CN102731052A - Aqueous organic-inorganic composite coating and preparation method thereof - Google Patents

Aqueous organic-inorganic composite coating and preparation method thereof Download PDF

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CN102731052A
CN102731052A CN201210188995XA CN201210188995A CN102731052A CN 102731052 A CN102731052 A CN 102731052A CN 201210188995X A CN201210188995X A CN 201210188995XA CN 201210188995 A CN201210188995 A CN 201210188995A CN 102731052 A CN102731052 A CN 102731052A
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water
inorganic composite
composite coating
organic
parts
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CN201210188995XA
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CN102731052B (en
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吴银萍
王代民
张旭
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嘉宝莉化工集团股份有限公司
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Abstract

The invention discloses an aqueous organic-inorganic composite coating, comprising the base materials of water-soluble film-forming material, pigment, filler, additive and water. The aqueous organic-inorganic composite coating is specifically composed of the following component, by weight: 15-25 parts of potassium silicate, 10-20 parts of styrene-acrylic emulsion, 0.2-0.5 part of stabilizer, 0.2-0.5 part of dispersing agent, 0.3-0.6 part of defoaming agent, 0.2-0.5 part of film-forming additive, 0.2-0.5 part of antifreeze, 0.1-0.3 part of thickening agent, 14-20 parts of titanium dioxide, 15-25 parts of heavy calcium, 5-10 parts of talcum powder and 20-25 parts of water. The invention has the following advantages: high film hardness, no cracking, excellent weather fastness, lasting replenished film, no addition of preservatives, excellent environmental protection performance, long recoating period of film and resource saving. In addition, the product has minimal construction resistance, and is easy for painting, promotion and application. The aqueous organic-inorganic composite coating has wide application range, and can be applied to coating of basement, underground parking, inner wall and outer wall.

Description

Water-based organic and inorganic composite coating and preparation method thereof
[technical field]
The present invention relates to paint field, tool is a kind of water-based organic and inorganic composite coating and preparation method thereof.
[background technology]
The Along with people's growth in the living standard, people increase the coating type demand gradually, and more pay close attention to the green environmental protection of product.Exterior wall and vault to cement-base concrete; Because its body of wall alkalescence is strong, humidity is high and hardness requirement is high; After the generic latex lacquer construction, be prone to that paint film adhesion is poor, hardness is low, the accumulation of salt in the surface soil, mildew and disadvantage such as be prone to peel off, be not suitable for the concrete base surface construction.
At present; The coating of domestic less suitable concrete base surface construction; Therefore develop that a paint film adhesion is good, hardness is high, water-fast, alkaline-resisting, temp. variation resistant, weathering resistance and the excellent coating of environmental-protecting performance, economic benefit will be very remarkable with environmental benefit, have wide application and development prospect.
[summary of the invention]
The objective of the invention is to solve the problem that above-mentioned prior art exists, a kind of excellent performance and water-based organic and inorganic composite coating that can save energy are provided.
Another object of the present invention provides a kind of preparation method of water-based organic and inorganic composite coating.
For achieving the above object, the technical scheme that the present invention adopts is: water-based organic and inorganic composite coating, to form by components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following parts by weight:
The label that said potassium silicate can select for use ocean, Xingtai chemical industry ltd to produce is the product of DY-403 or DY-404; The label of the production of Laiyang permanent letter chemical industry ltd is the product of HXY205 or HXY204, and perhaps the label of Jiangsu Guolian Technology Co., Ltd.'s product is the product of GHSK.
The label that said benzene emulsion can select for use BASF stock company to produce is distinguish the flavor of only emulsion or a 296D-S benzene emulsion of ECO502, the 998A emulsion of producing in the Foshan City Shunde District Batf Industry Co.,Ltd.
Said stablizer is a quaternary ammonium compound, the SPS that selects for use Clariant chemical industry (China) ltd to produce.
Said skimmer is a mineral oil defoaming agent, the SN-NXZ skimmer of selecting for use Nippon Nopco Assistant Co., Ltd. to produce.
Said dispersion agent is polycarboxylate sodium's class dispersion agent, and that select for use Dow Chemical company to produce is prone to dispersion agent soon.
Said thickening material is a Mierocrystalline cellulose, preferably adopts Natvosol class thickening material, and the model that can select for use Akzo Nobel N.V. to produce is the thickening material of HS30000, and this thickening material and system compatible stability are good, stores the back stable viscosity.
Said frostproofer adopts terepthaloyl moietie, the terepthaloyl moietie that can select for use Guangzhou rich chemical industry in morning ltd to produce.The antifreeze efficient of this frostproofer is high, and cost performance is high.
Said film coalescence aid adopts 2,2,4-trimethylammonium-1, and 3-pentanediol-isobutyrate, the model of selecting for use Eastman Chemical to produce is the film coalescence aid of TEXANOL.
Said white titanium pigment adopts rutile-type, and the model of selecting du pont company production for use is the white titanium pigment of R-706.
Said coarse whiting adopts 800~1250 order coarse whitings, and the model that can select for use Switzerland Ou Miya group to produce is Omyacard 2 or Omyacard 5 coarse whitings.
Said talcum powder adopts 1000-1250 order talcum powder, the talcum powder that can select for use Heshan chemical industry (Liaoning) ltd to produce.
A kind of preparation method of water-based organic and inorganic composite coating, it step that comprises is following:
(1) pre-mixing: the water that in disperseing cylinder, adds 13~17 parts; And then add stablizer, dispersion agent, skimmer, film coalescence aid, frostproofer and the thickening material of above parts by weight respectively; Fully mix and form gelationus mixture, mix the rotating speed that stirs and be controlled at 300~500rpm;
(2) grind to disperse: in disperseing cylinder, add white titanium pigment, coarse whiting, the talcum powder of above-mentioned parts by weight, the grinding 20~25 minutes of under 1500~2500rpm, pulling an oar of control rotating speed, to fineness less than 50um;
(3) add filmogen: after in disperseing cylinder, adding benzene emulsion, stirring velocity is controlled at 1000~1500rpm, stirs; Add potassium silicate again, stirring velocity is controlled at 1000~1500rpm, stirs;
(4) add auxiliary agent: in disperseing cylinder, add remaining water successively, mix, mix the rotating speed that stirs and be controlled at 800~1200rpm, promptly get water-based organic and inorganic composite coating.
(5) packing: as requested coating is contained in the Lacquered Tin Plate Can of different volumes.
The present invention has used inorganic filming substance matter potassium silicate in coating, it adds back coating and has excellent alkali resistance, weathering resistance and thermotolerance, and heat resisting temperature can reach 500~600 ℃, and with inorganic substrate firm cohesive force is arranged; Have adjustable wet, antisweat property, hardness of paint film height.Moreover, because of water glass potassium silicate pH>13, make coating system not possess the bacterial growth environment, need not to add Antisepticize and mildew preventive, paint film has from anticorrosion antimildew function, thereby reduces product cost, has excellent environmental-protecting performance.In addition, the water glass potassium silicate is because its inherent characteristic as paint binder, has some shortcomings simultaneously, for example: poor water resistance, and it is hard and crisp, nonelastic, easy to crack to film, and bad with the viscosity of organic materials, and the paint film porous is so anti-permeability is poor.With synthetic resin emulsion as the compound use of inorganic base materials such as auxiliary film forming matter and potassium silicate; Organic resin can be filled in-Si-O-Si-reticulated structure gap in; Shield remaining hydroxyl, improve the paint film water tolerance, synthetic resins has elasticity preferably; Can improve the anti-cracking performance of paint film, and have snappiness preferably.Synthetic resin coating film is fine and close, can improve the paint film permeability resistance.After the compound use of inorganic silicic acid potassium and benzene emulsion, paint film adhesion is good, hardness is high, do not ftracture, water-fast, alkaline-resisting, temp. variation resistant, weathering resistance and environmental-protecting performance are excellent.Simultaneously, during the two compound use, the consistent stability that could guarantee mixed system on electrical property only, otherwise gelation and the creaming of emulsion of potassium silicate will occur and can not get stable coating.
With prior art contrast, the present invention has following advantage: hardness of paint film is high, does not ftracture, excellent weather resistance and hard, and paint film is more new lastingly; Do not add Antisepticize and mildew preventive, environmental-protecting performance is excellent, and the paint film repainted period is long, can economize on resources; In addition, product construction resistance is minimum, is prone to japanning, very easily promotes the use of.It has wide range of applications, applicable to applications such as vault, underground parking, interior wall and exterior walls.
[description of drawings]
Fig. 1 compares comparison diagram (wherein 1-1 is the organic and inorganic composite coating, and 1-2 is existing common organic coating) for organic and inorganic composite coating of the present invention and existing common organic coating temp. variation resistant performance;
Fig. 2 compares (2-1 is existing common organic coating, and 2-2 is the organic and inorganic composite coating) for organic and inorganic composite coating of the present invention and existing common organic coating paint film fungicidal properties;
Fig. 3 is that organic and inorganic composite coating of the present invention and existing composite coating anti-cracking performance compare (3-1 is existing composite coating, and 3-2 is an organic and inorganic composite coating of the present invention).
[embodiment]
Below in conjunction with accompanying drawing and specific embodiment the bilateral supersonic welder of the present invention is carried out detailed explanation.
Embodiment 1
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
Embodiment 2
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
Embodiment 3
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
Embodiment 4
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
Embodiment 5
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
Embodiment 6
Water-based organic and inorganic composite coating is made up of components such as base-material (water-soluble, film-forming material), pigment, filler, auxiliary agent and water, and it specifically is made up of the component of following weight part:
The preparation method of said water-based organic and inorganic composite coating, it step that comprises is following:
(1) pre-mixing: the water that in disperseing cylinder, adds 13~17 parts; And then add stablizer, dispersion agent, skimmer, film coalescence aid, frostproofer and the thickening material of above parts by weight respectively; Fully mix and form gelationus mixture, mix the rotating speed that stirs and be controlled at 300~500rpm;
(2) grind to disperse: in disperseing cylinder, add white titanium pigment, coarse whiting, the talcum powder of above-mentioned parts by weight, the grinding 20~25 minutes of under 1500~2500rpm, pulling an oar of control rotating speed, to fineness less than 50um;
(3) add filmogen: after in disperseing cylinder, adding benzene emulsion, stirring velocity is controlled at 1000~1500rpm, stirs; Add potassium silicate again, stirring velocity is controlled at 1000~1500rpm, stirs;
(4) add auxiliary agent: in disperseing cylinder, add remaining water successively, mix, mix the rotating speed that stirs and be controlled at 800~1200rpm, promptly get water-based organic and inorganic composite coating.
(5) packing: as requested coating is contained in the Lacquered Tin Plate Can of different volumes.
Above-described potassium silicate, the product code numbering that can preferably use ocean, Xingtai chemical industry ltd to produce is DY-403 and DY-404, HXY205, the HXY204 of the production of Laiyang permanent letter chemical industry ltd, the perhaps GHSK of Jiangsu Guolian Technology Co., Ltd.'s product.Said benzene emulsion, ECO502, the 296D-S emulsion that can preferably produce, the 998A emulsion of producing in the Foshan City Shunde District Batf Industry Co.,Ltd with BASF stock company.Said stablizer is a quaternary ammonium compound, the SPS that selects for use Clariant chemical industry (China) ltd to produce.Said skimmer is a mineral oil defoaming agent, the NXZ skimmer of selecting for use Nippon Nopco Assistant Co., Ltd. to produce.Said dispersion agent is polycarboxylate sodium's class dispersion agent, and that select for use Dow Chemical company to produce is prone to dispersion agent soon.Said thickening material is a Mierocrystalline cellulose, preferably adopts Natvosol class thickening material, and the model that can select for use Akzo Nobel N.V. to produce is the thickening material of HS30000, and this thickening material and system compatible stability are good, stores the back stable viscosity.Said frostproofer adopts terepthaloyl moietie, the terepthaloyl moietie that can select for use Guangzhou rich chemical industry in morning ltd to produce.The antifreeze efficient of this frostproofer is high, and cost performance is high.Said film coalescence aid adopts 2,2,4-trimethylammonium-1, and 3-pentanediol-isobutyrate, the model of selecting for use Eastman Chemical to produce is the film coalescence aid of TEXANOL.Said white titanium pigment adopts rutile-type, and the model of selecting du pont company production for use is the white titanium pigment of R-706.Said coarse whiting adopts 800~1250 order coarse whitings, and the model that can select for use Switzerland Ou Miya group to produce is Omyacard 2 or Omyacard 5 coarse whitings.Said talcum powder adopts 1000-1250 order talcum powder, the talcum powder that can select for use Heshan chemical industry (Liaoning) ltd to produce.
The product performance test:
The product performance test is carried out according to GB JG/T26-2002 exterior wall inorganic architectural coatings specified standards, and test result is as shown in the table:
Project GB JG/T26-2002 technical indicator Organic and inorganic composite coating of the present invention
Condition in container Stirring the back does not have caking, is uniform state Stirring the back does not have caking, is uniform state
Application property It is accessible to brush two roads It is accessible to brush two roads
Appearance of film Appearance of film is normal Appearance of film is normal
Contrast ratio (white and light color) ≥0.95 0.96
Heat-storage stability (30d) No caking, cohesion, mildew phenomena No caking, cohesion, mildew phenomena
Low tempertaure storage stability (3 times) There are not caking, coacervation There are not caking, coacervation
Surface drying time/h ≤2 1
Abrasion resistance (inferior) ≥1000 10000
Water tolerance (168h) No foaming, crackle, peel off, allow slight dry linting No foaming, crackle, peel off, not dry linting
Alkali resistance (168h) No foaming, crackle, peel off, allow slight dry linting No foaming, crackle, peel off, not dry linting
Temperature-change resistance (10 times) No foaming, crackle, peel off, allow slight dry linting No foaming, crackle, peel off, not dry linting
Contamination resistance/%I ≤20% 15%
Artificial ageing resistance property (white and shallow No foaming, crackle, peel off, efflorescence<=1 grade, become No foaming, crackle, peel off, 0 grade of efflorescence,
Look) (II500h) Look<=2 grade 0 grade of variable color, qualified
Can find out that from last table water-based organic and inorganic composite coating of the present invention meets GB JG/T26-2002 exterior wall inorganic architectural coatings specified standards.
As shown in Figure 1, water-based organic and inorganic composite coating of the present invention and existing common organic coating temp. variation resistant performance are on the market compared, it is excellent to draw temp. variation resistant performance of the present invention, the anti-powder phenomenon-tion that do not occur of paint film.
As shown in Figure 2; Organic and inorganic composite coating of the present invention and common organic coating paint film fungicidal properties are relatively; Organic and inorganic composite coating (not adding mould inhibitor) compares with common organic coating (interpolation mould inhibitor) fungicidal properties, finds that the organic and inorganic composite coating is more excellent than the fungicidal properties of the organic coating that has added sanitas on the market.
Organic and inorganic composite coating as shown in Figure 3, that the present invention is on sale with respect to the market, splitting resistance are excellent more, can effectively prevent paint film cracking.
The above person; Be merely preferred embodiment of the present invention; When not limiting the scope that the present invention implements with this, the simple equivalent of promptly doing according to claim of the present invention and invention description generally changes and modifies, and all still belongs in the scope that patent of the present invention contains.

Claims (10)

1. water-based organic and inorganic composite coating is characterized in that, is made up of the component of following weight part:
2. water-based organic and inorganic composite coating according to claim 1 is characterized in that, the product that said potassium silicate selects for use ocean, Xingtai chemical industry ltd to produce, and label is DY-403 or DY-404; The HXY205 or the HXY204 of the production of Laiyang permanent letter chemical industry ltd; The perhaps GHSK that produces of Jiangsu Guolian Technology Co., Ltd..
3. water-based organic and inorganic composite coating according to claim 1 is characterized in that, ECO502 or 296D-S emulsion that said benzene emulsion selects for use BASF stock company to produce, perhaps the 998A emulsion of Foshan City Shunde District Batf Industry Co.,Ltd product.
4. water-based organic and inorganic composite coating according to claim 1 is characterized in that said stablizer is a quaternary ammonium compound, the SPS that selects for use Clariant chemical industry (China) ltd to produce.
5. water-based organic and inorganic composite coating according to claim 1 is characterized in that said skimmer is a mineral oil defoaming agent, the NXZ skimmer of selecting for use Nippon Nopco Assistant Co., Ltd. to produce.
6. water-based organic and inorganic composite coating according to claim 1; It is characterized in that; Said dispersion agent is polycarboxylate sodium's class dispersion agent, and that select for use Dow Chemical company to produce is prone to dispersion agent soon.
7. water-based organic and inorganic composite coating according to claim 1 is characterized in that, said thickening material adopts Natvosol class thickening material, and the model of selecting for use Akzo Nobel N.V. to produce is the thickening material of HS30000.
8. water-based organic and inorganic composite coating according to claim 1 is characterized in that, said film coalescence aid adopts 2,2,4-trimethylammonium-1,3-pentanediol-isobutyrate.
9. according to the preparation method of the arbitrary described water-based organic and inorganic composite coating of claim 1-8, it is characterized in that it step that comprises is following:
(1) pre-mixing: in disperseing cylinder, add 13~17 parts water, and then add stablizer, dispersion agent, skimmer, film coalescence aid, frostproofer and the thickening material of above parts by weight respectively, fully mix and form gelationus mixture;
(2) grind dispersion: in disperseing cylinder, add white titanium pigment, coarse whiting, the talcum powder of above-mentioned parts by weight, making beating is ground to fineness less than 50um;
(3) add filmogen: after in disperseing cylinder, adding benzene emulsion, stir; Add potassium silicate again, stir;
(4) add auxiliary agent: in disperseing cylinder, add remaining water successively and reach, mix.
10. according to the preparation method of the arbitrary described water-based organic and inorganic composite coating of claim 9, it is characterized in that, in said (1) step, mix the rotating speed that stirs and be controlled at 300~500rpm; (2) in the step, the rotating speed that making beating is ground is at 1500~2500rpm, and the time is 20~25 minutes.
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CN102976707A (en) * 2012-11-27 2013-03-20 东莞大宝化工制品有限公司 Inorganic silicate conditioning paint and preparation method thereof
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CN104530882A (en) * 2014-12-25 2015-04-22 三棵树涂料股份有限公司 Organosilicate composite exterior wall coating and preparation method thereof
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CN102976707A (en) * 2012-11-27 2013-03-20 东莞大宝化工制品有限公司 Inorganic silicate conditioning paint and preparation method thereof
CN104031448A (en) * 2014-06-17 2014-09-10 苏州靖羽新材料有限公司 Plain exterior wall coating
CN104530882A (en) * 2014-12-25 2015-04-22 三棵树涂料股份有限公司 Organosilicate composite exterior wall coating and preparation method thereof
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CN105542525A (en) * 2016-01-27 2016-05-04 广东施彩涂料有限公司 Inorganic coating with good storage stability and preparation method thereof
CN105542603A (en) * 2016-01-27 2016-05-04 广东施彩涂料有限公司 High-strength inorganic paint and preparation method thereof
CN105731977A (en) * 2016-01-27 2016-07-06 广东施彩涂料有限公司 Water-tolerant inorganic coating and preparation method thereof
CN105731977B (en) * 2016-01-27 2018-06-01 广东施彩新材料科技有限公司 A kind of water-fast inorganic coating and preparation method thereof
CN105906745A (en) * 2016-05-17 2016-08-31 梁少荣 Water-borne plastic compound material, synthetic method and water-borne polymer membrane of water-borne plastic compound material
CN106348717A (en) * 2016-08-24 2017-01-25 河南省德嘉丽科技开发有限公司 Inorganic silicate paint
CN106634357A (en) * 2017-01-12 2017-05-10 广东美涂士建材股份有限公司 Special interior wall coating used on glass fiber cloth and preparation method thereof
CN108610801A (en) * 2017-05-25 2018-10-02 太仓安托建筑材料有限公司 A kind of inner wall mold-proof paint
CN107555905A (en) * 2017-09-21 2018-01-09 中民筑友科技投资有限公司 A kind of ultra-high performance concrete decorative panel and preparation method thereof
CN108047779A (en) * 2018-01-05 2018-05-18 吕跃文 aqueous forest negative oxygen ion inorganic coating and preparation method thereof
CN108912755A (en) * 2018-05-29 2018-11-30 佛山市顺德区雅成化工有限公司 A kind of preparation method of aqueous inorganic paint
CN109135467A (en) * 2018-07-18 2019-01-04 成都虹润制漆有限公司 composite coating and preparation method thereof
CN111434735A (en) * 2019-01-14 2020-07-21 上海三银涂料科技股份有限公司 Water-based acid rain-proof building coating
CN110395965A (en) * 2019-08-19 2019-11-01 广东狮力德建材有限公司 It is a kind of to remove aldehyde interior wall coating and preparation method thereof by the inorganic of filler material of conch meal
CN111269596A (en) * 2020-04-09 2020-06-12 中山市美力德化工有限公司 Preparation method of inorganic polymer resin and water-based paint
CN111662580A (en) * 2020-07-01 2020-09-15 山西中阳钢铁有限公司 Environment-friendly inorganic coating produced by utilizing slag micro powder and preparation method thereof

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