WO2017028471A1 - Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof - Google Patents
Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof Download PDFInfo
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- WO2017028471A1 WO2017028471A1 PCT/CN2016/000455 CN2016000455W WO2017028471A1 WO 2017028471 A1 WO2017028471 A1 WO 2017028471A1 CN 2016000455 W CN2016000455 W CN 2016000455W WO 2017028471 A1 WO2017028471 A1 WO 2017028471A1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
Definitions
- the invention relates to a coating, in particular to a reflective heat-insulating stone-like color paint for building and a preparation method thereof.
- water-based imitation stone rock paint is a new type of environmentally-friendly architectural paint. It has both natural granite patterns and colors, as well as humanized and personalized patterns that transcend nature and return to nature.
- the decoration of the external wall can replace the rare stone with high price, and at the same time reduce the load-bearing capacity of the building, which has made a significant contribution to reducing engineering cost and beautiful environment.
- the water-based imitation stone color paint is suspended in an aqueous medium by a water-in-water process, and is sprayed to produce a plurality of colors for the exterior wall of the building. Single component coating. It is a water-based building stone rock color paint which is made of acrylic resin emulsion as a base material, combined with high-quality inorganic pigments and high-performance additives.
- brushing reflective thermal insulation coating is the easiest and most effective way to improve the thermal insulation of exterior walls and roofing, because it can improve the surface reflectance and emissivity of buildings.
- the composition of the solar radiation energy light the visible light reflectance and the near-infrared light reflectance are maximized, and the performance of the building reflective heat-insulating coating can be maximized.
- the higher the total reflectance of the outer surface coating film the more solar radiation heat reflected from the outer surface, and the less heat absorbed by the solar radiation. In other words, the less heat is conducted into the room, and the lower the air conditioning load in summer.
- reflective heat-insulating coatings have been successfully applied in the fields of construction, petrochemical, industrial, etc., and their energy-saving effects are remarkable, which has been widely recognized by the industry.
- the water-based imitation stone rock color paint and the reflective heat-insulating paint are scientifically combined to prepare a water-based building reflective heat-insulating stone rock color paint. It not only has the beautiful decorative effect of water-based imitation stone color paint, but also has the green energy-saving features of reflective heat-insulating paint, which satisfies the modern building decoration. The requirements for energy-saving integration are of great significance.
- the purpose of the invention is to select suitable low-cost and beautiful pigments, heat-insulating pigments and fillers to form a stone-like color paint with heat-reflecting and heat-insulating function, and to give the stone-like color paint better energy-saving.
- a reflective heat-insulating stone-like color paint for building is a colorless and transparent closed primer, and its composition and weight fraction:
- the emulsion described in the primer is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, such as BASF's Acronal JC 7043 emulsion.
- the water is distilled water or deionized water.
- the auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
- the film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
- a reflective heat-insulating imitation stone rock color coating for building, the intermediate paint is a reflective and heat-insulating water-based intermediate paint, and its component and weight content:
- the emulsion described in the intermediate coating is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, etc., and the emulsion may have elasticity or inelasticity, such as the AP 5085 emulsion of Zhaori Chemical.
- the coloring pigment is selected from one or more of titanium dioxide, iron oxide, ultramarine blue, organic pigment, etc., and the coloring pigment has a particle size controlled at 400-1500 nm, and at the same time, removes a pigment having strong solar absorption ability such as carbon black;
- the heat insulating pigment filler is selected from the group consisting of oxides having a reflective function, such as nano titanium dioxide, zirconium silicate, inorganic ceramic pigment, zirconia, talc, ceramic powder, aluminum silicate, potassium titanate ;
- the water is distilled water or deionized water.
- the auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
- the film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
- the utility model relates to a water-based reflective and heat-insulating imitation stone rock color paint for building, and the surface coating material is a water-in-water imitation stone rock color paint with reflection heat insulation, the component and the weight content thereof:
- Granulation base paint 50.0-60.0
- the emulsion described in the topcoat is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, and the like, and the emulsion may have elasticity or inelasticity, such as the SLX-1048-3 emulsion of Zhaori Chemical.
- the coloring pigment is selected from one or more of titanium dioxide, iron oxide, ultramarine blue, organic pigment, etc., and the coloring pigment has a particle diameter controlled at 400-1500 nm, and at the same time, removes a pigment having strong absorption ability for sunlight;
- the heat insulating pigment filler is selected from the group consisting of oxides having a reflective function, such as one or more of nano titanium dioxide, zirconium silicate, inorganic ceramic pigment, zirconia, talc, ceramic powder, aluminum silicate, and potassium titanate. ;
- the water is distilled water or deionized water.
- the auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
- the film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
- the utility model relates to a water-based reflective heat-insulating imitation stone rock color paint for building, and the cover varnish is a colorless transparent anti-staining excellent finish varnish, the composition and the weight content thereof:
- the emulsion described in the overcoat varnish is selected from one or more of a pure acrylic emulsion, a silicone-acrylic emulsion or a two-component polyurethane, such as the TD-661 emulsion of Sunrise.
- the water is distilled water or deionized water.
- the auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
- the film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
- a method for preparing a water-based reflective heat-insulating rock-rock color coating system for a building characterized in that the method comprises the following steps:
- the present invention has the following advantages:
- the water-based building reflection heat insulation imitation stone rock color paint has excellent reflection and heat insulation effect, energy saving and decoration integration.
- the water-based building reflective heat-insulating imitation stone rock color paint has long-term reflection and heat insulation performance.
- a water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
- a water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
- a water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
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Abstract
A water-based reflective heat-insulating faux stone texture coating system for construction comprises a base coating, an intermediate coating, a surface coating and a masking varnish. The surface coating comprises stone texture particles obtained by mixing water, a paint, a heat insulating filling, a latex paint, an additive, and a protective colloid, and granulating a mixture thereof.
Description
本发明涉及一种涂料,尤其是涉及一种建筑用反射隔热仿石岩彩涂料及其制备方法。The invention relates to a coating, in particular to a reflective heat-insulating stone-like color paint for building and a preparation method thereof.
现代社会,人们对建筑涂装的要求不仅仅注重外表美观,而是越来越重视建筑的绿色环保与低碳节能,即所谓的绿色建筑。当前建筑能耗占全社会能耗的30%,比重巨大,节能减排已经成为建筑行业的重要任务之一。因此,推进建筑节能装饰一体化具有重要社会经济意义。In modern society, people's requirements for architectural painting not only pay attention to the appearance of beauty, but also pay more and more attention to the green and low-carbon energy conservation of buildings, so-called green buildings. At present, building energy consumption accounts for 30% of the total energy consumption of the whole society, and the proportion is huge. Energy conservation and emission reduction has become one of the important tasks of the construction industry. Therefore, promoting the integration of building energy-saving decoration has important social and economic significance.
装饰性方面,水性仿石岩彩涂料是一种新型的环保建筑涂料,它既具有天然花岗石的花纹和色彩,还具有超越自然和回归自然的人性化、个性化图案,用于建筑物外墙的装饰,可以代替高昂价格的稀有石材,同时也降低的建筑物的承重,为降低工程成本和美观环保做出了重大的贡献。从制备工艺原理上讲,水性仿石岩彩涂料是通过水包水工艺将两种或两种以上的水性色粒悬浮在水性介质中,一次喷涂产生多种色彩的用于建筑物外墙的单组份涂料。它是采用丙烯酸类树脂乳液作为基料,结合优质无机颜料和高性能助剂,经特殊工艺加工而成的水性建筑仿石岩彩涂料。In terms of decoration, water-based imitation stone rock paint is a new type of environmentally-friendly architectural paint. It has both natural granite patterns and colors, as well as humanized and personalized patterns that transcend nature and return to nature. The decoration of the external wall can replace the rare stone with high price, and at the same time reduce the load-bearing capacity of the building, which has made a significant contribution to reducing engineering cost and beautiful environment. In principle, the water-based imitation stone color paint is suspended in an aqueous medium by a water-in-water process, and is sprayed to produce a plurality of colors for the exterior wall of the building. Single component coating. It is a water-based building stone rock color paint which is made of acrylic resin emulsion as a base material, combined with high-quality inorganic pigments and high-performance additives.
节能性方面,涂刷反射隔热涂料是提高外墙和屋面隔热性能最简便、有效的方式,因为它可以提高建筑物表层反射比和发射率。根据太阳光辐射能量光线的组成情况,将可见光反射比和近红外光反射比最大化,即可最大限度的提高建筑反射隔热涂料的性能。外表面涂膜的全反射率越高,外表面反射的太阳辐射热量就越多,而吸收的太阳辐射热量就越少。也就是说,向室内传导的热量就越少,夏天空调负荷就越低。目前,反射隔热涂料已成功地应用于建筑、石化、工业等领域,其节能效果显著,得到了业界的广泛认可。In terms of energy efficiency, brushing reflective thermal insulation coating is the easiest and most effective way to improve the thermal insulation of exterior walls and roofing, because it can improve the surface reflectance and emissivity of buildings. According to the composition of the solar radiation energy light, the visible light reflectance and the near-infrared light reflectance are maximized, and the performance of the building reflective heat-insulating coating can be maximized. The higher the total reflectance of the outer surface coating film, the more solar radiation heat reflected from the outer surface, and the less heat absorbed by the solar radiation. In other words, the less heat is conducted into the room, and the lower the air conditioning load in summer. At present, reflective heat-insulating coatings have been successfully applied in the fields of construction, petrochemical, industrial, etc., and their energy-saving effects are remarkable, which has been widely recognized by the industry.
因此,将水性仿石岩彩涂料与反射隔热涂料科学配合在一起,制备出水性建筑反射隔热仿石岩彩涂料。其不仅具备水性仿石岩彩涂料的美观装饰性,而且具备了反射隔热涂料的绿色节能特点,满足了现代建筑对装饰
节能一体化要求,意义重大。Therefore, the water-based imitation stone rock color paint and the reflective heat-insulating paint are scientifically combined to prepare a water-based building reflective heat-insulating stone rock color paint. It not only has the beautiful decorative effect of water-based imitation stone color paint, but also has the green energy-saving features of reflective heat-insulating paint, which satisfies the modern building decoration.
The requirements for energy-saving integration are of great significance.
发明内容Summary of the invention
本发明的目的就是选择合适的价廉物美的颜料和隔热颜料、填料搭配使用来制成具有热反射隔热功能的仿石岩彩涂料,赋予仿石岩彩涂料更好的节能性。The purpose of the invention is to select suitable low-cost and beautiful pigments, heat-insulating pigments and fillers to form a stone-like color paint with heat-reflecting and heat-insulating function, and to give the stone-like color paint better energy-saving.
本发明的目的可以通过以下技术方案来实现:一种建筑用反射隔热仿石岩彩涂料,底涂料是一种无色透明的封闭底漆,其组份和重量份含量:The object of the present invention can be achieved by the following technical solutions: a reflective heat-insulating stone-like color paint for building, the base paint is a colorless and transparent closed primer, and its composition and weight fraction:
底漆中所述的乳液选自苯丙乳液、纯丙乳液一种或几种,如BASF的Acronal JC 7043乳液。The emulsion described in the primer is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, such as BASF's Acronal JC 7043 emulsion.
所述的水为蒸馏水或去离子水。The water is distilled water or deionized water.
所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的几种;The auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
所述的成膜助剂为高沸点溶剂,如乙二醇丁醚、DBE、十二碳酯醇等。The film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
一种建筑用反射隔热仿石岩彩涂料,中间涂料是一种反射隔热的水性中间涂料,其组份和重量份含量:A reflective heat-insulating imitation stone rock color coating for building, the intermediate paint is a reflective and heat-insulating water-based intermediate paint, and its component and weight content:
中间涂料中所述的乳液选自苯丙乳液、纯丙乳液、硅丙乳液等的一种或几种,乳液可以具有弹性或非弹性,如昭日化工的AP 5085乳液。The emulsion described in the intermediate coating is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, etc., and the emulsion may have elasticity or inelasticity, such as the AP 5085 emulsion of Zhaori Chemical.
所述着色颜料选钛白粉、氧化铁、群青、有机颜料等的一种或几种,该着色颜料粒径控制在400-1500nm,同时摒除炭黑等对太阳光吸收能力强的颜料;The coloring pigment is selected from one or more of titanium dioxide, iron oxide, ultramarine blue, organic pigment, etc., and the coloring pigment has a particle size controlled at 400-1500 nm, and at the same time, removes a pigment having strong solar absorption ability such as carbon black;
所述隔热颜填料选自具有反射功能的氧化物,如纳米二氧化钛、硅酸锆,无机陶瓷颜料、氧化锆、滑石粉、陶瓷粉、硅酸铝、钛酸钾中的一种或几种;The heat insulating pigment filler is selected from the group consisting of oxides having a reflective function, such as nano titanium dioxide, zirconium silicate, inorganic ceramic pigment, zirconia, talc, ceramic powder, aluminum silicate, potassium titanate ;
所述的水为蒸馏水或去离子水。The water is distilled water or deionized water.
所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的几种;The auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
所述的成膜助剂为高沸点溶剂,如乙二醇丁醚、DBE、十二碳酯醇等。The film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
一种建筑用水性反射隔热仿石岩彩涂料,面涂料是一种反射隔热的水包水仿石岩彩涂料,其组份和重量份含量:The utility model relates to a water-based reflective and heat-insulating imitation stone rock color paint for building, and the surface coating material is a water-in-water imitation stone rock color paint with reflection heat insulation, the component and the weight content thereof:
1:保护胶溶液:1: protective glue solution:
水: 85.0-93.0Water: 85.0-93.0
保护胶: 7.0-15.0Protective glue: 7.0-15.0
2:造粒基础漆:2: Granulation base paint:
3:岩彩粒子:3: Rock particles:
造粒基础漆:50.0-60.0Granulation base paint: 50.0-60.0
保护胶溶液:40.0-50.0Protective glue solution: 40.0-50.0
4:面涂料成品:4: Finished surface coating:
面涂料中所述的乳液选自苯丙乳液、纯丙乳液、硅丙乳液等的一种或几种,乳液可以具有弹性或非弹性,如昭日化工的SLX-1048-3乳液。The emulsion described in the topcoat is selected from one or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, and the like, and the emulsion may have elasticity or inelasticity, such as the SLX-1048-3 emulsion of Zhaori Chemical.
所述着色颜料选钛白粉、氧化铁、群青、有机颜料等的一种或几种,该着色颜料粒径控制在400-1500nm,同时摒除对太阳光吸收能力强的颜料;The coloring pigment is selected from one or more of titanium dioxide, iron oxide, ultramarine blue, organic pigment, etc., and the coloring pigment has a particle diameter controlled at 400-1500 nm, and at the same time, removes a pigment having strong absorption ability for sunlight;
所述隔热颜填料选自具有反射功能的氧化物,如纳米二氧化钛、硅酸锆、无机陶瓷颜料、氧化锆、滑石粉、陶瓷粉、硅酸铝、钛酸钾中的一种或几种;The heat insulating pigment filler is selected from the group consisting of oxides having a reflective function, such as one or more of nano titanium dioxide, zirconium silicate, inorganic ceramic pigment, zirconia, talc, ceramic powder, aluminum silicate, and potassium titanate. ;
所述的水为蒸馏水或去离子水。The water is distilled water or deionized water.
所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的几种;The auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
所述的成膜助剂为高沸点溶剂,如乙二醇丁醚、DBE、十二碳酯醇等。
The film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
一种建筑用水性反射隔热仿石岩彩涂料,罩面清漆是一种无色透明的抗沾污优异的罩面清漆,其组份和重量份含量:The utility model relates to a water-based reflective heat-insulating imitation stone rock color paint for building, and the cover varnish is a colorless transparent anti-staining excellent finish varnish, the composition and the weight content thereof:
罩面清漆中所述的乳液选自纯丙乳液、硅丙乳液或双组份聚氨酯一种或几种,如日出的TD-661乳液。The emulsion described in the overcoat varnish is selected from one or more of a pure acrylic emulsion, a silicone-acrylic emulsion or a two-component polyurethane, such as the TD-661 emulsion of Sunrise.
所述的水为蒸馏水或去离子水。The water is distilled water or deionized water.
所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的几种;The auxiliary agent is a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;
所述的成膜助剂为高沸点溶剂,如乙二醇丁醚、DBE、十二碳酯醇等。The film forming aid is a high boiling point solvent such as ethylene glycol butyl ether, DBE, dodecyl alcohol or the like.
一种建筑用水性反射隔热仿石岩彩涂料系统的制备方法,其特征在于,该方法包括以下步骤:A method for preparing a water-based reflective heat-insulating rock-rock color coating system for a building, characterized in that the method comprises the following steps:
1)底涂料的制备1) Preparation of primer
(a)先将乳液投入搅拌釜后,加入蒸馏水,搅拌均匀:(a) After putting the emulsion into the stirred tank, add distilled water and mix well:
(b)按比例加入助剂,并搅拌均匀;(b) adding the auxiliary agent in proportion and stirring evenly;
(c)按比例加入成膜助剂,搅拌0.5-1小时,直至分散均匀,得到产品;(c) adding a film-forming auxiliary agent in proportion and stirring for 0.5-1 hour until the dispersion is uniform to obtain a product;
2)中间涂料的制备2) Preparation of intermediate coating
(a)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;(a) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred;
(b)按比例加入颜料和反射隔热填料,并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米;;(b) proportionally adding the pigment and the reflective heat insulating filler, and stirring uniformly, adding the above slurry to a sand mill for grinding to a fineness of 20-25 μm;
(c)按比例加入乳液,搅拌0.5-1小时,直至分散均匀:(c) Add the emulsion in proportion and stir for 0.5-1 hours until the dispersion is uniform:
(d)按比例加入成膜助剂,搅拌0.5-1小时,搅拌均匀:
(d) Add the film-forming aid in proportion, stir for 0.5-1 hour, and mix well:
(e)调整粘度,搅拌均匀,即得到产品。(e) Adjust the viscosity and stir evenly to obtain the product.
3)面涂料的制备3) Preparation of top coat
(a)先将蒸馏水投入搅拌釜后,加入保护胶粉体,搅拌溶解均匀,即得到保护胶溶液;(a) After the distilled water is first introduced into the stirred tank, the protective rubber powder is added, and the mixture is stirred and dissolved to obtain a protective gum solution;
(b)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;按比例加入颜料和反射隔热填料,并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米;按比例加入乳液,搅拌0.5-1小时,直至分散均匀;按比例加入保护胶溶液,搅拌0.5-1小时;按比例加入成膜助剂,搅拌0.5-1小时,调整粘度,搅拌均匀,即得到造粒基础漆。(b) After the distilled water is put into the stirred tank, the additives are added in sequence, and the mixture is evenly mixed; the pigment and the reflective heat insulating filler are added in proportion, and the mixture is uniformly stirred, and the slurry is added to the sand mill for grinding to fineness. Up to 20-25 microns; add the emulsion in proportion, stir for 0.5-1 hours until the dispersion is uniform; add the protective rubber solution in proportion, stir for 0.5-1 hour; add the film forming aid in proportion, stir for 0.5-1 hour, adjust the viscosity The mixture is evenly stirred to obtain a granulated base paint.
(c)先将保护胶溶液投入搅拌釜后,按比例加入各色上述基础漆,稳定1-2h,造粒,即得到岩彩粒子。(c) After the protective gum solution is first put into the stirred tank, the above-mentioned base paints are added in proportion, stabilized for 1-2 hours, and granulated to obtain rock colored particles.
(d)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;按比例加入乳液,搅拌0.5-1小时,直至分散均匀;按比例加入成膜助剂,搅拌0.5-1小时,搅拌均匀;按比例加入仿石岩彩粒子,搅拌0.5-1小时,搅拌均匀,即得到面涂料;(d) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred; the emulsion is added in proportion, stirred for 0.5-1 hour until the dispersion is uniform; the film-forming auxiliary agent is added in proportion, and stirred for 0.5-1 hour. Stir well; add the rock particles according to the proportion, stir for 0.5-1 hour, stir evenly to obtain the top coating;
4)罩面清漆的制备4) Preparation of overcoat varnish
(a)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;(a) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred;
(b)按比例加入乳液,搅拌0.5-1小时,直至分散均匀;(b) adding the emulsion in proportion and stirring for 0.5-1 hour until the dispersion is uniform;
(c)按比例加入成膜助剂,搅拌0.5-1小时.搅拌均匀,即得到产品。(c) Adding a film-forming auxiliary agent in proportion, stirring for 0.5-1 hour. Stirring uniformly, the product is obtained.
与现有技术相比,本发明具有以下优点:Compared with the prior art, the present invention has the following advantages:
(1)本水性建筑反射隔热仿石岩彩涂料具有优异的反射隔热效果,节能与装饰一体化。(1) The water-based building reflection heat insulation imitation stone rock color paint has excellent reflection and heat insulation effect, energy saving and decoration integration.
(2)更加优异的耐候性、耐水性和耐沾污性。(2) More excellent weather resistance, water resistance and stain resistance.
(3)适用范围更广泛。(3) The scope of application is wider.
(4)本水性建筑反射隔热仿石岩彩涂料具有长期反射隔热性能。(4) The water-based building reflective heat-insulating imitation stone rock color paint has long-term reflection and heat insulation performance.
下面结合具体实施例,对本发明作进一步描述,这些描述只是为进一
步说明本发明的特点和优点,而不是对本发明权利要求的限制。The present invention will be further described below in conjunction with specific embodiments, which are merely for further
The features and advantages of the invention are set forth in the description and not in the claims.
实施例1Example 1
一种建筑用水性反射隔热仿石岩彩涂料系统及其制备方法,该涂料的组分配比与制备方法如下:A water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
(1)底涂料(1) primer
组份名称Component name | 重量份Parts by weight |
Acronal JC 7043苯丙乳液Acronal JC 7043 styrene-acrylic emulsion | 40.040.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.20.2 |
NXZ消泡剂NXZ defoamer | 0.10.1 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.10.1 |
丙二醇防冻剂Propylene glycol antifreeze | 0.20.2 |
LXE杀菌剂LXE fungicide | 0.10.1 |
(2)中涂料(2) Medium coating
组份名称Component name | 重量份Parts by weight |
AP 5085弹性乳液AP 5085 Elastic Emulsion | 35.035.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.50.5 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 1.01.0 |
PH调节剂PH regulator | 0.10.1 |
防冻剂antifreeze | 0.20.2 |
杀菌剂Fungicide | 0.10.1 |
5040分散剂5040 dispersant | 2.02.0 |
钛白粉Titanium dioxide | 10.010.0 |
陶瓷微粉Ceramic powder | 10.010.0 |
空心玻璃微珠Hollow glass beads | 12.012.0 |
(3)面涂料(3) Topcoat
(4)罩面清漆(4) Cover varnish
组份名称Component name | 重量份Parts by weight |
TD-661硅丙乳液TD-661 Silicone Acrylic Emulsion | 55.055.0 |
蒸馏水Distilled water | 40.040.0 |
聚氨酯增稠剂Polyurethane thickener | 0.40.4 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.20.2 |
丙二醇防冻剂Propylene glycol antifreeze | 1.01.0 |
LXE杀菌剂LXE fungicide | 0.20.2 |
该涂料制备过程;The coating preparation process;
(1)底涂料的制备:(1) Preparation of primer:
先将40.0份苯丙乳液投入搅拌釜后,加入10.0份蒸馏水,搅拌均匀,加入0.1份NXZ消泡剂、0.2份聚氨酯增稠剂、3.0份十二碳酯醇、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀后,即得到底涂料。After putting 40.0 parts of styrene-acrylic emulsion into the stirred tank, add 10.0 parts of distilled water, stir evenly, add 0.1 part of NXZ defoamer, 0.2 part of polyurethane thickener, 3.0 parts of dodecyl alcohol, 0.1 part of LXE fungicide, 0.1 A portion of the pH adjuster and 0.2 parts of the propylene glycol antifreeze are stirred to obtain a primer.
(2)中涂料的制备:(2) Preparation of medium coating:
先将10.0份蒸馏水投入搅拌釜后,加入2.0份5040分散剂、加入0.2
份NXZ消泡剂、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀;依次加入10.0份钛白粉颜料和10.0份陶瓷微粉,在2000-3000RPM的转速下搅拌3-4小时,直至分散均匀,细度≤30μm;在上述浆料中加入35.0份AP5085丙烯酸酯弹性乳液,分散均匀后加入1.0份十二碳酯醇,并依次加入12.0份玻璃空心微珠,用0.5份聚氨酯增稠剂调整粘度;检测合格后,定量包装。After putting 10.0 parts of distilled water into the stirred tank, add 2.0 parts of 5040 dispersant and add 0.2.
NXZ defoamer, 0.1 part LXE bactericide, 0.1 part PH adjuster and 0.2 part propylene glycol antifreeze, stir evenly; add 10.0 parts of titanium dioxide pigment and 10.0 parts of ceramic powder in sequence, stir at 2000-3000RPM 4 hours, until the dispersion is uniform, fineness ≤ 30 μm; 35.0 parts of AP5085 acrylate elastic emulsion is added to the above slurry, uniformly dispersed, then 1.0 part of dodecyl alcohol is added, and 12.0 parts of glass hollow microbeads are sequentially added, and 0.5 is used. The polyurethane thickener adjusts the viscosity; after passing the test, the package is quantitatively prepared.
(3)面涂料的制备:(3) Preparation of top coat:
(a)先将90.0份蒸馏水投入搅拌釜后,加入7.0份保护胶粉体,搅拌溶解均匀,即得到保护胶溶液;(a) After putting 90.0 parts of distilled water into the stirred tank, adding 7.0 parts of the protective rubber powder, stirring and dissolving uniformly, thereby obtaining a protective gum solution;
(b)先将40.0蒸馏水投入搅拌釜后,加入0.3份NXZ消泡剂、0.2份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀;按比例加入5份钛白粉并搅拌均匀,将上述桨料加入砂磨机,进行研磨,至细度达到20-25微米;按比例加入40.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;按比例加入15.0份保护胶溶液,揽拌0.5-1小时;按比例加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;按比例加入反射隔热颜填料,搅拌0.5-1小时,调整粘度,搅拌均匀,即得到造粒基础漆。(b) After putting 40.0 distilled water into the stirred tank, add 0.3 parts of NXZ defoamer, 0.2 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze, and stir evenly; Add 5 parts of titanium dioxide and stir evenly. Add the above paddle to the sander and grind it to a fineness of 20-25 microns. Add 40.0 parts of SLX-1048-3 emulsion in proportion and stir for 0.5-1 hour until dispersed. Uniformly; 15.0 parts of protective glue solution is added in proportion, mixed for 0.5-1 hour; 3.0 parts of film-forming auxiliary agent is added in proportion, stirred for 0.5-1 hour, and stirred uniformly; proportionally added reflective heat-insulating pigment filler, stirring 0.5-1 In the hour, the viscosity is adjusted and the mixture is evenly stirred to obtain a granulated base paint.
(c)先将40.0份保护胶溶液投入搅拌釜后,按比例加入50.0份各色上述基础漆,稳定1-2h,造粒,即得到岩彩粒子。(c) After 40.0 parts of the protective gum solution is first put into the stirred tank, 50.0 parts of the above-mentioned base paints are added in proportion, stabilized for 1-2 hours, and granulated to obtain rock color particles.
(d)先将20.0份蒸馏水投入搅拌釜后,依次加入加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂和1.5份丙二醇防冻剂,搅拌均匀;按比例加入25.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;加入2.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;加入50.0份岩彩粒子,搅拌0.5-1小时,搅拌均匀,即得到面涂料。(d) After 20.0 parts of distilled water is first put into the stirred tank, 0.2 parts of NXZ defoamer, 0.4 parts of polyurethane thickener, 0.2 parts of LXE fungicide and 1.5 parts of propylene glycol antifreeze are added in sequence, and stirred uniformly; 25.0 parts are added in proportion. SLX-1048-3 emulsion, stirring for 0.5-1 hours until uniform dispersion; adding 2.0 parts of film-forming auxiliary, stirring for 0.5-1 hour, stirring evenly; adding 50.0 parts of rock color particles, stirring for 0.5-1 hours, stirring evenly, That is, a top coat is obtained.
(3)罩面清漆的制备(3) Preparation of overcoat varnish
先将40.0份蒸馏水投入搅拌釜后,加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀。加入55.0份TD-661硅丙乳液,搅拌0.5-1小时,直至分散均匀;加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀搅拌均匀后,即得到
罩面清漆。After 40.0 parts of distilled water was first put into the stirred tank, 0.2 part of NXZ defoaming agent, 0.4 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze were added and stirred uniformly. Add 55.0 parts of TD-661 silicone-acrylic emulsion, stir for 0.5-1 hour until uniform dispersion; add 3.0 parts of film-forming auxiliary, stir for 0.5-1 hour, stir evenly and evenly, then get
Cover varnish.
实施例2Example 2
一种建筑用水性反射隔热仿石岩彩涂料系统及其制备方法,该涂料的组分配比与制备方法如下:A water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
(1)底涂料(1) primer
组份名称Component name | 重量份Parts by weight |
Acronal JC 7043苯丙乳液Acronal JC 7043 styrene-acrylic emulsion | 30.030.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.20.2 |
NXZ消泡剂NXZ defoamer | 0.10.1 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.10.1 |
丙二醇防冻剂Propylene glycol antifreeze | 0.20.2 |
LXE杀菌剂LXE fungicide | 0.10.1 |
(2)中涂料(2) Medium coating
组份名称Component name | 重量份Parts by weight |
AP 5085弹性乳液AP 5085 Elastic Emulsion | 30.030.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.50.5 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 1.01.0 |
PH调节剂PH regulator | 0.10.1 |
防冻剂antifreeze | 0.20.2 |
杀菌剂Fungicide | 0.10.1 |
5040分散剂5040 dispersant | 2.02.0 |
钛白粉Titanium dioxide | 10.010.0 |
陶瓷微粉Ceramic powder | 10.010.0 |
空心玻璃微珠Hollow glass beads | 12.012.0 |
(3)面涂料(3) Topcoat
(4)罩面清漆(4) Cover varnish
组份名称Component name | 重量份Parts by weight |
TD-661硅丙乳液TD-661 Silicone Acrylic Emulsion | 50.050.0 |
蒸馏水Distilled water | 40.040.0 |
聚氨酯增稠剂Polyurethane thickener | 0.40.4 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.20.2 |
丙二醇防冻剂Propylene glycol antifreeze | 1.01.0 |
LXE杀菌剂LXE fungicide | 0.20.2 |
该涂料制备过程:The coating preparation process:
(1)底涂料的制备:(1) Preparation of primer:
先将30.0份苯丙乳液投入搅拌釜后,加入10.0份蒸馏水,搅拌均匀,加入0.1份NXZ消泡剂、0.2份聚氨酯增稠剂、3.0份十二碳酯醇、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀后,即得到底涂料。After putting 30.0 parts of styrene-acrylic emulsion into the stirred tank, add 10.0 parts of distilled water, stir evenly, add 0.1 part of NXZ defoamer, 0.2 part of polyurethane thickener, 3.0 parts of dodecyl alcohol, 0.1 part of LXE fungicide, 0.1 A portion of the pH adjuster and 0.2 parts of the propylene glycol antifreeze are stirred to obtain a primer.
(2)中涂料的制备:
(2) Preparation of medium coating:
先将10.0份蒸馏水投入搅拌釜后,加入2.0份5040分散剂、加入0.2份NXZ消泡剂、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀;依次加入10.0份钛白粉颜料和12.0份陶瓷微粉,在2000-3000RPM的转速下搅拌3-4小时,直至分散均匀,细度≤30μm;在上述浆料中加入30.0份AP5085丙烯酸酯弹性乳液,分散均匀后加入1.0份十二碳酯醇,并依次加入15.0份玻璃空心微珠,用0.5份聚氨酯增稠剂调整粘度;检测合格后,定量包装。After putting 10.0 parts of distilled water into the stirred tank, add 2.0 parts of 5040 dispersant, add 0.2 parts of NXZ defoamer, 0.1 part of LXE bactericide, 0.1 part of pH adjuster and 0.2 part of propylene glycol antifreeze, stir evenly; add 10.0 parts in order Titanium dioxide pigment and 12.0 parts of ceramic micropowder, stirred at 2000-3000RPM for 3-4 hours until uniform dispersion, fineness ≤ 30μm; add 30.0 parts of AP5085 acrylate elastic emulsion to the above slurry, evenly disperse and add 1.0 The dodecyl alcohol was added, and 15.0 parts of glass hollow microbeads were sequentially added, and the viscosity was adjusted with 0.5 part of a polyurethane thickener; after passing the test, the package was quantitatively prepared.
(3)面涂料的制备:(3) Preparation of top coat:
(a)先将100.0份蒸馏水投入搅拌釜后,加入7.0份保护胶粉体,搅拌溶解均匀,即得到保护胶溶液;(a) After 100.0 parts of distilled water is first put into the stirred tank, 7.0 parts of the protective rubber powder is added, and the mixture is stirred and dissolved to obtain a protective gum solution;
(b)先将40.0蒸馏水投入搅拌釜后,加入0.3份NXZ消泡剂、0.2份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀:按比例加入5份钛白粉并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米:按比例加入35.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;按比例加入15.0份保护胶溶液,搅拌0.5-1小时:按比例加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;按比例加入反射隔热颜填料,搅拌0.5-1小时,调整粘度,搅拌均匀,即得到造粒基础漆。(b) After putting 40.0 distilled water into the stirred tank, add 0.3 parts of NXZ defoamer, 0.2 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze. Stir well: proportional Add 5 parts of titanium dioxide and stir evenly. Add the above slurry to the sander and grind it to a fineness of 20-25 microns: add 35.0 parts of SLX-1048-3 emulsion in proportion and stir for 0.5-1 hour until dispersed. Uniform; proportionally add 15.0 parts of protective rubber solution, stir for 0.5-1 hours: add 3.0 parts of film-forming auxiliary agent in proportion, stir for 0.5-1 hour, stir evenly; add reflective heat-insulating pigment filler in proportion, stir for 0.5-1 hour The viscosity is adjusted and the mixture is evenly stirred to obtain a granulated base paint.
(c)先将40.0份保护胶溶液投入搅拌釜后,按比例加入50.0份各色上述基础漆,稳定1-2h,造粒,即得到岩彩粒子。(c) After 40.0 parts of the protective gum solution is first put into the stirred tank, 50.0 parts of the above-mentioned base paints are added in proportion, stabilized for 1-2 hours, and granulated to obtain rock color particles.
(d)先将20.0份蒸馏水投入搅拌釜后,依次加入加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂和1.5份丙二醇防冻剂,搅拌均匀,按比例加入25.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;加入2.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;加入50.0份岩彩粒子,搅拌0.5-1小时,搅拌均匀,即得到面涂料。(d) After putting 20.0 parts of distilled water into the stirred tank, add 0.2 parts of NXZ defoamer, 0.4 parts of polyurethane thickener, 0.2 parts of LXE fungicide and 1.5 parts of propylene glycol antifreeze, and mix well, and add 25.0 parts in proportion. SLX-1048-3 emulsion, stirring for 0.5-1 hours until uniform dispersion; adding 2.0 parts of film-forming auxiliary, stirring for 0.5-1 hour, stirring evenly; adding 50.0 parts of rock color particles, stirring for 0.5-1 hours, stirring evenly, That is, a top coat is obtained.
(3)罩面清漆的制备(3) Preparation of overcoat varnish
先将40.0份蒸馏水投入搅拌釜后,加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀。加入50.0份TD-661硅丙乳液,搅拌0.5-1小时,直至分散均
匀;加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀搅拌均匀后,即得到罩面清漆。After 40.0 parts of distilled water was first put into the stirred tank, 0.2 part of NXZ defoaming agent, 0.4 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze were added and stirred uniformly. Add 50.0 parts of TD-661 silicone-acrylic emulsion and stir for 0.5-1 hour until dispersed
Uniform; add 3.0 parts of film-forming auxiliary, stir for 0.5-1 hour, stir evenly and evenly to obtain the cover varnish.
实施例3Example 3
一种建筑用水性反射隔热仿石岩彩涂料系统及其制备方法,该涂料的组分配比与制备方法如下:A water-based reflective heat-insulating imitation stone rock color coating system for building and a preparation method thereof, the group distribution ratio and preparation method of the coating are as follows:
(1)底涂料(1) primer
组份名称Component name | 重量份Parts by weight |
Acronal JC 7043苯丙乳液Acronal JC 7043 styrene-acrylic emulsion | 45.045.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.20.2 |
NXZ消泡剂NXZ defoamer | 0.10.1 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.10.1 |
丙二醇防冻剂Propylene glycol antifreeze | 0.20.2 |
LXE杀菌剂LXE fungicide | 0.10.1 |
(2)中涂料(2) Medium coating
组份名称Component name | 重量份Parts by weight |
AP 5085弹性乳液AP 5085 Elastic Emulsion | 40.040.0 |
蒸馏水Distilled water | 10.010.0 |
聚氨酯增稠剂Polyurethane thickener | 0.50.5 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 1.01.0 |
PH调节剂PH regulator | 0.10.1 |
防冻剂antifreeze | 0.20.2 |
杀菌剂Fungicide | 0.10.1 |
5040分散剂5040 dispersant | 2.02.0 |
钛白粉Titanium dioxide | 10.010.0 |
陶瓷微粉Ceramic powder | 9.09.0 |
空心玻璃微珠Hollow glass beads | 15.015.0 |
(3)面涂料(3) Topcoat
(4)罩面清漆(4) Cover varnish
组份名称Component name | 重量份Parts by weight |
TD-661硅丙乳液TD-661 Silicone Acrylic Emulsion | 60.060.0 |
蒸馏水Distilled water | 40.040.0 |
聚氨酯增稠剂Polyurethane thickener | 0.40.4 |
NXZ消泡剂NXZ defoamer | 0.20.2 |
十二碳酯醇Dodecyl alcohol | 3.03.0 |
PH调节剂PH regulator | 0.20.2 |
丙二醇防冻剂Propylene glycol antifreeze | 1.01.0 |
LXE杀菌剂LXE fungicide | 0.20.2 |
该涂料制备过程:The coating preparation process:
(1)底涂料的制备:(1) Preparation of primer:
先将45.0份苯丙乳液投入搅拌釜后,加入10.0份蒸馏水,搅拌均匀,加入0.1份NXZ消泡剂、0.2份聚氨酯增稠剂、3.0份十二碳酯醇、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀后,即得到底涂料。After putting 45.0 parts of styrene-acrylic emulsion into the stirred tank, add 10.0 parts of distilled water, stir evenly, add 0.1 part of NXZ defoamer, 0.2 part of polyurethane thickener, 3.0 parts of dodecyl alcohol, 0.1 part of LXE fungicide, 0.1 A portion of the pH adjuster and 0.2 parts of the propylene glycol antifreeze are stirred to obtain a primer.
(2)中涂料的制备:
(2) Preparation of medium coating:
先将10.0份蒸馏水投入搅拌釜后,加入2.0份5040分散剂、加入0.2份NXZ消泡剂、0.1份LXE杀菌剂、0.1份PH调节剂和0.2份丙二醇防冻剂,搅拌均匀;依次加入10.0份钛白粉颜料和9.0份陶瓷微粉,在2000-3000RPM的转速下搅拌3-4小时,直至分散均匀,细度≤30μm;在上述浆料中加入40.0份AP5085丙烯酸酯弹性乳液,分散均匀后加入1.0份十二碳酯醇,并依次加入15.0份玻璃空心微珠,用0.5份聚氨酯增稠剂调整粘度;检测合格后,定量包装。After putting 10.0 parts of distilled water into the stirred tank, add 2.0 parts of 5040 dispersant, add 0.2 parts of NXZ defoamer, 0.1 part of LXE bactericide, 0.1 part of pH adjuster and 0.2 part of propylene glycol antifreeze, stir evenly; add 10.0 parts in order Titanium dioxide pigment and 9.0 parts of ceramic micropowder are stirred at 2000-3000RPM for 3-4 hours until uniform dispersion, fineness ≤30μm; 40.0 parts of AP5085 acrylate elastic emulsion is added to the above slurry, and evenly dispersed, 1.0 is added. The dodecyl alcohol was added, and 15.0 parts of glass hollow microbeads were sequentially added, and the viscosity was adjusted with 0.5 part of a polyurethane thickener; after passing the test, the package was quantitatively prepared.
(3)面涂料的制备:(3) Preparation of top coat:
(a)先将105.0份蒸馏水投入搅拌釜后,加入7.0份保护胶粉体,搅拌溶解均匀,即得到保护胶溶液;(a) After putting 105.0 parts of distilled water into the stirred tank, adding 7.0 parts of the protective rubber powder, stirring and dissolving uniformly, thereby obtaining a protective gum solution;
(b)先将40.0蒸馏水投入搅拌釜后,加入0.3份NXZ消泡剂、0.2份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀;按比例加入5份钛白粉并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米;按比例加入40.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;按比例加入15.0份保护胶溶液,搅拌0.5-1小时;按比例加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;按比例加入反射隔热颜填料,搅拌0.5-1小时,调整粘度,搅拌均匀,即得到造粒基础漆。(b) After putting 40.0 distilled water into the stirred tank, add 0.3 parts of NXZ defoamer, 0.2 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze, and stir evenly; Add 5 parts of titanium dioxide and stir evenly, add the above slurry to the sand mill, grind it to a fineness of 20-25 microns; add 40.0 parts of SLX-1048-3 emulsion in proportion, stir for 0.5-1 hour, until dispersed Uniformly; 15.0 parts of protective rubber solution is added in proportion, stirred for 0.5-1 hour; 3.0 parts of film-forming auxiliary agent is added in proportion, stirred for 0.5-1 hour, and stirred uniformly; reflective heat-insulating pigment filler is added in proportion, and stirred for 0.5-1 hour The viscosity is adjusted and the mixture is evenly stirred to obtain a granulated base paint.
(c)先将40.0份保护胶溶液投入搅拌釜后,按比例加入50.0份各色上述基础漆,稳定1-2h,造粒,即得到岩彩粒子。(c) After 40.0 parts of the protective gum solution is first put into the stirred tank, 50.0 parts of the above-mentioned base paints are added in proportion, stabilized for 1-2 hours, and granulated to obtain rock color particles.
(d)先将20.0份蒸馏水投入搅拌釜后,依次加入加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂和1.5份丙二醇防冻剂,搅拌均匀;按比例加入25.0份SLX-1048-3乳液,搅拌0.5-1小时,直至分散均匀;加入2.0份成膜助剂,搅拌0.5-1小时,搅拌均匀;加入50.0份岩彩粒子,搅拌0.5-1小时,搅拌均匀,即得到面涂料。(d) After 20.0 parts of distilled water is first put into the stirred tank, 0.2 parts of NXZ defoamer, 0.4 parts of polyurethane thickener, 0.2 parts of LXE fungicide and 1.5 parts of propylene glycol antifreeze are added in sequence, and stirred uniformly; 25.0 parts are added in proportion. SLX-1048-3 emulsion, stirring for 0.5-1 hours until uniform dispersion; adding 2.0 parts of film-forming auxiliary, stirring for 0.5-1 hour, stirring evenly; adding 50.0 parts of rock color particles, stirring for 0.5-1 hours, stirring evenly, That is, a top coat is obtained.
(3)罩面清漆的制备(3) Preparation of overcoat varnish
先将40.0份蒸馏水投入搅拌釜后,加入0.2份NXZ消泡剂、0.4份聚氨酯增稠剂、0.2份LXE杀菌剂、0.2份PH调节剂和1.0份丙二醇防冻剂,搅拌均匀。加入60.0份TD-661硅丙乳液,搅拌0.5-1小时,直至分散均
匀;加入3.0份成膜助剂,搅拌0.5-1小时,搅拌均匀搅拌均匀后,即得到罩面清漆。After 40.0 parts of distilled water was first put into the stirred tank, 0.2 part of NXZ defoaming agent, 0.4 part of polyurethane thickener, 0.2 part of LXE bactericide, 0.2 part of pH adjuster and 1.0 part of propylene glycol antifreeze were added and stirred uniformly. Add 60.0 parts of TD-661 silicone-acrylic emulsion and stir for 0.5-1 hour until dispersed
Uniform; add 3.0 parts of film-forming auxiliary, stir for 0.5-1 hour, stir evenly and evenly to obtain the cover varnish.
以上实施例中的组合物所有组分均可以商业购买。All of the components of the compositions in the above examples are commercially available.
上述实施例只是用于对本发明的内容进行阐述,而不是限制,因此在与本发明的权利要求书相当的含义和范围内的任何改变,都应该认为是包括在权利要求书的范围内。
The above-described embodiments are only intended to be illustrative of the invention, and are not to be construed as limiting the scope of the invention.
Claims (5)
- 一种建筑用水性反射隔热仿石岩彩涂料系统,包括底涂料、中间涂料、面涂料和罩面清漆,其特征在于:A water-based reflective and heat-insulating imitation stone rock color coating system for building, comprising a base paint, an intermediate paint, a top coat and a cover varnish, characterized in that:底涂料是一种无色透明的封闭底漆,其组份和重量份含量是:The primer is a colorless and transparent sealing primer whose components and parts by weight are:中间涂料是一种反射隔热的水性中间涂料,其组份和重量份含量是:The intermediate coating is a reflective, thermally insulating aqueous intermediate coating whose composition and parts by weight are:面涂料是一种反射隔热的水包水仿石岩彩涂料,其组份和重量份含量是:The top coat is a water-in-water imitation stone rock paint with reflection insulation. The composition and weight fraction are:罩面清漆其组份和重量份含量是:The composition and weight of the finish varnish are:
- 一种如权利要求1所述的建筑用水性反射隔热仿石岩彩涂料系统,其特征在于:An architectural water-based reflective and thermal insulation rock stone color coating system according to claim 1, wherein:所述面涂料其组份和重量份含量是:The composition and component parts of the top coat are:造粒基础漆:50.0-60.0Granulation base paint: 50.0-60.0保护胶溶液:40.0-50.0;Protective glue solution: 40.0-50.0;造粒基础漆和保护胶溶液其组份和重量份含量是:The components and parts by weight of the granulation base paint and the protective gum solution are:保护胶溶液:Protective glue solution:水:85.0-93.0Water: 85.0-93.0保护胶:7.0-15.0Protective adhesive: 7.0-15.0造粒基础漆:Granulation base paint:
- 一种如权利要求1所述的建筑用水性反射隔热仿石岩彩涂料系统,其特征在于:An architectural water-based reflective and thermal insulation rock stone color coating system according to claim 1, wherein:底漆中所述的乳液选自苯丙乳液、纯丙乳液一种或两种以上的混合物;The emulsion described in the primer is selected from the group consisting of a styrene-acrylic emulsion, a pure acrylic emulsion, or a mixture of two or more;底漆中所述的水为蒸馏水或去离子水;The water described in the primer is distilled water or deionized water;底漆中所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的一种或两种以上的混合物;The auxiliary agent described in the primer is one or a mixture of two or more of a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;底漆中所述的成膜助剂为高沸点溶剂;The film forming aid described in the primer is a high boiling point solvent;中间涂料中所述的乳液选自苯丙乳液、纯丙乳液、硅丙乳液等的一种或两种以上的混合物;The emulsion described in the intermediate coating is selected from one or a mixture of two or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, and the like;中间涂料中所述着色颜料选钛白粉、氧化铁、群青、有机颜料等的一种或两种以上的混合物;该着色颜料粒径控制在400-1500nm;The coloring pigment in the intermediate coating is selected from titanium oxide, iron oxide, ultramarine blue, organic pigment, etc.; or a mixture of two or more; the color pigment particle size is controlled at 400-1500 nm;中间涂料中所述隔热颜填料选自具有反射功能的氧化物;The heat insulating pigment filler in the intermediate coating is selected from the group consisting of oxides having a reflective function;中间涂料中所述的水为蒸馏水或去离子水;The water in the intermediate coating is distilled water or deionized water;中间涂料中所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的一种或两种以上的混合物;The auxiliary agent described in the intermediate coating is one or a mixture of two or more of a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;中间涂料中所述的成膜助剂为高沸点溶剂;The film forming aid described in the intermediate coating is a high boiling point solvent;面涂料中所述的乳液选自苯丙乳液、纯丙乳液、硅丙乳液等的一种或两种以上的混合物;The emulsion described in the top coat is selected from one or a mixture of two or more of a styrene-acrylic emulsion, a pure acrylic emulsion, a silicone-acrylic emulsion, and the like;面涂料中所述着色颜料选钛白粉、氧化铁、群青、有机颜料等的一种或两 种以上的混合物;该着色颜料粒径控制在400-1500nm;The coloring pigment in the top coating is one or two selected from the group consisting of titanium dioxide, iron oxide, ultramarine blue, organic pigment, and the like. a mixture of the above; the color pigment has a particle size controlled at 400-1500 nm;面涂料中所述隔热颜填料选自具有反射功能的氧化物;The heat insulating pigment filler in the top coating is selected from the group consisting of oxides having a reflective function;面涂料中所述的水为蒸馏水或去离子水;The water described in the topcoat is distilled water or deionized water;面涂料中所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的一种或两种以上的混合物;The auxiliary agent described in the top coat is one or a mixture of two or more of a mineral oil antifoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;所述的成膜助剂为高沸点溶剂;The film forming aid is a high boiling point solvent;罩面清漆中所述的乳液选自纯丙乳液、硅丙乳液或双组份聚氨酯一种或两种以上的混合物;The emulsion described in the finish varnish is selected from the group consisting of pure acrylic emulsion, silicone acrylic emulsion or two-component polyurethane, or a mixture of two or more;罩面清漆中所述的水为蒸馏水或去离子水;The water described in the finish varnish is distilled water or deionized water;罩面清漆中所述的助剂为矿物油消泡剂、硅油类消泡剂、聚氨酯增稠剂或碱溶胀性增稠剂中的一种或两种以上的混合物;The auxiliary agent described in the overcoat varnish is one or a mixture of two or more of a mineral oil defoaming agent, a silicone oil defoaming agent, a polyurethane thickener or an alkali swellable thickener;所述的成膜助剂为高沸点溶剂。The film forming aid is a high boiling point solvent.
- 一种如权利要求3所述的建筑用水性反射隔热仿石岩彩涂料系统,其特征在于;An architectural water-based reflective and thermal insulation rock stone color coating system according to claim 3, characterized in that;所述的成膜助剂为乙二醇丁醚、DBE、十二碳酯醇中的一种或两种以上的混合物;The film forming aid is one or a mixture of two or more of ethylene glycol butyl ether, DBE, and dodecyl alcohol;所述隔热颜填料为纳米二氧化钛、硅酸锆、无机陶瓷颜料、氧化锆、滑石粉、陶瓷粉、硅酸铝、钛酸钾中的一种或两种以上的混合物。The heat insulating pigment filler is one or a mixture of two or more of nano titanium dioxide, zirconium silicate, inorganic ceramic pigment, zirconia, talc, ceramic powder, aluminum silicate, and potassium titanate.
- 一种建筑用水性反射隔热仿石岩彩涂料系统的制备方法,其特征在于,该方法包括以下步骤;A method for preparing a water-based reflective heat insulation rock stone color coating system for building, characterized in that the method comprises the following steps;步骤一、底涂料的制备Step one, preparation of primer(a)先将乳液投入搅拌釜后,加入蒸馏水,搅拌均匀;(a) After the emulsion is first put into the stirred tank, distilled water is added and stirred uniformly;(b)按比例加入助剂,并搅拌均匀;(b) adding the auxiliary agent in proportion and stirring evenly;(c)按比例加入成膜助剂,搅拌0.5-1小时,直至分散均匀,得到底涂料;(c) adding a film-forming auxiliary agent in proportion, stirring for 0.5-1 hour, until the dispersion is uniform, to obtain a primer;步骤二、中间涂料的制备Step 2, preparation of intermediate coating(a)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀; (a) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred;(b)按比例加入颜料和反射隔热填料,并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米;;(b) proportionally adding the pigment and the reflective heat insulating filler, and stirring uniformly, adding the above slurry to a sand mill for grinding to a fineness of 20-25 μm;(c)按比例加入乳液,搅拌0.5-1小时,直至分散均匀;(c) adding the emulsion in proportion and stirring for 0.5-1 hour until the dispersion is uniform;(d)按比例加入成膜助剂,搅拌0.5-1小时,搅拌均匀;(d) adding a film-forming auxiliary agent in proportion, stirring for 0.5-1 hour, and stirring uniformly;(e)调整粘度,搅拌均匀,即得到中间涂料。(e) Adjust the viscosity and stir evenly to obtain an intermediate coating.步骤三、面涂料的制备Step three, preparation of the surface coating(a)先将蒸馏水投入搅拌釜后,加入保护胶粉体,搅拌溶解均匀,即得到保护胶溶液;(a) After the distilled water is first introduced into the stirred tank, the protective rubber powder is added, and the mixture is stirred and dissolved to obtain a protective gum solution;(b)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;按比例加入颜料和反射隔热填料,并搅拌均匀,将上述浆料加入砂磨机,进行研磨,至细度达到20-25微米;按比例加入乳液,搅拌0.5-1小时,直至分散均匀;按比例加入保护胶溶液,搅拌0.5-1小时;按比例加入成膜助剂,搅拌0.5-1小时,调整粘度,搅拌均匀,即得到造粒基础漆;(b) After the distilled water is put into the stirred tank, the additives are added in sequence, and the mixture is evenly mixed; the pigment and the reflective heat insulating filler are added in proportion, and the mixture is uniformly stirred, and the slurry is added to the sand mill for grinding to fineness. Up to 20-25 microns; add the emulsion in proportion, stir for 0.5-1 hours until the dispersion is uniform; add the protective rubber solution in proportion, stir for 0.5-1 hour; add the film forming aid in proportion, stir for 0.5-1 hour, adjust the viscosity , stirring evenly, that is, obtaining a granulation base paint;(c)先将保护胶溶液投入搅拌釜后,按比例加入各色上述基础漆,稳定1-2h,造粒,即得到岩彩粒子。(c) After the protective gum solution is first put into the stirred tank, the above-mentioned base paints are added in proportion, stabilized for 1-2 hours, and granulated to obtain rock colored particles.(d)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;按比例加入乳液,搅拌0.5-1小时,直至分散均匀;按比例加入成膜助剂,搅拌0.5-1小时,搅拌均匀;按比例加入仿石岩彩粒子,搅拌0.5-1小时,搅拌均匀,即得到面涂料;(d) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred; the emulsion is added in proportion, stirred for 0.5-1 hour until the dispersion is uniform; the film-forming auxiliary agent is added in proportion, and stirred for 0.5-1 hour. Stir well; add the rock particles according to the proportion, stir for 0.5-1 hour, stir evenly to obtain the top coating;步骤四、罩面清漆的制备Step 4, preparation of the cover varnish(a)先将蒸馏水投入搅拌釜后,依次加入各类助剂,搅拌均匀;(a) After the distilled water is first put into the stirred tank, various additives are added in sequence, and the mixture is uniformly stirred;(b)按比例加入乳液,搅拌0.5-1小时,直至分散均匀;(b) adding the emulsion in proportion and stirring for 0.5-1 hour until the dispersion is uniform;(c)按比例加入成膜助剂,搅拌0.5-1小时,搅拌均匀,即得到罩面清漆。 (c) Adding a film-forming auxiliary agent in proportion, stirring for 0.5-1 hour, and stirring uniformly to obtain a finish varnish.
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