-friendly dipping primer for motor tricycle, and preparation method therefor |
| CN106833200A (en) * | 2017-02-06 | 2017-06-13 | 中山蓝海洋水性涂料有限公司 | Impact-resistant high-weather-resistance water-based industrial coating and preparation method thereof |
| CN106833211A (en) * | 2017-03-07 | 2017-06-13 | 沈阳宣伯新材料科技有限公司 | A kind of color steel waterborne metallic paint |
| CN106867343A (en) * | 2017-03-07 | 2017-06-20 | 沈阳宣伯新材料科技有限公司 | A kind of shipyard water-based metal shop primer |
| CN106883702A (en) * | 2017-03-07 | 2017-06-23 | 沈阳宣伯新材料科技有限公司 | Waterborne metallic paint under a kind of heavy antisepsis ship waterline |
| CN106905792A (en) * | 2017-03-07 | 2017-06-30 | 沈阳宣伯新材料科技有限公司 | A kind of acid-fast alkali-proof waterborne metallic paint high |
| CN106947336A (en) * | 2017-03-07 | 2017-07-14 | 沈阳宣伯新材料科技有限公司 | A kind of long-acting highway water-based metal protective plates surface coating of high weathering |
| CN106947337A (en) * | 2017-03-07 | 2017-07-14 | 沈阳宣伯新材料科技有限公司 | A kind of color steel heat reflection waterborne metallic paint |
| CN108129967A (en) * | 2017-12-11 | 2018-06-08 | 郭文军 | A kind of aqueous polyurethane anticorrosive paint |
| CN109971280A (en) * | 2019-04-09 | 2019-07-05 | 兰州梓苑环保科技有限公司 | A kind of colorful lacquer and preparation method thereof |
| CN110003706A (en) * | 2019-04-15 | 2019-07-12 | 范振天 | A kind of nanometer of film forming accelerating and its film build method |
| CN112662293A (en) * | 2020-12-14 | 2021-04-16 | 上海涂固安高科技有限公司 | Water-based canned paint applied to heavy corrosion resistance and preparation method thereof |
| CN114181601A (en) * | 2021-12-20 | 2022-03-15 | 康达新材料(集团)股份有限公司 | Water-based metal anticorrosive paint and preparation method and application thereof |
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| CN106281046B (en) * | 2015-05-27 | 2018-06-26 | 温州市芬尼斯皮革化工有限公司 | A kind of water-borne wax breast shoe polish ornamenting agent based on the modified oxidized wax of anion polyurethane and preparation method thereof |
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Application publication date: 20150318 |