CN104004424A - Manufacture method and construction technology of reflective heat-insulation water-based coating with texture imitating granite - Google Patents
Manufacture method and construction technology of reflective heat-insulation water-based coating with texture imitating granite Download PDFInfo
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Abstract
The invention discloses a manufacture method and a construction technology of reflective heat-insulation water-based coating with texture imitating granite. The manufacture method includes the first step of preparing basic color paint, the second step of preparing a high-stability protective glue solution, the third step of granulating, the fourth step of obtaining finished coating through mixing and the fifth step of obtaining fluorine-modified acrylic acid finish varnish, wherein in the third step, the basic color paint obtained in the first step and the high-stability protective glue solution obtained in the second step are mixed, and granulation is achieved through a stirring or screening technology, so that a film insoluble in water is formed on the surfaces of basic color paint particles and exists in the high-stability protective glue solution in an unmixing particle state, and color particles are formed; in the fourth step, color particle components which are of various colors and obtained through granulation in the third step are mixed with silicone-acrylic elastic acrylic emulsion to form the finished coating. The coating manufactured in the method is completely water-based, has the texture of natural granite, has reflection and heat isolation functions, and meanwhile is high in contamination resistance, high in elasticity, self-cleaning, high in weather resistance and high in cost performance.
Description
Technical field
The present invention relates to technical field of coatings, making method and the construction technology of particularly reflective insulation character sense artificial granite water-borne coatings.
Background technology
The popular artificial granite coating of existing market comprises two classes:
(1) oil-in-water-type
Oil-in-water-type multicolor finish is a kind of versicolor enamel paint, evenly, is stably dispersed in the aqueous solution that contains protection glue composition, forms complicated oil and water mixed two-phase system mutually.External phase is water, is synthetic resin emulsion, the methyl protective colloid aqueous solution etc.; Disperse phase is oil phase, contains solvent and nitro protective colloid, vinyl toluene/butadienecopolymer, and the filmogens such as modified alkyd resin, add the auxiliary agent such as filler, pigment.It had both had the high gloss of paint, the premium properties such as good water-fast, alkaline-resisting, washable wiping, had the features such as aqueous architectural coating strong adhesion, good permeability again, made performance index, the specification of quality of multicolor finish be different from general coating.The advantages such as oil-in-water-type multicolor finish has that production technique is simple, storage, easy construction, film performance are good, production in a large number at home.Oil-in-water-type stone-like coating is actually the dispersion of a kind of enamel paint at water, preparation when this enamel paint organic solvent used be explosives, inflammable items as toluene, dimethylbenzene and basic film forming matter nitro-cotton etc., this brings very large difficulty to raw-material storage, transport and process of manufacture.And organic solvent cost is higher, pollution is large, production and workmen's health is had to certain harm, so the production and selling of this class coating is forbidden by some national environmental regulation.
(2) ortho-water water-in type
Water type multicolor paint for water drum, it is water-based stone-like coating, its decorative effect is identical with oil-in-water-type, the advantages such as oil-in-water-type multicolor finish production technique is simple except having, storage, easy construction, film performance are good, also overcome its poisonous shortcoming, become novel colorful stone-like coating nontoxic, free from environmental pollution.This be in aqueous latex paint, add can gelation water soluble paint disperse to form.Conventionally two-phase referred to as A component and B component, they are with contrary electric charge conventionally, the surface in contact at particle when two components are mixed produces gelation.But what also have does not need special cationic substance, but use the inorganic salt such as polynite and Na3P04, in the time that the two mixes, form sterically hinderedly, avoid the mutual bleeding of colour particles.Water bag water multicolor finish be in the market all generic latex paint as pigment particles, but color is abundant lacks texture, there is no concavo-convex gradation sense, lacks the rough style of nature, the non-constant of decorative effect of closely seeing.In addition, due to common water bag water multicolor finish without any reflective insulation effect, be unfavorable for the energy-saving and emission-reduction of buildings, if need independent construction outer wall external insulation system, cost can significantly rise first, construction technology is also complicated a lot of in addition.
In order to respond the call of government's energy-saving and emission-reduction, reduce the energy consumption of per GDP, make national economy increase to saving type and increase transition from extensive style, the every aspect of society is all mobilized, and proposes field energy-saving and emission-reduction scheme separately.As 1/3rd the building field that accounts for social total energy consumption, doing unremitting effort for this reason always.
So various novel energy-saving construction materials continue to bring out as emerging rapidly in large numbersBamboo shoots after a spring rain, on metope, energy-saving material the most effectively surely belongs to exterior wall heat-preserving system at present, mainly contain at present following several: 1, the outer insulation of traditional styrofoam or in-situ spraying polyurathamc thermal insulation layer, except construction trouble, also have security against fire potential problem, therefore popular unlike several years ago.2, rock wool material high insulating effect, ventilation property is pretty good, and fire resistance is also good, but its expensive cost, the employment injuries of rock wool fibers when easy water-permeable and on-site cutting to workmen, all allows the spread of this product be resisted.3, granular polystyrene heat insulating material for external starts to be back on construction site.From the angle of insulation, this is not a good method, is a kind of superseded technology, is a kind of helpless falling back.4, reflection type thermal insulation thermal insulation coatings is a kind of energy-saving heat preserving scheme of cheap easy construction, but the decorative effect of simple coating is very limited, and due in order to meet reflective insulation effect, have to adopt unified light application scheme, visual effect is not good.
Therefore, current exterior wall heat-preserving system is with high costs except having, exist the defects such as hidden fire-fighting danger, not environmental protection, also lacks ornamentally, cannot meet people's requirement attractive in appearance to facade; And common artificial granite coating no reflection events heat insulating function is helpless to the energy-saving and emission-reduction of buildings, due to its texture that lacks nature grouan, decorative effect is limited simultaneously.
Summary of the invention
In order to address the above problem, the invention provides making method and the construction technology thereof of reflection heat-insulating type texture artificial granite water-borne coatings.The technical problem to be solved in the present invention is: a kind of existing natural grouan texture is provided, has again the environment-friendly type coating of reflective insulation function.
In order to reach above-mentioned technical purpose of the present invention, the technical scheme in the present invention is: the making method of reflection heat-insulating type texture artificial granite water-borne coatings, it is characterized in that, and comprise following operation:
Operation one, prepare basic colored paint;
Operation two, preparation high stability protection sol solution;
Operation three, granulation: the high stability protection sol solution that the basic colored paint that operation one is made makes with operation two mixes, by stirring or the granulation of screen cloth technique, make base paint particle surface form water-fast coating, and be present in high stability protection sol solution with the graininess not merging mutually each other, form colour particles;
Operation four, allotment finished product paint: by the versicolor colour particles component making and silicon the third elastomeric propylene yogurt liquid mixing preparation, make finished product paint after operation three granulations;
Operation five, allotment fluorin modified crylic acid finishing varnish.
In such scheme, in described operation one, the composition mass percent of basic colored paint is:
Water 52.4%;
Sterilant 0.2%;
Natvosol 0.8%;
Defoamer 0.1%;
Wetting dispersing agent 0.2%;
Propylene glycol 1.5%;
Hollow glass micropearl VS55008%;
Solid ceramic microballoon W-21010%;
Organobentonite RD powder 0.4%;
Organic amine PH conditioning agent 0.1%;
Pure acrylic latex 25%;
Defoamer 0.1%;
Alcohol ester ten two 1.2%.
In such scheme, in described operation two, the composition mass percent of high stability protection sol solution is:
Water 92.3%;
Trisodium phosphate 0.6%;
Organobentonite RD powder 4.5%;
Cationic stabilized agent YT2.5%;
EDTA tetra-sodium 0.1%.
In such scheme, in described operation three, the mass percent of described basic colored paint and high stability protection sol solution is: basic colored paint 50～56.5%; High stability protection sol solution 43.5 ~ 50%.
In such scheme, in described operation four, the composition mass percent of described finished product paint is:
Colour particles component 60%;
Silicon the third elastomeric propylene yogurt liquid 10 ~ 20%;
Alcohol ester ten two 0.5%;
Sterilant 0.2%;
Propylene glycol 1%;
Defoamer 0.1%;
Organic amine PH conditioning agent 0.1%;
Thickening material 0.5%;
Water 17.6 ~ 27.6%.
In such scheme, the composition mass percent of described fluorin modified crylic acid finishing varnish is:
Fluorocarbon acrylic acid emulsion 60%;
Organic amine PH conditioning agent 0.1%;
Defoamer 0.1%;
Alcohol ester ten two 0.5%;
Sterilant 0.2%;
Propylene glycol 1%;
Thickening material 0.5%;
Water 37.6%.
The construction technology that the invention also discloses the reflection heat-insulating type texture artificial granite water-borne coatings that described manufacture method makes, its step comprises:
A. primary coat: conventional exterior wall infiltration priming paint is evenly coated in metope basic unit, it is penetrated in cement light face;
B. homochromy primary coat: after steps A completes, after described conventional exterior wall infiltration priming paint is dry, the conventional exterior coating of artificial granite background colour is evenly applied on conventional exterior wall infiltration priming paint with roller coating or spray gun;
C. jointing: demarcate the crack of stone position of design according to the pattern of planning with the line of ink marker, then cover described crack of stone position with jointing adhesive tape gluing;
D. in, be coated with: with suitable spray gun bore, blast, the finished product paint of described reflection heat-insulating type texture artificial granite water-borne coatings is sprayed to spray-coating surface;
E. jointing adhesive tape removes: complete after described middle painting step, according to jointing adhesive tape gluing initial, up and down order removed;
F. the coating of finishing paint: use spray gun evenly to coat on described finished product paint described fluorin modified crylic acid finishing varnish.
Advantage of the present invention and beneficial effect are: the invention provides a kind of making method of reflection heat-insulating type texture artificial granite water-borne coatings, and construction technology.The complete Water-borne modification of coating that this making method is made, VOC content is extremely low, is environment protecting building paint truly.Energy-conservation aspect, reflection heat-insulating type texture artificial granite water-borne coatings can be accomplished the effect playing the same tune on different musical instruments with grouan, contribute to reduce the exploitation of lithotome, can reflect most solar radiation energy simultaneously, and can launching the energy maximum amplitude of self, play the effect that reduces buildings temperature summer, thereby play the effect of building energy conservation.Aspect of performance, reflection heat-insulating type texture artificial granite water bag water multicolor finish has high anti-stain characteristic, snappiness, self-cleaning, high-weatherability, the feature of high performance-price ratio.
Specifically there are following advantage and beneficial effect: 1, be compared to glass curtain wall and dry-hang stone system, the trimming cost of unit surface of the present invention significantly reduces, and it is very convenient to construct; 2, be compared to common texture grouan water-soluble colorful coating, operation two has adopted cationic stabilized agent YT, has greatly increased the stability of coating, can store for a long time not bleeding mutually.3, be compared to water bag water multicolor finish conventional on market, owing to having added ceramic fine bead and hollow glass micropearl as aggregate, not only make the present invention there is good reflective insulation effect, belong to the building material of energy-saving and emission-reduction; And the effect that makes coating entirety is rich in grouan texture, outward appearance is the mad nature of overstriking more.4, use the emulsion of silicon the third elastomeric propylene yogurt liquid as external phase, ensure that coating can have good water-proof breathable properties, and have good anti-cracking behavior.5, the finishing varnish that uses fluorocarbon acrylic acid emulsion, guarantee system has good waterproof and oilproof anti-fouling effect, and air-permeable anti-bacterial is better in addition.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples are only for technical scheme of the present invention is more clearly described, and can not limit the scope of the invention with this.
Embodiment 1
Operation one, water 524kg, sterilant 2kg, Natvosol 8kg, defoamer 1kg, wetting dispersing agent 2kg, propylene glycol 15kg, hollow glass micropearl VS550080kg, solid ceramic microballoon W-210100kg, organobentonite RD powder 4kg, organic amine PH conditioning agent 1kg, pure acrylic latex 250kg, defoamer 1kg, alcohol ester 12 12kg are inserted in stirred vessel, make it to be uniformly mixed.Then the mixed solution of gained is divided into trisection, adds respectively appropriate brown, red, grey mill base, make the each 333.33kg of basic colored paint of brown, redness and grey.
Operation two, water 923kg, trisodium phosphate 6kg, organobentonite RD powder 45kg, cationic stabilized agent YT25kg are inserted in stirred vessel, and add EDTA tetra-sodium 1kg, then stir, make 1000kg high stability protection sol solution.
Operation three, brown, red, the basic colored paint of grey that operation one is made are respectively got 250kg; respectively add respectively the high stability that operation two makes to protect in sol solution 250kg; use middling speed dispersed with stirring; basic colored paint is dispersed in high stability protection sol solution; form little colored paint particle; also immiscible each other between these little colored paint particles, form colour particles component, obtain respectively the brown particles of 500kg, the red particles of 500kg, the grey colored particle of 500kg.
Operation four, brown, red, the grey colored particle component that operation three is made are respectively got 200kg, with silicon the third elastomeric propylene yogurt liquid 100kg, alcohol ester 12 5kg, sterilant 2kg, propylene glycol 10kg, defoamer 1kg, organic amine PH conditioning agent 1kg, thickening material 5kg, water 276kg, mixing and stirring, makes finished product paint 1000kg.
Operation five, by fluorine carbon pure acrylic latex 600kg; Organic amine PH conditioning agent 1kg; Defoamer 1kg; Alcohol ester 12 5kg; Sterilant 2kg; Propylene glycol 10kg; Thickening material 5kg; Water 376kg mixing and stirring, makes fluorin modified crylic acid finishing varnish 1000kg.
Conventional exterior wall infiltration priming paint is evenly coated to metope, make it to be penetrated in wall cement light face, increase the surface strength of cement light face, the sticking power of road paint to cement matrix after increasing; Then be evenly coated with the background colour of artificial granite coating with spray gun---the conventional exterior coating of light brown; Then demarcate the position of crack of stone according to the size of the artificial granite stone material of planning with the line of ink marker, and with jointing adhesive tape gluing covering line of ink marker position; Then use spray gun that artificial granite finished product paint of the present invention is evenly sprayed on metope; Finished product paint be coated with dry after, according to jointing adhesive tape gluing initial, order is torn up and down; Finally use spray gun that fluorin modified crylic acid finishing varnish is evenly coated on finished product paint, complete the construction of reflection heat-insulating type texture artificial granite water-borne coatings.
After testing, the water tolerance of reflection heat-insulating type texture artificial granite water-borne coatings is tested by GB/T1733-1993 national standard, without abnormal; Alkali resistance is tested according to GB/T9265-2009 national standard, without abnormal; Resistance to scrubbing tested according to the test of GB/T9266-2009 national standard, exceedes 5000 times; Other the key technical indexes:
Embodiment 2
Operation one, water 524kg, sterilant 2kg, Natvosol 8kg, defoamer 1kg, wetting dispersing agent 2kg, propylene glycol 15kg, hollow glass micropearl VS550080kg, solid ceramic microballoon W-210100kg, organobentonite RD powder 4kg, organic amine PH conditioning agent 1kg, pure acrylic latex 250kg, defoamer 1kg, alcohol ester 12 12kg are inserted in stirred vessel, make it to be uniformly mixed.Then the mixed solution of gained is divided into trisection, adds respectively appropriate brown, red, grey mill base, make the each 333.33kg of basic colored paint of brown, redness and grey.
Operation two, water 923kg, trisodium phosphate 6kg, organobentonite RD powder 45kg, cationic stabilized agent YT25kg are inserted in stirred vessel, and add 1kgEDTA tetra-sodium, then stir, make high stability protection sol solution 1000kg.
Operation three, brown, red, the basic colored paint of grey that operation one is made are respectively got 225kg; respectively add respectively the high stability that operation two makes to protect in sol solution 275kg; mixed solution is crossed to 100 order mesh screens; make basic colored paint form little colored paint particle; be dispersed in high stability protection sol solution; also immiscible each other between these little colored paint particles, form colour particles component, make the brown particles of 500kg, the red particles of 500kg, the grey colored particle of 500kg.
Operation four, brown, red, the grey colored particle component that operation three is made are respectively got 200kg, with silicon the third elastomeric propylene yogurt liquid 200kg, alcohol ester 12 5kg, sterilant 2kg, propylene glycol 10kg, defoamer 1kg, organic amine PH conditioning agent 1kg, thickening material 5kg, water 176kg, mixing and stirring, makes finished product paint 1000kg.
Operation five, by fluorine carbon pure acrylic latex 600kg; Organic amine PH conditioning agent 1kg; Defoamer 1kg; Alcohol ester 12 5kg; Sterilant 2kg; Propylene glycol 10kg; Thickening material 5kg; Water 376kg mixing and stirring, makes fluorin modified crylic acid finishing varnish 1000kg.
Conventional exterior wall infiltration priming paint is evenly coated to metope, make it to be penetrated in wall cement light face, increase the surface strength of cement light face, the sticking power of road paint to cement matrix after increasing; Then be evenly coated with the background colour of artificial granite coating with spray gun---the conventional exterior coating of light brown; Then demarcate the position of crack of stone with the line of ink marker according to the size of the artificial granite stone material of planning, and use jointing adhesive tape gluing; Then use spray gun that artificial granite finished product paint of the present invention is evenly sprayed on metope; Finished product paint be coated with dry after, according to jointing adhesive tape gluing initial, order is torn up and down; Finally use spray gun that fluorin modified crylic acid finishing varnish is evenly coated on finished product paint, complete the construction of reflection heat-insulating type texture artificial granite water-borne coatings.
After testing, the water tolerance of reflection heat-insulating type texture artificial granite water-borne coatings is tested by GB/T1733-1993 national standard, without abnormal; Alkali resistance is tested according to GB/T9265-2009 national standard, without abnormal; Resistance to scrubbing tested according to the test of GB/T9266-2009 national standard, exceedes 5000 times; Other the key technical indexes:
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any amendment of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (7)
1. the making method of reflection heat-insulating type texture artificial granite water-borne coatings, is characterized in that, comprises following operation:
Operation one, prepare basic colored paint;
Operation two, preparation high stability protection sol solution;
Operation three, granulation: the high stability protection sol solution that the basic colored paint that operation one is made makes with operation two mixes, by stirring or the granulation of screen cloth technique, make base paint particle surface form water-fast coating, and be present in high stability protection sol solution with the graininess not merging mutually each other, form colour particles;
Operation four, allotment finished product paint: by the versicolor colour particles component making and silicon the third elastomeric propylene yogurt liquid mixing preparation, make finished product paint after operation three granulations;
Operation five, allotment fluorin modified crylic acid finishing varnish.
2. the making method of reflection heat-insulating type texture artificial granite water-borne coatings according to claim 1, is characterized in that, in described operation one, the composition mass percent of basic colored paint is:
Water 52.4%;
Sterilant 0.2%;
Natvosol 0.8%;
Defoamer 0.1%;
Wetting dispersing agent 0.2%;
Propylene glycol 1.5%;
Hollow glass micropearl VS55008%;
Solid ceramic microballoon W-21010%;
Organobentonite RD powder 0.4%;
Organic amine PH conditioning agent 0.1%;
Pure acrylic latex 25%;
Defoamer 0.1%;
Alcohol ester ten two 1.2%;
Mill base is pressed the deep or light depth of required color and is added appropriate.
3. the making method of reflection heat-insulating type texture artificial granite water-borne coatings according to claim 1, is characterized in that, in described operation two, the composition mass percent of high stability protection sol solution is:
Water 92.3%;
Trisodium phosphate 0.6%;
Organobentonite RD powder 4.5%;
Cationic stabilized agent YT2.5%;
EDTA tetra-sodium 0.1%.
4. the making method of reflection heat-insulating type texture artificial granite water-borne coatings according to claim 1, is characterized in that, in described operation three, the mass percent of described basic colored paint and high stability protection sol solution is: basic colored paint 50 ~ 56.5%; High stability protection sol solution 43.5 ~ 50%.
5. the making method of reflection heat-insulating type texture artificial granite water-borne coatings according to claim 1, is characterized in that, in described operation four, the composition mass percent of described finished product paint is:
Colour particles component 60%;
Silicon the third elastomeric propylene yogurt liquid 10 ~ 20%;
Alcohol ester ten two 0.5%;
Sterilant 0.2%;
Propylene glycol 1%;
Defoamer 0.1%;
Organic amine PH conditioning agent 0.1%;
Thickening material 0.5%;
Water 17.6 ~ 27.6%.
6. the making method of reflection heat-insulating type texture artificial granite water-borne coatings according to claim 1, is characterized in that, the composition mass percent of described fluorin modified crylic acid finishing varnish is:
Fluorine carbon pure acrylic latex 60%;
Organic amine PH conditioning agent 0.1%;
Defoamer 0.1%;
Alcohol ester ten two 0.5%;
Sterilant 0.2%;
Propylene glycol 1%;
Thickening material 0.5%;
Water 37.6%.
7. the construction technology of the reflection heat-insulating type texture artificial granite water-borne coatings making according to the arbitrary making method described in claim 1 ~ 6, is characterized in that, comprises the following steps:
A. primary coat: conventional exterior wall infiltration priming paint is evenly coated in metope basic unit, it is penetrated in cement light face;
B. homochromy primary coat: after steps A completes, after described conventional exterior wall infiltration priming paint is dry, the conventional exterior coating of artificial granite background colour is evenly applied on conventional exterior wall infiltration priming paint with roller coating or spray gun;
C. jointing: demarcate the crack of stone position of design according to the pattern of planning with the line of ink marker, then cover described crack of stone position with jointing adhesive tape gluing;
D. in, be coated with: with suitable spray gun bore, blast, the finished product paint of described reflection heat-insulating type texture artificial granite water-borne coatings is sprayed to spray-coating surface;
E. jointing adhesive tape removes: complete after described middle painting step, according to jointing adhesive tape gluing initial, up and down order removed;
F. the coating of finishing paint: use spray gun evenly to coat on described finished product paint described fluorin modified crylic acid finishing varnish.
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| CN201310055905.4A CN104004424B (en) | 2013-02-21 | 2013-02-21 | The manufacture method of reflection heat-insulating type texture artificial granite water paint and construction technology |
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| CN201310055905.4A CN104004424B (en) | 2013-02-21 | 2013-02-21 | The manufacture method of reflection heat-insulating type texture artificial granite water paint and construction technology |
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| CN104004424B CN104004424B (en) | 2016-12-28 |
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| CN104151979A (en) * | 2014-08-28 | 2014-11-19 | 上海绿特丹保温工程有限公司 | W/W reflective thermal-insulation colorful paint |
| CN104194456A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Water-in-water colorful reflective insulating stone-like coating and preparation method thereof |
| CN104974614A (en) * | 2015-07-09 | 2015-10-14 | 浙江传化涂料有限公司 | Reflective insulation and self-cleaning external wall stone-imitation coating material |
| CN105969016A (en) * | 2016-05-19 | 2016-09-28 | 厦门富思特新材料科技有限公司 | Reflective insulation colorful coating and preparation method thereof |
| CN107189660A (en) * | 2017-06-22 | 2017-09-22 | 广州市维思涂料科技有限公司 | A kind of composite liquefied granite coating of reflective insulation and preparation method thereof |
| CN107236459A (en) * | 2017-06-05 | 2017-10-10 | 山东华德隆建材科技有限公司 | Colorful former stone stone-like coating |
| CN112480767A (en) * | 2020-12-03 | 2021-03-12 | 买乐 | Scrape coating rock slice paint and preparation method and construction process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104151979A (en) * | 2014-08-28 | 2014-11-19 | 上海绿特丹保温工程有限公司 | W/W reflective thermal-insulation colorful paint |
| CN104151979B (en) * | 2014-08-28 | 2016-11-02 | 上海绿特丹保温工程有限公司 | A kind of water-water reflective insulation multicolor finish |
| CN104194456A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Water-in-water colorful reflective insulating stone-like coating and preparation method thereof |
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| CN105969016A (en) * | 2016-05-19 | 2016-09-28 | 厦门富思特新材料科技有限公司 | Reflective insulation colorful coating and preparation method thereof |
| CN107236459A (en) * | 2017-06-05 | 2017-10-10 | 山东华德隆建材科技有限公司 | Colorful former stone stone-like coating |
| CN107189660A (en) * | 2017-06-22 | 2017-09-22 | 广州市维思涂料科技有限公司 | A kind of composite liquefied granite coating of reflective insulation and preparation method thereof |
| CN107189660B (en) * | 2017-06-22 | 2018-04-10 | 广州市维思涂料科技有限公司 | A kind of composite liquefied granite coating of reflective insulation and preparation method thereof |
| CN112480767A (en) * | 2020-12-03 | 2021-03-12 | 买乐 | Scrape coating rock slice paint and preparation method and construction process thereof |
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| CN104004424B (en) | 2016-12-28 |
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