CN107117872A - A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof - Google Patents

A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof Download PDF

Info

Publication number
CN107117872A
CN107117872A CN201710318486.7A CN201710318486A CN107117872A CN 107117872 A CN107117872 A CN 107117872A CN 201710318486 A CN201710318486 A CN 201710318486A CN 107117872 A CN107117872 A CN 107117872A
Authority
CN
China
Prior art keywords
parts
minutes
stirred
hydrophobic
super
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710318486.7A
Other languages
Chinese (zh)
Other versions
CN107117872B (en
Inventor
饶长贵
陈国栋
邱元进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Huaxialan New Material Technology Co Ltd
Original Assignee
Fujian Huaxialan New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Huaxialan New Material Technology Co Ltd filed Critical Fujian Huaxialan New Material Technology Co Ltd
Priority to CN201710318486.7A priority Critical patent/CN107117872B/en
Publication of CN107117872A publication Critical patent/CN107117872A/en
Application granted granted Critical
Publication of CN107117872B publication Critical patent/CN107117872B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses super-hydrophobic colorful true mineral varnish coating of one kind and preparation method thereof.The present invention super-hydrophobic colorful true mineral varnish coating according to weight than each group be divided into:30 60 parts of base paint containing sand of toning, 20 35 parts of protecting colloid, 20 35 parts of continuous phase.The made coating of the present invention has excellent hydrophobicity, rainwater can not be stopped in coating surface, substantially reduce holdup time of the steam in coating surface, it is to avoid coating is contacted with water for a long time, the resistance to soiling of coating is improved simultaneously, greatly extends the service life of coating;Prepared with the aqueous materials of environmental protection, it is good to various base material adhesive force, with excellent color developing, extremely strong third dimension;Coating result is rich and varied, constructs simple and convenient, and can be according to design requirement personalized customization.

Description

A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof
Technical field
The invention belongs to building coating technical field, and in particular to a kind of super-hydrophobic colorful true mineral varnish coating and its preparation side Method.
Background technology
For a long time, domestic building outer wall decorative material is based on ceramic tile, mosaic, marble etc..But such material There is the defects such as resource exhaustion, seriously polluted, cost be higher in terms of exploitation and processing, along with density of material is high, for building Exterior wall is built, is easily come off, there is serious potential safety hazard.Multicolor finish and emerging in large numbers for true mineral varnish coating once change exterior wall dress The theory of decorations, many external walls all start to decorate using coating.In recent years, engineers and technicians were even more to combine multicolor finish With the advantage of true mineral varnish coating, waterborne multicolor true stone paint coating is proposed.Such coating not only overcomes stone material cost height, deadweight The defect waited greatly, and aqueous materials are used, environmental pressure is not resulted in, is a kind of Green Product.But, such coating The characteristics of generally existing water resistance is not enough, adds colorful true mineral varnish and applies that film outer surface is coarse, even high-end water-fast on the market Colorful true mineral varnish, also has a large amount of steam to be detained, and easily causes film to turn white drum, or even stripping such as comes off at the serious disadvantage, seriously Influence outward appearance and service life.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of super-hydrophobic colorful true mineral varnish coating and its system Preparation Method.The colorful true mineral varnish coating that the present invention is provided has super-hydrophobicity, rainwater can not be stopped in coating surface, drops significantly Low steam, even if there is a little vapor adhesion, is also easily blown off in the holdup time of coating surface, it is to avoid coating is for a long time Contacted with water, while improving the resistance to soiling of coating, greatly extend the service life of coating;Also, the coating of the present invention Prepared with the aqueous materials of environmental protection, it is good to various base material adhesive force, with excellent color developing, extremely strong third dimension;Coating Effect is rich and varied, constructs simple and convenient, and can be according to design requirement personalized customization.
To achieve the above object, the present invention is adopted the following technical scheme that:
A kind of super-hydrophobic colorful true mineral varnish coating, by weight, is made up of following raw material:30-60 parts of base paint containing sand of toning, 20-35 parts of 20-35 parts of protecting colloid and continuous phase;Described protecting colloid by weight, is made up of following raw material:Deionization 85-95 parts of water, 1-3 parts of preservative protects 5-15 parts of rubber powder;Described continuous phase by weight, is made up of following raw material:Go 30-100 parts of ionized water, 10-30 parts of propane diols, 1-5 parts of defoamer, 1-5 parts of wetting agent, 130-300 parts of water-base resin, film forming is helped 3-25 parts of agent, 1-3 parts of preservative, 1-10 parts of mould inhibitor, 1-15 parts of thickener, 0-5 parts of pH adjusting agent.
In protecting colloid, described protection rubber powder is one kind in lithium magnesium silicate and aluminium-magnesium silicate;It is described in continuous phase Water-base resin is by Archsol®8087 and TEGO Phobe 1505 are by weight 25-100:1 mixes.
The preparation method of described protecting colloid is:
1)The deionized water of formula ratio is put into reactor, 400-500 revs/min of rotating speed is controlled;
2)The protection rubber powder of 1/2 formula ratio is put into reactor, stirring is extremely dissolved for 30-40 minutes;
3)Surplus protection rubber powder and preservative are put into reactor, is stirred 30-40 minutes under same rotational speed, Protection glue is made Body.
The preparation method of described continuous phase is:
1)The deionized water of formula ratio is added in reactor, 300-400 revs/min of rotating speed is controlled, sequentially adds defoamer, is moistened Humectant, propane diols, coalescents are stirred 5-10 minutes;
2)Water-base resin is slowly added to, is stirred 10-15 minutes;
3)Thickener is added, is stirred 30-40 minutes;
4)Preservative and mould inhibitor are added, is stirred 10-15 minutes;
5)The pH of base paint is determined using pH meter, if necessary, adding pH adjusting agent makes system pH between 8-10, is produced continuous Phase.
Described toning base paint containing sand by weight, is made up of following raw material:400-600 parts of base paint, quartz sand 400-500 parts, 0-5 parts of mill base.
Described mill base is the one or more in iron oxide red, iron oxide yellow and iron oxide black.
By weight, base paint is made up of following raw material:350-550 parts of deionized water, 10-40 parts of propane diols, froth breaking 1-5 parts of agent, 1-5 parts of wetting agent, 3-8 parts of dispersant, 5-20 parts of thickener, 5-80 parts of titanium dioxide, 40-250 parts of filler is aqueous 150-400 parts of resin, 3-25 parts of coalescents, 1-3 parts of preservative, 1-10 parts of mould inhibitor, 50-150 parts of protecting colloid, pH regulations 0-5 parts of agent;Water-base resin is Archsol® 8017。
The preparation method of described toning base paint containing sand is:
1)The deionized water of formula ratio is added in reactor, 300-400 revs/min of rotating speed is controlled, sequentially adds dispersant, disappear Infusion, wetting agent, propane diols, coalescents, water-base resin, titanium dioxide and filler, are stirred 10-15 minutes;
2)Thickener is slowly added to, is stirred 30-40 minutes;
3)Protecting colloid is added, is stirred 30-40 minutes;
4)Preservative and mould inhibitor are added, is stirred 10-15 minutes;
5)Make system pH between 8-10 if necessary, adding qs pH adjuster, produce base paint;
6)The base paint of formula ratio is added in reactor, stirred with 200-300 revs/min of speed;
7)Quartz sand is added in reactor, stirred 20-30 minutes, white base paint containing sand is made;
8)If needing other colors, the mill base of formula ratio is separately added into, is stirred 20-30 minutes, toning base paint containing sand is produced.
The preparation method of described super-hydrophobic colorful true mineral varnish coating, including step as described below:
1)The protecting colloid of formula ratio is added in reactor and stirred, control mixing speed is at 100-150 revs/min;
2)By the toning base paint containing sand of formula ratio by comminutor, gained particle is directly added into protecting colloid, and granulation terminates Continue to stir 10-15 minutes afterwards;
3)Continuous phase is slowly added to reactor, stirred 20-30 minutes with 150-200 revs/min of speed.Produce super-hydrophobic many Color true mineral varnish coating.
The beneficial effects of the present invention are:
1)The water-base resin TEGO Phobe 1505 that colorful true mineral varnish coating prepared by the present invention is used are special construction designs Water-base resin, surface tension is extremely low, and hydrophobicity is extremely strong, with water-base resin Archsol®8087 use cooperatively, and can make the best use of the advantages and keep away It is short, while coating is not reduced to the adhesive force of base material, improve the water resistance of coating.Obtained coating has strong super thin It is aqueous, the steam of rainwater and condensation is slid in time, even if there is a small amount of vapor adhesion, be also easily blown off, it is to avoid apply Layer is contacted with water for a long time, greatly prolongs the service life of coating;
2)The super-hydrophobic colorful true mineral varnish coating of the present invention has splendid anti-fouling effect, the dust of coating surface and other pollutions Thing can be washed down with rainwater;
3) super-hydrophobic colorful true mineral varnish coating of the invention is applied to various base materials, with excellent adhesive attraction, while between bottom surface Adhesive force it is good, construct simple and convenient, coating result is rich and varied, with various patterns effect, can be according to design requirement Personalized customization.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described. Obviously, described embodiment is only the part of the present invention, and based on the embodiment in the present invention, those skilled in the art exist The every other embodiment obtained under the premise of creative work is not made, the scope of protection of the invention is belonged to.
Embodiment 1
Super-hydrophobic colorful true mineral varnish coating, is made up of following raw material:Mix colours 50 parts of base paint containing sand, 20 parts of protecting colloid and continuously 30 parts of phase.
1st, the preparation of protecting colloid:
Protecting colloid is made up of the raw material of following parts by weight:91 parts of deionized water, 1 part of preservative LXE, protection rubber powder H516 8 Part.
Preparation process is:
1)91 parts of deionized waters are put into reactor, 450 revs/min of rotating speed is controlled;
2)The H516 of 4 parts of input is into reactor, and stirring is extremely dissolved for 30 minutes;
3)Surplus protection rubber powder and LXE are put into reactor, is stirred under same rotational speed 30 minutes, that is, it is 8wt% that concentration, which is made, Protecting colloid solution.
2nd, the preparation of continuous phase:
Continuous phase is made up of the raw material of following parts by weight:67 parts of deionized water, 13 parts of propane diols, defoamer Rodoline DF- 691 1 parts, Archsol®8087 250 parts, 1,505 5 parts of TEGO Phobe, 12 parts of coalescents Texanol, preservative 1 part of LXE, 342 3 parts of mould inhibitor, 2 parts of thickener U902,1 part of multifunctional assistant AMP-95.
Preparation process is:
1)The deionized water of formula ratio is added in reactor, 350 revs/min of rotating speed is controlled, sequentially adds Rodoline DF- 691, propane diols, Texanol is stirred 10 minutes;
2)Add Archsol®8087 and TEGO Phobe 1505, are stirred 10 minutes;
3)U902 is slowly added to, is stirred 30 minutes;
4)LXE and 342 is added, is stirred 10 minutes;
5)Add after AMP-95 and stir 10 minutes, system pH=9 produce continuous phase.
3rd, the preparation of toning base paint containing sand:
Toning base paint containing sand is made up of the raw material of following parts by weight:550 parts of base paint, 90 450 parts of mesh quartz sands, iron oxide red 1 part of mill base, 2 parts of iron oxide yellow mill base, 2 parts of iron oxide black mill base.
Base paint is made up of the raw material of following parts by weight:430 parts of deionized water, 10 parts of propane diols, defoamer Rodoline 1 part of 2 parts of DF-691, wetting agent Triton EF-106,3 parts of dispersing agent C oadd D-26,10 parts of thickener HBR250, titanium 80 parts of 100 parts of 20 parts of white powder R996, coarse whiting CC-800, calcined kaolin CK-400, Archsol®8017 250 parts, 5 parts of Texanol, 8wt% protecting colloid solution(Protecting colloid prepared by step 1)80 parts, 1 part of preservative LXE, mould inhibitor 342 2 parts, 20% 1.5 parts of ammoniacal liquor.
Preparation process is:
1)The deionized water of formula ratio is added in reactor, 350 revs/min of rotating speed is controlled, sequentially adds Coadd D-26, Rodoline DF-691, Triton EF-106, propane diols, Texanol, Archsol®8017, R996, CC-800 and CK- 400, stir 10 minutes;
2)HBR250 is slowly added to, is stirred 30 minutes;
3)Protecting colloid is added, is stirred 30 minutes;
4)LXE and 342 is added, is stirred 10 minutes;
5)Add after ammoniacal liquor and stir 10 minutes, system pH=9 produce base paint;
6)The base paint of formula ratio is added in reactor, stirred with 250 revs/min of speed;
7)90 mesh quartz sands are added in reactor, stirred 20 minutes, white base paint containing sand is made;
8)Extracting waste base paint containing sand, is separately added into iron oxide red, iron oxide yellow and the iron oxide black mill base of formula ratio, stirring 20 Minute, toning base paint containing sand is made.
4th, the preparation of super-hydrophobic colorful true mineral varnish coating, comprises the following steps:
1)The protecting colloid of formula ratio is added in reactor and stirred, control mixing speed is at 130 revs/min;
2)By the toning base paint containing sand of formula ratio by comminutor, gained particle is directly added into protecting colloid, and granulation terminates Continue to stir 15 minutes afterwards;
3)Continuous phase is slowly added to reactor, stirred 20 minutes with 150 revs/min of speed.Produce super-hydrophobic colorful true stone Paint coating.
The performance detection of super-hydrophobic colorful true mineral varnish coating is as shown in table 1 described in the present embodiment:
Table 1
Embodiment 2
Super-hydrophobic colorful true mineral varnish coating, is made up of following raw material:Mix colours 45 parts of base paint containing sand, 20 parts of protecting colloid and continuously 35 parts of phase.
1st, the preparation of protecting colloid:
Protecting colloid is made up of the raw material of following parts by weight:91 parts of deionized water, LXE1 parts of preservative, protection rubber powder H516 8 Part.
Preparation process is:
1)91 parts of deionized waters are put into reactor, 450 revs/min of rotating speed is controlled;
2)The protection rubber powder of 4 parts of input is into reactor, and stirring is extremely dissolved for 30 minutes;
3)Surplus H516 and LXE are put into reactor, is stirred under same rotational speed 30 minutes, that is, the guarantor that concentration is 8wt% is made Protect colloidal solution.
2nd, the preparation of continuous phase:
Continuous phase is made up of the raw material of following parts by weight:67 parts of deionized water, 13 parts of propane diols, defoamer Rodoline DF- 691 1 parts, Archsol®8087 240 parts, 1,505 8 parts of TEGO Phobe, 12 parts of Texanol, 1 part of preservative LXE, 342 3 parts of mould inhibitor, 2 parts of thickener U902,1 part of AMP-95.
Preparation process is:
1)The deionized water of formula ratio is added in reactor, 350 revs/min of rotating speed is controlled, sequentially adds Rodoline DF- 691, propane diols, Texanol is stirred 10 minutes;
2)Add Archsol®8087 and TEGO Phobe 1505, are stirred 10 minutes;
3)U902 is slowly added to, is stirred 30 minutes;
4)LXE and 342 is added, is stirred 10 minutes;
5)Add after AMP-95 and stir 10 minutes, system pH=9 produce continuous phase.
3rd, the preparation of toning base paint containing sand:
Toning base paint containing sand is made up of the raw material of following parts by weight:500 parts of base paint, 90 500 parts of mesh quartz sands, iron oxide black 5 parts of mill base.
Base paint is made up of the raw material of following parts by weight:430 parts of deionized water, 10 parts of propane diols, defoamer Rodoline 1 part of 2 parts of DF-691, wetting agent Triton EF-106,3 parts of dispersing agent C oadd D-26,10 parts of thickener MC-40, titanium white 160 parts of 20 parts of powder R996, calcined kaolin CK-400, Archsol®8017 270 parts, 6 parts of Texanol, 8wt% Protection glues 80 parts of liquid solution, 1 part of preservative LXE, 342 2 parts of mould inhibitor, 20% 1.5 parts of ammoniacal liquor.
Preparation process is:
1)The deionized water of formula ratio is added in reactor, 350 revs/min of rotating speed is controlled, sequentially adds Coadd D-26, Rodoline DF-691, Triton EF-106, propane diols, Texanol, Archsol®8017, R996, CC-800 and CK- 400, stir 10 minutes;
2)HBR250 is slowly added to, is stirred 30 minutes;
3)Protecting colloid is added, is stirred 30 minutes;
4)LXE and 342 is added, is stirred 10 minutes;
5)Add after ammoniacal liquor and stir 10 minutes, system pH=9 produce base paint;
6)The base paint of formula ratio is added in reactor, stirred with 250 revs/min of speed;
7)90 mesh quartz sands are added in reactor, stirred 20 minutes, white base paint containing sand is made;
8)Extracting waste base paint containing sand, is separately added into iron oxide red, iron oxide yellow and the iron oxide black mill base of formula ratio, stirring 20 Minute, toning base paint containing sand is made.
4th, the preparation of super-hydrophobic colorful true mineral varnish coating, comprises the following steps:
1)The protecting colloid of formula ratio is added in reactor and stirred, control mixing speed is at 130 revs/min;
2)By the toning base paint containing sand of formula ratio by comminutor, gained particle is directly added into protecting colloid, and granulation terminates Continue to stir 15 minutes afterwards;
3)Continuous phase is slowly added to reactor, stirred 20 minutes with 150 revs/min of speed.Produce super-hydrophobic colorful true stone Paint coating.
The performance detection of super-hydrophobic colorful true mineral varnish coating is as shown in table 2 described in the present embodiment:
Table 2
Contact angle θ refer to the tangent line of the liquid-vapor interface made at gas, liquid, solid three-phase intersection point through liquid and solid-liquid boundary line it Between angle, be measuring for wetness degree.In general, Wet Out can be divided into following several:θ=0 °, complete wetting;θ 90 ° of <, it is partially wetted;θ=90 °, are the lines of demarcation whether soaked;90 ° of θ >, it is nonwetting;θ=180 °, it is completely nonwetting. Use the super-hydrophobic colorful true mineral varnish coating of the present invention(Embodiment 1, embodiment 2, are calculated as A, B respectively)And 2 commercially available water-fast more Color true mineral varnish coating(C and D are designated as respectively)Test piece is made respectively.After model is maintained by standard method, contact angle is used The contact of tester test sample plate, as a result as shown in table 3.
The contact angle test result of table 3.
As it can be seen from table 1 model A and B contact angle are much larger than B and C, show to be applied by the super-hydrophobic colorful true mineral varnish of the present invention The model hydrophobicity that material makes is much larger than the model that commercially available water-fast colorful true mineral varnish coating makes.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, should all belong to the covering scope of the present invention.

Claims (10)

1. a kind of super-hydrophobic colorful true mineral varnish coating, it is characterised in that:By weight, it is made up of following raw material:Toning contains sand 20-35 parts of 30-60 parts of base paint, 20-35 parts of protecting colloid and continuous phase;Described continuous phase by weight, by following original Material composition:30-100 parts of deionized water, 10-30 parts of propane diols, 1-5 parts of defoamer, 1-5 parts of wetting agent, water-base resin 130-300 Part, 3-25 parts of coalescents, 1-3 parts of preservative, 1-10 parts of mould inhibitor, 1-15 parts of thickener, 0-5 parts of pH adjusting agent.
2. super-hydrophobic colorful true mineral varnish coating according to claim 1, it is characterised in that:The preparation side of described continuous phase Method is:
1)The deionized water of formula ratio is added in reactor, 300-400 revs/min of rotating speed is controlled, sequentially adds defoamer, is moistened Humectant, propane diols, coalescents are stirred 5-10 minutes;
2)Water-base resin is slowly added to, is stirred 10-15 minutes;
3)Thickener is added, is stirred 30-40 minutes;
4)Preservative and mould inhibitor are added, is stirred 10-15 minutes;
5)The pH of base paint is determined using pH meter, if necessary, adding pH adjusting agent makes system pH between 8-10, is produced continuous Phase.
3. super-hydrophobic colorful true mineral varnish coating according to claim 1, it is characterised in that:In continuous phase, described is aqueous Resin is by Archsol®8087 and TEGO Phobe 1505 are by weight 25-100:1 mixes.
4. super-hydrophobic colorful true mineral varnish coating according to claim 3, it is characterised in that:Described protecting colloid is by weight Part meter, is made up of following raw material:85-95 parts of deionized water, 1-3 parts of preservative protects 5-15 parts of rubber powder;Described protection rubber powder For one kind in lithium magnesium silicate and aluminium-magnesium silicate;The preparation method of described protecting colloid is:
1)The deionized water of formula ratio is put into reactor, 400-500 revs/min of rotating speed is controlled;
2)The protection rubber powder of 1/2 formula ratio is put into reactor, stirring is extremely dissolved for 30-40 minutes;
3)Surplus protection rubber powder and preservative are put into reactor, is stirred 30-40 minutes under same rotational speed, Protection glue is made Body.
5. super-hydrophobic colorful true mineral varnish coating according to claim 1, it is characterised in that:Described toning base paint containing sand By weight, it is made up of following raw material:400-600 parts of base paint, 400-500 parts of quartz sand, 0-5 parts of mill base.
6. super-hydrophobic colorful true mineral varnish coating according to claim 5, it is characterised in that:Described mill base is iron oxide One or more in red, iron oxide yellow and iron oxide black.
7. super-hydrophobic colorful true mineral varnish coating according to claim 5, it is characterised in that:By weight, base paint by Following raw material composition:350-550 parts of deionized water, 10-40 parts of propane diols, 1-5 parts of defoamer, 1-5 parts of wetting agent, dispersant 3- 8 parts, 5-20 parts of thickener, 5-80 parts of titanium dioxide, 40-250 parts of filler, 150-400 parts of water-base resin, 3-25 parts of coalescents, 1-3 parts of preservative, 1-10 parts of mould inhibitor, 50-150 parts of protecting colloid, 0-5 parts of pH adjusting agent.
8. super-hydrophobic colorful true mineral varnish coating according to claim 7, it is characterised in that:Water-base resin is Archsol® 8017。
9. super-hydrophobic colorful true mineral varnish coating according to claim 7, it is characterised in that:Described toning base paint containing sand Preparation method be:
1)The deionized water of formula ratio is added in reactor, 300-400 revs/min of rotating speed is controlled, sequentially adds dispersant, disappear Infusion, wetting agent, propane diols, coalescents, water-base resin, titanium dioxide and filler, are stirred 10-15 minutes;
2)Thickener is slowly added to, is stirred 30-40 minutes;
3)Protecting colloid is added, is stirred 30-40 minutes;
4)Preservative and mould inhibitor are added, is stirred 10-15 minutes;
5)Make system pH between 8-10 if necessary, adding qs pH adjuster, produce base paint;
6)The base paint of formula ratio is added in reactor, stirred with 200-300 revs/min of speed;
7)Quartz sand is added in reactor, stirred 20-30 minutes, white base paint containing sand is made;
8)If needing other colors, the mill base of formula ratio is separately added into, is stirred 20-30 minutes, toning base paint containing sand is produced.
10. a kind of method of the super-hydrophobic colorful true mineral varnish coating prepared as described in claim any one of 1-5, its feature exists In:Including step as described below:
1)The protecting colloid of formula ratio is added in reactor and stirred, control mixing speed is at 100-150 revs/min;
2)By the toning base paint containing sand of formula ratio by comminutor, gained particle is directly added into protecting colloid, and granulation terminates Continue to stir 10-15 minutes afterwards;
3)Continuous phase is slowly added to reactor, stirred 20-30 minutes with 150-200 revs/min of speed.Produce super-hydrophobic many Color true mineral varnish coating.
CN201710318486.7A 2017-05-08 2017-05-08 Super-hydrophobic colorful lacquer coating of one kind and preparation method thereof Active CN107117872B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710318486.7A CN107117872B (en) 2017-05-08 2017-05-08 Super-hydrophobic colorful lacquer coating of one kind and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710318486.7A CN107117872B (en) 2017-05-08 2017-05-08 Super-hydrophobic colorful lacquer coating of one kind and preparation method thereof

Publications (2)

Publication Number Publication Date
CN107117872A true CN107117872A (en) 2017-09-01
CN107117872B CN107117872B (en) 2019-10-25

Family

ID=59726688

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710318486.7A Active CN107117872B (en) 2017-05-08 2017-05-08 Super-hydrophobic colorful lacquer coating of one kind and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107117872B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535878A (en) * 2018-12-12 2019-03-29 厦门安必信新材料科技有限公司 One kind is containing colorful stone-like coating of sand and preparation method thereof
CN113462247A (en) * 2021-08-10 2021-10-01 卡本科技集团股份有限公司 Water-based sand-containing multicolor paint and preparation method thereof
CN114525061A (en) * 2021-12-24 2022-05-24 德爱威(中国)有限公司 Natural color sand-free stone-like paint granite effect coating and construction method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002932A1 (en) * 2000-05-25 2002-01-10 Winterowd Jack G. Labeling paint for use with metallic stencils on oriented strandboard finishing line
US20020165309A1 (en) * 2000-05-25 2002-11-07 Winterowd Jack G. Labeling paint and method for the manufacture thereof
CN105754442A (en) * 2016-04-05 2016-07-13 佛山市顺德区金涂宝涂料有限公司 Formula and production method of waterproof breathable water-in-water multicolour coating
CN106280806A (en) * 2016-08-29 2017-01-04 浙江德尔福新型建材有限公司 A kind of aqueous reflective insulation water burnt-in sand imitates bush-hammered face coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002932A1 (en) * 2000-05-25 2002-01-10 Winterowd Jack G. Labeling paint for use with metallic stencils on oriented strandboard finishing line
US20020165309A1 (en) * 2000-05-25 2002-11-07 Winterowd Jack G. Labeling paint and method for the manufacture thereof
CN105754442A (en) * 2016-04-05 2016-07-13 佛山市顺德区金涂宝涂料有限公司 Formula and production method of waterproof breathable water-in-water multicolour coating
CN106280806A (en) * 2016-08-29 2017-01-04 浙江德尔福新型建材有限公司 A kind of aqueous reflective insulation water burnt-in sand imitates bush-hammered face coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵莹等编: "《铸造工岗位手册》", 31 August 2016, 机械工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535878A (en) * 2018-12-12 2019-03-29 厦门安必信新材料科技有限公司 One kind is containing colorful stone-like coating of sand and preparation method thereof
CN113462247A (en) * 2021-08-10 2021-10-01 卡本科技集团股份有限公司 Water-based sand-containing multicolor paint and preparation method thereof
CN114525061A (en) * 2021-12-24 2022-05-24 德爱威(中国)有限公司 Natural color sand-free stone-like paint granite effect coating and construction method thereof

Also Published As

Publication number Publication date
CN107117872B (en) 2019-10-25

Similar Documents

Publication Publication Date Title
CN104591598B (en) A kind of true mineral varnish and preparation method thereof, construction method
CN101067062B (en) High performance outer wall paint preparation method
CN104403382B (en) Enamel paint of a kind of aqueous high-temperature-resistant and preparation method thereof and construction method
CN102532965B (en) Coating composition and decorative material
CN109266153B (en) Water-based anti-doodling self-cleaning coating and preparation method thereof
CN101654578B (en) Water-base fluorocarbon imitation marble paint, preparation method thereof and method for spraying with imitation marble effect
CN104193288A (en) Preparation and application method of water-based ceramic anticorrosive paint
CN107117872A (en) A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof
CN102433050B (en) Nanometer multifunctional substrate coating and preparation method thereof
CN103184004A (en) Water-based crack paint as well as preparation method and application method thereof
CN109135558A (en) A kind of ceramic resin and its application
CN101143986A (en) Terrace paint
CN107815215A (en) A kind of water-based stone-like coating formula and water-based imitative stone terrace
CN103289491A (en) Decorative coating constructed on ceramic tile directly and preparation method thereof
CN107141989A (en) PVC, PU artificial leather aqueous surface-treating agent and preparation method thereof, product
CN107629627B (en) Permeable hydrophobic multifunctional waterproof coating and preparation method and application thereof
CN105838173A (en) Water-based coating, preparing method thereof and using method of the coating
CN103102766A (en) High adhesive force water-based glass paint and preparation method thereof
CN104974643A (en) Water-based coating for protecting stony cultural relics and preparation method of coating
CN104774518B (en) A kind of aqueouss texture coating and preparation method thereof
CN112063296A (en) High-hardness fireproof hydrophobic stone-like ceramic coating, and preparation process and application thereof
CN101270263A (en) Nano-composite dry powder marble wall art paint
CN114015308A (en) Color sand-free star-color exquisite stone coating and preparation method thereof
CN101591481B (en) Inorganic dry powder painting
CN112010589B (en) Sand-in-sand multicolor paint and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant