CN101633812A - Flexible texture coating and preparation method thereof - Google Patents

Flexible texture coating and preparation method thereof Download PDF

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Publication number
CN101633812A
CN101633812A CN200910040196A CN200910040196A CN101633812A CN 101633812 A CN101633812 A CN 101633812A CN 200910040196 A CN200910040196 A CN 200910040196A CN 200910040196 A CN200910040196 A CN 200910040196A CN 101633812 A CN101633812 A CN 101633812A
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China
Prior art keywords
mierocrystalline cellulose
texture coating
agent
flexible texture
solvent
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CN200910040196A
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Chinese (zh)
Inventor
伍惠芝
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GUANGDONG ZIRANTU CHEMICAL CO Ltd
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GUANGDONG ZIRANTU CHEMICAL CO Ltd
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Priority to CN200910040196A priority Critical patent/CN101633812A/en
Publication of CN101633812A publication Critical patent/CN101633812A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a flexible texture coating which comprises the following components according to percentage by mass: 5-10% of water, 0.1-0.3% of anti-mildew anti-algae agent, 0.05-0.15% of preservative, 0.1-0.3% of dispersing agent, 0.05-0.15 of wetting agent, 0.02-0.07% of defoaming agent A, 7.5-11.5% of 600-mesh heavy calcium carbonate power, 10-15% of titanium dioxide, 1.5-3.0% of ultra-fine aluminium silicate, 10-15% of emulsion A, 15-20% of emulsion B, 10-12% of X1-X2-mesh heavy calcium stone tablet, 10-12% of X3-X4-mesh heavy calcium stone tablet, 13-15% of X5-X6-mesh heavy calcium stone tablet, 0.05-0.1% of defoaming agent B, 0.5-0.15% of solvent HA, 1-3% of solvent HB, 0.2-0.3% of cellulose A, 0.1-0.2% of cellulose B, 0.5-0.7% of thickening agent and 0.05-0.15% of PH value adjusting reagent. The flexible texture coating of the invention has the advantages of bridging slight crack, rich forms and colors and environmental protection; the preparation method of the invention has simple, easy and fast process.

Description

A kind of flexible texture coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings, especially a kind of coating, and the preparation method of this coating with flexible texture.
Background technology
Texture coating originates from the beginning of the '20s in last century, and world structure is at that time just transferring to from war greatly develops science and technology, and various countries are fundamental state policy to improve people's living standard also, and construction industry also is like this.Various new construction styles occur thereupon in a large number; Stucco (plaster) occurs at the north America region in this period, and it was the architectural style that comes from the Mediterranean Sea formula originally, adopts natural silt particle and stone material to do decoration of exterior wall and the substitute that occurs in a large number.
Owing to a large amount of appearance of cement products, the someone had found out the way of utilizing cement and sand to add toner, to replace those expensive original timbers at that time.Yet the cob wall that its rural silt in effect extraordinary image Europe is smeared is so name " colored cement mortar " has another name called Stucco, and comes into vogue.That age is less demanding to quality, neither be very strict for the coating requirement of mortar type, but As time goes on, its shortcoming is not more and more accepted by people yet, and decorative plaster is not used gradually.Up to the seventies, the problem of environmental protection is paid attention to by the people gradually, and Stucco is employed again, but cement has become improvement cement, and this has improved its superiority greatly.Enter the eighties, people are more and more higher to the requirement of product, and cement characteristic easy to crack can't solve all the time.At this moment arise with the sand wall slurry coating material of synthetic emulsion as binding agent, it is not only attractive in appearance charm, and has excellent protective, and other performance of product also improves greatly.After the nineties, the application of the sandy paint of pulpous state is very universal, North America market particularly, and the share of market of pulpous state texture coating surpasses 50% in the exterior coating.
In the middle and later periods nineties, outer wall building coating begins progressively to rise, and comprises the true mineral varnish that belongs to sandy paint, also comes into vogue at this moment.But because the restriction of whole trade management level and construction at that time, fading and problem such as peel off in various degree all appearred in early stage plane coating and true mineral varnish, and problem most serious of all ftractures.Plane coating can't solve the problem of wall crazing because construction thickness can't be controlled effectively at all in construction process.Until the end of the nineties, after housing industry formally became national leading industry, domestic active demand is a kind of can effectively to prevent wall crazing, and abundant expression forms, environment friendly and pollution-free wall body decoration product; Simultaneously,, build the Ministry of worker and revised " synthetic resin emulsion sandy paint " in spy in 2000 for standard market, and in formal enforcement on December 1st, 2000.The applicant overcomes all deficiencies that exist in the above-mentioned prior art, and developed a kind of novel flexible texture coating, this coating has bridging micro-cracks, manifestation and rich color, and the characteristic of environmental protection, this is that true mineral varnish or flat being coated with can not be than U.S.s, and flexible texture coating of the present invention can be widely used in all new buildings, comprise the decoration of exterior wall engineering of public building and residential housing, market outlook are wide.
Summary of the invention
The objective of the invention is to overcome all deficiencies that texture coating exists in the above-mentioned prior art, and a kind of have bridging micro-cracks, manifestation and rich color are provided, and have the novel elastic texture coating of environmental protection characteristic.
Another object of the present invention provides a kind of preparation method of above-mentioned flexible texture coating; It is simple and easy that this preparation method has technology, efficiently advantage.
The object of the present invention is achieved like this:
A kind of flexible texture coating, this flexible texture coating comprise following each component and mass percentage content is:
Water 5~10%;
Algae agent 0.1~0.3% is prevented in mildew-resistant;
Sanitas 0.05~0.15%;
Dispersion agent 0.1~0.3%;
Wetting agent 0.05~0.15%;
Defoamer A 0.02~0.07%;
600 order dicalcium powders 7.5~11.5%;
Titanium dioxide 10~15%;
Superfine alumina silicate 1.5~3.0%;
Latex A 10~15%;
Emulsion B 15~20%;
X1-X2 order coarse whiting stone grain 10~12%;
X3-X4 order coarse whiting stone grain 10~12%;
X5-X6 order coarse whiting stone grain 13~15%;
Defoamer B 0.05~0.15%;
Solvent HA 0.5~0.15%;
Solvent HB 1~3%;
Mierocrystalline cellulose A 0.2~0.3%;
Mierocrystalline cellulose B 0.1~0.2%;
Thickening material 0.5~0.7%;
PH value debugging agent 0.05~0.15%.
Above-mentioned flexible texture coating has bridging micro-cracks, manifestation and rich color, and has the advantage of environmental protection characteristic.
As scheme further, also include an amount of mill base in the described flexible texture coating so that coating is carried out color conditioning, full in the needs that use of different color.
As scheme more specifically, the anti-algae agent of described mildew-resistant can be an isothiazolinone, and sanitas can be an isothiazolinone, and dispersion agent can be the poly carboxylic acid ammonium salt, and wetting agent can be a non-ionic type, and defoamer A can be silicone based.
Described latex A can be a silicon the third, and emulsion B can be pure the third, and defoamer B can be non-silicon class.
Described Mierocrystalline cellulose A can be a hydroxypropylcellulose, and Mierocrystalline cellulose B can be a Natvosol, and thickening material can be the alkali swelling type.
Another object of the present invention is achieved in that
A kind of method for preparing above-mentioned flexible texture coating comprises the steps:
Step 1 with the anti-algae agent of water, mildew-resistant, sanitas, dispersion agent, wetting agent, defoamer A, 600 order dicalcium powders, titanium dioxide and superfine alumina silicate, mixes and carries out high speed dispersion by hundred parts of ratios of above-mentioned quality, and is standby;
Step 2 with latex A, emulsion B, X1-X2 order coarse whiting stone grain, X3-X4 order coarse whiting stone grain, X5-X6 order coarse whiting stone grain and defoamer B, mixes by hundred parts of ratios of above-mentioned quality, and joins in the mixed solution that above-mentioned steps one prepares, and carries out middling speed and stirs;
Step 3 is mixed solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B, and is stirred and make the Mierocrystalline cellulose compound by hundred parts of ratios of above-mentioned quality, standby;
Step 4 stirs the mixture make with above-mentioned steps two through middling speed again and carries out the moment high speed dispersion, and adds the Mierocrystalline cellulose compound that step 3 is made during the moment high speed dispersion, the Mierocrystalline cellulose compound is played equably increase the original text effect;
Step 5 joins thickening material and pH value debugging agent in the mixture that step 4 makes by hundred parts of ratios of above-mentioned quality, and carries out middling speed and stir; After toning was handled, packing got final product.
It is simple and easy that the preparation method of above-mentioned flexible texture coating has technology, efficiently advantage.
It can be to add an amount of mill base that the toning of described step 5 is handled, to realize toning, the processing of checking colors.
As enforcement more specifically, described step 3 is 20 seconds with the time that solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B stir, to make the Mierocrystalline cellulose compound.
Be three minutes during the described step 4 moment high speed dispersion, add the Mierocrystalline cellulose compound that step 3 is made in three minutes during the moment high speed dispersion.
The invention has the beneficial effects as follows:
(1) flexible texture coating of the present invention is that the growth requirement according to China's construction market carries out independent development; Satisfying under " synthetic resin emulsion sandy paint " the standard-required prerequisite of building Ministry of worker's revision, by prescription and supporting design, form unique formulation composition with innovative significance, can also directly carry out color conditioning; Its main performance index all is better than industry standard, in addition, and at external insulation system and oneself requirement, the standard-required of increase system flexility, have palpability price ratio and outstanding workability simultaneously, when satisfying the construction market demand, can demonstrate fully its economic and social benefit;
(2) this flexible texture coating---form needed surperficial texture of user and decorative pattern, rich color; Have Alps scratch effect as superficial makings, simpleness is slightly spacious; Adopt cylinder to create graceful changeable ancient Cortex fici microcarpae effect; Multiple constructional methods such as the thin spray of also available spray gun, batch cutter be thin criticize, rub with the hands, roll, pressure or trowelling produce the texture effect strongly and the changeable pattern effect of decorative pattern etc.; Have again, above-mentioned flexible texture coating also has simultaneously to be decorated and the function of protection metope, and it also is rich in tension folding, not easy to crack, the decorative appearance, weathering resistance, tint retention, resistivity against fire, wear resistance, contamination resistance, the water-repellancy of height and the outstanding perviousness that demonstrate fully inorganic materials; Its excellent sticking power and perfect hiding rare, flake etc. at coating difficult drop-off, volume skin, and antibacterial and mouldproof; Coat-thickness more than 1.0mm, is 10-15 a times of emulsion paint usually; Therefore, have functions such as stronger protection against the tide, insulation, sound insulation; Have again, its excellent snappiness, the energy bridging reaches the slight crack of 2mm, makes facade not be damaged, and protects buildings to greatest extent.
(3) the present invention also provides a kind of preparation technology simple and easy, the preparation method of flexible texture coating efficiently.
Description of drawings
Fig. 1 is preparation technology's schema of flexible texture coating of the present invention.
Embodiment
A kind of flexible texture coating, this flexible texture coating comprise following each component and mass percentage content is, water 5~10%, the anti-algae agent 0.1~0.3% of mildew-resistant, sanitas 0.05~0.15%, dispersion agent 0.1~0.3%; Wetting agent 0.05~0.15%, defoamer A 0.02~0.07%, 600 order dicalcium powders 7.5~11.5%, titanium dioxide 10~15%, superfine alumina silicate 1.5~3.0%, latex A 10~15%, emulsion B 15~20%, X1-X2 order coarse whiting stone grain 10~12%, X3-X4 order coarse whiting stone grain 10~12%, X5-X6 order coarse whiting stone grain 13~15%, defoamer B 0.05~0.15%, solvent HA 0.5~0.15%, solvent HB 1~3%, Mierocrystalline cellulose A 0.2~0.3%, Mierocrystalline cellulose B 0.1~0.2%, thickening material 0.5~0.7%, pH value debugging agent 0.05~0.15%; During enforcement, the concrete numerical value of above-mentioned each component, can select wherein between value, as: water 7.25%, the anti-algae agent 0.2% of mildew-resistant or the like, describe in detail no longer one by one here.
As better embodiment, also include an amount of mill base in the described flexible texture coating, so that coating is carried out color conditioning, the needs that full middle different color uses.
The component of above-mentioned flexible texture coating: the anti-algae agent of mildew-resistant is an isothiazolinone, and sanitas is an isothiazolinone, and dispersion agent is the poly carboxylic acid ammonium salt, and wetting agent is a non-ionic type, and defoamer A is silicone based; And latex A is a silicon the third, and emulsion B is pure the third, and defoamer B is non-silicon class; Described Mierocrystalline cellulose A is a hydroxypropylcellulose, and Mierocrystalline cellulose B is a Natvosol, and thickening material is the alkali swelling type.
As shown in Figure 1, a kind of method for preparing above-mentioned flexible texture coating comprises the steps:
Step 1 with the anti-algae agent of water, mildew-resistant, sanitas, dispersion agent, wetting agent, defoamer A, 600 order dicalcium powders, titanium dioxide and superfine alumina silicate, mixes and carries out high speed dispersion by hundred parts of ratios of above-mentioned quality, and is standby;
Step 2 with latex A, emulsion B, X1-X2 order coarse whiting stone grain, X3-X4 order coarse whiting stone grain, X5-X6 order coarse whiting stone grain and defoamer B, mixes by hundred parts of ratios of above-mentioned quality, and joins in the mixed solution that above-mentioned steps one prepares, and carries out middling speed and stirs;
Step 3 is mixed solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B, and is stirred and make the Mierocrystalline cellulose compound by hundred parts of ratios of above-mentioned quality, standby;
Step 4 stirs the mixture make with above-mentioned steps two through middling speed again and carries out the moment high speed dispersion, and adds the Mierocrystalline cellulose compound that step 3 is made during the moment high speed dispersion, the Mierocrystalline cellulose compound is played equably increase the original text effect;
Step 5 joins thickening material and pH value debugging agent in the mixture that step 4 makes by hundred parts of ratios of above-mentioned quality, and carries out middling speed and stir, and after toning was handled, packing got final product.
It is to add an amount of mill base that the toning of above-mentioned steps five is handled, to realize toning, the processing of checking colors.
As embodiment more specifically, above-mentioned steps three is 20 seconds with the time that solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B stir, to make the Mierocrystalline cellulose compound;
And step 4 moment high speed dispersion during be three minutes, add the Mierocrystalline cellulose compound that step 3 is made in three minutes during the moment high speed dispersion, make that compound can moment thickening equably in the cylinder.Because texture coating is the coating of high solids content, solid content reaches more than 75%; And have only the moisture content of minute quantity in this prescription, be not enough to the Mierocrystalline cellulose in the uniform dissolution prescription.So, the applicant invents above production technique, adopting solvent HB to carry out moistening to Mierocrystalline cellulose A, B, so that the material in the cylinder adds compounds such as above-mentioned Mierocrystalline cellulose under high speed dispersion, the state that seethes, make it in 3 minutes, can evenly spread in the cylinder in the middle of the material, play thickening effectiveness equably.
Flexible texture coating with above-mentioned preparation method makes has the following advantages: 1, the applicant adopts super Thin alumina silicate, cellulose A, B and alkali swelling thickener are effectively arranged in pairs or groups, guarantee highly filled before Put, coating system is carried out thickening; By experiment checking, above thickening combination can provide rubble effectively Grain balance support power guarantees that sedimentation does not appear in system in the storage life in 2 years, effectively solve thick pulpous state and be coated with The problem of material as true mineral varnish, the sedimentation of stone grain; 2, by above-mentioned thickener collocation, efficiently solve texture coating Contradiction between the grain effect of design, fixed effect and the construction levelability.

Claims (9)

1. a flexible texture coating is characterized in that, this flexible texture coating comprises following each component and mass percentage content is:
Water 5~1 0%;
Algae agent 0.1~0.3% is prevented in mildew-resistant;
Sanitas 0.05~0.1 5%;
Dispersion agent 0.1~0.3%;
Wetting agent 0.05~0.1 5%;
Defoamer A 0.02~0.07%;
600 order dicalcium powders 7.5~11.5%;
Titanium dioxide 10~15%;
Superfine alumina silicate 1.5~3.0%;
Latex A 10~1 5%;
Emulsion B 15~20%;
X1-X2 order coarse whiting stone grain 10~12%;
X3-X4 order coarse whiting stone grain 10~12%;
X5-X6 order coarse whiting stone grain 13~15%;
Defoamer B 0.05~0.15%;
Solvent HA 0.5~0.15%;
Solvent HB 1~3%;
Mierocrystalline cellulose A 0.2~0.3%;
Mierocrystalline cellulose B 0.1~0.2%;
Thickening material 0.5~0.7%;
PH value debugging agent 0.05~0.15%.
2. according to the described flexible texture coating of claim 1, it is characterized in that, also include an amount of mill base in the described flexible texture coating.
3. according to the described flexible texture coating of claim 1, it is characterized in that the anti-algae agent of described mildew-resistant is an isothiazolinone, sanitas is an isothiazolinone, and dispersion agent is the poly carboxylic acid ammonium salt, and wetting agent is a non-ionic type, and defoamer A is silicone based.
4. according to the described flexible texture coating of claim 1, it is characterized in that described latex A is a silicon the third, emulsion B is pure the third, and defoamer B is non-silicon class.
5. according to the described flexible texture coating of claim 1, it is characterized in that described Mierocrystalline cellulose A is a hydroxypropylcellulose, Mierocrystalline cellulose B is a Natvosol, and thickening material is the alkali swelling type.
6. a method for preparing above-mentioned flexible texture coating is characterized in that, comprises the steps:
Step 1 with the anti-algae agent of water, mildew-resistant, sanitas, dispersion agent, wetting agent, defoamer A, 600 order dicalcium powders, titanium dioxide and superfine alumina silicate, mixes and carries out high speed dispersion by hundred parts of ratios of above-mentioned quality, and is standby;
Step 2 with latex A, emulsion B, X1-X2 order coarse whiting stone grain, X3-X4 order coarse whiting stone grain, X5-X6 order coarse whiting stone grain and defoamer B, mixes by hundred parts of ratios of above-mentioned quality, and joins in the mixed solution that above-mentioned steps one prepares, and carries out middling speed and stirs;
Step 3 is mixed solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B, and is stirred and make the Mierocrystalline cellulose compound by hundred parts of ratios of above-mentioned quality, standby;
Step 4 stirs the mixture make with above-mentioned steps two through middling speed again and carries out the moment high speed dispersion, and adds the Mierocrystalline cellulose compound that step 3 is made during the moment high speed dispersion, the Mierocrystalline cellulose compound is played equably increase the original text effect;
Step 5 joins thickening material and pH value debugging agent in the mixture that step 4 makes by hundred parts of ratios of above-mentioned quality, and carries out middling speed and stir, and after toning was handled, packing got final product.
7. according to the preparation method of the described flexible texture coating of claim 6, it is characterized in that it is to add an amount of mill base that the toning of described step 5 is handled, to realize toning, the processing of checking colors.
8. according to the preparation method of the described flexible texture coating of claim 6, it is characterized in that described step 3 is 20 seconds with the time that solvent HA, solvent HB, Mierocrystalline cellulose A and Mierocrystalline cellulose B stir, to make the Mierocrystalline cellulose compound.
9. according to the preparation method of the described flexible texture coating of claim 6, it is characterized in that, is three minutes during the described step 4 moment high speed dispersion, adds the Mierocrystalline cellulose compound that step 3 is made in three minutes during the moment high speed dispersion.
CN200910040196A 2009-06-12 2009-06-12 Flexible texture coating and preparation method thereof Pending CN101633812A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296768A (en) * 2011-05-11 2011-12-28 安徽省建筑科学研究设计院 Anti-cracking-protective-layer-free building thermal insulation mortar exterior wall external thermal insulation system structure taking flexible polymer sandstone paint coating as protective and finishing coating
CN102993887A (en) * 2012-12-26 2013-03-27 广东自然涂化工有限公司 Elastic texture paint and preparation method thereof
CN103740207A (en) * 2013-12-31 2014-04-23 广东自然涂化工有限公司 High-performance low-gloss exterior wall texture coating and preparation method thereof
CN104194546A (en) * 2014-09-23 2014-12-10 苏州圣谱拉新材料科技有限公司 Coating for outer wall decoration and preparation method of coating
CN109233523A (en) * 2018-10-18 2019-01-18 扬州中涂科技集团有限公司 A kind of silica gel high-elastic waterproof coating

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102296768A (en) * 2011-05-11 2011-12-28 安徽省建筑科学研究设计院 Anti-cracking-protective-layer-free building thermal insulation mortar exterior wall external thermal insulation system structure taking flexible polymer sandstone paint coating as protective and finishing coating
CN102993887A (en) * 2012-12-26 2013-03-27 广东自然涂化工有限公司 Elastic texture paint and preparation method thereof
CN102993887B (en) * 2012-12-26 2015-10-28 广东自然涂化工有限公司 A kind of flexible texture coating and preparation method thereof
CN103740207A (en) * 2013-12-31 2014-04-23 广东自然涂化工有限公司 High-performance low-gloss exterior wall texture coating and preparation method thereof
CN103740207B (en) * 2013-12-31 2016-03-16 广东自然涂化工有限公司 Exterior wall texture coating of a kind of high-performance low gloss and preparation method thereof
CN104194546A (en) * 2014-09-23 2014-12-10 苏州圣谱拉新材料科技有限公司 Coating for outer wall decoration and preparation method of coating
CN109233523A (en) * 2018-10-18 2019-01-18 扬州中涂科技集团有限公司 A kind of silica gel high-elastic waterproof coating

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