CN107502102A - A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof - Google Patents
A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof Download PDFInfo
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- CN107502102A CN107502102A CN201710868086.3A CN201710868086A CN107502102A CN 107502102 A CN107502102 A CN 107502102A CN 201710868086 A CN201710868086 A CN 201710868086A CN 107502102 A CN107502102 A CN 107502102A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses high weather resistant water-thinned multicolor finish of a kind of water resistant low temperature and preparation method thereof, the coating includes the composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：30 ~ 40 parts, rutile titanium white powder：10 ~ 15 parts, lignocellulosic：5 ~ 10 parts, powdered whiting：10 ~ 15 parts, kaolin：5 ~ 10 parts, nano titanium oxide：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, antifreezing agent：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.The water-soluble colorful coating is formed using configure based on fluorine-silicon modified acrylic emulsion and water-base fluorocarbon emulsion, with high stability, do not ftracture, be impermeable, anti-stain characteristic it is strong, water resistance is excellent, water-fast, alkaline-resisting, salt spray resistance, chemical resistance, high-weatherability.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and its system
Preparation Method.
Background technology
Water-soluble colorful coating is actually a kind of scattered aqueous phase of water emulsion coating, is the company for protecting glue solution to form
The multiphase suspended substance of continuous phase.For water-soluble colorful coating mainly by continuous phase or scattered phase composition, continuous phase has continuous phase low dense
Degree, continuous phase low viscosity;Dispersed phase has high concentration, high viscosity etc..
Water-soluble colorful coating is to be used as product formula using the colloid chemistry in physicochemical system and the theory of surface chemistry
The main theoretical basis of the reform of Chinese economic structure of design, the physical change of material and the multinomial conversion of chemical reaction are incorporated, by the water-base resin of liquid
The hydrate colour particle of parcel agglutination is refined, and is uniformly suspended within specific water-based emulsion, is ultimately formed colourful more
The copolymer of the macromolecule liquid colloidal color, granular size is random.It not only has all characteristics of top-grade building coating, more
Has the characteristic such as extremely strong weatherability, crack resistance and the feature of environmental protection and artificial grantie, amplification reason stone.The technology both comes from building and applied
The synthesis theory of material, but surmounted the cognitive concept of building coating technology and technique, it is one to building coating manufacturing technology
Item important breakthrough.
Water-soluble colorful coating construction application is relatively broad, and domestic more coating producer all should in positive preparation exploitation at present
Coating, but majority only exists in the primary trial production stage, can only construct tens to hundreds of squares of engineering, and with lithotome decorative pattern
Simulation degree index is only 30% to 50%.
Color and style can choose at random or arrange in pairs or groups, and product does not receive the limitation of regular article size, excellent adhesive force
With perfect covering power, color is persistently protected.Pliability is good, and impact resistant and impact, moistureproof sound-absorbing, texture is strong, and expressive force is enriched, complete
The three-dimensional art modeling requirement to wall can be met entirely.The different decorative effect of various textures can be made according to personal like,
Natural harmony, color is soft abundant, excellent water proofing property and weatherability, can keep wall decoration effect effectively, for a long time.Extensively
Suitable for building inner-outer wall, luxurious hotel, garden villa, sculpture, mountain villa, karaoke halls and the occasion of particular/special requirement moulding.
Water-soluble colorful coating has complete Water-borne modification feature, environment-protecting and non-poisonous, substitutes increasingly rare natural granite,
Meet national energy-saving environmental requirement.High simulation quality feature, coating is uneven, and toning is ever-changing, and decorative pattern is changeable, color
It can be overlapped mutually, can imitate natural.It is cost-effective, compared with natural granite, cost be its 20% or so.Lightweight material
Material, no matter greatly lightened the burden than natural granite or true mineral varnish to wall, be more suitable for external thermal insulation system, meet country
Developing direction.
For water-soluble colorful coating, the current country is primarily present following patent document：
Publication No. 106867349A Chinese patent discloses a kind of aqueous colorful paint preparation method, and its step is as follows：（1）System
Standby protection glue；（2）Prepare base paint：During preparation, the Protection glue liquid prepared is slowly added into other mixed materials, done
After good base paint after 24 hours after be granulated again；During granulation, 400 parts of base paint for mixing up color is added to the guarantor that 300 parts of concentration are 6%
Protect in glue, be granulated after standing 3-5 minutes with screen granulator or dispersion impeller；（3）Prepare continuous items；（4）By step（2）Do
Good particle is added in continuous items, and particle presses 1 with slurry:1 mass ratio adds, and is slowly stirred and finished product uniformly is made.This
The aqueous colorful paint preparation method that invention is prepared to be obtained is simple, and it is good to prepare multi-color using effect, has and preferably kills
Bacterium effect, bright in luster, performance is good, easy to use.
The content of the invention
It is high weather resistant water-thinned colorful it is an object of the invention to provide a kind of water resistant low temperature to solve above-mentioned problem
Coating and preparation method thereof, the water-soluble colorful coating configure based on using fluorine-silicon modified acrylic emulsion and water-base fluorocarbon emulsion
Form, have high stability, do not ftracture, be impermeable, anti-stain characteristic it is strong, water resistance is excellent, water-fast, alkaline-resisting, salt spray resistance, resistance toization
The property learned, high-weatherability.
To reach above-mentioned purpose, the technical scheme is that：
A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature, the coating include the composition of following parts by weight：It is organic-silicon-modified
Acrylic acid fluorine carbon copolymer emulsion：30 ~ 40 parts, rutile titanium white powder：10 ~ 15 parts, lignocellulosic：5 ~ 10 parts, powdered whiting：
10 ~ 15 parts, kaolin：5 ~ 10 parts, nano titanium oxide：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1
~ 5 parts, antifreezing agent：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
Further, the coating includes the composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35~
40 parts, rutile titanium white powder：10 ~ 13 parts, lignocellulosic：5 ~ 7 parts, powdered whiting：13 ~ 15 parts, kaolin：5 ~ 8 parts, receive
Rice titanium dioxide：2 ~ 5 parts, mould inhibitor：3 ~ 5 parts, coalescents：1 ~ 3 part, defoamer：1 ~ 4 part, antifreezing agent：1 ~ 3 part, wetting
Agent：2 ~ 5 parts, deionized water：40 ~ 50 parts.
Preferably, the coating includes the composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35
Part, rutile titanium white powder：13 parts, lignocellulosic：6 parts, powdered whiting：14 parts, kaolin：7 parts, nano titanium oxide：3
Part, mould inhibitor：4 parts, coalescents：2 parts, defoamer：3 parts, antifreezing agent：2 parts, wetting agent：3 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the wetting agent is modified polyorganosiloxane.
Preferably, the antifreezing agent is ethylene glycol, propane diols or isopropanol.
Meanwhile the present invention also provides a kind of preparation method of the high weather resistant water-thinned multicolor finish of water resistant low temperature, its feature exists
In the preparation method comprises the following steps：1) mixer is taken, organosilicon-modified acrylic fluorine carbon is copolymerized breast by weight
Liquid, rutile titanium white powder, lignocellulosic, powdered whiting, kaolin, nano titanium oxide and 50wt% deionized water add
Enter in mixer, stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) mould inhibitor, coalescents are added, are disappeared
Infusion, antifreezing agent, wetting agent and remaining deionized water, are warming up to 30 ~ 40 DEG C, under 700 ~ 800 revs/min of rotating speed stir 10 ~
20 minutes, room temperature is cooled to, is filtered, stands, produces the high weather resistant water-thinned multicolor finish of the water resistant low temperature.
The invention has the advantages that：
The water-soluble colorful coating is formed using configure based on fluorine-silicon modified acrylic emulsion and water-base fluorocarbon emulsion, have it is high surely
It is qualitative, do not ftracture, be impermeable, anti-stain characteristic it is strong, water resistance is excellent, water-fast, alkaline-resisting, salt spray resistance, chemical resistance, high durable
Property.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
The high weather resistant water-thinned multicolor finish of a kind of water resistant low temperature provided by the present invention, the coating include following parts by weight
Composition：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：30 ~ 40 parts, rutile titanium white powder：10 ~ 15 parts, lignocellulosic：5
~ 10 parts, powdered whiting：10 ~ 15 parts, kaolin：5 ~ 10 parts, nano titanium oxide：1 ~ 5 part, mould inhibitor：1 ~ 5 part, film forming helps
Agent：1 ~ 5 part, defoamer：1 ~ 5 part, antifreezing agent：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
Further, the coating includes the composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35~
40 parts, rutile titanium white powder：10 ~ 13 parts, lignocellulosic：5 ~ 7 parts, powdered whiting：13 ~ 15 parts, kaolin：5 ~ 8 parts, receive
Rice titanium dioxide：2 ~ 5 parts, mould inhibitor：3 ~ 5 parts, coalescents：1 ~ 3 part, defoamer：1 ~ 4 part, antifreezing agent：1 ~ 3 part, wetting
Agent：2 ~ 5 parts, deionized water：40 ~ 50 parts.
Preferably, the coating includes the composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35
Part, rutile titanium white powder：13 parts, lignocellulosic：6 parts, powdered whiting：14 parts, kaolin：7 parts, nano titanium oxide：3
Part, mould inhibitor：4 parts, coalescents：2 parts, defoamer：3 parts, antifreezing agent：2 parts, wetting agent：3 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the wetting agent is modified polyorganosiloxane.
Preferably, the antifreezing agent is ethylene glycol, propane diols or isopropanol.
Meanwhile the present invention also provides a kind of preparation method of the high weather resistant water-thinned multicolor finish of water resistant low temperature, its feature exists
In the preparation method comprises the following steps：1) mixer is taken, organosilicon-modified acrylic fluorine carbon is copolymerized breast by weight
Liquid, rutile titanium white powder, lignocellulosic, powdered whiting, kaolin, nano titanium oxide and 50wt% deionized water add
Enter in mixer, stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) mould inhibitor, coalescents are added, are disappeared
Infusion, antifreezing agent, wetting agent and remaining deionized water, are warming up to 30 ~ 40 DEG C, under 700 ~ 800 revs/min of rotating speed stir 10 ~
20 minutes, room temperature is cooled to, is filtered, stands, produces the high weather resistant water-thinned multicolor finish of the water resistant low temperature.
The high weather resistant water-thinned multicolor finish of a kind of water resistant low temperature provided by the present invention, using fluorine-silicon modified acrylic emulsion and
Based on water-base fluorocarbon emulsion configuration form, have high stability, do not ftracture, be impermeable, anti-stain characteristic it is strong, water resistance is excellent
Different, water-fast, alkaline-resisting, salt spray resistance, chemical resistance, high-weatherability.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
- A kind of 1. high weather resistant water-thinned multicolor finish of water resistant low temperature, it is characterised in that the coating include following parts by weight into Point：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：30 ~ 40 parts, rutile titanium white powder：10 ~ 15 parts, lignocellulosic：5~10 Part, powdered whiting：10 ~ 15 parts, kaolin：5 ~ 10 parts, nano titanium oxide：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents： 1 ~ 5 part, defoamer：1 ~ 5 part, antifreezing agent：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
- 2. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the coating includes The composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35 ~ 40 parts, rutile titanium white powder：10 ~ 13 parts, wood Matter cellulose：5 ~ 7 parts, powdered whiting：13 ~ 15 parts, kaolin：5 ~ 8 parts, nano titanium oxide：2 ~ 5 parts, mould inhibitor：3~5 Part, coalescents：1 ~ 3 part, defoamer：1 ~ 4 part, antifreezing agent：1 ~ 3 part, wetting agent：2 ~ 5 parts, deionized water：40 ~ 50 parts.
- 3. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the coating includes The composition of following parts by weight：Organosilicon-modified acrylic fluorine carbon copolymer emulsion：35 parts, rutile titanium white powder：13 parts, wood fibre Element：6 parts, powdered whiting：14 parts, kaolin：7 parts, nano titanium oxide：3 parts, mould inhibitor：4 parts, coalescents：2 parts, disappear Infusion：3 parts, antifreezing agent：2 parts, wetting agent：3 parts, deionized water：45 parts.
- 4. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the defoamer is Amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
- 5. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the coalescents For propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
- 6. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the mould inhibitor For benzimidazole methyl carbamate.
- 7. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the wetting agent is Modified polyorganosiloxane.
- 8. the high weather resistant water-thinned multicolor finish of water resistant low temperature according to claim 1, it is characterised in that the antifreezing agent is Ethylene glycol, propane diols or isopropanol.
- 9. a kind of preparation method of high weather resistant water-thinned multicolor finish of water resistant low temperature as any one of claim 1 ~ 8, Characterized in that, the preparation method comprises the following steps：1) mixer is taken, by weight by organosilicon-modified acrylic fluorine carbon Copolymer emulsion, rutile titanium white powder, lignocellulosic, powdered whiting, kaolin, nano titanium oxide and 50wt% go from Sub- water is added in mixer, is stirred 20 ~ 30 minutes under normal temperature, 500 ~ 600 revs/min of rotating speed；2) mould inhibitor is added, film forming helps Agent, defoamer, antifreezing agent, wetting agent and remaining deionized water, are warming up to 30 ~ 40 DEG C, are stirred under 700 ~ 800 revs/min of rotating speed Mix 10 ~ 20 minutes, be cooled to room temperature, filter, stand, produce the high weather resistant water-thinned multicolor finish of the water resistant low temperature.
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| CN201710868086.3A CN107502102A (en) | 2017-09-22 | 2017-09-22 | A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710868086.3A CN107502102A (en) | 2017-09-22 | 2017-09-22 | A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627890A (en) * | 2018-11-27 | 2019-04-16 | 浙江欧路德交通科技有限公司 | A kind of fluorinated silicone modified waterborne road line paint |
| CN110591480A (en) * | 2019-09-05 | 2019-12-20 | 金鹏建筑产业有限公司 | Water-based building heat-insulation environment-friendly coating and preparation method thereof |
| CN113234365A (en) * | 2021-06-23 | 2021-08-10 | 河北晨阳工贸集团有限公司 | Water-based weather-resistant self-cleaning coating and preparation method and application thereof |
| CN116179080A (en) * | 2023-03-10 | 2023-05-30 | 深圳市纳能科技有限公司 | Anti-fouling high-weather-resistance damping coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570587A (en) * | 2009-05-08 | 2009-11-04 | 厦门大学 | Fluorine-silicon modified acrylic copolymer resin and preparation method thereof |
| CN102993851A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Building outer wall solar heat reflecting energy-saving coating and preparation method thereof |
| CN105694716A (en) * | 2016-01-29 | 2016-06-22 | 余悦 | Environment-friendly fluorine silicon multicolor paint and preparation method thereof |
| CN107022270A (en) * | 2017-05-16 | 2017-08-08 | 威海新元化工有限公司 | A kind of preparation method of fluorinated silicone modified stone similar paint |
-
2017
- 2017-09-22 CN CN201710868086.3A patent/CN107502102A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570587A (en) * | 2009-05-08 | 2009-11-04 | 厦门大学 | Fluorine-silicon modified acrylic copolymer resin and preparation method thereof |
| CN102993851A (en) * | 2012-09-29 | 2013-03-27 | 北京东方雨虹防水技术股份有限公司 | Building outer wall solar heat reflecting energy-saving coating and preparation method thereof |
| CN105694716A (en) * | 2016-01-29 | 2016-06-22 | 余悦 | Environment-friendly fluorine silicon multicolor paint and preparation method thereof |
| CN107022270A (en) * | 2017-05-16 | 2017-08-08 | 威海新元化工有限公司 | A kind of preparation method of fluorinated silicone modified stone similar paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109627890A (en) * | 2018-11-27 | 2019-04-16 | 浙江欧路德交通科技有限公司 | A kind of fluorinated silicone modified waterborne road line paint |
| CN110591480A (en) * | 2019-09-05 | 2019-12-20 | 金鹏建筑产业有限公司 | Water-based building heat-insulation environment-friendly coating and preparation method thereof |
| CN113234365A (en) * | 2021-06-23 | 2021-08-10 | 河北晨阳工贸集团有限公司 | Water-based weather-resistant self-cleaning coating and preparation method and application thereof |
| CN116179080A (en) * | 2023-03-10 | 2023-05-30 | 深圳市纳能科技有限公司 | Anti-fouling high-weather-resistance damping coating and preparation method thereof |
| CN116179080B (en) * | 2023-03-10 | 2024-03-19 | 深圳市纳能科技有限公司 | Anti-fouling high-weather-resistance damping coating and preparation method thereof |
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Application publication date: 20171222 |
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