CN105694550B - The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology - Google Patents

The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology Download PDF

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CN105694550B
CN105694550B CN201610148726.9A CN201610148726A CN105694550B CN 105694550 B CN105694550 B CN 105694550B CN 201610148726 A CN201610148726 A CN 201610148726A CN 105694550 B CN105694550 B CN 105694550B
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CN105694550A (en
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陈威
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Sichuan hongdarui Coating Technology Co.,Ltd.
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陈威
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The invention discloses a kind of single-component water-based inorganic floor coatings formula and manufacturing technologies, using aqueous inorganic film forming curing agent silicate and a small amount of organic silican polymer emulsion as base-material, adds a variety of pigments and fillers, silica flour and auxiliary agent and be dispersed, grind, modulate.Coating bottom surface unification, one-component, with it is non-toxic and tasteless, without the harmful substances such as formaldehyde, benzene, heavy metal, fire protection flame retarding, adhesive force are strong, hardness is high, resistant to chemical etching, impact resistance, rub resistance, scrubbing resistance, anti-skidding, the convenient feature of long service life, construction is simple.Traditional floor coatings bi-component is changed, the complex technical manipulations such as diluent, curing agent are needed, overcomes inflammable, poisonous and harmful, the drawbacks such as pollution environment, the complicated technology that simplified primary coat, middle painting, face apply.Use scope is wide, maintenance is simple, cost performance is high.

Description

The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology
Technical field
The present invention relates to a kind of inorganic polymers, more particularly to a kind of single-component water-based inorganic floor coatings formula And manufacturing technology.
Background technique
Current floor coatings are to use the raw materials such as polyurethane resin, alcohol ester for host agent, add pigment, solvent, and auxiliary agent is consolidated Agent is by floor coatings such as floor decorative materials, such as epoxide terrace paint made of allotment.Floor coatings are for beautifying, protecting Dust-proof, wear-resisting, cleaning, moisture-proof effect are played in ground, so commercial ground, garage floor etc. is extensively by modern industry ground It uses and promotes.But floor coatings smell weight in the prior art, fire resistance property are poor, poor adhesive force, cracking easy to aging, flake, A kind of very big ketone gas of toxicity can be discharged later by especially meeting high temperature, and a small amount of sucking can make one to be poisoned;Because double groups Curing agent or diluent must be used when part material construction, worker operation is difficult, and curing time is long;And need primary coat, in It applies, the complicated technologies such as face applies, it is long to survive the period, time-consuming.Therefore, it is necessary to a kind of new coating births.
Summary of the invention
The object of the invention is that providing the single-component water-based inorganic floor coatings of one kind to solve the above-mentioned problems and matching Side and manufacturing technology.
The present invention through the following technical solutions to achieve the above objectives:
The present invention the following steps are included:
(1) in parts by weight, 20 parts of water, 0.1 part of wetting agent, 0.3 part of dispersion are successively added into blender Agent, 0.2 part of defoaming agent, 0.5 part of antifreezing agent, 0.3 part of thickener, 22 parts of silica solution, 5 parts of lithium metasilicate solution, 5 parts of potassium silicate solution, 0.5 part of inorganic dispersant, speed are 300 revs/min, are stirred within mixing time 15 minutes;
(2) 20 parts of pigments and fillers are added, mixing speed is 1300 revs/min, is stirred within mixing time 15 minutes;
(3) 15 parts of silica flours are added, mixing speed is 1300 revs/min, stirs 15 minutes and stirs;
(4) 8 parts of organic silican polymer emulsion is added, 300 revs/min of speed, mixing time is to stir for 15 minutes;
(5) 3 parts of redisperse latex powder is added, 300 revs/min of speed, stirs 10 minutes;
(6) it is added that 5 parts of terraces are green or 3 parts of terrace ashes, 300 revs/min of speed, stirs 10 minutes;
(7) addition 0.5 part of thickener, 0.2 part of defoaming agent, 300 revs/min of speed, after stirring 10 minutes, grinding Inorganic floor coatings.,
Further, the modulus of the lithium metasilicate is 3.6-4.0, and the modulus of the potassium silicate is 2.5-3.0, the silica solution Average grain diameter is 7-10nm, and the silica flour is greater than 120 mesh
Further, the organic silicon emulsion is the silicone acrylic emulsion of model 996KD, and the inorganic dispersant is model The silicate paint dispersing agent of DISPERSOGEN SPS, the wetting agent model BYK -346;The dispersing agent model 324;The defoaming agent model 367;The coalescing agent is dipropylene and dipropylene glycol methyl ether acetate;It is described anti- Jelly agent is ethylene glycol;The thickener is gold group alkali swollen thickener 4280;The redisperse latex powder is the easy Lay in the U.S. Thailand 2350, the pigments and fillers are made of rutile titanium white powder, kaolin powder, talcum powder, mica powder and wollastonite in powder, the step (6) toning is that terrace is green or the grey inorganic mill base of terrace with pigment in.
The beneficial effects of the present invention are:
The present invention is the single-component water-based inorganic floor coatings formula of one kind and manufacturing technology, compared with prior art, this hair It is bright to have the following technical effect that
(1) compatibility that the present invention is had using silicate solutions and cement, concrete are natural, can permeate basal plane and base Face solidification one, makes film adhesive force with super strength, does not fall off, peeling, cracking.
(2) present invention is using the compounding between silicate solutions, and with silica solution blending and modifying so that it is inorganic at film liquid with Occur that demulsification, anti-thick, viscosity obviously rises or even the risk of gel substantially reduces when organic silicon emulsion is blended, make it is final made from Coating is with good stability.
(3) present invention prepares the inorganic floor coatings of one-component using organic silicon emulsion modification, is overcome using inorganic dispersant The shortcomings that poor storage stability.The disadvantage for overcoming traditional inorganic coating easy to crack using redisperse latex powder, while increasing painting The hardness and water resistance of film.
(3) present invention passes through the functional materials such as addition titanium dioxide, kaolin, talcum powder, mica, wollastonite, silica flour, Improve the fire-retardant of film, hardness, rub resistance, scrubbing resistance, impact resistance and chemical corrosion resistance.
(4) by the present invention in that with silicone acrylic emulsion, silicate is modified, forms final coating obtained with good The microcrystalline texture of good water-proof breathable properties, simultaneously because silicon surface enrichment and there is self-cleaning function and wear-resisting property.
(5) by the present invention in that ensure that the feature of environmental protection and weatherability with inorganic pigment terrace ash or the green toning of terrace.
(6) inorganic floor coatings provided by the invention fire-retardant, superpower hardness and adhesive force, rub resistance, scrubbing resistance, resistance toization Corrosivity is learned, VOC content is extremely low, is free of the harmful substances such as formaldehyde, stupid, heavy metal, simple process and low cost.
Specific embodiment
The invention will be further described below:
The present invention the following steps are included:
(1) in parts by weight, 20 parts of water, 0.1 part of wetting agent, 0.3 part of dispersion are successively added into blender Agent, 0.2 part of defoaming agent, 0.5 part of antifreezing agent, 0.3 part of thickener, 22 parts of silica solution, 5 parts of lithium metasilicate solution, 5 parts of potassium silicate solution, 0.5 part of inorganic dispersant, speed are 300 revs/min, are stirred within mixing time 15 minutes;
(2) 20 parts of pigments and fillers are added, mixing speed is 1300 revs/min, is stirred within mixing time 15 minutes;
(3) 15 parts of silica flours are added, mixing speed is 1300 revs/min, stirs 15 minutes and stirs;
(4) 8 parts of organic silican polymer emulsion is added, 300 revs/min of speed, mixing time is to stir for 15 minutes;
(5) 3 parts of redisperse latex powder is added, 300 revs/min of speed, stirs 10 minutes;
(6) it is added that 5 parts of terraces are green or 3 parts of terrace ashes, 300 revs/min of speed, stirs 10 minutes;
(7) addition 0.5 part of thickener, 0.2 part of defoaming agent, 300 revs/min of speed, after stirring 10 minutes, grinding Inorganic floor coatings.,
Further, the modulus of the lithium metasilicate is 3.6-4.0, and the modulus of the potassium silicate is 2.5-3.0, the silica solution Average grain diameter is 7-10nm, and the silica flour is greater than 120 mesh
Further, the organic silicon emulsion is the silicone acrylic emulsion of model 996KD, and the inorganic dispersant is model The silicate paint dispersing agent of DISPERSOGEN SPS, the wetting agent model BYK -346;The dispersing agent model 324;The defoaming agent model 367;The coalescing agent is dipropylene and dipropylene glycol methyl ether acetate;It is described anti- Jelly agent is ethylene glycol;The thickener is gold group alkali swollen thickener 4280;The redisperse latex powder is the easy Lay in the U.S. Thailand 2350, the pigments and fillers are made of rutile titanium white powder, kaolin powder, talcum powder, mica powder and wollastonite in powder, the step (6) toning is that terrace is green or the grey inorganic mill base of terrace with pigment in.
The present invention uses lithium metasilicate, potassium silicate, silica solution, applies with the modified inorganic terrace that one-component is made of organic silicon emulsion Material, overcomes double groups such as conventional epoxy terrace or multiple groups part coating process is complicated, and long at live time, the construction requirement time is long, at This high disadvantage.Silicate and cement, concrete, the substrates such as polymers have natural compatibility, can interpenetrate and combine together, Adhesive force is superpower.Silica flour that the present invention uses increase hard coating, wear-resisting, impact resistance, stable chemical performance performance.This The pigments and fillers used are invented as titanium dioxide, shape cloud powder, wollastonite in powder, kaolin powder, are interacted, film is fine and close after film forming, water Molecule is not easy to permeate.The redisperse latex powder that the present invention uses can increase the hardness and water resistance of film.The face that the present invention uses Material is inorganic pigment, colour-fast without harmful substances such as heavy metals.Aqueous inorganic floor coatings are with its fire protection flame retarding, nontoxic nothing Taste, superpower weatherability and adhesive force, hardness, impact resistance, rub resistance, scrubbing resistance, do not generate electrostatic especially, adapt to various water Mud, concrete, the materials basal plane such as polymers, can be used for the decoration of the various places such as office, family, factory, hospital, school, Use scope is very extensive.Raw material used arise directly from nature, and abundance is cheap.It can also be according to user The difference for selecting glossiness, film is applied over aqueous or oiliness gloss oil.Therefore, inorganic floor coatings have wide market Prospect.
Basic principle of the invention is as follows: silicate is also referred to as waterglass, and the general formula of waterglass molecular formula is M2O .m SiO2. nH2O, M can be 4 kinds of sodium, potassium, lithium and ammonium ions, and m is modulus.(wherein, ammonium waterglass price is too high, sodium water glass Glass it is cheap, but the water resistance of sodium silicate is very poor, and actual demand could be met by generally requiring additional curing agent.) at Film mechanism is that waterglass reacts to form silica sol with the CO2 in air, and with the evaporation of moisture, dehydration forms inorganic silicon oxygen Chain net macromolecular, but since alkali metal is dispersed in film in the form of an ion, when film meets water, film can because alkali metal from Son dissociation and destroy, that is, cause the poor water resistance of film.Common method of modifying has: the acid of waterglass is modified, sets with synthesis Fat liquor compound use, blending and modifying of different types of waterglass etc..The present invention uses organic silicon emulsion and silicic acid salt blend The shortcomings that being modified, overcoming its independent film forming poor water resistance.
Silica solution membrane formation mechanism is that, when silica solution dries out, monomeric silicic acid gradually polymerize, as moisture evaporates, glue Body molecule increases, and can form firm Si-O-Si keyboard between SiO2 particle, then forms silicon oxygen chain reticular structure, becomes company Continuous film.Since salt content soluble in silica solution is low, thus make film that there is preferable water resistance, and silica solution valence Lattice are cheap.But due to the capillary effect of holes, individually use silica solution as film forming matter, be easy to happen coating adhesion is poor, cracking very To be dusting phenomena such as.By the way that a small amount of silicone acrylic emulsion is added by addition silicone acrylic emulsion, organic-inorganic two is effectively raised The compatibility of phase avoids organic matter and is demulsified during storage and instead slightly cause gel, makes organic binder and inorganic filming substance The effective network structure for interting interaction is formed, film-formation result is further mentioned.
Since silicate and silica solution have very strong permeability, can permeate basal plane and cement, concrete curing melt is one Body has superpower adhesive force.
The chemical property such as titanium dioxide, mica powder, kaolin powder, wollastonite in powder, talcum powder stabilization has natural with silicate Compatibility, titanium dioxide improve film covering power, mica powder have good elasticity, toughness, insulating properties, high temperature resistant, acid and alkali-resistance, Characteristics, the kaolin such as corrosion-resistant, adhesive force is strong have very strong associativity, viscosity, suspension, its feature of wollastonite is nontoxic, resistance to Chemical attack, thermal stability and dimensionally stable are good, there is glass and pearly luster, low water absorption and an oil factor, mechanical property and Excellent electrical properties and there is certain reinforcing effect, talcum powder talcum have lubricity, it is anti-stick, help stream, fire resistance, acid-resisting, Insulating properties, fusing point are high, chemically the excellent physics such as torpescence, covering power good, softness, good luster, strong adsorption force, chemistry are special Property, these materials, which mix to be complementary to one another, forms one kind with function such as fire protection flame retarding, hardness height, rub resistance, antiacid alkali The coating of energy.
Silica flour is a kind of hard, wear-resisting, stable chemical performance silicate mineral.For the aggregate element of floor coatings, Further increase the hardness and wearability of film.
Silicone acrylic emulsion is modified silicate, and forming final coating obtained has the micro- of good water-proof breathable properties Crystal structure, simultaneously because silicon surface enrichment and have self-cleaning function and wear-resisting property.
It is iron oxide inorganic pigment that terrace is green or terrace is grey, and property is stablized, non-discolouring.
In conclusion the inorganic floor coatings of novel environment friendly provided by the invention are main with alkali silicate, silica solution It is independent to avoid silicate poor water resistance, silica solution so that total soluble-salt content in inorganic filming substance reduces for film forming matter There is the capillary effect of holes in film forming, so as to improve the water resistance and filming performance of coating, and keeps coating ultimate cost cheap, simultaneously It is modified to lead to too small amount of organic silicon emulsion, further increases the early stage water resistance of coating, the coating finally prepared is made to keep superelevation Hardness, rub resistance, super scrubbing resistance, impact resistance, stain resistant, good gas permeability;Titanium dioxide, mica, kaolin, wollastonite etc. Inorganic powder combines, and advanced optimizes various performances;The addition of inorganic dispersant increases SiO2 aggregate surface space Steric hindrance, can effectively prevent coating in storage or thermal histories it is further condensation and gel, substantially prolong coating Effective storage time;By adding silicone acrylic emulsion, the compatibility of organic-inorganic two-phase is effectively raised, organic matter is avoided and exists Demulsification is anti-during storage slightly causes gel, and organic binder and inorganic filming substance is made to form the network knot of effective interspersed interaction Structure further mentions film-formation result.
Performance of the invention is as follows:
The content (VOC) of total volatile organic compounds is low, is able to satisfy environmental labelling product authentication techniques and requires aqueous painting Expect GB24410-2009 standard, belongs to green product.Since the compatibility of silicate is wide, water can be used above film The further brightening of gloss oil or the beautifications such as property, oiliness.
Basic principles and main features and advantages of the present invention of the invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

1. a kind of single-component water-based inorganic floor coatings production method, which comprises the following steps:
(1) in parts by weight, 20 parts of water, 0.1 part of wetting agent, 0.3 part of dispersing agent, 0.2 are successively added into blender Defoaming agent, 0.5 part of the antifreezing agent, 0.3 part of thickener, 22 parts of silica solution, 5 parts of lithium metasilicate solution, 5 parts of silicic acid of part Potassium solution, 0.5 part of inorganic dispersant, speed are 300 revs/min, are stirred within mixing time 15 minutes;
(2) 20 parts of pigments and fillers are added, mixing speed is 1300 revs/min, is stirred within mixing time 15 minutes;
(3) 15 parts of silica flours are added, mixing speed is 1300 revs/min, stirs 15 minutes and stirs;
(4) 8 parts of organic silican polymer emulsion is added, 300 revs/min of speed, mixing time is to stir for 15 minutes;
(5) 3 parts of redisperse latex powder is added, 300 revs/min of speed, stirs 10 minutes;
(6) it is green that 5 parts of terraces are added, 300 revs/min of speed, stir 10 minutes;
(7) be added 0.5 part of thickener, 0.2 part of defoaming agent, 300 revs/min of speed, stirring 10 minutes, grinding after one-component Aqueous inorganic floor coatings.
2. single-component water-based inorganic floor coatings production method according to claim 1, it is characterised in that: the lithium metasilicate Modulus be 3.6-4.0, the modulus of the potassium silicate is 2.5-3.0, and the silica solution average grain diameter is 7-10nm, the quartz Powder is greater than 120 mesh.
3. single-component water-based inorganic floor coatings production method according to claim 1, it is characterised in that: the organosilicon Polymer emulsion is the silicone acrylic emulsion of model 996KD, and the silicate that the inorganic dispersant is model DISPERSOGEN SPS applies Expect dispersing agent, the wetting agent model BYK-346;The dispersing agent model 324;The defoaming agent model 367;Institute Stating antifreezing agent is ethylene glycol;The redisperse latex powder be U.S. Yi Laitai 2350, the pigments and fillers by rutile titanium white powder, Kaolin powder, talcum powder, mica powder and wollastonite in powder composition.
CN201610148726.9A 2016-03-16 2016-03-16 The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology Active CN105694550B (en)

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ES2741598T3 (en) 2016-09-30 2020-02-11 Daw Se Water treatment mass for walls, ceilings or floors of buildings
CN109651856B (en) * 2017-10-12 2020-11-10 石河子大学 Novel inorganic expansion steel structure fireproof coating and preparation method thereof
CN107779090B (en) * 2017-10-18 2020-05-01 固克节能科技股份有限公司 Inorganic lithium potassium silicate solution composite organic fluorine silicon coating and preparation method thereof
CN108441080A (en) * 2018-04-25 2018-08-24 上海嘉柏丽实业有限公司 A kind of pseudo-classic floor coatings of aqueous inorganic
CN108912755A (en) * 2018-05-29 2018-11-30 佛山市顺德区雅成化工有限公司 A kind of preparation method of aqueous inorganic paint
CN111019415A (en) * 2019-12-23 2020-04-17 广州市维思涂料科技有限公司 Water-based inorganic mineral composite floor coating and preparation method thereof
CN111647329A (en) * 2020-07-14 2020-09-11 上海保立佳新材料有限公司 Single-component waterproof high-hardness water-based floor paint and preparation method thereof

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CN101186776A (en) * 2006-11-16 2008-05-28 上海德锐环保材料科技有限公司 Terrace water borne coating
KR101083133B1 (en) * 2009-05-18 2011-11-11 이재환 Complex aerogel coating composition
CN102408220B (en) * 2011-08-08 2013-05-15 华南理工大学 All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof
CN103497545A (en) * 2013-10-10 2014-01-08 苏州弗克新型建材有限公司 Inorganic coating, and preparation method and application thereof
CN104387816A (en) * 2014-11-28 2015-03-04 佛山市南海万磊建筑涂料有限公司 Multifunctional inorganic diatom ooze coating and preparation method thereof
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Effective date of registration: 20201210

Address after: No.2828 Shuzhou Road, Zhengxing street, Tianfu New District, Chengdu 610000 China (Sichuan) pilot Free Trade Zone, Chengdu

Patentee after: Sichuan hongdarui Coating Technology Co.,Ltd.

Address before: No. 158-10, Jiefang street, Guhuai Town, Pingyu County, Zhumadian City, Henan Province

Patentee before: Chen Wei